Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name
Supplier

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp.

383 Madison Avenue, 10th Floor

New York, NY 10017

Synonyms
Chemical Family
Intended Use
24 Hour
Emergency
Numbers

MEG, Ethylene Glycol, 1,2-Ethanediol, 1,2-Dihydroxyethane, EG, Glycol, Ethylene

Glycol Polyester Grade, High Purity Grade, Industrial Grade and Antifreeze Grade
Ethylene Glycol
Multiple Uses Including Chemical Feedstock, Chemical Intermediate, Chemical
Component, Chemical Constituent
Chemtrec: 800-424-9300
J.P. Morgan Technical Information: 212-834-5788
California Poison Control: 800-222-1222

2. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous
Components
Name/CAS No.

Ethylene Glycol
107-21-1
Diethylene Glycol
111-46-5

Concentration
(%)

ACGIH
Exposure Limits

95 - > 99.9

100 mg/m Ceiling

Aerosol

OSHA
Exposure Limits

NIOSH
Exposure Limits

50 ppm Ceiling

50 ppm Ceiling

< 0.5 - 5

Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or
similar professional for further information.
ACGIH - American Conference of Government Industrial Hygienists, OSHA - Occupational Safety and Health Administration, NIOSH National Institute for Industrial Safety and Health, TWA - Time Weighted Average (8 hour average for ACGIH and OSHA, 10 hour
average for NIOSH), STEL - 15 Minute Short Term Exposure Level, Skin - indicates potential for cutaneous absorption, Ceiling Ceiling Level, Peak - Acceptable peak over the ceiling concentration for a specified number of minutes, IDLH - Immediately Dangerous
to Life and Health

3. HAZARDS IDENTIFICATION
Emergency
Overview

This product is a clear, colorless liquid with a slightly sweet odor. It is slightly
combustible. It is harmful or fatal if swallowed. Swallowing this material will result
in serious health hazard, potentially leading to collapse and death. Ingestion may
result in irritation of the mouth and digestive tract. May be irritating to the eyes, skin
and respiratory system.

Potential Acute Health Effects

Inhalation

High aerosol concentrations may cause respiratory irritation.

Eye Contact
Skin Contact

May include mild eye irritation with tearing, pain or blurred vision.
May be mildly irritating to the skin. Not a sensitizer. Not expected to be a skin
absorption hazard.
Ingestion may include inebriation, nausea and vomiting, metabolic acidosis and
CNS depression. Cardiopulmonary effects include tachycardia, hypertension,
severe metabolic acidosis with hyperventilation, hypoxia, congestive heart failure
and adult respiratory distress syndrome as well as renal failure. May also produce a
local irritation effect on the digestive system and cause pain and bleeding.

Ingestion

Potential Chronic Health Effects

Signs and
Repeated or prolonged exposure may result in kidney damage. May produce
Symptoms
symptoms of central nervous system depression including headache, dizziness,

nausea, euphoria, loss of equilibrium, drowsiness, visual disturbances, fatigue,

unconsciousness and respiratory arrest.

Page 1 of 8

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

3. HAZARDS IDENTIFICATION
Carcinogenic
Potential
Target Organs
Conditions
Aggravated by
Overexposure

None of the components present in this material in concentrations above 0.1% are
listed as known human carcinogens by OSHA, IARC and NTP.
May cause damage to the kidneys or liver.
Individuals with lung disorders like asthma, kidney or liver disease may have
increased susceptibility to exposure. Skin contact may aggravate an existing
dermatitis. May cause central nervous system depression.

