Professional Documents
Culture Documents
www.elsevier.com/locate/jsames
Division of Environmental Studies, Mathematics, and Natural Sciences, Brevard College, Brevard, NC 28712, USA
b
Magstrat, LLC, P.O. Box 300, Webster, NC 28788, USA
c
XR Exploracionistas y Servicios Regionales, s.r.l., Manzana N-Casa 14-18 Etapa, B8 General Belgrano, Salta 4400, Argentina
d
Department of Earth and Environmental Sciences, Lehigh University, 30 Williams Drive, Bethlehem, PA 18015, USA
Received 30 April 2000; revised 30 June 2000; accepted 30 April 2001
Abstract
We present a magnetostratigraphic investigation of Neogene Oran Group strata at Quebrada La Porcelana. The area is located in the
southern Sierras Subandinas of northwestern Argentina within the zone of `normal' subduction. The oldest datable Neogene strata were
deposited ,8.1 Ma at the base of the Terciario Subandino. We estimate that the youngest strata are considerably younger than 1 m.y. The
basal age is millions of years younger than lateral correlative units farther to the south in the Transition Zone. These chronostratigraphic
results suggest that foreland thrusting was initiated much later in northernmost Argentina than it was in the Transition Zone.
The data suggest that generation and migration of hydrocarbons from the Los Monos source horizon began about 3.8 Ma. Growth strata
deposition began at ,4.2 Ma, suggesting that trapping structures were available in the region when migration began. q 2001 Elsevier
Science Ltd. All rights reserved.
Keywords: Magnetostratigraphy; Oran Group; Transition Zone; Sierras Subandinas
1. Introduction
Distinct structural provinces in the Andes Mountains of
northwestern Argentina are closely related to the subduction angle of two segments of the Nazca Plate and an
intervening Transition Zone (Jordan et al., 1983). Recognition of this relationship generated numerous chronostratigraphic studies in an attempt to establish the
deformational history of the different structural provinces.
To date, most of this work has focused on the `at'
subduction area to the south (2836815 0 S) (Johnson et
al., 1986; Bercowski et al., 1986; Reynolds et al., 1990;
Jordan et al., 1990; Re and Jordan, 1999; Malizia et al.,
1995; Milana, 1991; Irigoyen et al., 2000). Similar work
has appeared, to a lesser extent, from strata in the Transition Zone (24288S) (Butler et al., 1984; Reynolds, 1990;
Viramonte et al., 1994; Galli et al., 1996; Reynolds et al.,
2000). Three abstracts (Reynolds et al., 1993, 1996, 2001),
* Corresponding author. Address: Division of Environmental Studies,
Mathematics, and Natural Sciences, Brevard College, Brevard, NC
28712, USA. Tel.: 11-828-883-8292; fax: 11-828-884-3790.
E-mail address: reynoljh@brevard.edu (J.H. Reynolds).
a preliminary report about the Ro Iruya section (Hernandez et al., 1996), and a synthesis of the Subandean tectonic
history (Hernandez et al., 1999) are the only published
chronostratigraphic records from the `normal' subduction
area (10248S) in northern Argentina. Several papers
concerning latest Oligoceneearliest Miocene strata are
available for the Bolivian portion of this segment
(MacFadden et al., 1985; McRae, 1990; Erikson and
Kelly, 1995). Current lithostratigraphic usage unites
Neogene strata of northernmost Argentina with moderately
well-dated strata from the Transition Zone.
The Neogene stratigraphy of the Sierras Subandinas (Fig.
1) in the Argentine portion of the normal subduction area
(22248S), has a complicated history due to a variety of
nomenclatures applied by workers in the past. In this
paper, we lay a chronostratigraphic foundation for the
Neogene strata exposed in the east-central portion of the
southernmost Sierras Subandinas in an attempt to clarify
present problems in the current lithostratigraphic classication. Our chronology was developed with the aid of magnetostratigraphy supported by two 40Ar/ 39Ar ages from
intercalated airfall tuffs. These data also appear in graphic
format in Reynolds (1999) and Hernandez et al. (1999).
0895-9811/01/$ - see front matter q 2001 Elsevier Science Ltd. All rights reserved.
PII: S 0895-981 1(01)00069-4
682
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
Fig. 1. Map showing the structural provinces of northwestern Argentina. The approximate boundaries of the Transition Zone are at 24 and 288S. The
rectangular area in the northeastern corner is shown in Fig. 2. Stratigraphic sections referred to in the text are GZ, Arroyo Gonzalez; RP, Ro Piedras; RY, Ro
Yacones. 5P denotes the Sierra de Cinco Picachos on the western edge of the Sierras Subandinas.
Fig. 2. Map showing the location of mountain ranges and magnetostratigraphy sections in the central Sierras Subandinas (adapted from Hernandez et al.
(1999)). The abbreviations used are S a, Sierra; A8, Arroyo.
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
683
Fig. 3. Stratigraphic nomenclatures that have been applied to the strata discussed in this work (adapted from Gebhard et al. (1974)).
2. Field area
3. Stratigraphy
Three lithostratigraphic units comprise the Quebrada
La Porcelana section. At the base is the Tranquitas
Formation. It is overlain by the thickest unit, informally
referred to as the Terciario Subandino. The section is
capped by another informal unit: the Estratos El Simbolar. All of these strata are included in the Oran Group.
Stratigraphic nomenclature and correlation within the
Oran Group is complicated (Fig. 3). Much of the foundation work is found in unpublished oil company reports.
The salient points of the lithostratigraphic terminology
are discussed later.
684
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
685
Table 1
40
Ar/ 39Ar ages of Quebrada La Porcelana Tuffs (age calculated using the decay constants recommended by Steiger and Jager (1977))
J ( 10 24)
Sample
Material
LP 26
LP 26
Biotite
2.351
Sanidine 2.351
2.378
40
Ar/ 39Ar
38
97.71
64.56
105.30
Ar/ 39Ar
37
Ar/ 39Ar
36
0.1998
0.0503
0.01660
0.13405
0.2861
0.1700
1.56
0.09
13.38
21.94
5.55
6.05
0.42
0.29
0.1905
0.01185
0.2999
1.38
15.76
5.88
7.12
0.48
0.34
40
^ 2s (Ma)
Fig. 4. Vector end-point diagrams (Zijderveld, 1967) showing the thermal demagnetization of representative samples from the Quebrada La Porcelana section.
686
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
Fig. 5. