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Oleh:
Gde Parie Perdana 1113021059/VIIA
Putu Aya Mahadewi 1113021063/VIIA
x + dx
Suppose on the rod occur a longitudinal wave in the x direction, and stated elastic
displacement at point x is u(x). Strain is defined as;
du
..................................................................................1.1
dx
and stress is defined as force per unit area which is also a function of x, according to
Hooke's law, the stress depends on the strain in the form;
= . .......................................................................................1.2
where Y is known as the elastic constants Young's modulus. Using Newton's second law,
the dynamics of the stem segment dx experiencing thermal vibration can be derived as
follows;
.A.dx
S x dx S ( x)A ................................................................1.3
where the mass density of rods and a cross section through which the wave by writing
1
12,3 o
A is obtained as;
V
2u 2u
0 ...........................................................................................1.4
x 2 Y t 2
known as the one-dimensional wave equation. 4.4 Completion of the wave equation is
u( x, t ) A.eik.x.t ....................................................................................1.5
where k is the wave number ( k
k.v ...........................................................................................................1.6
where
..........................................................................................................1.7
Equation 1.6 which connects the frequency and wave number is called dispersion
equation. Equation 1.7 states that the speed of propagation of mechanical waves that occur
in a solid medium properties of solids which are influenced by the nature of the medium
elasticity and the mass density of the medium. Figure 1.2 shows the elastic wave dispersion
relation, which is a straight line whose slope (slope) equal to the speed of sound waves,
where linearly related to the k
=v.k
k
Gb. 1.2 relation of elastic wave dispersion
Equation 1.7 can also be used for Young's modulus. The measurement results show
a certain solids have a mass density = 5 gr/cm3 with a speed of 5 x 105 m/s has Y = 1,25
x 1012 gr/cm.s2.
2
The above equation is derived for a longitudinal wave, but the same way can also be
applied to transverse waves. In understanding the elastic waves as described above is used
as a solid approach to continuous isotropic medium, but in fact crystalline solids are not
isotropic (anisotropic) and the effect of non isotropic crystal leads to characteristic values
(Young's modulus, conductivity) of the crystal . To further understand the effects of non
isotropic crystal used mathematical approaches Tensor. For simplicity of further discussion
on the discussion of the solids used approach isotropic solids.
u( x) A.eik .x ................................................................................................1.8
Further discussion of the boundary condition (boundary condition) of equation 4.8.
The boundary condition resulting from the application of the external effects of the ends of
the rod. Type of boundary condition that is often applied is the periodic boundary condition,
namely the right end of the rod is restricted so as to have the same state oscillation with the
left end of the rod. Suppose the length of the rod is L by taking a point cloud on the left end
point of the rod, the periodic condition states;
u(x = 0) = u(x = L) .........................................................................................1.9
where is the solution of equation 1.8. When inserted into equation 1.9 obtained;
eik.L 1 .........................................................................................................1.10
This equation determines a state of acceptable values of k and k values only from
1.10 equation is exactly what allowed. Because ein.2 1 for every integer n, thus the
value of k that are permitted;
kn
2
.........................................................................................................1.11
L
with n = 0, 1, 2, 3, .... When these prices is depicted along the axis k, then
formed an irregular space points one dimension, as shown in Figure 1.3
1.3
3
Each price k equations or 1.11 each image point 1.3 declares a vibrate mode. Suppose
chosen a certain interval dk in k space and can then be determined from the number of
modes of vibration occur in the interval k. By taking L large enough, the points can be
viewed as a quasi-continuous. Since the distance between the points is .................. 2/L
then the number of modes vibrate in the interval dk is
dn
L
dk .....................................................................................................1.12
2
L
dk ..........................................................................................1.13
2
L dk
.
................................................................................................1.14
d
Equation 1.14 is a general equation for the one-dimensional case, which shows that
the density condition g() determined by the dispersion equation. For linear relationship
equation 1.6 d/dk = v so that the equation can be expressed;
L 1
. ....................................................................................................1.15
v
i (k x k y y k z z )
u ( x, y, z, t ) A.e x
A.eik.r ..................................................1.16
where wave propagation is described by the vector k indicates arh wave propagation
direction and the magnitude is inversely proportional to wavelength. In the discussion of
three-dimensional waves in the medium once again takes the effect of the boundary
conditions for three-dimensional. For simplification, review the discussion of threedimensional rods as a medium in the form of a cube whose sides are L. By applying the
periodic boundary condition, the obtained velue allowable k is eligible;
4
i(k Lk y Lk z L)
e x
1 ....................................................................................1.17
ie value generated
kx , k y , kz nx 2L , n y 2L , nz 2L
............................................................1.18
space as shown Figure 1.4 each pair of the three value k x , k y , k z express a point in k
space stating an allowable vibration mode.