4. FIRST AID MEASURES

Inhalation

Eye

Skin

Ingestion
Notes to
Physician

Move the exposed person to fresh air. If not breathing, clear airways and give artificial
respiration. If breathing is difficult, humidified oxygen should be administered by
qualified personnel. Seek medical attention if breathing difficulties continue.
Flush eyes with water for at least 15 minutes. Hold eyelids apart to ensure complete
irrigation of the eye. Remove contact lenses, if worn, after initial flushing. Do not use
eye ointment. Seek medical attention.
Remove contaminated shoes and clothing, and flush affected areas with large amounts
of water. If skin surface is damaged, apply a clean dressing and seek medical attention.
If skin surface is not damaged, clean affected area thoroughly with mild soap and water.
Seek medical attention if tissue appears damaged or if pain or irritation persists.
Launder or discard contaminated clothing.
Immediately give two glasses of water and induce vomiting. Never give anything by
mouth to an unconscious person.. Seek medical attention.
The principal effects produced by ethylene glycols, especially by acute overexposure
from swallowing the liquid, are kidney injury and metabolic acidosis. Ethanol is antidotal
and should be administered early in the treatment. Ethanol decreases the metabolism
of ethylene glycol to toxic metabolites. Ethanol should be administered as soon as
possible in the case of severe poisoning since the elimination half-life of ethylene glycol
is 3 hours. The patient should be monitored for metabolic acidosis. Use of appropriate
buffering solutions such as bicarbonate may be indicated. Hemodialysis may be
indicated for more complete elimination.

5. FIRE FIGHTING MEASURES

Flammability
Classification
Flash Point
Flammable
Limits
Autoignition
Temperature
Combustion
Products
Fire and
Explosion
Hazards
Extinguishing
Media

Page 2 of 8

OSHA Classification (29 CFR 1910.1200): Combustible Liquid

NFPA Class-1IIA Combustible Liquid
NFPA Ratings: Health: 1, Flammability: 1, Reactivity: 0
o
o
116 C, 240 F Closed Cup (Tagliabue (ASTM D-56))
Lower Limit: 3.2%
Upper Limit: 15.3%
o

398 C, 748 F

Highly dependent on combustion conditions. May form carbon monoxide and carbon
dioxide.
This material has a slight to moderate exposure hazard when exposed to heat and
flame. Above the flash point, vapor-air mixtures are explosive within the flammable
limits. A product container, if not properly cooled, can rupture in the heat of a fire.
Dry chemical, carbon dioxide, water spray or alcohol resistant foam is recommended.
Water spray is recommended to cool or protect exposed materials or structures.
Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in
confined spaces. Water may be ineffective for extinguishment, unless used under
favorable conditions by experienced fire fighters. Water or foam may cause violent
frothing.

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

5. FIRE FIGHTING MEASURES

Fire Fighting
Instructions

Use water spray to cool fire-exposed containers and to protect personnel. Isolate
immediate hazard area and keep unauthorized personnel out. Water spray may be
useful in minimizing or dispersing vapors and to protect personnel. Cool equipment
exposed to fire with water. Avoid spreading burning liquid with water used for cooling.
For fires beyond the incipient stage, emergency responders in the immediate hazard
area should wear bunker gear. When the potential chemical hazard is unknown, in
enclosed or confined spaces, or when explicitly required by regulations, a self-contained
breathing apparatus should be worn. Wear other appropriate protective equipment as
conditions warrant.

6. ACCIDENTAL RELEASE MEASURES

Protective
Measures

Spill
Management

Reporting

Keep all sources of ignition and hot metal surfaces away from spill/release. The use of
explosion-proof electrical equipment is recommended. Stay upwind and away from
spill/release. Isolate immediate hazard area and keep unauthorized personnel out.
Wear appropriate protective equipment as conditions warrant per Exposure
Controls/Personal Protection guidelines.
Stop the leak if it can be done without risk. Prevent spilled material from entering
waterways, sewers, basements or confined areas. Contain release to prevent further
contamination of soils, surface water or groundwater. Clean up spill as soon as
possible using appropriate techniques such as applying non-combustible absorbent
materials or pumping. All equipment used when handling the product must be
grounded. A vapor suppressing foam may be used to reduce vapors. Use clean nonsparking tools to collect absorbed material. Where feasible and appropriate, remove
contaminated soil. Dispose of contaminated materials in a manner consistent with
applicable regulations.
Report spills/releases as required, to appropriate local, state and federal authorities. US
Coast Guard and Environmental Protection Agency regulations require immediate
reporting of spills/release that could reach any waterway including intermittent dry
creeks. Report spill/release to the National Response Center at (800) 424-8802. In
case of accident or road spill, notify Chemtrec at (800) 424-9300.

