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Select form type to navigate to the emission calculator for the source type:

Company Name:

Note: Don't forget to enable macros.

Insert Company and/or site name here.


Choose form type:

Blowdown and/or process vents

Throughout this workbook:

Boilers and Heaters

Input variables into the blue boxes.

Compressor engines

Emissions will be in the green boxes.

Flares
Frac tanks
Glycol dehydrators

To be notified of any updates to this workbook:

Loading
Piping component fugitive areas
Separators
Condensate storage tanks
Crude oil storage Tanks
Produced water storage tanks
Turbines
Other:
Non-flare combustive device
Complete a form for each piece of equipment (listed above) that meets one of the
following criteria for 2009:
Emitted 1 ton or more of NOx,
Emitted 1 ton or more of volatile organic compounds (VOC), or
Emitted 0.1 tons per year or more of a hazardous air pollutant (HAP)
If individual pieces of equipment do not meet the requirements listed above, they
may be omitted from the inventory provided that the total emissions from all such
unreported sources are:
less than 5 tons of NOx,
less than 5 tons of VOC, and
less than 1 ton of aggregate HAPs
If the total emissions from the omitted pieces of equipment do not satisfy these
requirements, report each source starting with the piece of equipment with the
highest emissions until the total emissions of the remaining omitted sources
satisfy the above requirements.

The Barnett Shale Special Inventory list server has been created to distribute
messages about the agencys special inventory efforts in the Barnett Shale area.
If you haven't already done so, we recommend you subscribe to this list server
to receive any important updates concerning the inventory, including this
emission calculator. To do so, you will need to create a profile with the
TCEQs distribution service, GovDelivery.com, so that you can add and
manage your subscriptions. To create a profile or update your current
subscriptions, please visit: http://service.govdelivery.com/ service/user.html?
code=TXTCEQ.

VENTING EMISSION CALCULATION (for blowdowns, starter vents, gas operated controllers, etc):

Barnett Shale Phase II Identification Information:


Company Name:
Insert Company and/or site name here.
Blowdown #:
Company's Unique
Identification Number:

Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*
TOTALS:

Input variables into the blue boxes


Emissions will be in the green boxes.

Molecular
Weight grams per
(grams/m 100 moles
ole)
of gas
28.01348
0

mole %
Gas Analysis:

Back to Workbook Navigation Tab.

weight %
#DIV/0!

44.0095

#DIV/0!

34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16
106.16
156.31

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

0.0000

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value, or if
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match
the lab analysis.

VOC content of total gas sample (VAPOR)


VOC weight% =

#DIV/0!

VOC weight fraction = #DIV/0!


(VOC: total sample)
HAP content of gas sample
Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =

Molecular Weight of Gas = 0


Specific Gravity of Gas = 0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

lb/lb-mole or grams/mole

1 lb-mole of gas = 379.48322 SCF


Enter Venting Volume per Event (SCF):
Enter number of events per year:

(standard cubic feet)

tpy
VOC emissions:
benzene
toluene
ethylbenzene

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

xylene
n-hexane (C6)

#DIV/0!
#DIV/0!

Report Total VOC emissions


on Blowdown(s) tab.
Report HAP emissions on
Blowdown(s) tab or HAP
speciation tab if the values are
greater than or equal to 0.1
tpy.

at STP (standard temperature (60F) and pressure (14.696


psia))

Heater and Boiler Emission Calculations (fueled by natural gas)


Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Heater or Boiler #:
Company's Unique Identification
Number:

Input variables into the blue boxes


Emissions will be in the green boxes.

Heater/Boiler rating (MMBtu/hr):


Rating above is (select from list):

pick from list

Operating hours/year:
Fuel Heat Value (Btu/SCF):
pollutant
VOC
NOX

emission factor (lb/MMCF)*


5.5

tpy
#DIV/0!

#DIV/0!

* Emission Factors from AP-42, Chapter 1, Tables 1.4-1 and 1.4-2.

Back to Workbook Navigation Tab.

Engine Emission Calculations (fueled by natural gas)

Back to Workbook Navigation


Tab.

Barnett Shale Phase II Identification Information:


Company Name:

Insert Company and/or site name here.

Input variables into the blue boxes

Engine #:

Emissions will be in the green boxes.

Company's Unique
Identification Number:
Notes:
The TCEQ preference for emission factor sources:

Horsepower:

1. Stack test data from the engine

Fuel consumption (Btu/hp-hr):

2. Manufacturer's specification sheet and control specification


sheet (if control used)

Hours of operation per year:


Type of engine (select from
list):

pick from list

Engine Load:

pick from list

If available, enter
stack test or
manufacturer's
emission factor
(g/hp-hr)
VOC
NOX
Formaldehyde

3. AP-42 emission factors


(If no stack testing or manufacturer's emission factors are
available, the spreadsheet will automatically use appropriate AP42 factors based on the type of engine and load.)

Appropriate
AP-42 factor (From
AP-42 Section 3.2)
0.0296
2.21
0.0205

emission factor
used
units
0.0296
lb/MMBtu
2.21
lb/MMBtu
0.0205
lb/MMBtu

If present, enter the


efficiency of any
control device
(ex: catalytic
Annual
Uncontrolled
Uncontrolled
converter)
Emissions
lb/hr
tpy
(%)
(tpy)
Contaminant
0.0000
0.0000
0.000
VOC
0.0000
0.0000
0.000
NOx
0.0000
0.0000
0.000
Formaldehyde*
* If formaldehyde emissions are greater than or equal to 0.1 tpy,
report the emission rate on the Phase II form.

If bold, value is greater than or equal to 0.1 ton and should be included on
the "HAPS >=0.1" Tab in the Barnett Shale Phase II workbook for this piece
of equipment.
If VOC factor used
above was a non-APIf VOC factor used
42 factor (stack test
above was from AP- or manufacturer), use
42, use this column this column to check
Hazardous Air Pollutant (HAP): to check for HAPs
for HAPs
1,1,2,2-Tetrachloroethane
Choose Engine Type
Choose Engine Type
1,1,2-Trichloroethane
Choose Engine Type
Choose Engine Type
1,2,4-Trimethylbenzene
Choose Engine Type
Choose Engine Type
1,2-Dichloropropane
Choose Engine Type
Choose Engine Type
1,3-Dichloropropene
Choose Engine Type
Choose Engine Type
2,2,4-trimethlypentane
Choose Engine Type
Choose Engine Type
Acenaphthylene
Choose Engine Type
Choose Engine Type
Acetaldehyde
Choose Engine Type
Choose Engine Type
Acrolein
Choose Engine Type
Choose Engine Type
Benzene
Choose Engine Type
Choose Engine Type
Biphenyl
Choose Engine Type
Choose Engine Type
Carbon Tetrachloride
Choose Engine Type
Choose Engine Type
Chloroform
Choose Engine Type
Choose Engine Type
Ethylbenzene
Choose Engine Type
Choose Engine Type
Ethylene Dibromide
Choose Engine Type
Choose Engine Type
Fluoranthene
Choose Engine Type
Choose Engine Type
Methanol
Choose Engine Type
Choose Engine Type
Methylene Chloride
Choose Engine Type
Choose Engine Type
n-Hexane
Choose Engine Type
Choose Engine Type
Naphthalene
Choose Engine Type
Choose Engine Type
Phenanthrene
Choose Engine Type
Choose Engine Type
Phenol
Choose Engine Type
Choose Engine Type
Pyrene
Choose Engine Type
Choose Engine Type
Styrene
Choose Engine Type
Choose Engine Type
Toluene
Choose Engine Type
Choose Engine Type
Vinyl Chloride
Choose Engine Type
Choose Engine Type
Xylene-u
Choose Engine Type
Choose Engine Type

% (AP-42 speciated/total)
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type

Flare

Back to Workbook Navigation


Tab.

Barnett Shale Phase II Identification Information:


Company Name:
Insert Company and/or site name here.
Flare #:

Notes:
Input variables into the blue boxes
Emissions will be in the green boxes.

Company's Unique
Identification Number:

Instructions are shaded.

General Information

Emission Factors
Emission Factors from TCEQ Guidance (lb/MMBtu)

(1) What type of flare is


this? Pick from list.

non-steam assisted flare with high Btu stream flared


Emission Factors for Waste Gas Stream(s) (lb/MMBtu)
NOx
0.138

(2) Is there one or more


continuous pilot streams?
Pick Yes or No. Follow
instructions below.

Non-steam assisted, high Btu


NOx
0.138

Steam assisted, high Btu


NOx
0.0485

Non-steam assisted, low Btu


NOx
0.0641

Steam assisted, low Btu


NOx
0.068

Yes
Emission Factors from AP-42 Table 1.4-1
and 1.4-2 (lb/MMscf)
Enter pilot stream information into the boxes in the column for
Stream No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream.
Emission Factors for Pilot Stream (lb/MMscf)
NOx
100

(3) Is there an added fuel


stream? Pick Yes or No.
Follow instructions below.

NOx

Emission Factors from AP-42 Table 1.4-3 (lb/MMscf)

100

Total VOC
benzene

5.5
2.10E-03

toluene
ethylbenzene
xylene

3.40E-03
0 none listed
0 none listed

No
n-hexane

1.8

Enter zeros into the boxes in the column for Stream No. 2 below.
Emission Factors for Added Fuel Stream (lb/MMBtu)
NOx
0

(4) VOC percent destruction


efficiency (%)

98

Stream Information
Stream Sent to Flare No.
Enter Names of Each
Stream sent to the flare
Here

Pilot(s)

Added
fuel

ex: oil tank

ex: water tank

ex: glycol ex: amine


unit vent unit vent

ex: glycol
unit flash
tank

ex: amine unit


flash tank

ex: truck
loading

10

11

12

Annual Volumetric Flow


Rate of Stream (scf/yr)

Heat Value of Stream


(Btu/scf)
Uncontrolled VOC and HAP
Emissions for each of these
stream
Total VOC Annual Emissions
(tpy)
benzene Annual Emissions
(tpy)
toluene Annual Emissions
(tpy)
ethylbenzene Annual
Emissions (tpy)
xylene Annual
Emissions
(tpy)
n-hexane
Annual
Emissions
(tpy)
other HAP (fill in name)
Annual
Emissions
(tpy)
other
HAP
(fill in name)
Annual Emissions (tpy)

#DIV/0!

Pilot(s)

Added
fuel

ex: oil tank

ex: water tank

ex: glycol ex: amine


unit vent unit vent

ex: glycol
unit flash
tank

ex: amine unit


flash tank

Annual
Emissions
(tpy)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

ex: truck
loading

Total for all


Streams
0
0
0
0
0
0
0
0

Flare Total Emissions

NOX
Total VOC
Benzene
Toluene
Ethylbenzene
Xylene(s)
n-hexane
other HAP
other HAP

Total for all


Streams

Report NOx and Total VOC on the "Flare(s)" tab in the Phase II workbook.

Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other
HAPs on the Phase II workbook if they are 0.1 tpy on the "Flare(s)" tab.

Frac Storage Tank


Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Frac Tank#:
Company's Unique
Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working

Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com

Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp

Controlled Emissions [ton/yr]

Back to Workbook Navigation


Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ing and flash losses.

Flash losses

Total Emissions

Valid Methods for Condensate (Use one of the


following accepted methods):
Direct Measurement of Emissions
Process Simulator Models
the gas/oil ratio (GOR) method
Flash losses
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

VOCs, C3+
0.0000
Benzene
0.0000
Toluene
0.0000
E benzene
0.0000
Xylenes
0.0000
n-C6
0.0000
2,2,4 - Trimethylpentane
0.0000
Any Additional HAP (if applicable):
0.0000
0.0000
0.0000
0.0000

Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane

tons per year


0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Report VOC emissions on


Frac Tank(s) Tab.

Report HAP emissions on


Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal
to 0.1 tpy.

Report VOC emissions on


Frac Tank(s) Tab.

Report HAP emissions on


Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal
to 0.1 tpy.

Glycol Dehydrator Emission Calculations


Company Name:
Still#:

Insert Company and/or site name here.

Company's Unique Identification Number:


There are two options that are used most commonly to determine the emissions from a glycol dehydrator.
Please chose the option you prefer:
GRI-GLYCalc Software Program
Rich/Lean Analysis

GRI-GLYCalc Program

Run the software program making sure to using a wet gas analysis for your input. This analysis should include an extended ga

The total emissions for a glycol dehydrator should include both the "Controlled Regenerator Emissions" or "Uncontrolled Regen
present and if the flash tank is not 100% controlled with the recycled/recompression option). By reviewing the GRI-GLYCalc Ag
emissions.
Click to see example reports:
Controlled regenerator with flash tank
Uncontrolled regenerator with flash tank
Uncontrolled regenerator vent with a flash tank with recycle/recompression option

Uncontrolled/ Controlled Regenerator Emissions


Component
tpy
Propane
Isobutane
n-butane
Isopentane
n-pentane
cyclopentane
n-hexane
cyclohexane
other hexanes
heptanes
methylcyclohexane
2,2,4 Trimethylpentane
Benzene
Toluene
Ethylbenzene
Xylene(s)
C8+ Heavies
Total VOC

Rich/Lean Analysis

Flash Gas Emissions


Component
Propane
Isobutane
n-butane
Isopentane
n-pentane
cyclopentane
n-hexane
cyclohexane
other hexanes
heptanes
methylcyclohexane
2,2,4 Trimethylpentane
Benzene
Toluene
Ethylbenzene
Xylene(s)
C8+ Heavies
Total VOC

Using a laboratory analysis of enriched and lean glycol samples that includes benzene, toluene, ethylbenzene and xyl
following information.
Glycol recirculation rate (gal/min)
Annual hour of operation (hr)
Component
Total VOC
n-hexane
2,2,4 Trimethylpentane
Benzene
Toluene
Ethylbenzene
Xylene(s)
Additional HAPs

Rich (mg/L)

Lean (mg/L)

tpy
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

Equation used in Rich/Lean Analysis:


(Crich - Clean) * Qrecirc * t * 3.785 L/gal * 60 min/hr * lb/453,600 mg * ton/2,000 lb = tpy
Where:
Crich = concentration of the contaminant in rich sample
Clean = concentration of the contaminant in lean sample
Qrecirc = glycol recirculation rate (gal/min)
t = annual hours of operation

Back to Workbook Navigation


Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes
Instructions for using this form.

ycol dehydrator.

nalysis should include an extended gas analysis that includes but not limited to BTEX.

or Emissions" or "Uncontrolled Regenerator Emissions" and the "Flash Gas Emissions" (if the flash tank is
n). By reviewing the GRI-GLYCalc Aggregate Calculations report you will be able to determine your total

ecompression option

sh Gas Emissions
tpy

Total Glycol Still Emissions


Component
tpy
Total VOC
0
Benzene
0
Toluene
0
Ethylbenzene
0
Xylene(s)
0
2,2,4 Trimethylpentane
0
n-hexane
0

zene, toluene, ethylbenzene and xylene(s), complete the

ading Emission Calculations

Back to Workbook
Navigation Tab.

on LL = 12.46* SPM/T from AP-42, Chapter 5, Section 5.2-4

e Phase II Identification Information:


Insert Company and/or site name here.

Notes:
Enter variables into blue boxes
Emissions will be in green boxes
Use these cells to convert data, completion is optional.

for your convenience (completion is optional)


T
Temperature in
Rankine (R):
459.67

Enter Barrels of Gallons of liquid per


Liquid per year
year:
0
List additional HAPs if present and
percentages:

Composition of Material Loaded

True Vapor
Molecular
Pressure (P)
Weight (M)
Temperature in
Saturation Factor (S) (See
(psia)
below table(lb/lb-mole)
for list of options) Rankine (R)

Annual Loading
Rate
(gallons/year)

Total VOC Percentage


(This should be 100% unless
produced water is being

Control Efficiency (%)* See discussionloaded)


below before applying
% Benzene
an efficiency. % Ethylbenzene
0
0
0
0
0
0
0
0
0
0
0
0
0

tpy
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

% Toluene

% Xylene(s) % n-Hexane

100
100
100
100
100
100
100
100
100
100
100
100
100

Report VOC emissions on "Loading" Tab.

