Professional Documents
Culture Documents
12
Chemistry
9.2
Production
of
Materials
STUDY
GUIDE
Contextual
Outline
Humans
have
always
exploited
their
natural
environment
for
all
their
needs
including
food,
clothing
and
shelter.
As
the
cultural
development
of
humans
continued,
they
looked
for
a
greater
variety
of
materials
to
cater
for
their
needs.
The
twentieth
century
saw
an
explosion
in
both
the
use
of
traditional
materials
and
in
the
research
for
development
of
a
wider
range
of
materials
to
satisfy
technological
developments.
Added
to
this
was
a
reduction
in
availability
of
the
traditional
resources
to
supply
the
increasing
world
population.
Chemists
and
chemical
engineers
continue
to
play
a
pivotal
role
in
the
search
for
new
sources
of
traditional
materials
such
as
those
from
the
petrochemical
industry.
As
the
fossil
organic
reserves
dwindle,
new
sources
of
the
organic
chemicals
presently
used
have
to
be
found.
In
addition,
chemists
are
continually
searching
for
compounds
to
be
used
in
the
design
and
production
of
new
materials
to
replace
those
that
have
been
deemed
no
longer
satisfactory
for
needs.
This
module
increases
students
understanding
of
the
implications
of
chemistry
for
society
and
the
environment
and
the
current
issues,
research
and
developments
in
chemistry.
Syllabus
Dot-Points
Students:
-
2
-
Students:
2.
Some
scientists
research
the
extraction
of
materials
from
biomass
to
reduce
our
dependence
on
fossil
fuels
describe
the
dehydration
of
ethanol
to
ethylene
and
identify
the
need
for
a
catalyst
in
this
process
and
the
catalyst
used
describe
the
addition
of
water
to
ethylene
resulting
in
the
production
of
ethanol
and
identify
the
need
for
a
catalyst
in
this
process
and
the
catalyst
used
describe
and
account
for
the
many
uses
of
ethanol
as
a
solvent
for
polar
and
non-polar
substances
-
3
-
4. Oxidation-reduction
reactions
are
increasingly
important
as
a
source
of energy
Students:
5.
Nuclear
chemistry
provides
a
range
of
materials
-
4
-
Concept
Map
The
main
concepts
in
this
module
are
organised
as
shown
in
the
concept
map
below.
-
5
-
Week
Number
1
Content
Key Concepts
Condensation
polymerisation
Cellulose
as
a
condensation
polymer
Cellulose
as
a
potential
replacement
for
petrochemicals
Biological
polymers
9.2.C - Ethanol
Use
as
a
solvent
Dehydration
reaction
Fermentation
Combustion
Potential
as
a
fuel
9.2.D - Electrochemistry
Oxidation-reduction
reactions
Metal
displacement
reactions
Galvanic
cells
Different
types
of
batteries
Oxidation
states
2013 Term 4
Textbook
References
Preliminary
Course
Thickett,
Geoffrey.
2006,
Chemistry
1
:
Preliminary
course
/
Geoffrey
Thickett
John
Wiley
&
Sons,
Milton,
Qld.
HSC
Course
Thickett,
Geoffrey.
2006,
Chemistry
2
:
HSC
course
/
Geoffrey
Thickett
John
Wiley
&
Sons,
Milton,
Qld.
-
6
-
A
polymer
is
a
large
molecule
(macromolecule)
composed
of
repeating
structural
units.
These
sub-units
are
called
monomers
and
are
typically
connected
by
covalent
chemical
bonds.
Although
the
term
polymer
is
sometimes
taken
to
refer
to
plastics,
it
actually
encompasses
a
large
class
of
compounds
comprising
both
natural
and
synthetic
materials
with
a
wide
variety
of
properties.
Polymeric
materials
play
an
essential
and
ubiquitous
role
in
everyday
life.
