Professional Documents
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Submitted by : Imtisal-e-Noor
Sample: T 50
Question 1
0.598659443
0.653148056
0.715626278
0.766208851
0.818239743
0.839010414
0.850718025
0.862803316
0.87549289
0.900013596
0.925358108
0.931431581
0.937621486
0.944051703
0.950137913
0.974453596
0.980339436
0.989936459
0.994806719
450.17917
491.18912
538.20325
576.26025
615.40857
631.04712
639.86969
648.97681
658.53894
677.001
696.08392
700.67108
705.34607
710.20209
714.79956
733.11188
737.55945
744.79944
748.52295
0.972437357
0.932412841
0.906753787
731.7157
701.61755
682.32776
0.900380914
0.876112446
0.851174413
0.826029647
0.80094614
0.751202447
0.700988286
0.650953737
0.600842414
0.551087526
0.502432613
0.455189571
0.419393687
0.4006340626
0.364062627
0.338707454
0.32186929
0.300782083
677.53375
659.26282
640.4903
621.56262
602.68146
565.24506
527.45691
489.80319
452.09253
414.65088
378.03665
342.45676
315.51321
301.39502
273.8775
254.7998
242.12964
226.26347
0.270864853
0.251271825
0.220816759
0.200879973
0.190980364
203.75711
189.01833
166.10861
151.11124
143.66429
0.186580498
0.166045649
0.143895228
0.127388973
0.123264121
0.100639351
Question 2- part 2
140.35451
124.90724
108.24467
95.8279
92.72499
75.70559
and V molar =
no. of moles =
Avagadro's Number=
no. of molecules=
Adsorption Cross section of nitrogen =
and
and
Conclusion :
on experiment:
material, N2 adsorption-desorption on the porous material is a type of intrusive method which gives us Spec
desorption equipment.In this process, nitrogen gas behaves like an adsorbate( it is also an inert gas so there
ch adsorbes on the surface of the porous material.The specific temperature at which this determination is do
Equipment basically uses the volumetric method of adsorption in which equipment measures how many mole
f molecules gives us the specific surface area of the adsorbent by using Adsorption Cross section area of nitr
e starting the experiment ,with the help of pump and degassing for the sample prepration depends on the ex
mbers seperated by a valve with volumes V1 and V2 respectively and sample is placed and Basically pressur
c volumes.Glass tube is used for the measurement of sample volume ,which is in powdered form that helps t
e is closed with the help of crok to isolate the sample from atmosphere and it is at controllable temperature
gas adsorbed is determined by measuring Pressure of the gas at precise volume. And vaccum system is con
pressure. After the introduction of N2 we can measure the free volume is measured corresponding to the vo
ep by step for further measurements. After equilibrium is achieved, the valve is open therefore allowing the
d before and after dosing, density of free gas is determined at each step.In case of desorption, the reactor ha
ecific amount of gas confined can also be calculated with respect to the total amount of the gas that will be a
s, it is IV b type sample. Sample given is a mesoporous material associated with Network perculation. In this
e is a hystersis occurs in N2 adsorptionprocess in meso pores of sample because the curvature of meniscus
124.9448
137.9267
145.6777
146.8485
147.3098
147.5057
147.5905
147.6905
147.7736
147.9638
148.1849
148.256
148.3221
148.3763
148.4324
148.7513
148.8674
149.1031
149.2552
3:58
4:09
4:17
4:21
4:25
4:29
4:33
4:37
4:41
4:45
4:49
4:53
4:57
5:01
5:05
5:09
5:13
5:17
5:29
148.7586
148.2248
147.949
5:34
5:38
5:42
5:44
5:48
5:53
5:57
6:01
6:05
6:09
6:12
6:16
6:20
6:24
6:29
7:05
7:20
7:27
7:33
7:38
7:43
7:48
7:50
7:56
8:00
8:05
8:10
8:14
147.8577
147.6425
147.4254
147.2327
147.0136
146.6149
146.1852
145.6975
145.1538
144.5168
143.3646
114.1183
97.6958
94.8495
90.9849
88.7251
87.2663
85.4767
82.9726
81.3469
78.8364
77.1267
76.24
75.8497
74.0485
72.0133
70.4
69.9809
67.5547
8:17
8:22
8:27
8:32
8:35
8:40
/Ps)))=(C-1/Vm*C)(P/Ps)+(1/Vm*C)
ure range :0.05<P/Ps<0.35
y=0.016x-5*10^-5
y=(P/Ps)/(V*(1-(P/Ps)))
x=P/Ps
a=C-1/Vm*C
0.016
b=1/Vm*C
0.00005
Vm*C
20000
C
Vm
321
62.3052959502
22400
0.0027814864
6.02E+23
1675050425567420000000
1.62E-19
Vm/V molar=
Na=
no. of moles*Na=
oss section of nitrogen =
no. of molecules* adsorption
cross section of the N2
271.3581689419
Numerical Value
34.65
T
Ps
R
8.85E-05
7.74E+01
7.60E+02
8.31E+00
rk(m)
0.4006
0.7009
0.5257
0.000000001
2.68161988601425E-009
1.48209117163498E-009
= Vads*(34.65/22400) cm3/g
rve (Vads vs P/Ps) we can know that
Vads
Vpore
2.2
149.5
0.2312578125
Vpores/(Vpores+(1/Density of solid))
33.7207219056
dsorption Measurements
e of intrusive method which gives us Specific Surface area, Pore size, pore volume
n adsorbate( it is also an inert gas so there will be no chemical reaction occurs
perature at which this determination is done, is 77 K and the pressure should be in
which equipment measures how many molecules of nitrogen are adsorbed in pores
using Adsorption Cross section area of nitrogen gas. In this equipment, vaccum is
r the sample prepration depends on the extent upto which vaccumis created. In this
nd sample is placed and Basically pressure is measured before and after the
me ,which is in powdered form that helps to reduce the free volume is placed in one
phere and it is at controllable temperature while the rest of the equipment is at
precise volume. And vaccum system is connected with computer so that it can
lume is measured corresponding to the volume of the bath .Number of moles can
d, the valve is open therefore allowing the gas to be exposed to the sample. The
h step.In case of desorption, the reactor has high pressure while the staying
o the total amount of the gas that will be available for adsorbtion.
