SULIT

4541/1
Chemistry
Julai
2013
1jam

4541/1

UJIAN PENILAIAN 2
TINGKATAN 5
______________________________________________

KIMIA
Kertas 1
Satu jam

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU

1.
2.
3.
4.

Kertas soalan ini 1 bahagian soalan.

Jawab semua soalan
Bagi setiap soalan, jawab pada ruangan yang disediakan
Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh
diprogramkan.

Prepared by,

Checked by,

........................................
(NAZREEN BT NASHRUDDIN)

.........................................
(PN. ROBEATON ADON)

Answer all question

Section A :Choose the correct answer in the space provided
1. Which of the following is an organic compound?
A. Carbon dioxide
B. Ethanol
C. Calcium carbonate
D. Potassium cyanide
2. A hydrocarbon is an organic compound consisting of
A. Carbon and hydrogen
B. Carbon and oxygen only
C. Carbon, hydrogen and oxygen only
D. Carbon, hydrogen, oxygen and nitrogen only
3. Which of the following statements is not true about hydrocarbons
A. Contains only the carbon and hydrogen
B. Obtained from the fractional distillation of petroleum
C. Produces carbon dioxide and water when burned
D. All exist as gas because of low boiling point
4. The following information shows four different types of hydrocarbon

I.
II.
III.

Methane

Propane

Ethane

Butane

All the compounds exist as gases at room temperature

The melting point increases from methane to butane
The number of molecules per one mole of compound increases from methane to
butane
IV.
Each subsequent member differs by CH2
A. II and IV only
B. I, II and III only
C. I, II and IV only
D. II, III and IV only

5. The reaction between compound X and bromine gas to produce 2-bromo-2methylpropane is shown in the equation below
H
X + Br2

Br H

H C C C H + HBr

H CH3 H
Which of the following is the molecular formula of compound X?
A. CH3CH2CH3
B. CH3CHCH2
C. CH3C(CH3)CH2
D. CH3CH(CH3)CH3
6. Methane reacts with chlorine gas as shown in the following equation :
CH4 + Cl2
CH3Cl + HCl
In this reaction, methane undergoes
A. Oxidation
B. Reduction
C. Substitution
D. Addition
7. In the homologous series alkane, the number of carbon atoms increases down the group.
Which of the following is true about the properties of the members of this series at room
conditions?
I.
More reactive
II.
Molecular mass increases
III.
Melting and boiling point increases
IV.
Density increases
A.
B.
C.
D.

I, II and III only

I, II and IV only
II, III and IV only
I, II, III and IV

8. Which of the following equations represents complete combustion of ethane?

A. C2H6 + 3 O2
2C + 3H2O
2
B. 2C2H6 + 7O2
4CO2 + 6H2O
C. 2C2H6 + 5O2
4CO2 + 6H2O
D. C2H6 + 3O2
CO + CO2 + 3H2O

9. Which of the following comparisons on alkanes and alkenes is not true?

Alkanes
A Insoluble in water
B Do not decolourize brown
coloured bromine water
C

React with chlorine by

substitution
D Have a general formula
CnH2n+2

Alkenes
Soluble in water
Decolourize brown
coloured bromine
water
React with chlorine
by addition
Have a general
formula CnH2n

10. What type of reaction occurs when the product from the dehydration of ethanol, reacts
with hydrogen in the presence of a catalyst?
A. Addition
B. Oxidation
C. Polymerisation
D. Substitution
11. What is the IUPAC name for the hydrocarbon with the structural formula as shown
below?
H

HCC=CCH
H
H
HCH
H
A.
B.
C.
D.