Report Benzene, Ethylbenzene, Toluene, Xylene, and n-hexane on the Phase II


calculator if they are greater than 0.1 tpy on the "Loading" tab.

Report any Additional HAPs if they are greater than or equal to 0.1 tpy.

Note: According to AP-42, 5.2-6, if a control is being claimed (such as from a VRU or flare), even though the control device may have a very high efficiency, not all the truck vapors actually get there (due to leaks). See
the following
control
limitations:
Can
assume for
99.2%
of loading
emissions get to control device if tanker truck passes the MACT-level annual leak test (not more than 1 inch water column pressure change in 5 minutes after pressurizing to 18 inches
water followed by pulling a vacuum of 6 inches water).
Can assume 98.7% of loading emissions get to control device if tanker truck passes the NSPS-level annual test (3 inches pressure change)
Otherwise, can only assume 70% of loading emissions reach the control device.

###
###
###
###
###
###
###
###
###
###
###
###
###
###

Fugitives Emission Calculations


Back to Workbook Navigation
Tab.

Complete this form for each type of each stream type.


Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Fugitive Area #:

Notes:
Input variables into the blue boxes
Emissions will be in the green boxes.

Company's Unique
Identification Number:
Gas Analysis:

mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*

Molecular
Weight
(grams/mole)
28.01348

grams per
100 moles
of gas
weight %
0
#DIV/0!

VOC content of hydrocarbon fraction only (VAPOR)

44.0095

#DIV/0!

VOC weight% =

#DIV/0!

34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16
106.16
156.31

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

VOC weight fraction =

#DIV/0!
(VOC:THC)

TOTALS:
0.0000
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

HAP content of gas sample


Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Liquids Analysis:

mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene

Molecular
Weight
(grams/mole)
28.01348

grams per
100 moles
of gas
weight %
0
#DIV/0!

VOC content of hydrocarbon fraction only (LIQUIDS)

44.0095

#DIV/0!

VOC weight% =

#DIV/0!

34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

VOC weight fraction =

#DIV/0!

HAP content of gas sample


Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

xylenes (M, P, O)
undecanes (C11+)*

106.16
156.31

TOTALS:
0.0000
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

0
0
0

#DIV/0!
#DIV/0!
#DIV/0!

Fugitives Emission Calculations


LDAR Program (Choose
from list)

Back to Workbook Navigation Tab.

Please choose from the following:

Gas

Gas

number

component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other

emission factor
(kg/hr per
component)*
0.0045
0.0024
0.0002
0.00039
0.002
0.0088

emission factor
(lb/hr of TOC per
component)
0.00992
0.00529
0.00044
0.00086
0.00441
0.01940
Total:

lb/hr
0
0
0
0
0
0
0

tpy
0
0
0
0
0
0
0

Light Oil

VOC
content* (wt
%)
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Benzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Toluene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Ethylbenz
ene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Xylene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

n-hexane
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Control
Efficiency
(%)
0
0
0
0
0
0
Total:

Light Oil

number

component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other

emission factor
(kg/hr per
component)
0.0025
0.013
0.00021
0.00011
0.0014
0.0075

emission factor
(lb/hr of TOC per
component)
0.00551
0.02866
0.00046
0.00024
0.00309
0.01653
Total:

lb/hr
0
0
0
0
0
0
0

tpy
0
0
0
0
0
0
0

Heavy Oil

VOC
content*
(%)
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Benzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Toluene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Ethylbenz
ene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Xylene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

n-hexane
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Control
Efficiency
(%)
0
0
0
0
0
0
Total:

Heavy Oil

number

component
Valve
Pumps**
Connector
Flange
Open-ended Line
Other**

emission factor
(kg/hr per
component)
0.0000084
0.0000075
0.00000039
0.00014
-

emission factor
(lb/hr of TOC per
component)
0.0000185
0.00113
0.0000165
0.0000009
0.0003086
0.0000683
Total:

lb/hr
0
0
0
0
0
0
0

tpy
0
0
0
0
0
0
0

Water/Oil

VOC
content*
(%)
100.0000
100.0000
100.0000
100.0000
100.0000
100.0000

Benzene

Toluene

Ethylbenz
ene

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

Xylene

n-hexane

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

Control
Efficiency
(%)
0
0
0
0
0
0
Total:

Water/Oil

number

Annual Emission Totals


Contaminant
Total VOC
Benzene

component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other

tpy
#DIV/0!
#DIV/0!

emission factor
(kg/hr per
component)
0.000098
0.000024
0.00011
0.0000029
0.00025
0.014

emission factor
(lb/hr of TOC per
component)
0.0002161
0.0000529
0.0002425
0.0000064
0.0005512
0.0308649
Total:

lb/hr
0
0
0
0
0
0
0

tpy
0
0
0
0
0
0
0

VOC
content*
(%)
100.0000
100.0000
100.0000
100.0000
100.0000
100.0000

Report Total VOC emissions on the "Fugitives" tab.

Benzene

Toluene

Ethylbenz
ene

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

Xylene

n-hexane

0.0000
0.0000
0.0000
0.0000
0.0000

0.0000
0.0000
0.0000
0.0000
0.0000

Control
Efficiency
(%)
0
0
0
0
0
0
Total:

Toluene
Ethylbenzene
Xylene(s)
n-Hexane

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Report Benzene, Ethylbenzene, Toluene,


Xylene, and n-hexane on the Phase II
calculator if they are greater than 0.1 tpy on
the "Fugitive(s)" tab.