7. HANDLING AND STORAGE

Handling

Storage
Special
Precautions
Portable
Containers
Empty
Container
Warning

Page 3 of 8

Avoid open heating or agitation that may generate vapors or mists. Bond and ground all
equipment when transferring from one vessel to another. Use non-sparking tools and
explosion-proof equipment.
Use and store this material in cool, dry, well-ventilated areas away from sources of
ignition. Keep away from incompatible material.
Electrical equipment and fittings should comply with local fire codes.
Use only approved containers. Keep containers tightly closed.
Empty containers retain liquid and vapor residues and can be dangerous. Do NOT
pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat, flame,
sparks, static electricity or other sources of ignition; they may explode and cause injury
or death. Do not attempt to refill or clean containers since residue is difficult to remove.
Empty drums should be completely drained, properly closed and returned to the supplier
or a qualified drum reconditioner. All containers should be disposed of in an
environmentally safe manner in accordance with government regulations.

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

8. EXPOSURE CONTROL / PERSONAL PROTECTION

General
Considerations
Engineering
Controls
Personal
Protective
Equipment
Respiratory
Protection

Eye
Protection
Skin and
Body
Protection
Hand
Protection

Consider the potential hazards of this material, applicable exposure limits, job activities
and other substances in the work place when designing engineering controls and
selecting personal protective equipment.
Use process enclosures, local exhaust ventilation or other engineering controls to
maintain airborne levels below the recommended exposure limits. An emergency eye
wash station and safety shower should be located near the work station.
If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, personal protective equipment (PPE) is recommended. A
hazard assessment of the work should be conducted by a qualified professional to
determine what PPE is required.
When airborne concentrations are expected to exceed the established exposure limits
given in Section 2, use a NIOSH approved organic vapor respirator. Use a full-face
positive-pressure supplied air respirator in circumstances where air-purifying respirators
may not provide adequate protection. If internal combustion devices are used in an
enclosed space, carbon monoxide will be present in the exhaust. If the airborne
concentrations are above the occupational exposure limit for carbon monoxide, use a
positive pressure air-supplying respirator.
Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Chemical goggles should be worn during transfer operations or
when there is a likelihood of misting, splashing or spraying of this material.
Avoid skin contact. Wear long-sleeved fire-retardant garments while working with
flammable and combustible liquids. Additional chemical-resistant protective gear may
be required if splashing or spraying conditions exist. This may include an apron, arm
covers, impervious gloves, boots and additional facial protection.
Avoid skin contact. Use impervious gloves (e.g., PVC, neoprene, nitrile rubber). Wash
hands with plenty of mild soap and water before eating, drinking, smoking, using toilet
facilities or leaving work.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Odor
pH
Vapor Density
Percent Volatile
Specific Gravity
Molecular Weight
Flash Point
Explosive Limits

Clear, colorless
Slightly sweet
Neutral
> 2 (air = 1)
100%
o
1.15 @ 60 F
62
o
o
240 F/116 C
3.2% LEL, 15.3% UEL

Solubility in Water

Essentially 100%

Physical Form
Odor Threshold
Vapor Pressure
Boiling Point/Range
Partition Coefficient
Density
Evaporation Rate
Test Method
Autoignition
Temperature

Liquid
Not established
o
o
<0.1 psi 100 F, 38 C
o
o
388 F/1989 C
<3
o
9.3 lb/gal @ 60 F
Not established
ASTM 56
o

748 F/398 C

10. STABILITY AND REACTIVITY

Stability
Conditions to
Avoid
Incompatibility
(Materials to
Avoid)
Hazardous
Decomposition
Products

Page 4 of 8

Stable under normal anticipated storage and handling temperatures and pressures.
Avoid all possible sources of ignition.
Avoid contact with strong oxidizing agents such as strong acids, alkalies, chlorine and
other halogens, dichromates or permanganates, which can cause fire or explosion.
Carbon monoxide and carbon dioxide.

