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Classification of elements
1.2 Atoms
Elements are made up of tiny particles called atoms. Atoms differ from one
element to another.
It is the smallest particle in any element, having a diameter of only 0.1
nanometre. It cannot be seen with the naked eye, only to be seen with the
electron microscope, or the scanning tunnelling microscope (STM). Every element
consists of only a specific type of atom. (So Sodium, Na, can only contain Sodium
atoms, not any others)
Not all elements exist as atoms. However, some are. They are under Group 0 in
the Periodic Table of elements, founded by William Randsey. These elements are
also called the noble gases, since they are extremely unreactive with other
elements. Thus, they were once known as inert gases, but this mistake was
corrected when it was realized that the noble gases gets more reactive as it goes
down the group. One example would be Xenon reacting with Fluorine to form
Xenon Tetrafluoride (XeF4)
It is possible for the atoms to exist as atoms as they have a stable octet electron
configuration, and a stable duplet electron configuration in the case of Helium.
(This would be explained further under the chapter of Atomic Structure)
Metals are also able to exist as atoms. This is due to metals arrangement to form
giant structures. Most non-metals exist as molecules.
1.3 Molecule
A molecule is a group of two or more atoms that are covalently bonded together.
Molecules of elements consist of a fixed number of the same type of atoms
combined together.
For example, Fluorine molecules are formed from two chemically combined
atoms of Fluorine. Thus, its molecular formula is F2.
Ne (Neon) is an example of a monatomic (mono = 1) element, since it exists as
single atoms.
F2 (Fluorine molecule) is an example of a diatomic (di = 2) molecule, since it is
formed by the combination of 2 atoms
O3 (Ozone), is an example of a triatomic ( tri = 3) molecule, consisting of 3 atoms
chemically combined together.
1.4 Compounds
Compounds are made up of molecules and ions.
Compounds are made up of 2 or more different elements chemically combined
together.
Molecules of compounds consist of a fixed number of two or more different types
of atoms combined together.
Symbol for element
NH4.
Relationship between
the two elements, 1 N
atom for every 4 H
atoms.
The structure of the atoms is quite simple, although the processes going on are
quite complicated. Lets now look at the sub-atomic particles inside the atom.
Source: Google Images
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As you can see, the atom is made up of 3 fundamental sub-atomic particles, the
Proton, Neutron, and the Electron. The neutrons and the protons are grouped
together in the nucleus, and together called the nucleons. The nucleus is very
dense, since it accounts for all the mass inside the atom, although it takes up little
spaces, but surrounded by electrons. These electrons are attracted to the
protons electrostatically.
Relative charges
Relative masses
Location in the
atom
Proton
+1
1
Nucleus
Neutron
0
1
Nucleus
Electron
-1
1/1836
Electron shell
2.3 Isotopes
Isotopes are atoms of the same element, but have different number of neutrons.
Isotopes of an element have the same
Proton Number
Number of electrons in an atom
Electron configuration
Chemical properties
Isotopes on an element have different
Nucleon Numbers
Number of neutrons in an atom
Physical properties, i.e. Boiling/Melting points
One example would be Carbon. It could have the mass number of 12, 13 or even
14.
2.4 Shells
Electrons move around within the atom along their shells. These shells can hold
up to a maximum number of 2n2 electrons, where n is the number of the shell.
The shells are numbered 1, 2, 3, 4, 5...Etc. The 1st is nearest to the nucleus,
followed by the 2nd shell, and then the 3rd shell.
Now, look at the electronic configuration of the first 20 elements in the Periodic
Table of Elements.
Element
Hydrogen
Helium
Lithium
Beryllium
Boron
Carbon
Nitrogen
Oxygen
Fluorine
Neon
Sodium
Magnesium
Aluminium
Silicon
Phosphorus
Sulfur
Chlorine
Argon
Potassium
Calcium
Electronic Configuration
1
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.8.1
2.8.2
2.8.3
2.8.4
2.8.5
2.8.6
2.8.7
2.8.8
2.8.8.1
2.8.8.2
Notice that the first shell can only hold up to 2 electrons, while the second shell
can hold up to eight. The third shell, for the first 20 elements, can only hold up to
8 electrons. This is due to the energy levels of the shells that will not be tested in
Secondary 2.
Look at the noble gases, highlighted in red. They all have a stable duplet structure
for Helium; since it is the valence shell (last shell) had been fully occupied by the
electrons and is stable. On the other hand, for both Neon and Argon, they have a
stable octet structure. Thus, few can combine with them to form compounds or
even with each other to form molecules. This explains why they are monatomic.
Ionic bonding takes place due to most atoms not having the stable electronic
configuration of a noble gas. Thus, the atoms would have to either lose or gain
electrons to achieve that configuration.
To remember which ions are cations and which are anions, there is a simple
method. Metals will form cations while non-metals will form anions.
Ion of chlorine
Source:
http://www.bbc.co.uk/schools/gcsebitesize/sc
ience/add_aqa/atomic/ionicrev3.shtml
Atom of Sodium
Ion of Sodium
If you have ionic compounds such as Calcium Chloride, CaCl2, the Calcium atom
will transfer one electron to one of each Chlorine atom and then all of them will
achieve a stable octet structure.
Covalent Bonding
This type of bonding is only achieved between non-metals. Like ionic bonding, it is
to attain the electronic configuration of a noble gas.
Source: Google Images
Oxygen Electrons
Hydrogen Electrons
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The electrons of the Hydrogen atoms and those of Oxygens will share, giving all
of the atoms an electronic configuration of a noble gas.
Ca2+
Cl-
Next, do a switch.