2,3-dimethylpentane
2-methylbut-2-ene
3-methyl-but-2-ene
2-methylpent-2-ene

12. Which of the following are isomers?

I.
2-methylpentane
II.
3-methylpentane
III.
2,2-dimethylbutane
IV.
2,3-dimethylbutane
A.
B.
C.
D.

I and II only
I and III only
I, II and III only
I, II, III and IV

13. Diagram 1 below shows the stuctural formula of pentene

H H

H H

HC=CCCCH
H

Diagram 1
How many isomers can pentene have?
A. 4
B. 5
C. 6
D. 7
14. Isomers are
A. Compound with the same molecular formula and the same structural formula
B. Compound with the same molecular formula but different structural formula
C. Compound with the same structural formula but different molecular formula
D. Compound with the different structural formula and different molecular formula
15. Diagram 2 shows the apparatus set up to prepare a carbon compound

The carbon compound that is produced

A. Burns with a sooty flame
B. Does not dissolve in water
C. Has a double bond in its structural formula
D. Decolourises acidified potassium manganate(VII) solution
16. What is the functional group for 2-methylbutan-1-ol?
A. Carboxylate
B. Diol
C. Hydroxide
D. Hydroxyl

17. A mixture of grape juice and yeast is kept at 35C for three days. What are the products
formed?
A. Ethanol and water
B. Ethanoic acid and oxygen
C. Ethanol and carbon dioxide
D. Starch and carbon dioxide
18. Compound X has the following properties :

Complete combustion produces carbon dioxide gas and water

Very miscible in water
Can be prepared from alkene

What is the molecular formula of compound X?

A. C2H6
B. C2H5OH
C. HCOOCH3
D. CH3COOH
19. Which of the following is the physical property of ethanol?
A. Fruity smell
B. Low boiling point
C. Insoluble in water
D. Turns lime water milky
20. The following flow chart shows the conversion of ethanol to ethene and ethanol to
ethanoic acid
Ethene

Process I
Process II
Ethanol
Ethanoic acid

What are Process I and Process II?

Process I
A.
B.
C.
D.

Oxidation
Dehydration
Fermentation
Esterification

Process II
Esterification
Oxidation
Dehydration
Fermentation

Section B : Answer all the question given

1. In diagram below, X and Y are the structures of two hydrocarbon molecules that have
the same number of hydrogen and carbon atoms

H H H

HC=CCCH
H H

H
HCH
H

HC=CCH
H
X

a) i )

What are X and Y known as?

_________________________________________________________
(2 marks)

ii)

Name each of hydrocarbons X and Y

X : ______________________________________________________
Y : ______________________________________________________
(2 marks)

iii)

Name another hydrocarbon that has the same molecular formula as X and
Y but with different structural formula
_________________________________________________________
(1 mark)

iv)

Draw the structural formula of the hydrocarbon named in (a)(iii)

(1 mark)

b) X will react with steam(water) to form an alcohol under the following conditions :
Temperature : 300C
Pressure : 60 atmosphere
Catalyst : Phosporic acid
i)

Name the alcohol

________________________________________________________
(1 mark)

ii)

Name the reaction involved in this process

________________________________________________________
(1 mark)

iii)

Write a balanced equation to represent the reaction

(2 marks)
2. Table 1 shows the molecular formula and boiling points for three compounds, which
are members of a homologous series
Compound
P
Q
R

Molecular formula
C2H5OH
C3H7OH
C4H9OH

Boiling point (C)

78
97
118

Table 1
a) i ) Name the homologous series for these compounds
________________________________________________________________
(1 mark)
ii) Write the general formula for this homologous series
________________________________________________________________
(1 mark)
b) Explain why the boiling point for the members of this homologous series increases
when the number of carbon atoms per molecule increases
_____________________________________________________________________
_____________________________________________________________________
_____________________________________________________________________
(3 marks)

3. Alkene is an unsaturated hydrocarbon

a) What is meant by unsaturated hydrocarbon ?
__________________________________________________________________
(2 marks)
b) Write the chemical equation for the complete combustion of propene
__________________________________________________________________
(1 mark)
c) Draw the structural formula of one isomer of butene and name the isomer

(2 marks)

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