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

10. STABILITY AND REACTIVITY

Hazardous
Polymerization

Will not occur

11. TOXICOLOGICAL INFORMATION

Ethylene Glycol 107-21-1
Acute Toxicity:
Dermal LD50 = 9530 mg/kg (Rabbit)
Oral LD50 = 4700 - 13,400 mg/kg (Rat)
Carcinogenicity: Ethylene glycol was not carcinogenic in two-year studies in rats and mice. This
material is not classified as a carcinogen. Not listed by IARC, NTP or OSHA.
Target Organs: If exposures are sufficiently high to cause accumulation of calcium oxalate crystals,
kidney pathology may occur. In rats, crystal nephropathy has been seen after dietary administration of
500 mg/kg bwt/day for 16 weeks, whereas no effects were seen in rats that ingested 200 mg/kg
3
bwt/day for 2 years or in several animal species that inhaled 12 mg/m for 3 months. Human
exposures at occupational relevant concentrations are unlikely to cause crystal nephropathy.
Developmental: Doses of ethylene glycol that result in high levels of the metabolite glycolic acid
induce developmental/teratogenic effects in rats and mice, although at doses greater than those
associated with kidney effects in rats. Human exposure is not expected to generate sufficient levels of
glycolic acid; therefore, no developmental effects are expected in humans.
Mutagenicity: Negative for genotoxicity both in vitro and in vivo tests.
Diethylene Glycol 111-46-6
Acute Data:
Dermal LD50 = 11,900 mg/kg (Rabbit)
Oral LD50 = 13,300 mg/kg (Mouse); 25,300 mg/kg (Rat)
Carcinogenicity: No evidence of carcinogenicity was found with a chronic skin painting study in mice.
No carcinogenic or tumor promoting effects in rats exposed up to 2.5% solutions in drinking water for
108 weeks. Older feed studies utilizing limited number of tissues but very high doses also provide no
evidence of carcinogenicity. Not listed by IARC, NTP or OSHA.
Target Organs: Diethylene glycol given to rats in the diet for two years caused bladder stones, tumors
and kidney and liver damage. These effects were probably due to contamination with ethylene glycol
and the bladder stones were formed from oxalate crystals.
Developmental: Reproductive and developmental effects have been noted in animals following very
large (>3000 mg/kg bwt/day) oral doses. However, comparable internal dose levels are not possible with
dermal or inhalation exposures under normal conditions of use. Therefore, diethylene glycol is not
considered a reproductive or developmental hazard except during very large oral doses.
12. ECOLOGICAL INFORMATION
Ecotoxicity

Environmental
Fate

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96 hours LC50: 22,810 mg/l (Rainbow trout)

96 hours LC50: 49,000 mg/l (Fathead minnow)
48 hours EC50: 41,000 mg/l (Daphnia magna)
48 hours EC50: 10,000 mg/l (Daphnia)
This material is not expected to be toxic to aquatic organisms.
Ethylene glycol is water soluble. It is mobile in soil, not likely to adsorb to sediment or
suspended particulate matter. It is not likely to volatize from surface waters or soils. It
has an environmental half-life of 0.35 to 24 days in soil, air, surface and ground water.
Undergoes photooxidation with hydroxyl radicals in air with a half-life of 8.3 to 83 hours.
Reported biodegradation studies show ethylene glycol with 97% biodegradation after
20 days and 96% biodegradation after 28 days. Biodegradable under aerobic
conditions. This material is not expected to bioaccumulate.

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

13. DISPOSAL CONSIDERATIONS

This material, if discarded as produced, is not a RCRA "listed" hazardous waste. However, it should be
fully characterized for ignitability (D001) prior to disposal (40 CFR 261). Use which results in chemical or
physical change or contamination may subject it to regulation as a hazardous waste. Along with properly
characterizing all waste materials, consult state and local regulations regarding the proper disposal of this
material.
Container contents should be completely used and containers should be emptied prior to discard.
Container rinsate could be considered a RCRA hazardous waste and must be disposed of with care
and in full compliance with federal, state and local regulations. Larger empty containers, such as drums,
should be returned to the distributor or to a qualified drum reconditioner. To assure proper disposal of
smaller empty containers, consult with state and local regulations and disposal authorities.
14. TRANSPORTATION INFORMATION
United States Department
of Transportation
(US DOT)
Transportation of
Dangerous Goods (TDG)
Canada

International Maritime
Organization
International Maritime
Dangerous Goods Code
(IMO/IMDG)

European Agreements
Concerning the
International Carriage by
Rail (RID) and by Road
(ADR)
International Civil Aviation
Organization /
International Air
Transport Association
(ICAO/IATA)

Shipping Description: Environmentally hazardous substance, liquid, n.o.s.