This
role
ranges
from
familiar
synthetic
plastics
and
elastomers
to
natural
biopolymers
such
as
nucleic
acids,
proteins
and
cellulose
that
are
essential
for
life.
Most
commonly,
the
continuously
linked
backbone
of
a
polymer
used
for
the
preparation
of
plastics
consists
mainly
of
carbon
atoms.
A
simple
example
is
polyethylene
whose
repeating
unit
is
based
on
ethylene
monomer.
In
this
topic
students:
Describe
the
structure,
properties,
uses,
chemistry
and
production
of
the
addition
polymers
polyethylene,
polyvinyl
chloride
(PVC)
and
polystyrene.
Describe
the
structure,
properties,
identification
and
reactions
of
ethene
Explain
how
ethene
serves
as
a
useful
monomer
from
which
many
commercially
important
polymers
are
made
Describe
the
process
of
sourcing
ethene
for
polymer
production
Write
equations
for
some
of
the
chemical
reactions
of
ethene
-
7
-
Preliminary Dot-Points
Organic chemistry
Jacaranda Chemistry 1
Chapter
16
Carbon
and
carbon
compounds
pp.293-312
9.2.A
Syllabus
Dot-Points
Ethene
sources
identify
the
industrial
source
of
ethylene
from
the
cracking
of
some
of
the
fractions
from
the
refining
of
petroleum
Ethene
properties
uses
and
reactions
construct
word
and
balanced
formulae
equations
of
chemical
reactions
as
they
are
encountered
identify
that
ethylene,
because
of
the
high
reactivity
of
its
double
bond,
is
readily
transformed
into
many
useful
products
identify
data,
plan
and
perform
a
first-hand
investigation
to
compare
the
reactivities
of
appropriate
alkenes
with
the
corresponding
alkanes
in
bromine
water
identify
that
ethylene
serves
as
a
monomer
from
which
polymers
are
made
analyse
information
from
secondary
sources
such
as
computer
simulations,
molecular
model
kits
or
multimedia
resources
to
model
the
polymerisation
process
Polyethylene
PVC
Polystyrene
identify
polyethylene
as
an
addition
polymer
and
explain
the
meaning
of
this
term
outline
the
steps
in
the
production
of
polyethylene
as
an
example
of
a
commercially
and
industrially
important
polymer
describe
the
uses
of
the
polymers
made
from
the
above
monomers
in
terms
of
their
properties
identify
the
following
as
commercially
significant
monomers:
-
vinyl
chloride
by
both
their
systematic
and
common
names
describe
the
uses
of
the
polymers
made
from
the
above
monomers
in
terms
of
their
properties
identify
the
following
as
commercially
significant
monomers:
-
styrene
by
both
their
systematic
and
common
names
describe
the
uses
of
the
polymers
made
from
the
above
monomers
in
terms
of
their
properties
-
8
-
9.2.A
Resources
Websites
Jacaranda Chemistry 2
Twig-World Video
Quarkology
9.2.A
Synthetic
Polymers
http://www.quarkology.com/12-
chemistry/92-production-
materials/92A-synthetic-
polymers.html
Chapter
Reference
Chapter
1
Ethylene
and
addition
polymers,
pp.2-27
Fractional
Distillation
http://australia.twig-
world.com/films/fractional-
distillation-1371/
Monomers
http://australia.twig-
world.com/films/glossary/mono
mer-425/
Polymers
http://australia.twig-
world.com/films/glossary/polym
er-549/
Plastics
http://australia.twig-
world.com/films/plastics-and-
polymers-1372/
9.2.A
Student
Activities
Completed
-
9
-
-
10
-
Fossil
fuels
are
non-renewable
resources,
available
in
fixed
amounts.
Human
activity
has
the
potential
to
completely
exhaust
reserves
of
fossil
fuel
resources.
Biomass,
organic
matter
produced
by
photosynthesis
in
plants,
is
a
renewable
resource.