Emission factors are for oil and gas production facilities (not refineries), and come from the EPA's "Protocol for Equipment Leak Emission Estimates" November 1995, EPA 4531,
R-95-017, Table 2-4.
Emission factors that are not based on the EPA document are from the TCEQ "Air Permit Technical Guidance for Chemical Source Equipment
Leak Fugitives (Draft October 2000)
* For fugitive calculations, VOC content should be VOC content of total hydrocarbons, not of total sample.

VOC

Benzene

Toluene

Ethylbenzene

Xylene

n-hexane

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000

VENTED SEPARATOR EMISSION CALCULATION

Back to Workbook Navigation


Tab.

For separators that vent to the atmosphere under normal operating conditions. This does not
include separators that vent to the atmosphere through a pressure relief valve only under upset
conditions.
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Separators #:
Company's Unique
Identification Number:

Input variables into the blue boxes


Emissions will be in the green boxes.

Gas Analysis of separator vent gas:

mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*
TOTALS:

Molecular
Weight grams per
(grams/m 100 moles
ole)
of gas
28.01348
0
44.0095
0
34.08188
0
16.04246
0
30.06904
0
44.09562
0
58.1222
0
58.1222
0
72.14878
0
72.14878
0
86.17
0
100.2
0
114.23
0
128.26
0
142.29
0
78.11
0
92.14
0
106.16
0
106.16
0
156.31
0
0.0000
0

weight %
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value. If
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match
the lab analysis.

VOC content of total gas sample (VAPOR)


VOC weight% = #DIV/0!
VOC weight fraction = #DIV/0!
(VOC: total sample)
HAP content of gas sample
Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =

Molecular Weight of Gas = 0


Specific Gravity of Gas = 0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

lb/lb-mole or grams/mole

1 lb-mole of gas = 379.48322 SCF


Enter Venting Volume (SCF):

(standard cubic feet)


tpy

VOC emissions:
benzene
toluene
ethylbenzene

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

xylene
n-hexane (C6)

#DIV/0!
#DIV/0!

Report Total VOC emissions


on Separator(s) tab.
Report HAP emissions on
Separator(s) tab or HAP
speciation tab if the values are
greater than or equal to 0.1
tpy.

at STP (standard temperature (60F) and pressure


(14.696 psia))

Condensate Storage Tank

Gas condensate is defined as a liquid hydrocarbon with an API gravity greater than 40 at 60F (and a specific gravity les
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Condensate Tank#:
Company's Unique
Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working

Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com

Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp

Controlled Emissions [ton/yr]

at 60F (and a specific gravity less than 0.8252).

Back to Workbook Navigation


Tab.

Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ing and flash losses.

Flash losses

Total Emissions

Valid Methods for Condensate (Use one of the following


accepted methods):
Direct Measurement of Emissions
Process Simulator Models
the gas/oil ratio (GOR) method
Flash losses
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane

ook Navigation
ab.

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
HAP (if applicable):
0.0000
0.0000
0.0000
0.0000

Report VOC emissions on


Condensate Tank(s) Tab.

Report HAP emissions on


Condensate Tank(s) tab or
HAP speciation tab if the
values are greater than or
equal to 0.1 tpy.

tons per year


0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Report VOC emissions on


Condensate Tank(s) Tab.

Report HAP emissions on


Condensate Tank(s) tab or
HAP speciation tab if the
values are greater than or
equal to 0.1 tpy.

Crude Oil Storage Tank

Crude oil is defined as heavy, low volatility oil approximated by a GOR less than 1,750 cubic feet per barrel and an A

Barnett Shale Phase II Identification Information:


Company Name:
Insert Company and/or site name here.
Crude Oil Tank#:
Company's Unique Identification
Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working

Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com

Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes

Controlled Emissions [ton/yr]

n-C6
224Trimethylp

ubic feet per barrel and an API gravity less than 40.

Back to Workbook Navigation


Tab.

Notes:
Enter variables into blue boxes
Emissions will be in green boxes

d flash losses.

Flash losses

Total Emissions

Valid Methods for Crude Oil (Use one of the following


accepted methods):
Direct Measurement of Emissions
Process Simulator Models
Vasquez-Beggs correlation
Rollins, McCain, and Creeger correlations
the gas/oil ratio (GOR) method
Flash losses
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes

n-C6
2,2,4 - Trimethylpentane

ck to Workbook Navigation
Tab.

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

HAP (if applicable):

Report VOC emissions on Crude


Oil Tank(s) Tab.

Report HAP emissions on Crude


Oil Tank(s) tab or HAP speciation
tab if the values are greater than
or equal to 0.1 tpy.

0.0000
0.0000
0.0000
0.0000

tons per year


0.0000
0.0000
0.0000
0.0000
0.0000

Report VOC emissions on Crude


Oil Tank(s) Tab.

Report HAP emissions on Crude


Oil Tank(s) tab or HAP speciation
tab if the values are greater than
or equal to 0.1 tpy.

0.0000
0.0000

Report HAP emissions on Crude


Oil Tank(s) tab or HAP speciation
tab if the values are greater than
or equal to 0.1 tpy.

Produced Water Storage Tank


Barnett Shale Phase II Identification Information:
Company Name:
Produced Water Tank#:
Company's Unique Identification Number:

Insert Company and/or site name here.

Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0*
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html

Working

Breathing

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

*It is possible to create a mixture in the EPA TANKS program similar to the composition of the produced
water stored in the tanks (e.g., a mixture of 99% water and 1% condensate) to determine the emissions.

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com

Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp

Controlled Emissions [ton/yr]

Back to Workbook Navigation


Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes

ng and flash losses.

Flash losses

Total Emissions

Direct Measurement of Emissions


Process Simulator Models
the gas/oil ratio (GOR) method
Vasquez-Beggs correlation
Flash losses
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):

Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane

k Navigation

0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

HAP (if applicable):


0.0000
0.0000
0.0000
0.0000

Report VOC emissions on


Produced Water Tank(s)
Tab.

Report HAP emissions on


Produced Water Tank(s)
tab or HAP speciation tab if
the values are greater than
or equal to 0.1 tpy.

tons per year


0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Report VOC emissions on


Produced Water Tank(s)
Tab.

Report HAP emissions on


Produced Water Tank(s)
tab or HAP speciation tab if
the values are greater than
or equal to 0.1 tpy.

Turbine Emission Calculations (fueled by natural gas)

Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information:


Company Name:
Insert Company and/or site name here.
Turbine #:
Company's Unique Identification
Number:

Input variables into the blue boxes


Emissions will be in the green boxes.

Turbine rating (MMBtu/hr):


Operating hours/year:
pollutant
VOC
NOX

emission factor (lb/MMBtu)*


0.0021

tpy
0.000

0.32

0.000

* Emission Factors from AP-42, Chapter 3, Tables 3.1-1 and 3.1-2a.

Non-Flare Combustive Devices

Back to Workbook Navigation


Tab.

Barnett Shale Phase II Identification Information:

Notes:

Company Name:
Other #:
Company's Unique
Identification Number:

Input variables into the blue boxes


Emissions will be in the green boxes.

Insert Company and/or site name here.

Instructions are shaded.

General Information

Emission Factors

(1) What kind of device is


this? Enter a short
description of the device
type.

Emission Factors from AP-42 Table 1.4-1 and 1.4-2


(lb/MMscf)
Emission Factors for Waste Gas Stream(s) (lb/MMscf)
NOx
100

(2) Is there one or more


continuous pilot streams?
Pick Yes or No. Follow
instructions below.

NOx
Other Vendor Factor

Emission Factors from AP-42 Table 1.4-3


(lb/MMscf)

100

VOC
benzene
toluene

5.5
2.10E-03
3.40E-03

Yes
ethylbenzene
Enter pilot stream information into the boxes in the column for
Steam No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream.
Emission Factors for Pilot Stream (lb/MMscf)
NOx
100

(3) Is there an added fuel


stream? Pick Yes or No.
Follow instructions below.

0 none listed

xylene
n-hexane

0 none listed
1.8

Yes
Enter added fuel stream information into the boxes in the
column for Steam No. 2 below.
Emission Factors for Added Fuel Stream (lb/MMscf)
NOx
100

(4) VOC percent destruction


efficiency (%)

98

Stream Information
Stream Sent to Flare No.
Enter Names of Each
Stream sent to the flare
Here

Pilot(s)

Added
fuel

ex: glycol ex: amine


ex: oil tank ex: water tank unit vent unit vent

ex: glycol unit


flash tank

ex: amine unit flash


tank

10

11

12

Total for all


Streams

ex: truck
loading

Volumetric Flow Rate of


Stream (scf/yr)

Heat Value of Stream - from


program results or gas
analysis (Btu/scf)
Uncontrolled VOC and HAP
Emissions for each of these
stream
Total
VOC Annual Emissions
(tpy)
benzene Annual Emissions
(tpy)
toluene Annual Emissions
(tpy)
ethylbenzene Annual
Emissions (tpy)
xylene Annual
Emissions
(tpy)
n-hexane
Annual
Emissions
(tpy)
other HAP (fill in name)
Annual
Emissions
(tpy)
other
HAP
(fill in name)
Annual Emissions (tpy)

0
Added
fuel

Pilot(s)
-

ex: oil tank ex: water tank

ex: glycol
unit vent

ex: amine
unit vent

ex: glycol unit


flash tank

ex: amine unit flash


tank

Annual
Emissions
(tpy)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00

Total for all


Streams
0
0
0
0
0
0
0
0

Other Combustion Device


Total Emissions

NOX
Total VOC
benzene
toluene
ethylbenzene
xylene
n-hexane
other HAP
other HAP

ex: truck
loading

Report NOx and Total VOC on the "Other Source(s)" tab in the Phase II workbook.

Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other HAPs on
the Phase II workbook if they are 0.1 tpy on the "Other Source(s)" tab.

Flash Emission Calculation - Vasquez-Beggs Solution Gas/Oil Ratio Correlation Method

Back to Crude Oil Storage


Tank Tab.

(For Estimating VOC Flashing Emissions, Using Stock Tank Gas-Oil Ratios For Crude Oil Facilities)
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Tank#:

Notes:
Enter variables into blue boxes
Emissions will be in green boxes

Back to Workbook Navigation


Tab.

