Professional Documents
Culture Documents
Company Name:
Compressor engines
Flares
Frac tanks
Glycol dehydrators
Loading
Piping component fugitive areas
Separators
Condensate storage tanks
Crude oil storage Tanks
Produced water storage tanks
Turbines
Other:
Non-flare combustive device
Complete a form for each piece of equipment (listed above) that meets one of the
following criteria for 2009:
Emitted 1 ton or more of NOx,
Emitted 1 ton or more of volatile organic compounds (VOC), or
Emitted 0.1 tons per year or more of a hazardous air pollutant (HAP)
If individual pieces of equipment do not meet the requirements listed above, they
may be omitted from the inventory provided that the total emissions from all such
unreported sources are:
less than 5 tons of NOx,
less than 5 tons of VOC, and
less than 1 ton of aggregate HAPs
If the total emissions from the omitted pieces of equipment do not satisfy these
requirements, report each source starting with the piece of equipment with the
highest emissions until the total emissions of the remaining omitted sources
satisfy the above requirements.
The Barnett Shale Special Inventory list server has been created to distribute
messages about the agencys special inventory efforts in the Barnett Shale area.
If you haven't already done so, we recommend you subscribe to this list server
to receive any important updates concerning the inventory, including this
emission calculator. To do so, you will need to create a profile with the
TCEQs distribution service, GovDelivery.com, so that you can add and
manage your subscriptions. To create a profile or update your current
subscriptions, please visit: http://service.govdelivery.com/ service/user.html?
code=TXTCEQ.
VENTING EMISSION CALCULATION (for blowdowns, starter vents, gas operated controllers, etc):
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*
TOTALS:
Molecular
Weight grams per
(grams/m 100 moles
ole)
of gas
28.01348
0
mole %
Gas Analysis:
weight %
#DIV/0!
44.0095
#DIV/0!
34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16
106.16
156.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0.0000
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value, or if
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match
the lab analysis.
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
lb/lb-mole or grams/mole
tpy
VOC emissions:
benzene
toluene
ethylbenzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
xylene
n-hexane (C6)
#DIV/0!
#DIV/0!
Operating hours/year:
Fuel Heat Value (Btu/SCF):
pollutant
VOC
NOX
tpy
#DIV/0!
#DIV/0!
Engine #:
Company's Unique
Identification Number:
Notes:
The TCEQ preference for emission factor sources:
Horsepower:
Engine Load:
If available, enter
stack test or
manufacturer's
emission factor
(g/hp-hr)
VOC
NOX
Formaldehyde
Appropriate
AP-42 factor (From
AP-42 Section 3.2)
0.0296
2.21
0.0205
emission factor
used
units
0.0296
lb/MMBtu
2.21
lb/MMBtu
0.0205
lb/MMBtu
If bold, value is greater than or equal to 0.1 ton and should be included on
the "HAPS >=0.1" Tab in the Barnett Shale Phase II workbook for this piece
of equipment.
If VOC factor used
above was a non-APIf VOC factor used
42 factor (stack test
above was from AP- or manufacturer), use
42, use this column this column to check
Hazardous Air Pollutant (HAP): to check for HAPs
for HAPs
1,1,2,2-Tetrachloroethane
Choose Engine Type
Choose Engine Type
1,1,2-Trichloroethane
Choose Engine Type
Choose Engine Type
1,2,4-Trimethylbenzene
Choose Engine Type
Choose Engine Type
1,2-Dichloropropane
Choose Engine Type
Choose Engine Type
1,3-Dichloropropene
Choose Engine Type
Choose Engine Type
2,2,4-trimethlypentane
Choose Engine Type
Choose Engine Type
Acenaphthylene
Choose Engine Type
Choose Engine Type
Acetaldehyde
Choose Engine Type
Choose Engine Type
Acrolein
Choose Engine Type
Choose Engine Type
Benzene
Choose Engine Type
Choose Engine Type
Biphenyl
Choose Engine Type
Choose Engine Type
Carbon Tetrachloride
Choose Engine Type
Choose Engine Type
Chloroform
Choose Engine Type
Choose Engine Type
Ethylbenzene
Choose Engine Type
Choose Engine Type
Ethylene Dibromide
Choose Engine Type
Choose Engine Type
Fluoranthene
Choose Engine Type
Choose Engine Type
Methanol
Choose Engine Type
Choose Engine Type
Methylene Chloride
Choose Engine Type
Choose Engine Type
n-Hexane
Choose Engine Type
Choose Engine Type
Naphthalene
Choose Engine Type
Choose Engine Type
Phenanthrene
Choose Engine Type
Choose Engine Type
Phenol
Choose Engine Type
Choose Engine Type
Pyrene
Choose Engine Type
Choose Engine Type
Styrene
Choose Engine Type
Choose Engine Type
Toluene
Choose Engine Type
Choose Engine Type
Vinyl Chloride
Choose Engine Type
Choose Engine Type
Xylene-u
Choose Engine Type
Choose Engine Type
% (AP-42 speciated/total)
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Choose Engine Type
Flare
Notes:
Input variables into the blue boxes
Emissions will be in the green boxes.