Biomass
consists
mostly
of
cellulose
and
can
be
used
and
then
formed
again
from
its
products
by
the
input
of
solar
energy
during
photosynthesis.
If
the
matter
involved
is
recycled,
biomass
could
be
a
source
of
raw
materials
for
as
long
as
the
sun
supplies
solar
energy.
Petrochemicals
are
chemicals
made
from
compounds
in
petroleum
or
natural
gas.
Currently
Australia
has
petroleum
reserves
that
will
last
about
ten
years
and
natural
gas
reserves
that
will
last
about
one
hundred
years.
Fossil
fuels
have
taken
hundreds
of
millions
of
years
to
accumulate.
Over
95%
of
fossil
fuel
is
burnt
as
a
source
of
energy
and
once
burnt,
fossil
fuels
are
no
longer
available.
Less
than
5%
of
fossil
fuel
is
used
to
make
plastics
and
only
a
small
percentage
of
that
plastic
is
recycled.
If
energy
and
material
needs
are
to
be
met
in
the
future,
alternative
sources
will
be
needed
as
fossil
fuel
sources
are
used
up.
In
this
topic
students:
-
11
-
Preliminary Dot-Points
Role
of
photosynthesis
in
transforming
light
energy
to
chemical
energy
Jacaranda Chemistry 1
Chapter
15
Photosynthesis
and
Fuels
pp.280-292
9.2.B
Syllabus
Dot-Points
Condensation
polymers
Cellulose
discuss
the
need
for
alternative
sources
of
the
compounds
presently
obtained
from
the
petrochemical
industry
identify
that
cellulose
contains
the
basic
carbon-chain
structures
needed
to
build
petrochemicals
and
discuss
its
potential
as
a
raw
material
Biopolymers
(eg.
Biopol)
use
available
evidence
to
gather
and
present
data
from
secondary
sources
and
analyse
progress
in
the
recent
development
and
use
of
a
named
biopolymer.
This
analysis
should
name
the
specific
enzyme(s)
used
or
organism
used
to
synthesise
the
material
and
an
evaluation
of
the
use
or
potential
use
of
the
polymer
produced
related
to
its
properties
-
12
-
9.2.B
Resources
Websites
Jacaranda Chemistry 2
Twig-World Video
Quarkology
9.2.B
Biological
Polymers
http://www.quarkology.com/12-
chemistry/92-production-
materials/92B-biological-
polymers.html
Chapter
Reference
Chapter
2
Condensation
polymers
and
Biomass
pp.30-42
Cellulose
http://australia.twig-
world.com/films/glossary/cellul
ose-649/
Nylon
http://australia.twig-
world.com/films/invention-of-
nylon-1377/
9.2.B
Student
Activities
Completed
-
13
-
-
14
-
Humans
discovered
ethanol
not
long
after
they
figured
out
how
to
put
fire
to
good
use.
Today,
ethanol
has
many
uses:
we
drink
it;
dissolve
solutes
in
it,
use
it
in
food,
industry
and
other
manufacturing;
and
blend
it
with
petrol
to
make
a
sustainable
and
renewable
transport
fuel.
Ethanol
belongs
to
the
homologous
series
of
alkanols,
each
with
a
hydroxyl
(-OH)
functional
group.
It
can
be
made
by
fermenting
the
sugars
found
in
plants
using
yeasts
(fungi)
and
bacteria.
Ethanol
can
be
used
as
a
fuel
for
vehicles
in
its
pure
form
as
a
replacement
for
petrol,
but
it
is
usually
blended
with
petrol
so
as
to
improve
vehicle
emissions
and
make
motor
fuel
more
sustainable.
