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CY : CHEMISTRY
Max,,,,,,,,, Mark,. JOO
Read the followin!: instructions carefully.
Thi, que,[ioll paper contains 24 pages mcluding blank pages for rough work. Please check "II pages
and repon discrepancy. If any.
2.
Wnte your registration number, your name and name of the examination centre at the specified
location' on the right half of the Optical Re,ponse Sheet (ORS).
3.
Using HB pencil. darken the appropriate bubble under each digit of your registration numher and the
letters corresponding to your paper code.
4.
5. Questions must be answered on the ORS by darkening the appropriate bubble (marked A. B. C. Dj
using HB pencil against the question number on the left hand side of the ORS. For each 'Iuestion
darkcn the bubble of the correct anSwcr. In case you wish to change an answer. erase the old
answer completely. More than one anSWer bubbled against a q...estion will be treated as an incorrect
response.
6. There arc a tOlal of65 questions carrying 100 marks.
7. Queslions Q.I - Q.25 will carT)' I-mark each, arid queslions Q.26 - Q_55 will carry 2-rnark. each.
8. Questions QA8 - Q.51 (2 pairs) are common data questions and question pairs (0.52. 0.53) and
(Q.54, Q.55) are linked answer quesuom. The answer to the second question of the linked answer
questions depends on the anSwer to the first question of the pair. If the first question in the linked pair
is wrongly answered or is un-attempled, lhcn the anSwer to the second question in t1K: pair will not be
evaluuted.
9.
Questions Q.56 _ Q.65 belong to General Aptitude (GA). Questions Q.56 - 0.60 will carry I-mark
ea,h, and questions Q.61 - Q.65 will ,arry 2marks each. The GA ql.>estions will hegin on a fresh
page ,taning from page 15.
10.
IJn-a!t~mpted
II. Wrong answer, will carry NEGATIVE marks. For 0.1 - Q.25 and Q.56 -Q.60. % mark WIll be
deducted for ea,h wrong anSwer. For 0.26 - Q.51 and Q.61 - Q.65. . mark will be deducted for each
wrong answer. The question pair' (Q.52. Q.53). and (Q.54, Q.55) are questions ... ith linked answers.
There will be negative marks only for wrong anSWer to the first queSlion of the linked answer question
pair i.c. for Q.52 and Q.54. +.I mark will he deducted for each wrong answer. There is no negative
marking for 0.53 and Q.55.
12. CalculutOl (wjthout data connectivity) is allowed in Ihe examinalion hall.
13. Chan" graph ,heelS or tables are NOT allowed in the exammal10n hall.
14. Rough work can be done on lhe question paper itself. Additionally, blank pages are provided at the
end of Ihe question paper for rough work.
Cy
",.
2010
I, Physical Constants
(a) Planck Constant, h" 6.626 x lO - ....