Company's Unique
Identification Number:
General Information
Emission Factors
Emission Factors from TCEQ Guidance (lb/MMBtu)
Yes
Emission Factors from AP-42 Table 1.4-1
and 1.4-2 (lb/MMscf)
Enter pilot stream information into the boxes in the column for
Stream No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream.
Emission Factors for Pilot Stream (lb/MMscf)
NOx
100
NOx
100
Total VOC
benzene
5.5
2.10E-03
toluene
ethylbenzene
xylene
3.40E-03
0 none listed
0 none listed
No
n-hexane
1.8
Enter zeros into the boxes in the column for Stream No. 2 below.
Emission Factors for Added Fuel Stream (lb/MMBtu)
NOx
0
98
Stream Information
Stream Sent to Flare No.
Enter Names of Each
Stream sent to the flare
Here
Pilot(s)
Added
fuel
ex: glycol
unit flash
tank
ex: truck
loading
10
11
12
#DIV/0!
Pilot(s)
Added
fuel
ex: glycol
unit flash
tank
Annual
Emissions
(tpy)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ex: truck
loading
NOX
Total VOC
Benzene
Toluene
Ethylbenzene
Xylene(s)
n-hexane
other HAP
other HAP
Report NOx and Total VOC on the "Flare(s)" tab in the Phase II workbook.
Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other
HAPs on the Phase II workbook if they are 0.1 tpy on the "Flare(s)" tab.
Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html
Working
Breathing
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Flash losses
Total Emissions
VOCs, C3+
0.0000
Benzene
0.0000
Toluene
0.0000
E benzene
0.0000
Xylenes
0.0000
n-C6
0.0000
2,2,4 - Trimethylpentane
0.0000
Any Additional HAP (if applicable):
0.0000
0.0000
0.0000
0.0000
Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
GRI-GLYCalc Program
Run the software program making sure to using a wet gas analysis for your input. This analysis should include an extended ga
The total emissions for a glycol dehydrator should include both the "Controlled Regenerator Emissions" or "Uncontrolled Regen
present and if the flash tank is not 100% controlled with the recycled/recompression option). By reviewing the GRI-GLYCalc Ag
emissions.
Click to see example reports:
Controlled regenerator with flash tank
Uncontrolled regenerator with flash tank
Uncontrolled regenerator vent with a flash tank with recycle/recompression option
Rich/Lean Analysis
Using a laboratory analysis of enriched and lean glycol samples that includes benzene, toluene, ethylbenzene and xyl
following information.
Glycol recirculation rate (gal/min)
Annual hour of operation (hr)
Component
Total VOC
n-hexane
2,2,4 Trimethylpentane
Benzene
Toluene
Ethylbenzene
Xylene(s)
Additional HAPs
Rich (mg/L)
Lean (mg/L)
tpy
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
ycol dehydrator.
nalysis should include an extended gas analysis that includes but not limited to BTEX.
or Emissions" or "Uncontrolled Regenerator Emissions" and the "Flash Gas Emissions" (if the flash tank is
n). By reviewing the GRI-GLYCalc Aggregate Calculations report you will be able to determine your total
ecompression option
sh Gas Emissions
tpy
Back to Workbook
Navigation Tab.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes
Use these cells to convert data, completion is optional.
True Vapor
Molecular
Pressure (P)
Weight (M)
Temperature in
Saturation Factor (S) (See
(psia)
below table(lb/lb-mole)
for list of options) Rankine (R)
Annual Loading
Rate
(gallons/year)
tpy
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
% Toluene
% Xylene(s) % n-Hexane
100
100
100
100
100
100
100
100
100
100
100
100
100
Report any Additional HAPs if they are greater than or equal to 0.1 tpy.
Note: According to AP-42, 5.2-6, if a control is being claimed (such as from a VRU or flare), even though the control device may have a very high efficiency, not all the truck vapors actually get there (due to leaks). See
the following
control
limitations:
Can
assume for
99.2%
of loading
emissions get to control device if tanker truck passes the MACT-level annual leak test (not more than 1 inch water column pressure change in 5 minutes after pressurizing to 18 inches
water followed by pulling a vacuum of 6 inches water).
Can assume 98.7% of loading emissions get to control device if tanker truck passes the NSPS-level annual test (3 inches pressure change)
Otherwise, can only assume 70% of loading emissions reach the control device.
###
###
###
###
###
###
###
###
###
###
###
###
###
###
Notes:
Input variables into the blue boxes
Emissions will be in the green boxes.
Company's Unique
Identification Number:
Gas Analysis:
mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*
Molecular
Weight
(grams/mole)
28.01348
grams per
100 moles
of gas
weight %
0
#DIV/0!
44.0095
#DIV/0!
VOC weight% =
#DIV/0!
34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16
106.16
156.31
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
(VOC:THC)
TOTALS:
0.0000
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Liquids Analysis:
mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
Molecular
Weight
(grams/mole)
28.01348
grams per
100 moles
of gas
weight %
0
#DIV/0!
44.0095
#DIV/0!
VOC weight% =
#DIV/0!
34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.17
100.2
114.23
128.26
142.29
78.11
92.14
106.16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
xylenes (M, P, O)
undecanes (C11+)*
106.16
156.31
TOTALS:
0.0000
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.
0
0
0
#DIV/0!
#DIV/0!
#DIV/0!
Gas
Gas
number
component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other
emission factor
(kg/hr per
component)*
0.0045
0.0024
0.0002
0.00039
0.002
0.0088
emission factor
(lb/hr of TOC per
component)
0.00992
0.00529
0.00044
0.00086
0.00441
0.01940
Total:
lb/hr
0
0
0
0
0
0
0
tpy
0
0
0
0
0
0
0
Light Oil
VOC
content* (wt
%)
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Benzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Toluene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Ethylbenz
ene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Xylene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
n-hexane
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Control
Efficiency
(%)
0
0
0
0
0
0
Total:
Light Oil
number
component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other
emission factor
(kg/hr per
component)
0.0025
0.013
0.00021
0.00011
0.0014
0.0075
emission factor
(lb/hr of TOC per
component)
0.00551
0.02866
0.00046
0.00024
0.00309
0.01653
Total:
lb/hr
0
0
0
0
0
0
0
tpy
0
0
0
0
0
0
0
Heavy Oil
VOC
content*
(%)
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Benzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Toluene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Ethylbenz
ene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Xylene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
n-hexane
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Control
Efficiency
(%)
0
0
0
0
0
0
Total:
Heavy Oil
number
component
Valve
Pumps**
Connector
Flange
Open-ended Line
Other**
emission factor
(kg/hr per
component)
0.0000084
0.0000075
0.00000039
0.00014
-
emission factor
(lb/hr of TOC per
component)
0.0000185
0.00113
0.0000165
0.0000009
0.0003086
0.0000683
Total:
lb/hr
0
0
0
0
0
0
0
tpy
0
0
0
0
0
0
0
Water/Oil
VOC
content*
(%)
100.0000
100.0000
100.0000
100.0000
100.0000
100.0000
Benzene
Toluene
Ethylbenz
ene
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Xylene
n-hexane
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Control
Efficiency
(%)
0
0
0
0
0
0
Total:
Water/Oil
number
component
Valve
Pump Seal
Connector
Flange
Open-ended Line
Other
tpy
#DIV/0!
#DIV/0!
emission factor
(kg/hr per
component)
0.000098
0.000024
0.00011
0.0000029
0.00025
0.014
emission factor
(lb/hr of TOC per
component)
0.0002161
0.0000529
0.0002425
0.0000064
0.0005512
0.0308649
Total:
lb/hr
0
0
0
0
0
0
0
tpy
0
0
0
0
0
0
0
VOC
content*
(%)
100.0000
100.0000
100.0000
100.0000
100.0000
100.0000
Benzene
Toluene
Ethylbenz
ene
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Xylene
n-hexane
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Control
Efficiency
(%)
0
0
0
0
0
0
Total:
Toluene
Ethylbenzene
Xylene(s)
n-Hexane
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
Emission factors are for oil and gas production facilities (not refineries), and come from the EPA's "Protocol for Equipment Leak Emission Estimates" November 1995, EPA 4531,
R-95-017, Table 2-4.
Emission factors that are not based on the EPA document are from the TCEQ "Air Permit Technical Guidance for Chemical Source Equipment
Leak Fugitives (Draft October 2000)
* For fugitive calculations, VOC content should be VOC content of total hydrocarbons, not of total sample.
VOC
Benzene
Toluene
Ethylbenzene
Xylene
n-hexane
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
tpy
0.000
0.000
0.000
0.000
0.000
0.000
0.000
For separators that vent to the atmosphere under normal operating conditions. This does not
include separators that vent to the atmosphere through a pressure relief valve only under upset
conditions.
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Separators #:
Company's Unique
Identification Number:
mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
n-hexane (C6)
heptanes (C7+)*
octanes (C8+)*
nonanes (C9+)*
decanes (C10+)*
benzene
toluene
ethylbenzene
xylenes (M, P, O)
undecanes (C11+)*
TOTALS:
Molecular
Weight grams per
(grams/m 100 moles
ole)
of gas
28.01348
0
44.0095
0
34.08188
0
16.04246
0
30.06904
0
44.09562
0
58.1222
0
58.1222
0
72.14878
0
72.14878
0
86.17
0
100.2
0
114.23
0
128.26
0
142.29
0
78.11
0
92.14
0
106.16
0
106.16
0
156.31
0
0.0000
0
weight %
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value. If
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match
the lab analysis.
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
lb/lb-mole or grams/mole
VOC emissions:
benzene
toluene
ethylbenzene
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
xylene
n-hexane (C6)
#DIV/0!
#DIV/0!
Gas condensate is defined as a liquid hydrocarbon with an API gravity greater than 40 at 60F (and a specific gravity les
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Condensate Tank#:
Company's Unique
Identification Number:
Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html
Working
Breathing
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Notes:
Enter variables into blue boxes
Emissions will be in green boxes
Flash losses
Total Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
ook Navigation
ab.
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
HAP (if applicable):
0.0000
0.0000
0.0000
0.0000
Crude oil is defined as heavy, low volatility oil approximated by a GOR less than 1,750 cubic feet per barrel and an A
Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html
Working
Breathing
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
ubic feet per barrel and an API gravity less than 40.
Notes:
Enter variables into blue boxes
Emissions will be in green boxes
d flash losses.
Flash losses
Total Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
ck to Workbook Navigation
Tab.
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Tank emissions are made up of 3 different components, working, breathing and flash losses.
Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0*
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html
Working
Breathing
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
*It is possible to create a mixture in the EPA TANKS program similar to the composition of the produced
water stored in the tanks (e.g., a mixture of 99% water and 1% condensate) to determine the emissions.
Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
Flash losses
Total Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):
Annual Emissions
VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
2,2,4 - Trimethylpentane
k Navigation
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
tpy
0.000
0.32
0.000
Notes:
Company Name:
Other #:
Company's Unique
Identification Number:
General Information
Emission Factors
NOx
Other Vendor Factor
100
VOC
benzene
toluene
5.5
2.10E-03
3.40E-03
Yes
ethylbenzene
Enter pilot stream information into the boxes in the column for
Steam No. 1 below. If there is more than one continous pilot
stream, please enter it as one combined stream.
Emission Factors for Pilot Stream (lb/MMscf)
NOx
100
0 none listed
xylene
n-hexane
0 none listed
1.8
Yes
Enter added fuel stream information into the boxes in the
column for Steam No. 2 below.
Emission Factors for Added Fuel Stream (lb/MMscf)
NOx
100
98
Stream Information
Stream Sent to Flare No.
Enter Names of Each
Stream sent to the flare
Here
Pilot(s)
Added
fuel
10
11
12
ex: truck
loading
0
Added
fuel
Pilot(s)
-
ex: glycol
unit vent
ex: amine
unit vent
Annual
Emissions
(tpy)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
NOX
Total VOC
benzene
toluene
ethylbenzene
xylene
n-hexane
other HAP
other HAP
ex: truck
loading
Report NOx and Total VOC on the "Other Source(s)" tab in the Phase II workbook.
Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other HAPs on
the Phase II workbook if they are 0.1 tpy on the "Other Source(s)" tab.
(For Estimating VOC Flashing Emissions, Using Stock Tank Gas-Oil Ratios For Crude Oil Facilities)
Barnett Shale Phase II Identification Information:
Company Name:
Insert Company and/or site name here.
Tank#:
Notes:
Enter variables into blue boxes
Emissions will be in green boxes
Company's Unique
Identification
Number:
INPUTS:
Stock Tank API Gravity
Separator Pressure (psig)
Separator Temperature (F)
Separator Gas Gravity at Initial Condition
Stock Tank Barrels of Oil per day (BOPD)
Stock Tank Gas Molecular Weight
Fraction VOC (C3+) of Stock Tank Gas
Atmospheric Pressure (psia)
CONSTRAINTS:
16
>API>
50
> P+Patm >
70
> Ti >
0.56
> SGi >
None
>Q >
18
> MW >
0.5
> VOC >
None
> Patm >
API
P
Ti
SGi
Q
MW
VOC
Patm
40
5250
295
1.18
None
125
1.00
None
API
(psia)
(F)
(MW/28.97)
(BOPD)
(lb/lb-mole)
fraction
(psia)
2070
(scf/STB)
OUTPUTS:
SGx = Dissolved gas gravity at 100 psig = SGi [1.0+0.00005912*API*Ti*Log(Pi/114.7)]
SGx =
0.00
Rs
SGx
Pi
API
Ti
APTI
C1
C2
C3
Rs =
0.00 scf/bbl
for P + Patm =
CONSTRAINTS:
20
> Rs >
Within Valid
Range?
No
No
No
No
Yes
No
No
Yes
in standard cubic feet of flash gas per barrel (SCF/bbl) of oil/condensate produced
Flash Gas MW =
mole %
Nitrogen
CO2
H2S
methane (C1)
ethane (C2)
propane (C3)
i-butane (C4)
n-butane (C4)
i-pentane (C5)
n-pentane (C5)
hexanes (C6)
heptanes (C7+)*
octane (C8+)*
nonane (C9+)*
decane (C10+)*
benzene
toluene
ethylbenzene
molecular weight
(grams/mole)
28.01348
44.0095
34.08188
16.04246
30.06904
44.09562
58.1222
58.1222
72.14878
72.14878
86.18
100
114.23
128.26
142.29
78.11
92.14
106.16
weight %
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
VOC wt% =
Benzene weight% =
Toluene weight% =
Ethylbenzene weight% =
Xylene weight% =
n-hexane weight% =
Contaminant
Total VOC
benzene
toluene
TPY
#DIV/0!
#DIV/0!
#DIV/0!
xylenes (M, P, O)
undecanes (C11+)*
106.16
156.31
TOTALS:
0.0000
0
0
0
#DIV/0!
#DIV/0!
#DIV/0!
ethylbenzene
xylene
n-hexane (C6)
#DIV/0!
