ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE 2013

TIME: 1HR

TW TEST
TOPIC: ATOMIC STRUCTURE

MARKS: 69
DATE: 28/06/13

SECTION-I
This section contains 12 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONLY ONE is correct.
(+3, - 1)
1.

With increasing quantum number, the energy difference between adjacent orbits of hydrogen atom
(A) increases
(B) decreases
(C) remains constant
(D) first increases followed by a decrease

2.

A photon of 300 nm is absorbed by a gas and then emits two photons. One photon has a wavelength
496 nm then the wavelength of second photon is
(A) 757
(B) 857
(C) 957
(D) 657

3.

According to Bohr's Model of hydrogen atom

(A) total energy of the electron is quantized
(B) angular momentum of the electron is quantized and given as

l (l 1)

h
2

(C) both (A) and (B)

(D) none of these
4.

Correct order of radius of the 1 st orbit of H, He+, Li2+, Be3+ is

(A) H > He+ > Li2+ > Be3+
(B) Be3+ > Li2+ > He+ > H
+
3+
2+
(C) He > Be > Li > H
(D) He+ > H > Li2+ > Be3+

5.

Photoelectric emission is observed from a surface for frequencies 1 and 2 of incident radiations (1
> 2). If the maximum kinetic energy of photoelectrons in the two cases are in the ratio of 2 : 1, then
threshold frequency v0 is given by
1
21 2
2 2 1
1
(A) 2
(B)
(C)
(D) 2
2 1
2 1
2 1
2

6.

The ratio of (E2 E1) to (E4 E3) for the hydrogen atom is approximately equal to
(A) 11
(B)12
(C)15
(D)10

7.

If the K.E. of a particle is doubled, its de Broglie wavelength becomes

(A) 2 times

(B) 4 times

(C) 2 times

(D)

1
times
2

8.

An element with atomic number 20 will be placed in the period of the periodic table
(A) 5
(B) 4
(C) 3
(D) 2

9.

If electrons are excited to 4th shell in He+ ion, the number of wavelengths emitted by electrons during
deexcitation are
(A) 4
(B) 5
(C) 6
(D) 7

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

10.

Which one of the following set of quantum numbers is not permitted?

1
1
(A) n = 3, l = 3, m = 0, s = +
(B) n = 3, l = 2, m = + 2, s =
2
2
1
1
(C) n = 3, l = 1, m = 1, s =
(D) n = 3, l = 0, m = 0, s = + .
2
2

11.

Radial part of the wave function depends on quantum numbers

(A) n and s
(B) l and m
(C) l and s

12.

(D) n and l

If the shortest wavelength of H atom in Lyman series is x, the longest wavelength in the Balmer
series of He+ would be
36x
x
5x
9x
(A)
(B)
(C)
(D)
4
9
5
4

SECTION-II
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct.
(+4, 1)
13.

Choose the correct statements.

(A) Higher the energy difference between two levels, lower is the wavelength of light emitted when
an electron jumps from one level to the other.
(B) -rays are electromagnetic radiations of wavelength ranging from 106 m to 105 cm.
(C) The electron density in the xy-plane in 3d 2 2 orbital is not zero.
x y

(D) When sodium metal is dissolved in liquid NH3, blue solution is formed.
14.

Which of the following is the nodal plane of d xy orbital?

(A) XY
(B) YZ
(C) ZX

(D) All

15.

Which of the following statement(s) is/are correct?

(A) Electrons in motion behave as they are waves
(B) s- orbital is non-directional
(C) An orbital can accommodate a maximum of two electrons with parallel spins
(D) The energies of various sub-levels in the same shell are in order s>p>d>f

16.

A sample of hydrogen like atoms in ground state absorbs n photons having the same energy and it
emits exactly n photons when electronic transition takes place. Then, the energy of the absorbed
photon may be
(A) 91.8 eV
(B) 40.8 ev
(C) 48.4 eV
(D) 54.4 eV

17.

Which of following is/are correct?

(A) Total energy of electron in hydrogen and hydrogen like species equal to twice of its potential
energy.
(B) The energy of an electron depends only upon the principal quantum number not on the other
quantum numbers.
(C) The energy of an electron depends only upon principal quantum number, in case of hydrogen and
hydrogen like species.
(D) The difference in potential energies of any energy level is always more than difference in K.E. of
these two levels.

18.

The electronic configuration of an element is 1s2, 2s22p6, 3s23p63d5,4s1. This represents its

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA

(A) excited state

(B) ground state

(C) cationic form

SECTION-III

(Paragraph Type)

(D) anionic form

This section contains 3 groups of questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which ONLY ONE is correct.
(+3, -1)

Paragraph for Question Nos. 19 to 21

For hydrogen atom or 1-electron ions, the wave functions of 1s and 2s atomic orbitals are given as under:

The wave functions for any 1-electron system is given by = k ekr where k and k are constants.
19.

What is the ratio of finding the electron at the nucleus to the probability of finding the electron at a0
(A) e
(B) e2
(C) 1/e2
(D) Zero

20.

Which of the following is the correct representation of plot radial probability (4r2R2) in Y-axis vs
distance from the nucleus in X-axis for 1-elelectron of 4d-atomic orbital?
Y

(A)

(B)

2 2

4 r R

(C)

(D)

2 2

4 r R

21.

2 2

4 r R

2 2

4 r R

The distance from the nucleus of the radial node of 2s-electron of Li2+ ion is
(A) 0.67a0
(B) 2a0
(C) a0
(D) 0.5a0

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA