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Product Name:
CAS #:
65997-15-1
Product Use:
MSDS Information:
This MSDS was produced in November of 2014 and replaces any previous versions. This MSDS
covers Oilwell Cement, Class G, Moderate Sulphate Resistant. Individual composition of
constituents will vary within the range shown in Section 2.
Product Code:
Not Applicable.
Chemical Family:
Formula:
Supplier/Manufacturer:
Lehigh Cement
12640 Inland Way
Edmonton, Alberta, Canada, T5V 1K2
Lehigh Cement
12640 Inland Way
Edmonton, Alberta, Canada, T5V 1K2
10 mg total dust/m3
15 mg total dust/m3
5 mg respirable dust/m3
ACGIH TLV-TWA
OSHA PEL-TWA
OSHA PEL-TWA
CAS#
% By Weight
ACGIH TLV-TWA
OSHA PEL-TWA
3
15 mg total dust/m3
5 mg respirable dust/m3
15 mg total dust/m3
5 mg respirable dust/m3
various
60-80%
10 mg total dust/m
Gypsum
7778-18-9
3-7%
10 mg total dust/m3
Crystalline Silica
14808-60-7
>0.1%
Magnesium Oxide
1309-48-4
1-4%
10 mg total dust/m3
10 mg total dust/m
Calcium Oxide
1305-78-8
0.5-1.5%
2 mg total dust/m3
5 mg total dust/m3
Trace Elements:
Oilwell cement is made from materials mined from the earth and is processed using energy provided by fuels. Trace amounts of
chemicals, some of which may be potentially harmful, might be detected during chemical analysis. For example, in addition to the
ingredients listed above, oilwell cement may contain potassium and sodium sulfate compounds, chromium compounds (including up
to 0.003% hexavalent chromium) and nickel compounds.
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OILWELL CEMENT
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Emergency Overview:
Oilwell cement is a light gray powder that poses little immediate hazard. A single short term exposure to the dry powder is not
likely to cause serious harm. However, exposure of sufficient duration to wet oilwell cement can cause serious, potentially
irreversible tissue (skin or eye) destruction in the form of chemical (caustic) burns, including third degree burns. The same type
of tissue destruction can occur if wet or moist areas of the body are exposed for sufficient duration to dry oilwell cement.
Potential Health Effects:
Carcinogenic Potential:
Oilwell cement is not listed as a carcinogen by NTP, OSHA, or IARC. It may, however, contain trace amounts of substances
listed as carcinogens by these organizations.
Crystalline silica, a potential trace level contaminant in oilwell cement, is now classified by IARC as a known human carcinogen
(Group 1). NTP has characterized respirable silica as reasonably anticipated to be [a] carcinogen.
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OILWELL CEMENT
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Eyes:
Immediately flush eyes thoroughly with water. Continue flushing for at least 15 minutes, including under lids, to remove all particles.
Call physician immediately.
Skin:
Wash skin with cool water and pH-neutral soap or a mild detergent intended for use on skin. Seek medical treatment in all cases of
prolonged exposure to wet cement, cement mixtures, liquids from fresh cement products, or prolonged wet skin exposure to dry
cement.
Inhalation Of Airborne Dust:
Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. (Inhalation of gross amounts of oilwell
cement requires immediate medical attention.)
Ingestion:
Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability:
Flash Point:
Lower Explosive Limit:
Upper Explosive Limit:
Auto ignition Temperature:
Sensitivity To Static Discharge:
Sensitivity To Impact:
Extinguishing Media:
Special Fire-Fighting Procedures:
Hazardous Combustion Products:
Unusual Fire And Explosion Hazards:
Not Flammable.
Not Applicable.
Not Applicable.
Not Applicable.
Not Applicable.
Not Applicable.
Not Applicable.
Not Applicable.
None.
Not Applicable.
Not Applicable.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Wear
appropriate personal protective equipment as described in Section 8.
Scrape up wet material and place in an appropriate container. Allow the material to dry before disposal. Do not attempt to wash oilwell
cement down drains.
Dispose of waste material according to local, provincial, state and federal regulations.
SECTION 7 - HANDLING AND STORAGE
Keep oilwell cement dry until used. Normal temperatures and pressures do not affect the material.
Promptly remove dusty clothing or clothing which is wet with cement fluids and launder before reuse. Wash thoroughly after exposure to
dust or wet cement mixtures or fluids.
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OILWELL CEMENT
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Eye Protection:
When engaged in activities where cement dust or wet cement or concrete could contact the eye, wear safety glasses with side shields
or goggles. In extremely dusty environments and unpredictable environments, wear unvented or indirectly vented goggles to avoid eye
irritation or injury. Contact lenses should not be worn when working with oilwell cement or fresh cement products.
Skin Protection:
Prevention is essential to avoiding potentially severe skin injury. Avoid contact with unhardened (wet) oilwell cement products. If
contact occurs, promptly wash affected area with soap and water. Where prolonged exposure to unhardened oilwell cement products
might occur, wear impervious clothing and gloves to eliminate skin contact. Where required, wear boots that are impervious to water to
eliminate foot and ankle exposure.
Do not rely on barrier creams; barrier creams should not be used in place of gloves.
Periodically wash areas contacted by dry oilwell cement or by wet cement or concrete fluids with a pH-neutral soap. Wash again at the
end of work. If irritation occurs, immediately wash the affected area and seek treatment. If clothing becomes saturated with wet
concrete, it should be removed and replaced with clean dry clothing.
Respiratory Protection:
Avoid actions that cause dust to become airborne. Use local or general ventilation to control exposures below applicable exposure
limits.
Use NIOSH/MSHA-approved (under 30 CFR 11) or NIOSH-approved (under 42 CFR 84 after July 10, 1998) respirators in poorly
ventilated areas, if an applicable exposure limit is exceeded, or when dust causes discomfort or irritation.
Ventilation:
Use local exhaust or general dilution ventilation to control exposure within applicable limits.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odor:
Odor Threshold:
Physical State:
pH (as a solid):
pH (in water) (ASTM D 1293-95):
Solubility In Water:
Vapor Pressure:
Vapor Density:
Boiling Point:
Freezing Point:
Melting Point:
Specific Gravity (H2O = 1.0):
Evaporation Rate:
Coeff. Water/Oil Dist.:
Stability:
Conditions to avoid:
Incompatibility:
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Stable
Unintentional contact with water.
Oilwell cement reacts with water to produce a caustic solution, pH 12 to pH 13. Wet oilwell
cement is alkaline. As such it is incompatible with acids, ammonium salts and aluminum metal.
Aluminum powder and other alkali and alkaline earth elements will react in wet mortar or
concrete, liberating hydrogen gas. Oilwell cement dissolves in hydrofluoric acid producing
corrosive silicon tetrafluoride gas. Silicates react with powerful oxidizers such as fluorine,
chlorine, trifluoride and oxygen difluoride.
OILWELL CEMENT
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Will not spontaneously occur. Adding water results in hydration and produces (caustic)
calcium hydroxide.
Hazardous Polymerization:
Ecotoxicity:
Relevant Physical and Chemical Properties:
Dispose of waste material according to local, provincial, state and federal regulations. (Since oilwell cement is stable, uncontaminated
material may be saved for future use.)
Dispose of bags in an approved landfill or incinerator.
SECTION 14 - TRANSPORT INFORMATION
Oilwell cement is not hazardous under the TDG Act DOT regulations
(USA).
Not applicable.
Not applicable.
Not applicable.
Not applicable.
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