2014- Chemistry

1.

Which one of the following properties is not

statement is true about these solutions, assuming

shown by NO?

all salts to be strong electrolytes?

2. (1) It combines with oxygen to form nitrogen

24. (1) 0.125 M Na3PO4 (aq) has the highest

3.
4.
5.
6.
7.

dioxide
(2) Its bond order is 2.5
(3) It is diamagnetic in gaseous state
(4) It is a neutral oxide

osmotic pressure.
25. (2) 0.500 M C2H5OH (aq) has the highest
26.

pressure.
27. (4) 0.100 M Mg3(PO4)2(aq) has the highest

If Z is a compressibility factor, van der Waals

equation at low pressure can be written as :
Pb
Z 1
RT
8.

11.

29.

(2)
Z 1

9.
10.

osmotic pressure.
28.

Pb
Z 1
RT

(1)
RT
Pb

Z 1

(3)

30.
31.
32.
33.
34.
35.
36.
37.

(4)

of an aqueous solution of its salts is :

15.

(1) Cu
(3) Ag

(2) Cr
(4) Ca

38.

(1) (a), (c)

(3) (a), (b)

(2) (b), (d)

(4) (c), (d)

In SN2 reactions, the correct order of reactivity for

the following compounds : CH3Cl, CH3CH2Cl,

. The specific conductance of the solution is 1.4

(CH3)2CHCl and (CH3)3CCl is :

S m1. The resistance of 0.5 M solution of the

39.

same electrolyte is 280 . The molar conductivity

(CH3)3CCl
40.
(2) (CH3)2CHCl > CH3CH2Cl > CH3Cl >

16.
17.

(1) 5 103
(3) 5 104

(CH3)3CCl
42.
(4) CH3Cl > CH3CH2Cl > (CH3)2CHCl >

CsCl crystallises in body centred cubic lattice. If a

(CH3)3CCl
43.

is its edge length then which of the following

expressions is correct ?

rCs rCl
20.

44.

wavelengths in the region of red, green, yellow

(2)

and blue, respectively. The increasing order of

ligand strength of the four ligands is :

rCs rCl 3a

3
rCs rCl a
2

rCs rCl 3a
21.
22.

(3)

Consider

(4)
separate

The octahedral complex of a metal ion M 3+ with

four monodentate ligands L1, L2, L3 and L4 absorb

3
a
2

(1)

(1) CH3CH2Cl > CH3Cl > (CH3)2CHCl >

(CH3)3CCl
41.
(3) CH3Cl > (CH3)2CHCl > CH3CH2Cl >

(2) 5 102
(4) 5 103

18.

23.

(a) H2O2 + 2H+ + 2e 2H2O

(b) H2O2 2e O2 + 2H+
(c) H2O2 + 2e 2OH
(d) H2O2 + 2OH 2e O2 + 2H2O

Resistance of 0.2 M solution of an electrolyte is 50

of 0.5 M solution of the electrolyte in S m2 mol1 is

19.

In which of the following reactions H 2O2 acts as a

reducing agent?

a
VRT

The metal that cannot be obtained by electrolysis

12.
13.
14.

osmotic pressure.
(3) They all have the same osmotic

solutions

of

45.

(1) L3 < L2 < L4 < L1

(2) L1 < L2 < L4 <

L3
46.

(3) L4 < L3 < L2 < L1

(4) L1 < L3 < L2 <

L4
47.
0.500

48.

For the estimation of nitrogen, 1.4 g of an organic

C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M

compound was digested by Kjeldahl method and

KBr(aq) and 0.125 M Na3PO4(aq) at 25C. Which

the evolved ammonia was absorbed in 60 mL of

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M
10

70.
OH
COCH 3

sulphuric acid. The unreacted acid required

M
10

20 mL of

71.

(1)

(2)

OCOCH 3

sodium hydroxide for complete

neutralization. The percentage of nitrogenin the

COOH

compound is :

52.

49.
50.
51.

(1) 3 %
(3) 6 %

(2) 5 %
(4) 10 %

The

equivalent

conductance

of

OCOCH 3
COOH

NaCl

at

concentration C and at infinite dilution are C and

72.

(3)

(4)

OH

, respectively. The correct relationship between

COCH 3

C and is given as : (where the constant B is

positive)
COCH 3

C
53.

(1) C = (B)

(2) C =

73.

chloroform and ethanolic potassium

C
+ (B)
54.
(3) C = + (B) C
55.
56.
57.

74.
75.

61.
62.
63.

COOH

LiAlH 4

PCl 5

Alc KOH

(1) Ethylene

83.

chloride
65.
(3) Acetaldehyde
66.

(2)

(1) it contains Cs3+ and I ions.

(2) it contains Cs+, I and lattice I2

The equation which is balanced and represents

84.

(1)

Mg H2 O 6

85.

(2) CuSO4 + 4KCN K2[Cu(CN)4] +

Excess NaOH

Mg EDTA

6H2O

Cl
88.
89.

The major product C would be:

EDTA

K2SO4
86.
(3) Li2O + 2KCl 2LiCl + K2O
87.
(4) [CoCl(NH3)5]+ + 5H+ Co2+ + 5NH4+ +

H
C
AC2O

68.

JTJEE

The correct statement for the molecule, CsI3, is :

(4) Acetylene

pressure at 125C yields a product which on

69.

(4) an alkanediol

the correct product(s) is :

Acetyl

Sodium phenoxide when heated with CO2 under

acetylation produces C.
ONa
O
125
+ CO 2
5 Atm

an

molecule.
80.
(3) it is a covalent molecule.
81.
(4) it contains Cs+ and I3 ions.
82.

the product C is :
64.

67.

(3) an alkanol

78.
79.

(2) 1
(4)

In the reaction,

H3C

(2)

76.
77.

