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Department of Earth and Space Sciences, University of Washington, Seattle, WA 98195, USA
School of Environmental Science, University of Ulster, Coleraine, UK
c
Space Science Institute, Boulder, CO 80301, USA
d
United States Geological Survey, Flagstaff, AZ 86001, USA
b
a r t i c l e
i n f o
Article history:
Received 26 January 2015
Revised 7 April 2015
Accepted 13 April 2015
Available online 18 April 2015
Keywords:
Aeolian processes
Mars, surface
Mineralogy
Mars
a b s t r a c t
Sediment maturity, or the mineralogical and physical characterization of sedimentary deposits, has been
used to identify sediment sources, transport medium and distance, weathering processes, and paleoenvironments on Earth. Mature terrestrial sands are dominated by quartz, which is abundant in source
lithologies on Earth and is physically and chemically stable under a wide range of conditions.
Immature sands, such as those rich in feldspars or mac minerals, are composed of grains that are easily
physically weathered and highly susceptible to chemical weathering. On Mars, which is predominately
mac in composition, terrestrial standards of sediment maturity are not applicable. In addition, the martian climate today is cold and dry and sediments are likely to be heavily inuenced by physical weathering rather than chemical weathering. Due to these large differences in weathering processes and
composition, martian sediments require an alternate maturity index. This paper reports the results of
abrasion tests conducted on a variety of mac materials and results suggest that mature martian sediments may be composed of well sorted, well rounded, spherical polycrystalline materials, such as basalt.
Volcanic glass is also likely to persist in a mechanical weathering environment while more fragile and
chemically altered products are likely to be winnowed away. A modied sediment maturity index is proposed that can be used in future studies to constrain sediment source, paleoclimate, mechanisms for sediment production, and surface evolution. This maturity index may also provide insights into erosional and
sediment transport systems and preservation processes of layered deposits.
2015 Elsevier Inc. All rights reserved.
1. Introduction
Mineralogical and physical characterization of sediment grains
on Earth has been an important area of study that has signicantly
increased understanding of sediment source, transport medium
and distance, weathering processes, and paleoenvironments (e.g.,
Bagnold, 1941; Folk, 1951, 1954; Suttner and Dutta, 1986; Weltje
and von Eynatten, 2004; Garcia et al., 2004). The term sediment
maturity has been commonly applied to clastic deposits on Earth
and describes composition as well as grain texture (Folk, 1951;
Boggs, 2006). Sediment maturity refers to the degree to which sediment has been modied by physical and chemical processes. In
general, mature sediment grains are those that are well rounded,
well sorted (consisting of similar sizes), and composed of minerals
that are resistant to aqueous and physical weathering (Folk, 1951;
Pettijohn, 1975). The majority of mature terrestrial sands are dominated by quartz, which is abundant in source lithologies on Earth
and is physically and chemically stable under a wide range of
conditions.
On Mars, however, terrestrial standards of sediment maturity
are not applicable due to the martian surface having a predominantly mac composition (e.g., Christensen et al., 2000;
Bandeld, 2002; Bibring et al., 2005). The presence of mac minerals indicates sediment immaturity under terrestrial conditions
because many common mac minerals are highly susceptible to
chemical weathering, softer than quartz, and may include a wider
assemblage of minerals that contain cleavage planes, making them
less durable during physical transport. The martian climate today
is cold, dry and dominated by wind-blown (aeolian) activity.
Signicant aqueous activity on the martian surface is thought to
have ended early in the planets history with geologic evidence
relating to liquid water on the surface dating to over 3 billion years
ago (e.g., Carr and Head, 2010). Thus, modern martian sediments
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2. Sediment samples
The natural terrestrial samples used for this study are mac
sands collected from South Point Beach, Hawaii; Hilo, Hawaii;
and the Moses Lake dune eld in Washington. The Hawaiian sediments are predominantly composed of olivine (South Point) and
volcanic glass (Hilo; Moberly et al., 1965; Marsaglia, 1993). The
Moses Lake sediment is composed of granodiorite and basalt grains
with minor smectite alteration products (Bandeld et al., 2002).