y=(P/Ps)/(V*(1-(P/Ps)))
751.62585
0.0002023404
0.000552339
0.0010635714
0.0012922881
0.0016417655
0.0019583593
0.0022732183
0.0025966544
0.0029299464
0.0032768727
0.0040409454
0.0050737136
0.0061523782
0.0070503965
0.0081925736
0.009396919
0.0106497255
Volume Adsorbed
0.0119384681
0.0136527193
0.0172744306
0.0223177077
0.0305597644
0.0353313934
0.0386117832
0.0425809778
0.0475840735
0.0608348784
0.0836610371
0.0916251175
0.1013413442
0.1137219692
0.1283770779
0.2564310536
0.3349507061
0.659735458
1.2834159046
0.2371694202
0.0930728862
0.0657273528
752.505
0.0611279429
0.0478983751
0.0387943644
0.0322489897
0.0273700252
0.0205936241
0.0160368531
0.0128001492
0.0103702156
0.0084945538
0.0070434265
0.0073213572
0.0073937411
0.0070472677
0.0062920538
0.005772775
0.0054390064
0.0050325914
752.2464
0.0044772353
0.0041255192
0.0035947248
0.0032592665
0.0030963266
(P/Ps)/(V*(1-P/Ps))
0.0030241115
0.0026888647
0.0023340318
0.0020736644
0.0020090391
0.0016564502
cm3/g
cm3/g (STP)
dimension less
no. of molecules / mole
moleclues / g
m2
m2/g (STP)
Units
cm3/mol
degree
N/cm
K
mm Hg
J/mol.K
t(thickness)(m)
alculation of rp.
g/cm3
cm3/g(STP)
cm3/g(STP)
rp=rk+t (m)
6.038524171709E-010
1.64564245286595E-009
8.27306194557472E-010
3.50892608057172E-009
6.79065006762076E-010
2.16115617839706E-009
Adsorption-Desorption Isotherm
160
140
120
100
Volume Adsorbed
ads
80
des
60
40
20
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
20
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
BET isotherm
0.0045
0.004
0.0035
0.003
0.0025
(P/Ps)/(V*(1-P/Ps))
BET
0.002
Linear (BET)
0.0015
0.001
0.0005
0
0
0.05
0.1
0.15
0.2
0.25
0.3
ads
des
0.9
0.9
0.3
BET
Linear (BET)
x
0.0599
0.0781
0.086
0.1006
0.1116
0.1208
0.1364
0.14007
0.16117
0.1873
0.2013
0.2128
0.2373
0.2521
0.2632
0.2873
0.3026
0.3139
0.3378
y
0.000613
0.000774
0.000842
0.000968
0.001063
0.001143
0.00127
0.00131
0.001495
0.00173
0.001858
0.001965
0.002198
0.002343
0.002454
0.002702
0.002864
0.002987
0.003255
BET graph
0.0035
0.003
0.0025
0.002
0.0015
0.001
0.0005
0
0
0.05
0.1
0.15
0.2
0.25
0.3
0.
BET graph
093734345x + 0.00000958
.15
BET graph
Linear (BET graph)
0.2
0.25
0.3
0.35
0.4
0.062878
0.077668
0.100368
0.120798
0.140953
0.161312
0.181879
0.202779
0.247469
0.001064
0.001292
0.001642
0.001958
0.002273
0.002597
0.00293
0.003277
0.004041
BET
0.0045
0.004
0.0035
0.003
0.0025
0.002
0.0015
0.001
0.0005
0
0.05
0.1
0.15
0.2
BET
03178x + 3.15226845601979E-005
BET
Linear (BET)
0.15
0.2
0.25
0.3
0.303897 0.005074