EEE 5356, Integrated Circuit Technology

University of South Florida

Fall 2014.

CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH AND

SAFETY RISK ASSESSMENT FORM(1,2)

Date:

10/27/2014

Laboratory:

ENB 111

Course title:

ICT-Lab

Section
number

S1

Materials information
Explanation of Practice

University/ Location / Lab number

Check the MSDS and see of any of these materials are:

Check of any of these materials are

hazardous to health:

(Use of the material as solvent/solute/solution?)

67-56-1

1314-56-3

Methyl Alcohol

CASN
(if available)

Amount

Metals, Acids and oxidizing agents.

have to make contact with?

Note the lowest flash point

PROCESS INFORMATION
Brief description of process and controls in place minimise risk

If suitable, main experimental work should

only be performed by these Engineers/
Scientist/ Staff

Engineer with sufficient experience or a scientist or a well-trained professional.

METHODS OF PREVENTIONS/ ENGINEERING CONTROLS AND MEASURES

Prepared by: Hemanth Kumar Chaturvedula

Carcinogen (C)/
Mutagen (M)/
Teratogens (T)

If ingested

Toxic
(T)

If inhaled

Very
Toxic (T+)

Amount
(mg, g, ml, etc)

Hazardous for
Environment
(N)
Irritant
(Xi)

Oxidising
(O)

64-17-5

Chemical Reactions: Any chemical or material (s) should not

Harmful
(Xn)
Corrosive (C)

Explosive
(E)

Ethyl Alcohol

Materials produced and waste

Highly
Flammable
(F)

Ethyl Acetate

CASN
(if available)
141-78-6

Phosphorus Pentoxide

Extremely
Flammable
(F+)

Material(s) used

If in contact with
eyes

USF/ENB/ 111

as a solution

If in contact with
skin

PHOSPHOROSILICAFILM 5 x 1020

131o F
(open
cup)

EEE 5356, Integrated Circuit Technology

University of South Florida

Fall 2014.

Any less hazardous materials or processes

If yes, why cannot being

replaced?
If yes, provide information

be used?
Any of these materials have Workplace

Other: (e.g. Competent

Individuals(I)l/ Back up
person) (B)

Guests (V) / Suppliers

(S) /Cleaners (C)

Pregnant women (PW)

Minors

Engineers /
Researchers(S/R)

Safe Access control:

Employees /Staff

Protective clothing

Engineering measures required to prevent and control risks

Gloves

Respirator

200 ppm

Approved Personal
Protective Equipment
Goggles / Facemask

Methyl Alcohol

Full enclosure/ Glove

Box (GB)

Fume Cupboard (FC)

1000 ppm (skin)

Local Exhaust
Ventilation (LEV)

Short Term Exposure

Limit (mins?)

Ethyl Alcohol

Extra precautions (e.g. Specify types of eye

protection, laboratory coats, gloves, etc)

Engineering Controls

Open Bench (OB)

Ethyl Acetate

below
Threshold Limit Value, or
Permissible Exposure
Limits (PPM)
400 ppm (skin)

Other:

Exposure Limits?
Material(s)

Use clean safety glasses with protection and laboratory coat. Use appropriate NIOSH-approved respirator for organic vapor if exposure is likely to exceed
acceptable limits.

EMERGENCY PROCEDURES AND PRECAUTIONS

First Aid: Action to be taken if any substance(s) are:

Note the necessary procedures to prevent and control accidental leakage, release or spillage

Ingested/Swallowed: Can

cause depression of central nervous system. Nausea,

vomiting, diarrhoea.
In contact with Skin:

In contact with Eyes:

May cause irritation and defatting of skin on prolonged contact

Liquid or vapor may cause irritation

Safety glasses should be worn if there is any danger of splashing. Persons with sensitive skin should wear
gloves and protective clothing.

Note the necessary actions to be taken in the incident of a fire caused by these materials(s)?
(e.g. fighter fighters should wear SCBA, use water fog, alcohol free resistance foam, dry powder, CO2
extinguisher, or other fire precautions)

Dry chemical, Carbon Dioxide, or Alcohol "foam". Water may be ineffective, but should be used to keep fireexposed containers and surfaces cool. If a leak or spill has not ignited, use water spray to disperse vapours
and to protect men attempting to stop leak. Water spray may be used to flush spills away from exposure and
to dilute spills to non-flammable mixtures (NFPA-49 1975).
Fire-fighter should wear self-contained breathing apparatus in the positive mode with full face piece when
there is a possibility of exposure to smoke, fumes or hazardous decomposition products
Handling and storage requirements: Note any special requirements e.g. ventilation, chemical

incompatibility, flash point, etc.

At least 10 air changes per hour for good general room ventilation
Note the Disposal procedure/ treatment of these materials (or not disposed of)?
(e.g (non)halogenated waste, acid waste, photoresist waste, etc)
Observe all federal, state and local laws regarding hazardous waste removal and recycling.
Inhaled:

Exposure to more than above listed threshold limit may cause headache,

Prepared by: Hemanth Kumar Chaturvedula

EEE 5356, Integrated Circuit Technology

University of South Florida

Fall 2014.

Reference of MSDS Information

(e.g. Merck Chemicals. Sigma

drowsiness and lassitude, loss of appetite, throat irritation and inability to

concentrate.
Is heath examination necessary?

Is training necessary for this practice?

Aldrich, etc)

Authorization

EMULSITONE COMPANY
http://www.emulsitone.com/psif5x10_20msds.htm

REASSESSMENT (Yearly)
(e.g. If significant change occurs, change of Lab, pregnancy,
etc)

Assessment
completed By:

Name: Hemanth Kumar Chaturvedula

Signature:

Date:10/26/2014

TA(s):

Name:

Signature:

Date:

Departmental
Professor:

Name:

Signature:

Date:

(1) United States Occupational Safety and Health Administration

(2) COSHH risk assessments form, UK Health and Safety Executive

Prepared by: Hemanth Kumar Chaturvedula

Date for reassessment

Reassess date

reassessed by