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The spent pickling liquor of galvanized steel factories contains high concentration of zinc and iron
besides other heavy metals such as Pb, Ni, Cu and Mn in low concentration. Since these metals are
considered as secondary materials, removing from picking liquor plays a vital role in conserving the
environment and recycling valuable metals in particular zinc and iron.
Selective extraction of zinc and iron has been considered by several authors recently, and the solvent
extraction (SX) has been known as a widely used clean hydrometallurgical separation technique. The
main extractant used in zinc extraction is di(2-ethylhexyl) phosphoric acid (D2EHPA), which extracts
iron (III) as well. In addition to the D2EHPA, tri-n-butyl phosphate (TBP) has been reported as the
most effective extractant for zinc extraction and stripping from chloride solutions which showed a
lower extraction power compared with D2EHPA. Whilst sole D2EHPA extracted 99% of iron (III)
and 97% for zinc (II) at A/O =1, it showed poor selectivity for zinc over iron (III) (pH0.5 ~ 0.97).
According to the problems associated with sole extractant, synergistic effect of TBP with D2EHPA
diluted in kerosene on the extraction of zinc (II) and iron (III) from leach solutions was investigated
with the aim of obtaining a higher extraction efficiency as well as boosting selective extraction. Increasing TBP to D2EHPA ratios in the organic phase caused a slight shift to the right in the extraction
isotherm of iron and a marked shift to the right in the extraction isotherm of zinc and thus, superior
separation of iron over zinc was achieved. As a result, the separation factor and pH0.5 increased.
Decreasing the ratio of D2EHPA to TBP, enhanced selective extraction. It is worth to note that, the
mixture of 0.15 M D2EHPA and 0.55 M TBP (D2EHPA to TBP volume ratio of 1:3) resulted in
highest separation factor (9.72103) and the largest pH0.5 (1.7).
A
widely
used
separation
technique
Hydrometallurgical
zinc and iron from waste liquor
separation
Clean
method
Consuming less energy compared
technique
Preventing
water
pollution
with primary metals production
Selecting
proper
extractant(s)
is
a
Conserving raw materials
determining
factor
in
extractions
Environmentally friendly
efficiency
100
80
% Extraction
60
Zn (0.6 M D2EHPA)
40
Fe (0.6 M D2EHPA)
20
0
% Extraction
80
Fe (0.73 M TBP)
60
Zn (0.73 M TBP)
40
20
0
0
80
Fe(sole D2EHPA)
Zn(sole D2EHPA)
Fe(D2EHPA:TBP=3:1)
Zn(D2EHPA:TBP=3:1)
Fe(D2EHPA:TBP=2:1)
Zn(D2EHPA:TBP=2:1)
Fe(D2EHPA:TBP=1:1)
Zn(D2EHPA:TBP=1:1)
Fe(D2EHPA:TBP=1:2)
Zn(D2EHPA:TBP=1:2)
Fe(D2EHPA:TBP=1:3)
Zn(D2EHPA:TBP=1:3)
Slight shift
60
50
40
30
20
10
Marked shift
0
0
pH
2.5
Fe
Zn
pH0.5
%Extraction
70
2
pH
Increasing TBP
to D2EHPA ratio
90
100
pH
1.5
1
0.5
0
0
5
0.2
0.4
XTBP
0.6
0.8
Conclusions: The mixture of 0.15 M D2EHPA and 0.55 M TBP (D2EHPA to TBP volume ratio of
3
1:3) resulted in highest separation factor (9.7210 ) and the largest pH0.5 (1.7).
University
of
Tehran