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EXAMINATIONS
COUNCIL
Paper 01
1 hour 30 minutes
(
21
1.
This test consists of 45 items. You will have I hour and 30 minutes to answer them.
2.
In addition to this test booklet, you should have an answer sheet'and a Data Booklet.
3.
Each item in this test has four suggested answers lettered (A), (B), (C), (D). Read each item
you are about to answer and decide which choi<;e is best.
4.
On your answer sheet, find the number which corresponds to your item and shade the space
having the same letter as.the answer you have cl10sen. Look at the sample item below.
Which of the followi11g transitions requires the HIGHEST energy in an organic compound?
(A)
n to er
(B)
n to 7t
(C)
7t to 7t
cr to cr
(D)
Sample Answer
..
The best answer to this item is "cr to cr", so answer space (D) has been shaded.
--=--=
5.
If you want to change your answer, erase it completely before you fill in your new choice.
6.
When you are told to begin, turn the page and work as quickly and as carefully as you can. If
you cannot answer an item, go on to the next one. You may return to this item later. Your score
will be the total number of correct answers.
7.
8.
9.
""""'
..
~---~--------~
. .~
"-'
-2l.
4.
5.
==========::::;==::i===n=S
(C)
=_-=i=_-==-~:1=_1::=~-<:!=~-= ::~
(D)
5 dm' of
amount of
number of
with each
- - - - - - - - - - n=l
6.
2.
(A)
(B)
(C)
(D)
3.
Balmer
Dalton
Lyman
Paschen
( C)
(D)
Carbon dioxide
Copper oxide
Magnesium oxide
Silicon dioxide
Be'+
(B)
Ca2
(C)
Li+
(D)
Sr
!
GO ON TO 11iE NEXT PAGE
7.
.= 2NH,(g)
(C)
(D)
Cu metal
JO cm'
15 cm'
20cm'
40cm'
11.
8.
(A)
(B)
(A)
(B)
(C)
(D)
9.
10.
12.5
62.5
125
250
(C)
(D)
SO
(B)
(C)
so,
s,o
(D)
s,o.
(A)
(B)
(C)
(D)
(A)
(B),
Mno.---+ Mno
(C)
Mno.---+ MnO,
(D)
-. -- .... -
12.
gas?
""""~""'
.I
"
2-
13.
Ammonia
Helium
Methane
Oxygen
(A)
(B)
(C)
(D)
20kPa
125 kPa
20 OOOkPa
125 000 kPa
-414.
kJmot 1
(A)
L\H = +1150
(B)
L\H =+1150
(C)
L\H =-1150
(D)
L\H =-1150
Item 15 refers to the following standard enthalpies of combustion for carbon, hydrogen and octane.
kJmot 1
Carbon
Hydrogen
Octane
15.
-394
-286
-5476
MJ , is calculated using
(C)
MIJ (octane)= -8 (-394}-9(-286)-5476 kJ rnoJMIJ (octane)= -8 (-394}-9(-286)-{-5476) kJ mo1MIJ (octane)= 8 (-394) + 9(-286)-{-5476) kJ mo1-
(D)
(A)
(B)
00 ON TO T1IE NEXTPAOE
-5Item 16 refers to the following reaction which occurs in the presence of dilute acid.
CH,COCH, (aq) + 12 (aq)--+ CH) COCH, (aq) + H (aq) + 1- (aq)
16.
(A)
(Il)
(C)
(D)
OH
II
CH,-C-CH, + H -+CH,-C-CH,
Ea
II
II
OH
II
CH-C-CH
,
, +I, +H -+CH-C
, I -CH,
l
17.
The rate Jaw for a given reaction is Rate= k[A) 2 [B] . What are the units fork?
(A)
(B)
(C)
(D)
moJ-2 dm-2 s- 1
mo) dm-3 s- 1
moJ- 1 dm' s- 1
mo1-2 dm' s- 1
-618.
(A)
(B)
(C)
(D)
20.
(A)
(B)
~ 2NO(g),
(C)
(D)
21.
19.
II.
Ill.
(D)
(A)
(B)
(C)
.CD)
22.
-----,(A)
Temperature (UC)
25
(B)
50
(C)
(D)
100
200
-723.
'
(A)
(B)
(C)
(D)
Acid
Base
Conjugate acid
Acid
24.
(H]
[Propanone]
[Iodine]
Rate
0.5
10.8
0.5
3
4
0.5
0.25
5.3
5.4
0.5
0.5
10.6
C2H 50H
Base
Acid
Base
Conjugate base
Rate
[Propanone)
(B)
Rate
[Propanone)
(C)
Rate
[Propanone)
(D)
Rate
lPs
M1, ..,~,,.,,..A~"'"'..,
- 8-
25.
(B)
27.
(A)
(B)
(C)
(0)
[Fe>+] [JOH-]
[Fe 3+] [OH-]3
[Fe(OH) 3 ]
(C)
[Fe1 ] [30H-]3
(D)
[Fe1 ] [OH-] 3
mol dm-'
mol' dm-6
moP dm_.
mol 4 dm-12
Whichofthe following indicators is MOST suitable for use when titrating a weak acid against a
strong base?
Indicator
(A)
(B)
(C)
(0)
28.
pH of Change
Methyl orange
Litmus
Bromothymol blue
Phenolphthalein
3.5
6.0
7.0
9.5
Colour Change
Acid ~Alkali
red -+ yellow
red-+ blue
yenow -+ blue
colourless -+ pink
29.
the--
S
6
7
8
Using standard electrode potentials, which of the following reactions would be MOST feasible?
(A)
(B)
(C)
(D)
...
-9-
31.
(C)
(D)
(D)
Acidic Amphoteric
Basic
co,
CuO
MgO
so,
so,
Al,03
so,
co
P,0 10
Feature
State at 25 C
Barium
Beryllium
Magnesium
Strontium
Solid
(C)
(B)
Solid
Liquid
(D)
Gas
Bonding and
Ionic Giant
Covalent Covalent
Structure in Oxide lattice covalent molecular molecular
10
Oxide of silicon
34.
Oxide of sulphur
35.
Cao
(A)
Na,O
so,
(B)
()
(A)
pH of Aqueous
Solution
(B)
(A)
(B)
(C)
32.
Ag'(aq) I Ag(s)
(D)
36.
The high
(A)
(B)
(C)
(D)
delocalised electrons
hexagonal arrangement of the
carbon atoms
van der Waals' forces between the
layers
strong covalent bonds within the
layers
,..,.., _...,
____ . ____ _
- I0 -
37.
(A)
(B)
(C)
(D)
38.
Aluminium
Chlorine
Sulphur
Phosphorus
s
g
11-1
39.
no precipitate
white silver fluoride
yellow silver fluoride
cream-coloured ammonium fluoride
Br-, Cl -, 1-
(B)
Cl-, 1-, Br
(C)
c1-, Br,1-
(D)
I-, Br-, Cl -
Ca Sc Ti V Cr MnFe Co Ni Cu Zn
Elements
41.
1000
900
800
700
600
500
400
300
200
100
0
4s-orbitals
d-orbitals
4s and d-orbitals
4s-orbitals and half-filled d-orbitals
40.
(B)
(C)
(D)
42.
Melting
Point (C)
1538
Density
(g cm-l)
7.86
II
660
2.70
III
328
11.34
I only
II only
I and II only
II and Ill only
- 11 -
43.
(A)
(B)
(C)
(D)
Calcium
Copper
Magnesium
Sodium
[Co(H,O)J>+
45.
CH,NH 2
END OF TEST.
IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST.
02112010/CAPE 2013