Company's Unique
Identification
Number:
INPUTS:
Stock Tank API Gravity
Separator Pressure (psig)
Separator Temperature (F)
Separator Gas Gravity at Initial Condition
Stock Tank Barrels of Oil per day (BOPD)
Stock Tank Gas Molecular Weight
Fraction VOC (C3+) of Stock Tank Gas
Atmospheric Pressure (psia)

CONSTRAINTS:
16
>API>
50
> P+Patm >
70
> Ti >
0.56
> SGi >
None
>Q >
18
> MW >
0.5
> VOC >
None
> Patm >

API
P
Ti
SGi
Q
MW
VOC
Patm

40
5250
295
1.18
None
125
1.00
None

API
(psia)
(F)
(MW/28.97)
(BOPD)
(lb/lb-mole)
fraction
(psia)

2070

(scf/STB)

OUTPUTS:
SGx = Dissolved gas gravity at 100 psig = SGi [1.0+0.00005912*API*Ti*Log(Pi/114.7)]
SGx =

0.00

Rs = (C1 * SGx * Pi^C2) exp ((C3 * API) / (Ti + 460))


Where:

Rs
SGx
Pi
API
Ti

APTI
C1
C2
C3
Rs =

Gas/Oil Ratio of liquid at pressure of interest


Dissolved gas gravity at 100 psig
Pressure of initial condition (psia)
API Gravity of liquid hydrocarbon at final condition
Temperature of initial condition (F)
Constants
API Gravity
< 30
>= 30
Given API
0.0362
0.0178
0.0362
1.0937
1.187
1.0937
25.724
23.931
25.724

0.00 scf/bbl

for P + Patm =

CONSTRAINTS:
20
> Rs >

THC = Rs * Q * MW * 1/385 scf/lb-mole * 365 D/Yr * 1 ton/2000 lbs


THC
Rs
Q
MW
385
THC =

Total Hydrocarbon (tons/year)


Solution Gas/Oil Ratio (scf/STB)
Oil Production Rate (bbl/day)
Molecular Weight of Stock Tank Gas (lb/lb-mole)
Volume of 1 lb-mole of gas at 14.7 psia and 68 F (WAQS&R Std Cond)
0.000 TPY

VOC = THC * Frac. of C3+ in the Stock Tank Vapor


VOC* =
0.00
TPY
from "FLASHING" of oil from separator to tank press
*Before reporting these emissions, make sure to review the Within Valid Range section to verify this method is valid for your conditions.

Within Valid
Range?
No
No
No
No
Yes
No
No
Yes

GOR Method for Estimating Flash Emissions


Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Tank#:
Company's Unique
Identification Number:
Enter variables into blue boxes
Emissions will be in green boxes
Gas Oil Ratio:
Barrels of Oil or Condensate per day:

in standard cubic feet of flash gas per barrel (SCF/bbl) of oil/condensate produced

This information is based on an analysis submitted by the applicant.

Flash Gas MW =

Flash Gas Speciation:

mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
hexanes (C6)
heptanes (C7+)*
octane (C8+)*
nonane (C9+)*
decane (C10+)*
benzene
toluene
ethylbenzene

molecular weight
(grams/mole)
28.01348
44.0095
34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.18
100
114.23
128.26
142.29
78.11
92.14
106.16

grams per 100


moles of gas
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

weight %
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Total gas emitted:


tpy:

VOC wt% =
Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =

Contaminant
Total VOC
benzene
toluene

TPY
#DIV/0!
#DIV/0!
#DIV/0!

xylenes (M, P, O)
undecanes (C11+)*

106.16
156.31
TOTALS:

0.0000

0
0
0

#DIV/0!
#DIV/0!
#DIV/0!

ethylbenzene
xylene
n-hexane (C6)

#DIV/0!
#DIV/0!
#DIV/0!

* If MW of heptanes plus is given, you can change the value in the table above.
* If the MW of the total sample is given, you can adjust the MW of heptanes+ until the "Flash Gas MW" value above equals the value on the lab report.

Back to Workbook Navigation


Tab.

es into blue boxes


ll be in green boxes

ate produced

Total gas emitted:


0

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

Report Total VOC emissions on the


appropriate tank tab.
Report HAP emissions on the
appropriate tank tab or HAP
speciation tab if the values are
greater than or equal to 0.1 tpy.

Report HAP emissions on the


appropriate tank tab or HAP
speciation tab if the values are
greater than or equal to 0.1 tpy.

Example First page of a GRI-GLYCalc Report:

Controlled Regenerator with Flash Tank

Controlled Regenerator Emissions section example:

Report these emissions as


the uncontrolled/controlled
regenerator emissions

Total VOC is 1.2836 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.

Flash Gas Emissions section example:

Report these emissions as


the flash tank emissions.

Total VOC is 0.0168 tpy for


the flash tank emissions for
this example.

Uncontrolled Regenerator with Flash Tank


Uncontrolled Regenerator Emissions section example:

Report these emissions as


the "uncontrolled/controlled
regenerator emissions".

Total VOC is 2.1251 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.

Flash Gas Emissions section example:

Report these emissions as


the flash tank emissions.

Total VOC is 0.0168 tpy for


the flash tank emissions for
this example.

Uncontrolled Regenerator with Flash Tank with recycle/recompression option


Uncontrolled Regenerator Emissions section example:

Report these emissions as


the "uncontrolled/controlled
regenerator emissions".

Total VOC is 2.1251 tpy for


this example for the
uncontrolled /controlled
regenerator emissions.

Flash Gas Emissions section example:


No emissions to report for flash
tank that is
recycled/recompressed. You
may leave this section blank or
enter zeros.

Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.

Back to Glycol Dehydrator Tab.

E&P Tank Example

Back to Condensate Tanks Tab.


Look for the "Calculation Results" Section of
the E&P Tank printout for emissions data.