Js
2. Atomic Numbers
M"
25
26
"15
F,
Co
27
A,
33
Co
29
Sb
51
Z"
30
Bi
83
Mo
42
C,
20
Mg
The Lewis ,,~idi(y of BF, is less than Uci" even though f1u(}rine is more electronegative than
chlmine, It,s due to
(A) Slronger 2p(B )-2p(F) a-bonding
CC) stronger 2p(B )3p(CI) abonding
Q_2
P] \
stru<;tur~,
as shown
/]
~
b
\:0'l'
b = Silicon
0 = Oxygen
0.3
Among the followmg pentachlorides the one which does not e,ist due to the 'inert-pair dfect' is
(A) PCI,
QA
(B) BiCi s
"
(D) AsCI,
The numher of 'framework electron pair" present in the borane cluster [B"H,,}'- i,
(A) 10
Q.6
(0 SbC'I,
Band lhco')' predicts that magoesium is an insulator. Howe,-er. in practice il acts os a ~ond""tor due
(A) preoetlce of filled 3s orbital
(C) overlap of filled 3. and empty Jp orbital
Q.S
(C) ]Si,O,lo-
(B) II
(e) 12
(D) D
The r~action hetween IPdCI,J'- and C,II. produces a new compound_ Compared to free C,I-I,. the
0,7
Among 1he following pair of metal ions pre&en( in Nature. (he firs! one functions ~s ~n electrontran,fer agent and the second one catalyl.cs tile hydrolysis reactions_ Tile correct pair i.l
(A) Fe .lnd Zn
(') Co and Mo
Q8
(B) Mg and Fe
(0) Ca and Cu
Ni~kdloccne
(n)adlcation
(I)) a dlanion
<"y
::.0",
Q_9
"0
M,
x
(Al R. S
Q.iO
;:=.-<;
"
"
y
(D) S, S
(C) R, R
(B) S, R
In the reaction
C",
f'I'lHSO 2M NaOMa
~;
180C
(A)
Q.ll
Q.12
(D)
(Al cis-1.2-<1nnethy!cyc1oheunc
(D) rr~ns-l.3-dimelhykycloltexane
In tlte rcacMn
"NO,
[X]
o
(A)
(B)
r""Y CHO
L-J
('J
~"
(D)
2010
Q 13
CY
The del:reasmg order of isoelectric point for the followmg a-amino acids is
Lysme
Alanine
UIUIJrntc acid
(I)
(II)
(III)
(B)II>i>UI
(l)1>1II>1I
(All>!l>lIl
(ej III > 1>11
Q_14
Too decreasing order of the reactivily of the following compounds towards electrophiles is
Q Q
"
,"
I!:> 1II:>1
(D)I>lI>m
(B)
(C)Ui:> 1:>11
Q.15
In the reaction
heat
-'-"-... [X]
IB,
,A)
Q.16
(0)
'C)
,
(A)
l>ll>lIT
>11:>1
(C) III
"
m
(B) 1II > 1>11
(D)lI
>1 >m
211101
Q_17
I:Y
(A)
Q_18
Q_J9
(B) -Rln 2
(C) Rln
(D) 2Rln 2
Q.20
~ VIIbSin(~)
\b
functions
functions
funclions
functions
II Sin( 21'-")
of particle in a I-D box of length
Vb
b
and VI, =
b(O"'_t",b)
(AJ ,+" i. normalized and OTlhogonaito ,+"
(B) 'fI, is normalized but not OTlhogonal to ,+"
(C) ,+" is nonnalized and orthogonal 10 '+'1
{OJ ,+" is neither normalized nor orthogonal (0 ,,
Q.22
Q.23
(C) 2
(0) 3
Sulfur can exi<t 1ll four phase<_ The possible number of triple points is
(A) 1
Q.24
(B) 1
(B) 2
(C) 3
(D) 4
The standard reduction potentials at 298 K for single electrodes are gi,en below.
Electrode
-2.34
-H76
"
2010
Q.25
CY
N,(g)+3H,(g)~2NH\(g)
i,) :;:N,(g)+"2H,(g)
NH,lg)
K,~
Q.27
The number of unpaired electron(s) prescm in the species (Fe(H,O),(NO)" which is formed
during 'hrown ring test' is
(A) 2
Q.28
IS
(B) 3
(C) 4
(D) 5
Fe,O, and Cop, are metal oxides having spinel structure. Considering their CFSEs, the correct
slatemcm regarding their structure is
(A) both have nonnal spinel structure
(B) both have inverse spinel structure
(C) Fe.D. h" nonnal and Co,O. has inverse spinel structure
(D) Fe,O. ha., inverse and Co,O. has nonnal spinel structure
Q.29
The mechanism of lhe reaclion between [Fc(CN) 014- and [Fe(bpYhl' (bpy = 2,2'-bipyridine) is
(A) ouler -'pi>ere electron-transfer
(B) inner-sphere electron-transfer
(C) self -exchange reaction
(D) ligand-e~change followed by electron-transfer
Q.30
('y
(B) 'A"
(C)'E.
ry
1010
Q.32
ChCHCHCh
"I
-+t=t
Q.33
ICoCI.)'- i, a blue coloured complex. Controlled-treatment of this complex with water generales
two isomeric light pink coloured complexe, of composition [Co(H,O).Cl,i.
