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Introduction of Perfect matematerial absorber

1 Introduction of absorbing layers


An absorber is a kind of device in which all incident radiation is absorbed. That
is to say, all wave actions such as reflection, transmission, scattering, and other light
propagation are impossible. The most typical EM wave absorber is so called Salisbury
screen[1] which is developed by the well know scientist W. W. Salisbury as a basic
example of the resonant absorber. Such a device consists of two layers, a resistive
sheet to absorb EM wave and a metal plate to reflect the wave [1].
As reference [2] summarized, another similar absorber device is Jaumann
absorber in which has more than one resistive sheet are placed in front of the
mental ground plate in order to achieve a broadband response.[3] Circuit Analog
absorber also have more than one resistive sheet to achieve absorption at high
incidence angle[4,5] and over broad bands[6].
Another two type of resonant EM wave absorber are Dallenbach layer employs
consists of a homogeneous layer in front of mental plate[2]; Crossed Grating absorber
uses a reflective metal plate with an etched shallow periodic grid[7, 8].

2. Introduction of Metamaterial Perfect Absorbers (MPA)


Metamaterials are artificial structural materials composed of metals and
dielectrics arranged in a periodic way. Owing to its tailored property, e.g., permittivity
and permeability, metamaterials have been found many applications such as
invisibility cloak [9-12], sub-wavelength imaging [13, 14], perfect lens [15,16] and perfect
absorber[17-39].
The most famous metamaterial perfect absorber unit cell is so called three
layered structure, which consists of two metallic layers, one ground plane and a varied
shaped electric ring resonator (ERR) separated by a dielectric layer. The ERR on the
top of the dielectric layer couples strongly to uniform electric field of the incidence
wave, but weakly to magnetic field, providing frequency dependent electric response

(). The magnetic field of incident waves will penetrate the space between the ERR
and back metallic ground plane, leading to a frequency dependent magnetic response

(). One can tuned the effective () and () through adjusting the dimension of
the ERR, back ground plane and the space gap between them. Thus realize the perfect
impedance matching between the absorber and free space and minimize the reflection
near to zero. Simultaneously, by varying the imaginary part of the material
permittivity to achieve large loss and minimize the transmission near to zero. The
resulting absorption A, is calculated A()=1-R()-T(), where R() is the refection
and T() is the transmission, approximately equal to zero.
Generally, when electromagnetic wave incident the boundary between metal and

dielectric layer and satisfy the surface electromagnetic wave(SEWs) propagation


conditions which write as k1=k0, where k1 is the real part of the wave vector parallel
to the surface some SEWs propagate along the surface. In optics the surface wave are
termed surface plasmon wave because there exists an interaction between the free
electron in the metal layer and the electromagnetic waves. These surface waves
propagate but they are damped too and we have to determine how they propagate and
how they are damped. The last term play the most important role when we dealing
with absorbers.
The way that SEWs propagates can be determined from the so-called dispersion
characteristic, the key parameter being the velocity of the waves propagating along
the surface k=k1+ik2 and the propagate length is described as Lp=1/2k2,[40] which
characterise the penetration intensity of the SEWs or plasmon decays by 1/e. If k2 is
carefully selected, the SEWs be in form of loss, and Lp is perfectly matched k1=k0, so
as to reduce the reflection and transmission and reach to nearly unit absorption.
To analyze the absorption feature, one most important concept is the operation
bandwidth characterized by the full wave at half maximum (FWHM), which defined
f
as FWHM=
100% , where f 0 is the centre frequency of the incident wave of the
f0
absorption spectrum, f f 2 - f1 , is the frequency gap when the absorption reduce to
half of the maximum value.

3 State of the art in terms of absorbance and fractional bandwidth,


thickness.
Since the first metamaterial(MM) perfect absorber is demonstrated by N. I.
Landy et al[17], numerically and experimentally, which consists of three layers,
operated at microwave, science, including the design, analysis and experiment of
MM absorber, grow rapidly at microwave[17-26], THz[29,30], infrared [27,28,29,31-35,38] and
visible [36,37,39]wavelength with varied structure.
In case for the absorber operated in the microwave region, the general method is
to build split ring resonators( electric field coupled(ELC))connected to a split-wire
the magnetic coupling required a more complicated arrangement, and thus in order
to couple to the incident H-field, we needed flux created by circulating charges
perpendicular to the propagation vector.. In a word, the absorber cell mainly contents
two elements, of which one responds to the electric-field the other responds to the
magnetic field.
Then multiple of such units are arranged orderly onto a substrate. For modifying
and optimizing the absorption properties, such as the absorption ratio and the location
of the absorption peak, the respond to polarized wave and incident wave with
arbitrary angular, firstly one have to carefully choose material for fabricating the

absorber unit, and then the shape (ring or quadrate) with proper structure parameters
such as length, height and the gap between these two elements, and the last work is
how to compile this elements.
Fig. 3.1 shows the absorber unit cell with a ring shape and a quadrate shape.
Experimentally can achieve an absorption of 88% which have a little error compared
to the simulation results, and the authors explained that due to fabrication errors.