Ca2+
Cl-
Ca
Cl2
3.3 Molecules
This chapter had been explained earlier on. However, whats new is the
nomenclature (naming of compounds).
Assuming we are asked for the chemical composition of Sulfur Trioxide, how do
we find it out?
Look at the table below:
Amount of element in a molecule
1
2
3
4
5
6
7
Prefix
mono
di
tri
tetra
penta
hexa
hepta
Prefix of 3
Sulfur Trioxide
Thus, we can conclude that the chemical composition is SO3.
Magnesium Oxide
Step 1: Write down the reactant (Left hand side) and Product (Right hand side).
Mg + O2
MgO
Mg atom: 1
Mg atom: 1
O atoms: 2
O atoms : 2
2MgO
Mg atom: 1
Mg atoms: 2
O atoms: 2
O atoms: 2
Step 3: Recheck
We realize that the Mg atoms are not balanced. So, we have to add one more Mg
atom to the side of the reactant.
Therefore,
2Mg + O2
2MgO
Mg atoms: 2
Mg atoms: 2
O atoms: 2
O atoms: 2
Acids
Organic
Acids: Naturally
occurring acids i.e. citric acid, ethanoic acid
Mineral/
Inorganic
acids
Organic acids
Inorganic Acids (mineral acids): Mostly man-made acids i.e. hydrochloric acid
H+ (aq) + Cl-
CH3COOH (l)
Ethanoic acid, being a weak acid, dissociates in water partially to give hydrogen
ions and ethanoate ions.
Tastes sour
Turn blue litmus paper red
pH values below 7
Dissolves in water to form solutions to conduct electricity (due to the
mobile ions) in aqueous form.
Metals placed above Hydrogen in the series will react with acids to form
hydrogen (fulfilling the above equation).
Metals placed below Hydrogen in the series will not react with acids to form
hydrogen.
Example: Mg(s) + 2HCl (aq) = MgCl2(s) + 2H(g)
Metal
Acid
Salt
Hydrogen
Another equation:
Carbonate + Acid CO2 + H2O + Salt
Example: (Chemical Equation)
MgCO3 + H2SO4 CO2 + H2O + MgSO4
Example:
KOH K+ + OHPotassium Hydroxide Potassium ion + Hydroxide ion
LiOH (s)
NH3(aq)
Alkali (A) + Salt (B) B Hydroxide + Salt (A) Where A and B are metals.
Example:
2NaOH +NiCl2 Ni(OH)2 + 2NaCl
However, the metal hydroxide produced mustnt be soluble in water.
Enough about the equations, if we cant apply them in real life, the knowledge
wouldnt help us much.
The following table will tell you more about the bases/ alkalis and their uses.
(Continued in the next page)
Calcium oxide
Ammonia solution
Potassium hydroxide
Uses
Making soaps and detergents
Involved in the production of paper
Used in toothpastes
Used in antacids to aid gastric problems
and indigestion
Make iron, concrete and cement
Used in fertilisers
Used in solutions for cleaning windows
Used to neutralise acidic soil
4.9 pH
Above you see the pH scale. It compares the strength of acids and how acidity or
alkaline a solution is.
As you can see, pH of 7 is neutral. They are neither acidic nor are they alkaline i.e.
Deionised water
pH < 7 are acidic i.e. Hydrochloric acid
4. 11 Oxides
This is the last section to be studied at Secondary 2 level (although this may vary
from school to school)
Oxides can be branched out into 4 different types shown below
Oxides
Acidic Oxides
Basic Oxides
Amphoteric Oxides
Neutral Oxides
Acidic oxides are oxides of non-metals that dissolve in water to form an acid
However, they also react with bases to form salt and water (like acids)
Basic oxides are oxides of metals that react with acids the same way bases do.
(Form salt and water).
Oxides of reactive metals will dissolve in water to form alkalis.
Basic oxides, as the name suggests, are insoluble in water (bases). However, some
are alkaline, dissolving in water readily e.g. NaOH
Note: Basic oxides are solids at room temperature.
Amphoteric oxides are metallic oxides which react in both acids and alkalis to
form salts and water, displaying properties of both acidic and basic oxides.
Neutral oxides are usually non-metals, showing neither acidic nor basic
properties. They are insoluble in water.
Alkaline metals
Alkaline earth metals
Metalloids
Halogens
Noble Gases
Transition elements
5.4 Metalloids
Metalloids have properties of non-metals and metals. They are semi-conductors
and so, they do not conduct electricity as well as metals do, but better than nonmetals. Some examples are silicon and germanium. They are modified to become
transistors, allowing the use of electronic devices and are responsible for solidstate electronics rapid growth.
5.5 Halogens
Halogens are found in group VII of the Periodic Table. The name is derived from
the two Greek words, halas and gennau, which means salt and generate
respectively. Fluorine from this group is highly reactive, being able to form bonds
with noble gases. However, it is less reactive as you go down the group.
For transition elements, there is no pattern for us to recognise the charges. Below
will list some common charges transition metals when they are ions and some
compounds associated with transition elements.
Iron (II), Iron (III)
Zinc
Copper
Chromium (II), Chromium (III)
Silver
Barium
Potassium Dichromate
Permanganate ion
Fe2+, Fe3+
Zn2+
Cu+, Cu2+
Cr2+, Cr3+
Ag+
Barium2+
K2Cr2O7
MnO4-
Some transition elements will have a Roman numeral behind its name, like
Chromium (II). This shows that Chromium has a charge of +3.
Credits
O-Level Chemistry Guide by Bob Ryan
Chemistry Matter and its Changes, Brady, Senese
Secondary 2 Chemistry Notes