Natural sediment samples were collected and chosen for analysis
based on the composition and environment in which they were
weathered and deposited. The Hawaiian beach sand samples range
in size from 420 lm (South Point) to 560 lm (Hilo) and originate
from a humid environment, where aqueous activity dominates.
The olivine grains of South Point are thought to originate from lava
phenocrysts or crystal ejecta in tuffs from Mauna Loa lava ows
(Moberly et al., 1965) ranging in age from <200 ka to approximately 400 ka (Sharp et al., 1996). These olivine grains were
weathered out of basalt and tuff deposits and subsequently transported to the beach primarily by uvial activity. The volcanic glass
grains originate from Mauna Loa lava ows as well but were
produced when lava came in contact with the ocean and rapidly
cooled (Moberly et al., 1965). The Moses Lake dune eld sand grain
sizes average 237 lm and originate from a relatively arid environment. The basaltic dune sand originated from the Quincy Basin,
where sediment was deposited by one or more of the Missoula
or Channeled Scabland ood events that scoured the underlying
Columbia Basalts between 17,000 and 12,000 years ago (Bretz
et al., 1956; Nummedal, 1978). These sediments were subsequently reworked by aeolian processes. For the purposes of this
study, only weathering textures of basaltic grains were analyzed
from the Moses Lake sediments. Grains of basalt were manually
separated from the granodiorite particles under a microscope.
The abrasion samples were used to determine physical durability of common materials on Mars as well as to provide a comparison to terrestrial quartz-rich sediments. The variety of mac
minerals and volcanic materials were chosen based on remote
sensing observations of Mars. The surface of Mars is predominantly
basaltic in composition and comprised of minerals rich in magnesium and calcium (e.g., Bandeld, 2002). Therefore, the materials
chosen for this study include olivine (forsterite), clinopyroxene
(augite), plagioclase (labradorite), volcanic glass and ne-grained
basalt from the Columbia River Basalt Group volcanic deposits.
The varieties of silica-rich samples that were used to relate abrasion results to familiar terrestrial materials include crystalline
quartz, polycrystalline quartz, and microcrystalline chert.
15
4pA=P2 ;
where A is the area of the grain silhouette and P is the perimeter of
the grain. Roundness values close to 1 indicate that a grain is well
rounded. Sphericity measurements are calculated by dividing the
width by length of the grain (minimum extension divided by the
maximum extension). Values close to 1 indicate that a grain shape
is highly spherical.
In addition, the amount of material being abraded during the
abrasion tests was recorded for the homogenous samples.
Sediment samples were weighed prior to abrasion and in-between
each abrasion run and recorded as the percentage of material lost
to equalize between variances in mineral properties and small differences in sample weights.
3.4. Grain surface textures
Fig. 1. Figure adapted from Nitkiewicz and Sterner (1988) showing design and
dimensions (in mm) of Bond air mill. The modied air mill used in this study has
similar dimensions and is composed entirely of silicon carbide with copper tubing
for the air entrance but lacks guidepins.
16
Fig. 3. Graphs of grain shape changes during homogenous abrasion tests including
grain size (A), sphericity (B), and roundness (C) vs abrasion time. Colors represent
olivine (green), Columbia River Basalt (red), volcanic glass (black), augite (orange),
and labradorite (violet). Volcanic materials are plotted as circle symbols with solid
lines; minerals containing cleavage planes are triangles with dot-dashed lines;
olivine is represented as a diamond symbol with a solid line. Solid points joined by
lines in (A) represent the 50th percentile value of the sample. Solid points joined by
lines in (B) and (C) represent average values of shape parameters. Hollow points
represent the minimum value of the sample and correspond to the shape and color
of the solid points. Capped lines above solid points show the maximum value for
each mineral sample. (For interpretation of the references to color in this gure
legend, the reader is referred to the web version of this article.)
17
Fig. 4. (A) Grain size vs% material passing a particular sieve size, (B) sphericity (b/l)
vs sample volume percent, and (C) rounding (SPHT) vs sample volume percent of
crystalline quartz (light blue squares), microcrystalline chert (medium blue
triangles), polycrystalline quartz (dark blue circles), Columbia River Basalt (red
circles), volcanic glass (black triangles), and olivine (green diamonds) after two
hours of abrasion. (For interpretation of the references to color in this gure legend,
the reader is referred to the web version of this article.)