#DIV/0!
#DIV/0!
* If MW of heptanes plus is given, you can change the value in the table above.
* If the MW of the total sample is given, you can adjust the MW of heptanes+ until the "Flash Gas MW" value above equals the value on the lab report.
ate produced
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
2 Stroke Lean
Nox (90-105% Load)
Nox (<90% Load)
CO (90-105 Load)
CO (<90% Load)
SO2
3.17
1.94
0.386
0.353
0.000588
VOC total
PM total
For Error Finding Only:
TOC
PM filterable
PM condensable
VOC Speciation C or better
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene
Biphenyl
Butane
Butyr/isobutyaldehyde
Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene
0.12
0.04831
0.118
0.009987
0.0296
0.01941
1.64
0.0384
0.00991
1.47
0.0000771
0.00991
0.358
0.0095
0.00991
2 Stroke Lean
6.63E-05
5.27E-05
3.91E-05
1.11E-04
4.46E-05
4.38E-05
2.14E-05
1.33E-06
8.46E-04
3.17E-06
7.76E-03
7.78E-03
7.18E-07
3.36E-07
1.94E-03
3.95E-06
4.75E-03
4.37E-04
6.07E-05
4.44E-05
4.71E-05
6.72E-07
3.08E-04
9.47E-05
1.08E-04
7.34E-05
3.61E-07
1.43E-05
3.32E-05
1.25E-06
2.50E-04
5.53E-06
8.36E-03
5.14E-03
2.79E-03
2.63E-03
4.40E-04
1.58E-03
4.00E-05
6.40E-06
2.10E-03
1.20E-05
1.01E-04
6.93E-07
2.27E-04
3.97E-05
1.11E-06
3.20E-05
Fluorene
Formaldehyde
Isobutane
Methanol
Methycyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u
1.37E-06
5.52E-02
3.75E-03
2.48E-03
3.38E-04
1.47E-04
4.45E-04
3.08E-05
7.44E-05
1.53E-03
9.63E-05
3.53E-06
4.21E-05
2.87E-02
5.84E-07
5.48E-05
9.63E-04
2.47E-05
2.68E-04
5.67E-06
5.28E-02
2.50E-03
1.23E-03
2.00E-05
1.11E-03
1.10E-04
3.51E-04
2.60E-03
7.44E-05
2.05E-02
7.50E-02
4.12E-05
1.30E-06
4.19E-02
1.36E-06
4.08E-04
1.49E-05
1.84E-04
7.10E-04
5.58E-04
1.95E-04
3.40E-03
BOILER
Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Large Wall Fired (>100 MMBtu/hr) Residential Furnaces - (< 0.3) Uncon
Small Boilers (<100 MMBtu/hr) - Co
Small Boilers (<100 MMBtu/hr) - Con
Small Boilers (<100 MMBtu/hr) - Unc
Tangential Fired Boilers (All) - Low
Tangential Fired Boilers (All) Uncon
NOX
100
140
190
280
94
50
32
100
76
170
CO
84
84
84
84
40
84
84
84
98
24
TURBINES
Nox
CO
SO2
VOC total
PM total
For Error Finding Only:
PM filterable
PM condensable
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene
Biphenyl
Butane
Butyr/isobutyaldehyde
5.50E-05
Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene
Fluorene
Formaldehyde
Isobutane
Methanol
Methylcyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u
2.80E-04
3.50E-05
1.40E-01
4.40E-01
4.50E-02
1.30E-02
2.30E-02
1.20E-02
5.50E-05
2.10E-05
2.80E-04
3.50E-05
1.10E-04
3.10E-05
1.90E-03
1.90E-03
4.00E-05
6.40E-06
4.00E-05
6.40E-06
4.00E-05
6.40E-06
1.20E-05
1.20E-05
1.20E-05
3.20E-05
3.20E-05
3.20E-05
7.10E-04
7.10E-04
7.10E-04
1.30E-06
1.30E-06
1.30E-06
1.30E-04
1.30E-04
1.30E-04
6.40E-05
6.40E-05
6.40E-05