Fig. 3.1 Electric resonator, magnetic resonator, unit cell


and results of a metamaterial perfect absorber.[17]

Ref. [20] demonstrated a perfect absorber using non-magnetic metamaterials,


which functions as a black body and be able to effectively absorb incident waves
from all directions. The unit cell used here consists of an I-shaped unit and an ELC
resonator illustrated in Fig.3.2. Based on this unit cells, the mainly difference from the
other metamaterial absorber is that this absorber is formed by orderly compiling these
I-shaped unit and ELC resonators into a ring disc, thus all the incoming wave with all
direction and be effectively trapped and consequently spirally travels inside the disc
as shown in Fig.3.2.

Fig. 3.2 Unit cell and the electric field distribution at resonance frequency 18GHz[20]

Aside from the mainstream idea of arraying those absorber units into a two
dimension plate, Ref.[18] demonstrated an 3-dimension absorber based on a cubic
with three absorber units on each surface, of which the unit cell is formed by
combining an electric resonators with a magnetic resonator, but not the split-wire mentioned
above. The unit cell and result are show in Fig.3.3.

Fig. 3.3 unit cell of 3-diemention and the absorption spectrum[18]

Comparing with the absorbers operating in microwave band, the typical unit cells
used for constructing the infrared absorbers are with a cross shaped geometries [29,
30] and the detail structures are show as Fig. 3.4. As a development from this type of
cells, Ref[31] Fig. 3.4 shows a H shaped nanoresonator, based on which a narrow
band, polarization-independent absorptivity of >90% over a wide 50 angular range
centered at mid-infrared wavelengths of 3.3 and 3.9 m was achieved.

Fig. 3.4 simulation structure of cross unit cell and low-magnification field emission scanning
electron microscope image and the experimental and simulation absorption results [29, 30,31]

The other method for realizing IR absorb is by generating surface plasma using a
so called Plasmonic metamaterials (MMs). Generally, a narrow band absorber(NBA)
is fabricated by sandwiching an array of plasmonic strips[28]/patches[27] by a thin
dielectric spacer from a ground plate, show in Fig.3.5 and the absorb ratio at the peak
can be up to nearly 100%. For expanding the absorb band, one can combining several

NBAs with their absorption peaks being close to each other[28]. Apart from the
approach based on plasmonic material used above, Kamil Boratay Alici and etc.
demonstrated a polarization independent absorber utilizing both electrical and
magnetic impedance matching at the near-infrared regime, the half absorption width
of which is as large as 893nm, and when the incidence angles is up to 60respecting
to the surface of the plane, the absorption still remains more than 70% .

Fig. 3.5 Geometry of the sample and measured and simulated absorbance spectra [27,28]

As another wave band, visible wavelength has attracted much attention in recent
years. Similar to the mechanism exploited in infrared absorbers, the Plasmonic
material is also widely used for realizing visible light absorb. Developing from grating
configuration, Koray Aydin and etc. proposed a visible light absorber consisting of a
metalinsulatormetal stack with a nanostructured top silver film composed of
crossed trapezoidal arrays, whose absorption ranges from 400nm~700nm, covering
the entire visible spectrum. On the other hand, Peng Zhu and L. Jay Guo also realized
an absorber with the same absorption range and an average absorption of more than
80% by designing the dispersion and geometry of a Cu/Si3N4/Cu stack[36]. Show as
Fig. 3.6(left).
Additionally, a perfect black absorber operating in visible regime was also
demonstrated by using the Plasmonic material, but different from the stripe and cross
structure used in the above approaches, the nanocomposite-SiO2-Gold film-Glass
substrate multi-layers structure designed in this work is relatively simple and cost
effectively.[39] Show as Fig.3.6(right).
In conclusion, the absorbers operating at microwave regime mainly constructed
by orderly arraying a great deal of unit cells that generally formed by electric
resonators with cut wire or magnetic field resonators and, each of the unit cell with
certain structure parameters could provide an absorption peak. Different from the

mechanism utilized in the microwave absorbers, plasmonic materials are intensively


used for realizing a broadband absorption in infrared and visible regime. Additionally,
the absorption properties (bandwidth, absorptivity, location of the absorption peak or
band) greatly depend on the fixed material of the matematerial and the structure of the
unit cells. Considering that the effective permittivity e(x) and permeability l(x) of the
metamaterial can be independently changed by modifying the geometry of its unit cell,
it is possible to realize an efficient absorption in different frequency bands with
perfect absorption ability by designing unit cells with an optimized structure using a
material with perfect electro-magnetic properties respecting to a target operating wave
band[25].