The rapid changes in grain size and morphology within the rst
15 min of abrasion are due to the rounding and chipping of jagged
edges and, for some minerals, cleaving along planes of weakness.
This process creates multiple small grains and the rate of material
lost declines as grains attain a more physically stable, spherical
form.
Olivine was the least durable material abraded of the homogenous samples. It has a similar Mohs hardness to quartz with identical fracture habits but may be more susceptible to abrasion due
to differences in crystalline structure and density (Willetts,
1983). Minerals that possess cleavage planes, such as labradorite
and augite, were moderately durable and abraded into thin, elongate, tabular grains. A comparison between different forms of
quartz showed discrepancies in abrasion rates. Crystalline quartz
(from a single crystal), as used in this experiment, was found to
abrade more rapidly than polycrystalline quartz. Polycrystalline
quartz is composed of multiple quartz crystal fragments of variable
grain sizes and, in the case of chert, the grains are composed of
microscopic crystal fragments. Previous studies have shown that
mono-crystalline structures are less durable during physical
transport than polycrystalline forms due to the formation of
18
Fig. 6. Minerals in a heterogeneous basaltic mixture at various stages of abrasion (45 min, 225 min and 540 min). Minerals shown here include Columbia River Basalt (CRB),
olivine (ol), labradorite (Plag), augite (CPX), volcanic glass (VG), and Phyllosilicate (PS) and are from the same experiment batch. These images correlate with results shown in
Fig. 5. We considered grains after 45 min of abrasion to represent an immature texture and composition; 225 min represents mature grains; and 540 min represents
supermature grains where only basalt and volcanic glass remain with highly spherical shapes.
Fig. 7. Chemical and physical weathering textures of terrestrial grains (Krinsley and Doornkamp, 1973; Marshall et al., 1987). (A) Aqueous pitting due to chemical weathering
on an olivine grain from South Point Beach, Hawaii. (B) scratches due to abrasion on the same olivine grain. (C) Gas vesicles and chipping on the surface of a volcanic glass
grain from Hilo, Hawaii. (D) Fracture on the surface of a basalt grain from Moses Lake.
19
Fig. 9. Textural and compositional maturity index for mac sediments on Mars.
Materials with high physical durability are polycrystalline basalt and volcanic glass.
Materials indicating immature sediments contain minerals with cleavage planes
that weaken physical durability. Olivine may indicate a local or more regional
source depending on the other minerals present in the sediment. Fig. 6 displays
examples of immature, mature and supermature grains produced during abrasion
experiments.
Fig. 8. Differences in grain textures of basalt grains. (A) Unabraded Columbia River
Basalt grain. (B) Abraded Columbia River Basalt after 14 h of abrasion. (C) Basalt
grain from Moses Lake dune eld.
20
6. Conclusion
Abrasion of a variety of mac materials indicates that mature
martian sediments are likely composed of very well sorted, well
rounded, spherical poly-crystalline basalt grains (Figs. 6 and 9).
Any volcanic glass present is also likely to persist in this environment (Figs. 6 and 9) while chemically altered products are likely
to be weathered locally or in situ. Immature sediments are likely
to contain minerals with cleavage planes and be poorly sorted,
sub rounded and angular (Figs. 6 and 9). The presence and relative
abundance of olivine may be used as an index mineral, indicating
local and regional sources as well as sediment maturity and relative deposit age.
As grain surface textures in arid environments on Earth appear
to be heavily inuenced by aqueous interaction, grain surfaces are
likely to have rougher textures because physical weathering processes have dominated the surface of Mars for the past 3 billion
years.
Acknowledgments
Special thanks to Dave McDougall for help involving equipment
training and sample preparation in the laboratory, Dr. Hanson Fong
for SEM sample preparation, and Mike Harrell for donating some
mineral samples and use of his modied Bond air mill which made
this study possible. This research was partially funded by a
University of Washington departmental research grant in the
department of Earth and Space Sciences. Any use of trade, rm,
or product names is for descriptive purposes only and does not
imply endorsement by the U.S. Government.
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