(1)
(3) 1

(1) an alkyl cyanide

alkyl isocyanide

meaning then the value of x is : (assuming

ideality)

hydroxide,

the organic compound formed is :

(4) C = (B)C

For the reaction SO2(g) + O2(g) SO3(g).

if KP = KC(RT)x where the symbols have usual

58.
59.
60.

On heating an aliphatic primary amine with

For which of the following molecule significant

0?

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Cl

113.

Which series of reactions correctly represents

chemical

relations

related

to

iron

and

its

compound?
114.

Cl

(a)

90.

(b)

(1)

Fe

Cl2 ,heat

115.

FeCl
3

heat,air

FeCl2

Zn

Fe

(2)

CN

Fe

Fe
3 O 4

O2 ,heat

116.

CO,6000 C

Fe

dilH2SO4

117.

Fe

OH

91.

(c)

(d)

CO,7000 C

Fe

(3)

CN
OH

FeO

FeSO4

H2SO4 ,O2

Fe2 SO4 3

heat

Fe

(4)

O2 ,heat

FeO

dilH2 SO4

FeSO 4

heat

Fe

118.
119.

Considering the basic strength of amines in

aqueous solution, which one has the smallest pKb

SH

value?
120.

95.
96.

(1) Only (c)

(3) Only (a)

(2) (c) and (d)

(4) (a) and (b)

122.
123. Which one of the following bases is not present in

For the non-stoichiometre reaction

2A + B C + D, the following kinetic data were

DNA?
124.

obtained in three separate experiments, all at 298

Thymine
125.

K.

Adenine

97.
Initial
concentration (A)

98.
Initial
Concentration (B)

100.

0.1 M

101.

103.

0.1 M

104.

106. 0.2 M

107.

109.

The rate law

99.
Initial
127.
rate of formation
of C (mol L
0.1 M
102.
1.2
103
0.2 M
105.
1.2
103
0.1 M
108.
2.4
103 131.
for the formation of

C is :
dc
2
k A B
dt

110.

(1)

dc
k A
dt

(2)
dc
k A B
dt

111.
112.

JTJEE

(2) C6H5NH2
(4)

CH3NH2

SH

92.
93.
94.

(1) (CH3)3N
121.
(3) (CH3)2NH

(3)

dc
2
k A B
dt

(4)

(1) Cytosine

(2)

(3) Quinoline

(4)

126.
The correct set of four quantum numbers for the
valence electrons of rubidium atom (Z = 37) is :
128.
1, +
129.
130.

(1) 5, 1, 1, +

(3) 5, 0, 0, +

(2) 5, 0,
(4) 5,1, 0, +

The major organic compound formed by the

reaction of 1, 1, 1 trichloroethane with silver
powder is :
132.

(1) 2 Butyne

(2) 2

133.

(3) Acetylene

(4)

Butene
Ethene
134.

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135. Given below are the half cell reaction :

136.
137.
138.
139.
140.
141.
142.
143.
144.

2+

Mn + 2e Mn; E = 1.18 V
2(Mn3+ + e Mn2+); E = +1.51 V.
The E for 3Mn2+ Mn + 2Mn3+ will be
(1) 0.33 V ; the reaction will not occur
(2) 0.33 V ; the reaction will occur
(3) 2.69 V ; the reaction will not occur
(4) 2.69 V ; the reaction will occur

145. The ratio of masses of oxygen and nitrogen in a

particular gaseous mixture is 1 : 4. The ratio of
(1) 1 : 8
(3) 1 : 4

cH, for the reaction will be: (R = 8.314 kJ mol1)

(1) 1460.50 kJ mol1

(2) 1350.50 kJ

(3) 1366.95 kJ mol1

(4) 1361.95 kJ

mol
164.

165. The most suitable reagent for the conversion of

(1) Teflon
(3) Dacron
the

following

(2) Acrylonitrile
(4) Neoprene
oxoacids,

decreasing order of acid strength is :

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Assuming ideality the Enthalpy of combustion,

mol
163.

(2) 3 : 16
(4) 7 : 32

polymer?

153. Among

bomb calorimeter, is 1364.47 kJ mol1 at 25C.

149. Which one is classified as a condensation

150.
151.
152.

(1) HClO4 > HClO3 > HClO2 > HOCl

(2) HClO2 > HClO4 > HClO3 > HOCl
(3) HOCl > HClO2 > HClO3 > HClO4
(4) HClO4 > HOCl > HClO2 > HClO3

159. For complete combustion of ethanol,

160. C2H5OH (l) + 3O2 (g) 2CO2 (g) + 3H2O (l),
161. the amount of heat produced as measured in

162.

number of their molecule is :

146.
147.
148.

154.
155.
156.
157.
158.

the

correct

RCH2OH RCHO is :
166.
167.
168.
169.
170.

(1) CrO3
(2) PCC (Pyridinium Chlorochromate)
(3) KMnO4
(4) K2Cr2O7

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1. 2. 3. 4. 5. 6. 7. 8. 9. 10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.
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172.
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184.
185.
186.
187.
188.
189.
190.
191.
192.
193.
194.
195.
196.
197.
198.
199.200.

3 4 4 3 1 3 2 4 4 4 1 4 1 3 2 4 3 2 2 2 3 3 3 1 3 4 4 1 3

201.
202.
203.
204.
205.
206.
207.
208.
209.
210.
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212.
213.
214.
215.
216.
217.
218.
219.
220.
221.
222.
223.
224.
225.
226.
227.
228.
229.230.
231.

JTJEE

BBSR Centre, Counseling House, 218, Ground Floor, Dharma Vihar, Near
Khandagiri,
Bhubaneswar-751030, Ph: 0674-2351980, E-mail: info@jtjee.com, www.jtjee.com