Fig. 3.6 Geometry of the sample and measured and simulated absorbance spectra [36,39]

Generally, a single SRR type absorber exhibits one corresponding absorption


peak. So its reasonably to suppose that multi-absorption peaks can be achieved by
combining multi-SSR units with different resonance peaks together.
Based on the former mechanism mentioned above, a three absorption bands
absorber were realized by adjacently placed multiple unit cells, which comprises an
electric ring resonator and a pair of crossed wires imprinted on the opposite faces of a
dielectric substrate, with different resonant resonances together. As shown in Figure
3.7, three types of resonances were placed together as a unit and the corresponding
resonances are shown in Figure.3.7(left). [23]

Fig. 3.7unit cell of multy-band metamaterial


absorber and the simulation results[23]

Beside the proposal for achieving multi-peaks absorption, Jingping Zhou and
etc.
have proposed a metamatrerial absorber based on a cross-circular-loop
resonator, of which the absorption effect can be easily altered form single-band to
dual-band by adjusting the positions of the shorted stubs inside the loop. Show as Fig.
3.7(right).
[26]

When it comes to the absorption bandwidth of the absorber, one can also extend
it by overlapping multi-SRRs with multiple absorption peaks, but the frequency peak
differences among each SSR should not be big. Ref. [24] shows an absorber
constructed by overlapping multiple ELC and SRR layers show as Fig. 3.8(above). A
maximum absorption of 99.9% at 2.4 GHz with a relative broad half maximum
bandwidth (700MHz) was achieved, which was contributed by the different
resonances provided by multiple elements. Additionally, the resistors embedded in the
metamaterial structure effectively lower the Q factor.

Fig.3.8 broad band absorption structure and results[24,29]

Based on the interference theory that is also used in Ref. [29], a metamaterial
absorber with a multilayered SRRs structure was numerically demonstrated to be with
an ultra broad band absorption of 60Hz, ranging from 0Hz to 70Hz with a bandwidth

of absorptance >90%, which is originated from the destructive interference of the


reflection wave based on the anti-reflection formed by the SRR and substrate together,
but not the intrinsic electromagnetic resonance loss. Show as Fig. 3.8(below)In
contrast to the perfect absorber realized by exploiting the coherent effect of among
SRRs, herein the resonance was mainly used for providing an optimal refractive
index for forming the destructive interference, rather than for realizing an effective
absorber by itself with its insufficient loss[21].
Similar to the method of combining multi-absorber units with single absorption
peak for realizing multiband absorption, a microwave[25] and infrared[32]
rization-independent absorption with an width band and an absorption of nearly 7GHz
and more than 90%, respectively, was realized by an pyramids structure formed by
periodically overlapping 20 metal-dielectric quadrangular frustum layers. Show as Fig.
3.9, in the left is operated at microwave, in the right one is operated at infrared wave.

Fig. 3.9 pyramid structure for broad band absorber and results[25,32]

4 Optimization of PMA
Although lots of works about PMA explored the very affirmative results of high
absorbance with broad band spectrum, it is a perpetual issue to optimize the PMA. For
one thing to reach to unit absorption under the condition of perfect impendence
matched determined by the thickness and loss tan of the absorber. One the other hand,
in order to achieve broad band absorbance through designing multiresonance in planar
and stack structure[23-26,29,30,32] or useing broadband periodic structure like
grating[27,28,36].
Additionally, operation flexible is another significant element, including
polarization independence, broad incidence angle, and selected waveband. There are
three kinds of method to realize polarization independence by appealing to repeat of
unit cells[20,41,42]; by utilizing an asymmetric unit cell[26]; by using chiral
metamaterials[43].

5 Conclusion and prospects


As conclusion, we have experimentally design a perfect electromagnetic
absorber using BST cube with high permittivity. The experiment results show great
agreement with the simulation we have done before, and the absorptive very close to
100% with FWHM around 4% at Mie resonance frequency. It is notably that the

absorption characters are significantly influenced by the lattice period, space gap and
loss tangent. In other word, we can optimize the BST absorber through adjusting the
geometry and BST local properties.

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