The volume of each point in k space is (2/L)3. The number of modes vibrate is the
same as the number of points k price pairs are allowed in the ball room. Volume of a sphere
which radius k is (4/3).k3, due to the volume of each point is (2/L)3 then the number of
modes of vibration are permitted in k space
L
N
2
3
V 4 3
4 3
k
k
3
2 3 3 .................................................................1.19
with V = L3 is the volume of the solid sample. 1.19 equation states that the sum of
all allowable wave that has a price k is smaller than a certain price and spread in every
direction. With 4:19 to lower the k equation is obtained
dN
2 3
4k 2dk .......................................................................................1.20
stating the amount of vibration mode in the spherical shell elements whose fingers
between k to (k + dk)
g ( )d
2 3
2
v3
d
..........................................................................1.21
Based on the equation of state of 1.21, the meeting of the vibrating modes allowable
wave frequency is
g ( )
2 3
2
v3
.....................................................................................1.22
From 1.22 equations show that g () increases with 2, unlike the one-dimensional
case where g () constant value does not depend on . This increase is the fact that the
volume of the ball element in Figure 4.4 increases to k2.
E / kT
dE
E.e
E
......................................................................................1.23
E / kT dE
e
E.e
E / kT dv.dx
........................................................................... 1.25
E
E / kT dv.dx
e
by including that expressed by the equation E 1.24 to equation 1.25 equations
obtained
2
2
1 mv2 1 Kx2 .e mv Kx / 2kT dv.dx
2
2
mv2 Kx2 / 2kT dv.dx
e
1m
2
2
2
1 m v 2emv / 2kT dv 1 K x 2e Kx / 2kT dx
2
2
mv2 / 2kT dv
Kx2 / 2kT dx
e
e
.................................1.26
By exampling
1 mv2
1 Kx2
2
2
2
y
z 2
kT and
kT
2kT 2
y
We get v 2
m
dv
2kT
dy ................................................................................................1.27
m
And
7
x2
dx
2kT 2
z
K
2kT
dz .................................................................................................1.28
K
by inserting equation 1.27 and the 1.28 to 1.26 equations resulting equations;
2
2
2
y
kT y e
dy kT z 2e z dz
E
2
2
y
z
e dy
e dz
........................................................1.29
equation is a form of special functions known as shape functions Gama. 1.29
equations used to complete the following formula;
2e 2 d
and
2 d
e
............................................1.30
E 1 kT 1 kT kT
2
2
...................................................................................1.31
The average kinetic energy equal to the average potential energy is equal to 1 kT ,
2
so that the average vibrational energy of particles is equal to kT.
In statistical mechanics has been discussed that the vibration of a particle in one
dimension has two degrees of freedom, one degree of freedom associated with each of the
two modes is the energy possessed by 1 kT . Thus for the three-dimensional vibration each
2
particle will have three degrees of freedom, each degree of freedom will contribute an
average vibrational energy of kT. So that every vibration of a particle in three dimensions
would contribute an average energy of 3 kT.
The amplitude of a harmonic vibration is the maximum displacement on either side
of the equilibrium position. When x = A, then all the energy in the form of potential energy
2kT
.....................................................................................................1.32
K
U
cv
........................................................................................................ 1.34
T V
Thus, the specific heat of the solids obtained
cv = 5.97 kkal/kmole.K ......................................................................................... 1.35
Dulong and Petit then show experimental results that the specific heat of solids at
room temperature and greater temperature is cv 3R, known as the Dulong-Petit law.
However, the Dulong-Petit law failed to account for the specific heat of light elements such
as boron, beryllium and carbon like diamond, each of which has a specific heat respectively
3.34, 3.85 and 1.46 kcal / kmole.K at room temperature. Even the Dulong-Petit law also
fails to explain the specific heat of all solids were down sharply as a function of T3 at low
temperatures near zero at temperatures near 0 K. Figure 1.4 shows how the change of
specific heat against T for several types of solids. The two failures of the Dulong-Petit law
is a very serious failure of the experimental results.
7
Lead
CV (kkal/kmole.K)
Aluminum
Silicon
Carbon
(diamond)
4
3
2
1
0
200
400
600
800
Absolute Temperature (K)
1000
1200
10
E e
n 0
En / kT
............................................................................................... 1.37
En / kT
n 0
Factor e En / kT known as the Boltzmann factor, which represents the probability of the
oscillator has energy state En. By inserting equation 1.36 to 1.37 and the equation 1.37
expressed in the form
E / kT
E
ln e n
1/ kT n0
Therefore, the summation inside the logarithm will be infinite geometric series. By
summing the series and differentiated then obtained the average energy per oscillator
according to Einstein is
h.