Back to Crude Tanks Tab.

From the "Controlled [ton/yr]" column, read


the VOCs, C3+ emissions. This is your
Total VOC emissions. (For this example
74.897 tpy)

Back to Produced Water Tanks


Tab.

Report the Benzene through 2,2,4 Trimethylpentane


emissions.

Back to Frac Tanks Tab.

IC Engines List of Types


2 Stroke Lean
4 Stroke Lean
4 Stroke Rich

2 Stroke Lean
Nox (90-105% Load)
Nox (<90% Load)
CO (90-105 Load)
CO (<90% Load)
SO2

3.17
1.94
0.386
0.353
0.000588

VOC total
PM total
For Error Finding Only:
TOC
PM filterable
PM condensable
VOC Speciation C or better
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene
Biphenyl
Butane
Butyr/isobutyaldehyde
Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene

4 Stroke Lean 4 Stroke Rich


4.08
2.21
0.847
2.27
0.317
3.72
0.557
3.51
0.000588
0.000588

0.12
0.04831

0.118
0.009987

0.0296
0.01941

1.64
0.0384
0.00991

1.47
0.0000771
0.00991

0.358
0.0095
0.00991

2 Stroke Lean
6.63E-05
5.27E-05
3.91E-05
1.11E-04
4.46E-05
4.38E-05
2.14E-05
1.33E-06
8.46E-04
3.17E-06
7.76E-03
7.78E-03
7.18E-07
3.36E-07
1.94E-03
3.95E-06
4.75E-03
4.37E-04
6.07E-05
4.44E-05
4.71E-05
6.72E-07
3.08E-04
9.47E-05
1.08E-04
7.34E-05
3.61E-07

4 Stroke Lean 4 Stroke Rich BOILERS turbines


2.53E-05

1.43E-05

3.32E-05
1.25E-06
2.50E-04
5.53E-06
8.36E-03
5.14E-03

2.79E-03
2.63E-03

4.40E-04

1.58E-03

4.00E-05
6.40E-06

2.10E-03

1.20E-05

1.01E-04

6.93E-07
2.27E-04
3.97E-05
1.11E-06

3.20E-05

Fluorene
Formaldehyde
Isobutane
Methanol
Methycyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u

1.37E-06
5.52E-02
3.75E-03
2.48E-03
3.38E-04
1.47E-04
4.45E-04
3.08E-05
7.44E-05
1.53E-03
9.63E-05
3.53E-06
4.21E-05
2.87E-02
5.84E-07
5.48E-05
9.63E-04
2.47E-05
2.68E-04

5.67E-06
5.28E-02
2.50E-03
1.23E-03
2.00E-05
1.11E-03
1.10E-04
3.51E-04
2.60E-03
7.44E-05

2.05E-02

7.50E-02

4.12E-05

1.30E-06

4.19E-02
1.36E-06
4.08E-04
1.49E-05
1.84E-04

7.10E-04

5.58E-04
1.95E-04

3.40E-03

BOILER
Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Residential Furnaces - (< 0.3) Uncon
Small Boilers (<100 MMBtu/hr) - Co
Small Boilers (<100 MMBtu/hr) - Con
Small Boilers (<100 MMBtu/hr) - Unc
Tangential Fired Boilers (All) - Low
Tangential Fired Boilers (All) Uncon

NOX
100
140
190
280
94
50
32
100
76
170

CO
84
84
84
84
40
84
84
84
98
24

Digester Gas - Uncontrolled


Distillate Oil - Uncontrolled
Distillate Oil - Water-Steam Injection
Landfill Gas - Uncontrolled
Natural Gas - Lean Premix
Natural Gas - Uncontrolled
Natural Gas - Water-Steam Injection

TURBINES
Nox
CO
SO2
VOC total
PM total
For Error Finding Only:
PM filterable
PM condensable
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene
Biphenyl
Butane
Butyr/isobutyaldehyde

Digester Gas - Uncontrolled Distillate Oil - Uncontrolled


1.60E-01
8.80E-01
1.70E-02
3.30E-03
6.50E-03
3.30E-02
5.80E-03
4.10E-04
1.20E-02
1.20E-02
1.20E-02

5.50E-05

Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene
Fluorene
Formaldehyde
Isobutane
Methanol
Methylcyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u

2.80E-04

3.50E-05

Distillate Oil - Water-Steam Injec Landfill Gas - Uncontrolled


2.40E-01
7.60E-02
4.10E-04
1.20E-02

1.40E-01
4.40E-01
4.50E-02
1.30E-02
2.30E-02

1.20E-02

5.50E-05

2.10E-05

2.80E-04

3.50E-05

1.10E-04
3.10E-05

Natural Gas - Lean Premix


Natural Gas - Uncontrolled Natural Gas - Water-Steam Injection
9.90E-02
3.20E-01
1.30E-01
1.50E-02
8.20E-02
3.00E-02
3.40E-03
2.10E-03
2.10E-03
2.10E-03
6.60E-03
6.60E-03
6.60E-03
1.90E-03

1.90E-03

1.90E-03

4.00E-05
6.40E-06

4.00E-05
6.40E-06

4.00E-05
6.40E-06

1.20E-05

1.20E-05

1.20E-05

3.20E-05

3.20E-05

3.20E-05

7.10E-04

7.10E-04

7.10E-04

1.30E-06

1.30E-06

1.30E-06

1.30E-04

1.30E-04

1.30E-04

6.40E-05

6.40E-05

6.40E-05

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