(Ethylene Glycol), 9, UN3082, III
Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
(Ethylene Glycol)
Hazard Class and Division: 9
ID Number: UN3082
Packing Group: PGIII
Label: Class 9
Placard: Class 9
Reportable Quantity: 5000 lb
Emergency Response Guide: 171
MARPOL III Status: Not a DOT Marine Pollutant per 49 CFR 171.8
Shipping Description: UN3082, Environmentally hazardous substance,
liquid, n.o.s. (Ethylene Glycol), 9, III
Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
(Ethylene Glycol)
Hazard Class and Division: 9
UN Number: 3082
Label: Class 9
Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
(Ethylene Glycol)
Hazard Class: 9
Packing Group: III
Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
(Ethylene Glycol)
UN/ID Number: UN3082
Hazard Class/Division: 9
Packing Group: III

15. REGULATORY INFORMATION

United States Federal Regulatory Information
EPA TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act

(TSCA) Inventory

Page 6 of 8

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

15. REGULATORY INFORMATION

EPA SARA 302/304
Emergency Planning
and Notification
EPA SARA 311/312
(Title III Hazard
Categories)

EPA SARA Toxic

Chemical Notification
and Release
Reporting (40 CFR
372) and CERCLA
Reportable Quantities
(40 CFR 302.4)
EPA CWA and OPA

This material contains the following chemicals subject to reporting under the
Superfund Amendments and Reauthorization Act of 1986 (SARA): Product is
not listed as an extremely hazardous substance
Acute Health: Yes
Chronic Health: Yes
Fire Hazard: No
Pressure Hazard: No
Reactive Hazard: No
Component
CAS Number
Concentration
RQ
Ethylene Glycol
107-21-1
> 95 %
5000 lb
The reportable quantity for this material is 5000 lb.

This product is not classified as an oil under Section 311 of the Clean Water
Act (CWA) and Oil Pollution Act of 1990 (OPA).

Canadian Regulatory Information

This product and/or its constituents are listed either on the Domestic
DSL/NDSL Inventory

Substances List (DSL) or the Non Domestic Substances List (NDSL).

Workplace Hazardous
D2B - Materials Causing Other Toxic Effects - Toxic Material
Materials Information
System (WHMIS)
Hazard Class
European Union Regulatory Information
Labeling
Product is dangerous as defined by the European Union Dangerous

Substances / Preparations Directives

Xn Harmful
R22
Harmful if swallowed.
S2
Keep out of the reach of children.

Symbol
Risk Phrases
Safety Phrases
California Proposition 65

This product does not contain a chemical known to the State of California to cause cancer, birth defects, or
other reproductive harm.
Carcinogen Identification by International Agency for Research on Cancer
Carcinogenic to
Group 1
Group 2A
Group 2B
Group 3

Humans
Probably Carcinogenic
to Humans
Possibly Carcinogenic
to Humans
Not Classifiable

16. OTHER INFORMATION

Prepared By

J.P. Morgan Ventures Energy Corp.

383 Madison Avenue, 10th Floor

New York, NY 10017

Precautionary
Label

DANGER!
This product is harmful or fatal if swallowed. Swallowing this material will result in
serious health hazard, potentially leading to collapse and death. Ingestion may result

Page 7 of 8

Issue Date: November 1, 2006

Material Safety Data Sheet

Monoethylene Glycol

J.P. Morgan Ventures Energy Corp

16. OTHER INFORMATION

in irritation of the mouth and digestive tract. May cause liver and kidney damage.
May be irritating to the eyes, skin and respiratory system.
In case of contact, wash skin with soap and water. Immediately remove contaminated
clothing, including shoes. Destroy or wash clothing before reuse. If swallowed, give 2
glasses of water and induce vomiting. Seek medical attention.
The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the
date this Material Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY,
FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE
IMPLIED REGARDING THE ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED
ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT,
THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No responsibility is assumed
for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices.
The information provided above, and the product, are furnished on the condition that the person receiving them
shall make their own determination as to the suitability of the product for their particular purpose and on the
condition that they assume the risk of their use. In addition, no authorization is given nor implied to practice any
patented invention without a license.

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Issue Date: November 1, 2006