Identify the correct poim groups for [CoCl.I).. and two isomeric complexes [Co(H,o).CI,I.
(S) T" and (C",. and D",)
(D) T d and (e,_ and C4 ,)
Q.34
In the reaction
Et~CXC~H
L&He
[X]
ii. Ii"
(A)
(0)
(8)
v,
;0
Q.35
In the reaclion
OH
x:::
heat
"
",SO,
:0
OH
[~
(C)
(e)
aee(
(D)
Oy
o
l~IO
Q.3b
'" '"
--_.
I~
(A)
=e
(8)
..
''''''OH
"
Q.37
6~
~e
""DH
(m
(e)
"
0"
"
In the reactions
IYJ
mCP""
_0--
- - _ . I"
(.)
,.,
moe
,~
~
~
and
"""
"
(e)
(D)
,,'
<,
~~
,,'
,~
2010
Q_38
"
In the reaction
SnCI.
~,----,
the major product [X J i,
IA)
Q.39
(e)
(8)
(D)
i. Hg(OAc)2IM9OH
OHH;';
..
HO
[X]
HCI
ii. NaSH.
(A)
(II)
,~
.00
~ ~
,OiiEt
'"" ~
M~
"'"
IP)
(C)
,~o
O~
Q.40
M~
OM,
O~
g~.'
OM.
500 K is
(I,) _6.37 J K-' mole-'
--,-:y- - - - - - . - - -
(I))
,012'
2010
QAI
CY
Iny=
J7"P
o
~oetTidcl11
(y) i, given by
whcr~ Z i, the compressibility factor. The fugacity ,()emdenl of a real gas govcrned by equation of
state P (V - b) = RT wilh b a constant is given by
"'
(A) RT
bP
Q.42
(el
(B) ~.,'
1>1'
RT
(2000
Ink 0=5.0--T
The activation energy of decomposition for lhis compound al 300 K i,
(A) 24 keal/mole
QAJ
(0 24 callmole
31u'
2tri
Iu
2tri
(8(-
(O(
9h
8mb-
(D) -
2h
",b'
(B) C',.and 4
(0 C. and-,
(0) C,.and
The most populated rotational Slate for Hel (B = 8.5 em") at 300 K is
{A)2
Q.47
2!rj
The point group of elF, molecule and its corresponding number of irreducible representations are
respectively
(A) C'" and 4
Q.46
31u'
An electron of mass . III' l' confined to a One dimensional 00. of length . b'. IF it makes a radiative
transition from second ncited state to the ground state. the frequency of the photon emitted is
(A) - - ,
Q,45
(0) 12 callmole
Q.44
(B) 12 kcaVmole
(B) 3
(e)
(D) 7
The ratio of life times of two states that give rise to line widths of I () CIl" and 0.2 em-' respectively
,;
(A) 1'2
(B) I ; 5
(e)
(0)5:1
2. I
The metal-,on along with it" oxidation <tatc ond the number of unpaired electron present are
(A) Fe(Il) and 4
(el Fe(llI) and 1
Q,49
~omple"
The complex is
(A) [Mn(H,O).)'+
(B) [Fe(CN),],(C) iFe(H,O),)"
1"'~
speclr~1
dalJ
IR. _1720cm L
'H :-IMR: 2.3511. bH). 3.10 (5, 3H), 3.83 {t, 2H).4.42 (I. 2H). 7.07 (., IH). 7 5H (so 2H)
The compound IXI with an excess of MeMgBr give> a J'J mixtu,"" of compounds IY] and IZj. The
compound IZI exhibit. the following 'H NMR data. 2.0 (bs. IH). 3.30 Is, 3H). 3.56 (t. 2H). 3.70 (I, 2H)
050
Q.51
(Al
(B)
(C)
(D)
(B)
(A)
0"
~ "'"
0"
~"
(C)
"y
+y
,,..,
~"
,od
~H
(D)
""
/a.Y.