.................................................................................................. 1.38
eh / kT 1
U 3N o E
3No.h.
.................................................................................... 1.39
eh / kT 1
From the equation 1.39 can be determined molar specific heat of solids is
2
eh / kT
U
h
cv
.......................................................... 1.40
3R
T V
kT h / kT 2
1
e
To give an interpretation of the equation 1.40, for the high temperature at which the
prevailing circumstances h << kT so
eh / kT 1
h
................................................................................................. 1.41
kT
Because e x 1 x
x2 x3
molar specific heat obtained cv 3R , which corresponds to the Dulong-Petit law. For the
low temperature h >> kT then e h / kT 1 so that the equation 1.40 becomes
E h.e h / kT ...................................................................................................... 1.42
Which shows that the average energy down exponentially with decrease in temperature
solids. From equations 1.42, can be derived molar specific heat of solids, which produce
11
2
h h / kT
..................................................................................... 1.43
cv 3R e
kT
Which indicates that the molar specific heat of solids down exponentially with decrease in
temperature solids. Einstein's formulations cv down near zero at very low temperatures, as
opposed to the Dulong-Petit law.
Einstein also argued that the possibility of a oscillator harmonic energy is
En n 1 .h
2
(n = 0, 1 , 2, ) ...................................................................... 1.44
Equation 1.44 states that the oscillator in the ground state has an energy h means that
the energy of the ground state is not equal to zero as obtained from the classical discussion
above. The ground state energy h known as zero-point energy. The existence of zero
point energy does not affect the analysis of the specific heat of solids due to the zero-point
energy is not dependent solids temperature.
2 3
2
v3
4 . 2
n d 3 d .............................................................................................. 1.45
v
12
With v is the speed of the wave. In solids, there are two types of waves that can occur are
longitudinal waves and transverse waves, each of which has a different speed rates are vl
and vt, further there are two directions of polarization of transverse waves, so the statement
2 2
1
n d 4 d ............................................................................... 1.46
v3 vt3
l
Average energy of elastic waves that occur can be obtained from the equation 1.36
developed by Einstein. In the calculation of the total energy by the Debye frequency elastic
waves is restricted from 0 until D known as maximum frequency or the Debye frequency.
Thus the energy in solids is
2 D
h 3
1
U 4V .
d ................................................................ 1.47
h
/
kT
v3 vt3
e
1
l
0
The upper limit is the maximum frequency of a particular frequency D who interpret the
fact that it cannot happen to infinity standing waves in solids or solids will have a certain
energy. Debye assumed that the total number of standing waves in solids is 3No. So from
equations 1.46 obtained
2 D 2
1
3No 4V . d
v3 vt3
l
0
4 1
2 3
V 3 3 . D
3 vl vt
1
9N 0
....................................................................................... 1.48
D
1 2
4V 3 3
vl vt
9 N0 D
U
.
3
D
h 3
d .................................................................................. 1.49
h / kT
e
1
0
13
To further simplify the form of the integral equation 1.49 is more appropriate change
variables to a dimensionless quantities x where x
defined Debye characteristic temperature
kT
h
which d
dx , in addition
kT
h
h D
. In x and equation 1.49 become
k
x3
T 4 D x3
U 9 N o k 3 . x dx 9R .
dx ................................................... 1.50
0 e 1
3 0 ex 1
T4
T 3 / T x3dx
1
U
........................................ 1.51
cv
9 R 4 . x
0 e 1 T e / T 1
T V
Equation 1.51 shown that specific heat is function T/. Next to the two extremes of
temperature, state of high temperature and low temperature can explained as follows.
For high temperature then T/ is very small so e / T 1 / T then obtained
1
1
1 and
/T
T e
1 T 1 1
T
/T
x 3 dx
e x 1
/T
1
x 2 dx
3 T
x dx
0e
4
15
Results shown equation 1.52 shows that the calculation results according to the
experimental results stating that the specific heat of solids as a function of T3. At moderate
temperature, specific heat of solids according to the Debye formula to calculated
numerically. Interchangeability of specific heat of solids to the T/ according to the Debye
theory shown in Figure 1.7
14
CV (kkal/kmole.K)
6
5
4
3
2
1
T/
0
0,5
1,0
1,5
2,0
2,5
Figure 1.7 Changes in specific heat of the T/ according to the Debye theory
15