In
this
topic
students:
-
15
-
Preliminary Dot-Points
Intermolecular
bonding
Jacaranda Chemistry 1
Chapter
12.1
Intermolecular
forces
and
polarity
of
molecules
pp.216-226
Solvent behaviour
Chapter
12.2
Interactions
with
water
pp.227-232
Chapter
14
Water
and
energy
pp.262-275
9.2.C
Syllabus
Dot-Points
Alkanols
Reactions
of
ethanol
describe
the
dehydration
of
ethanol
to
ethylene
and
identify
the
need
for
a
catalyst
in
this
process
and
the
catalyst
used
describe
the
addition
of
water
to
ethylene
resulting
in
the
production
of
ethanol
and
identify
the
need
for
a
catalyst
in
this
process
and
the
catalyst
used
process
information
from
secondary
sources
such
as
molecular
model
kits,
digital
technologies
or
computer
simulations
to
model:
-
the
addition
of
water
to
ethylene
the
dehydration
of
ethanol
Ethanol
as
a
solvent
Fermentation
Molar
heat
of
combustion
of
a
fuel
Ethanol
as
a
fuel
describe
and
account
for
the
many
uses
of
ethanol
as
a
solvent
for
polar
and
non-polar
substances
describe
conditions
under
which
fermentation
of
sugars
is
promoted
summarise
the
chemistry
of
the
fermentation
process
process
information
from
secondary
sources
to
summarise
the
processes
involved
in
the
industrial
production
of
ethanol
from
sugar
cane
solve
problems,
plan
and
perform
a
first-hand
investigation
to
carry
out
the
fermentation
of
glucose
and
monitor
mass
changes
present
information
from
secondary
sources
by
writing
a
balanced
equation
for
the
fermentation
of
glucose
to
ethanol
define
the
molar
heat
of
combustion
of
a
compound
and
calculate
the
value
for
ethanol
from
first-hand
data
identify
data
sources,
choose
resources
and
perform
a
first-hand
investigation
to
determine
and
compare
heats
of
combustion
of
at
least
three
liquid
alkanols
per
gram
and
per
mole
outline
the
use
of
ethanol
as
a
fuel
and
explain
why
it
can
be
called
a
renewable
resource
assess
the
potential
of
ethanol
as
an
alternative
fuel
and
discuss
the
advantages
and
disadvantages
of
its
use
process
information
from
secondary
sources
to
summarise
the
use
of
ethanol
as
an
alternative
car
fuel,
evaluating
the
success
of
current
usage
-
16
-
9.2.C
Resources
Websites
Jacaranda Chemistry 2
Twig-World Video
Quarkology
9.2.C
-
Ethanol
http://www.quarkology.com/12-
chemistry/92-production-
materials/92C-ethanol.html
Chapter
Reference
Chapter
3
Ethanol
and
Biofuels
pp.44-62
Alcohols
http://australia.twig-
world.com/films/glossary/alcohol-
399/
Fermentation
http://australia.twig-
world.com/films/fermentation-
1382/
Combustion
http://australia.twig-
world.com/films/glossary/combus
tion-410/
Biofuels
http://australia.twig-
world.com/films/biofuels-1327/
-
17
-
Completed
Textbook 3.4 Data Analysis Industrial Preparation of Ethanol from Sugar Cane, p.61
-
18
-
-
19
-
The
term
oxidation
was
originally
used
to
describe
reactions
in
which
an
element
combines
with
oxygen.
After
electrons
were
discovered,
chemists
extended
the
definition
of
oxidation
to
involve
the
transfer
of
electrons
from
one
atom
to
another.
Because
electrons
cannot
be
created
or
destroyed,
the
species
losing
electrons
is
said
to
be
oxidised
while
the
species
gaining
electrons
is
said
to
be
reduced.
If
the
electrons
from
an
oxidation
reaction
can
be
made
to
flow
around
a
circuit
to
the
site
of
reduction,
we
have
a
galvanic
cell
or
battery.
These
cells
convert
chemical
energy
to
electrical
energy
and
rely
on
oxidation-reduction
reactions.