OH
)::)
__. _ - - - -
20,"
IVef'olgBr
Ph
'x
HSC "
i. TsCVPy
[~
rZr
ii. NaOEtfEtOH
Q.52
Ph
(A)
H,C+ H '
OH
Ph
(B)
H,C+
Cf<,
OH
Ph
(e)
~~ -I--~
CH,
(0)
OH
Q.53
:+
CH,
M,
(A)
1(:eo
M,
(B)
M,
"0
(C)
"'
reo
Mo,
eo
'~
Ph
(D)
Mo-{-Mo
H
11110
th~
""
""
""
""
F::E :0
T
Q.54
Q.55
pha,e.
phase,
phase.
phase,
'OHl
2j persons an: in a room. 15 of them play hockey. 17 of lhem play football and 10 of lhem play
both hockey and football. Then lhe number of persons playing neither hockey nor foolball is;
(A) 2
Q,57
(B) 17
(C) J3
/h~
(D) 3
selllfnce:
If we mana~e to _______ our natural resources, we would leave a better planet for
our cblldren.
(A) uphold
(8) restrain
(C) cherish
(0) conserve
Q.58
TM ques/ion below consis/s of a pair ofre/aleel word. followed by four pairs of words. Select the
poir that bcM expresses the relalion in /he or,ginol poir.
Unemployed: Worker
(A) fallow: land
(B) unaware: sleeper
(C) wit: jesler
(0) renovated: house
Q.59
W/,kh of/he following opri01lS is the dosestln meaning to the word belolll:
Cin:uilous
(A) cyclic
(B) indirect
(C) confusing
(D) crooked
Q,60
Choose the most appropria!e word from the options given below 10 compleTe the following
,enlen<'c:
His rather casulIl reJIlllrl<s on po6tics _ _ _ _ _ _ bis IacI< of seriousness about the subject.
(A) masked
(B) belied
(C) betrayed
(D) suppressed
Hari (H), Gita (G), Irfan (I) and Saira (S) are siblings (i.e. brolhers and sister~). All were born on
I" Ianuary. The age difference between any IWO SUCCeSSlVe siblings (thaI is
one after another)
is bs than 3 years. Given the following raet.:
L Hari 's age + Gita', age > Irf~n'.\ age + Saira's age,
n. The age difference belwn Gila "nd Saira is I year. However. Gita is nOI the
oldest and Saira is not the younge,t.
n'- There are no twin"
In what order were they born (oldest firsl)"
oom
(A)
HSJG
(8) SGHJ
(C) IGSH
(D) lHSG
cy
,010
Q.62
5 ~killed workers can build a wall m 20 days, 8 semiskilled workers can bUild a wall in 25 day,;
II) Lm,killed workers Can build a wall in 10 days If a team has 2 ,killed, (, semiskilled and
5 umkillcd workers, how long will illake lO huild the wall?
(AJ 20 days
Q_63
(B) 18 days
(e) 16 day,
(D) 15 day,
Modern warfare has changed from large scale clashes of armies to snppre&Sion of dvilian
populalions. Chemical agents that do their work silently appear to be soited to such warfare;
and rellrdfully. there exist people in military estahlishments wbo think that chemical agents
are u""fullools for their CIIIl5e.
WI,;ch ofthefollow;llg stolemellts best SlImJ up the meonillg of the above possage:
(A) Modem warfare has resulted in civil ,trifc.
(B) Chemical agents are useful in modem ..... arfare.
(e) D.e of chemical agents in warfare would be undesirable.
Q.64
Given digils 2, 2, 3, 3, 3, 4, 4, 4, 4 how many distioct 4 digit numbers greater than 30()() can be
formed?
(Al50
Q.65
(E) 51
(e) 52
(0) 54
(e) 1623
(0) 151)
(B) 1403
~QIO
17114
rom
10'0
.,
,~.
lOlO
>(\fl4
1"10
"
Space for Rough Work
"
!UIO
:010
CY
"