In
this
unit
you
will
learn
to:
-
20
-
Preliminary Dot-Points
Oxidation-reduction
Jacaranda Chemistry 1
Chapter
7.1
Metals
and
their
reactivity
pp.128-131
9.2.D
Syllabus
Dot-Points
Metal
displacement
reactions
Oxidation
states
account for changes in the oxidation state of species in terms of their loss or gain of electrons
Galvanic
cells
Comparison
of
galvanic
cells
gather
and
present
information
on
the
structure
and
chemistry
of
a
dry
cell
or
lead-acid
cell
and
evaluate
it
in
comparison
to
one
of
the
following:
- button
cell
- fuel
cell
- vanadium
redox
cell
- lithium
cell
- liquid
junction
photovoltaic
device
(eg
the
Gratzel
cell)
in
terms
of:
- chemistry
- cost
and
practicality
- impact
on
society
- environmental
impact
-
21
-
9.2.D
Resources
Websites
Jacaranda Chemistry 2
Twig-World Video
Quarkology
9.2.D
-
Electrochemistry
http://www.quarkology.com/12-
chemistry/92-production-
materials/92D-
electrochemistry.html
Chapter
Reference
Chapter
4
Electrochemistry
and
batteries,
pp.63-91
Redox
Reaction
http://australia.twig-
world.com/films/glossary/redox
-reaction-775/
Oxidation
http://australia.twig-
world.com/films/glossary/oxida
tion-750/
Reduction
http://australia.twig-
world.com/films/glossary/reduc
tion-552/
Eco-Transport
http://australia.twig-
world.com/films/eco-transport-
1341/
9.2.D
Student
Activities
Completed
-
22
-
-
23
-
Radioactive
materials
that
release
alpha,
beta
or
gamma
radiation
have
a
range
of
uses
in
both
industry
and
medicine.
They
are
used
as
diagnostic
tools
in
both
industry
and
medicine
and
are
used
in
the
treatment
of
diseases
such
as
cancer
in
medicine.
Radioisotopes
have
an
unstable
nucleus
and
release
energy
by
ejecting
particles
or
electromagnetic
radiation
from
the
nucleus.
They
are
made
in
nuclear
reactors
where
radioactive
decay
processes
are
artificially
induced
by
bombarding
nuclei
with
neutrons.
Some
radioisotopes
can
be
made
by
smashing
the
nuclei
of
atoms
together
in
particle
accelerators
through
a
process
known
as
nuclear
fusion.
Many
artifically
synthesised
elements
called
transuranic
elements
have
been
made
in
this
way
in
particle
accelerators.
In
this
unit
you
will
learn
to:
-
24
-
Preliminary Dot-Points
Atomic structure
Jacaranda Chemistry 1
Chapter
2.1
Classifying
elements
pp.40-45
9.2.E
Syllabus
Dot-Points
Radioactive
decay
(fission)
and
nuclear
stability
distinguish
between
stable
and
radioactive
isotopes
and
describe
the
conditions
under
which
a
nucleus
is
unstable
identify
instruments
and
processes
that
can
be
used
to
detect
radiation
Radioisotope
production
Transuranic
elements
Industrial
uses
of
radioisotopes
Medical
uses
of
radioisotopes
-
25
-
9.2.E
Resources
Websites
Jacaranda Chemistry 2
Twig-World Video
Quarkology
9.2.E
Nuclear
Chemistry
http://www.quarkology.com/12-
chemistry/92-production-
materials/92E-nuclear-
chemistry.html
Chapter
Reference
Chapter
5
Nuclear
chemistry
and
radioisotopes,
pp.
93-106
Isotopes
http://australia.twig-
world.com/films/glossary/isoto
pe-520/
Radioactive
Substances
http://australia.twig-
world.com/films/radioactive-
substances-1532/
Radioactive
Half-Life
http://australia.twig-
world.com/films/radioactive-
half-life-1533/
Nuclear
Fission
http://australia.twig-
world.com/films/nuclear-
fission-1564/
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26
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Completed
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27
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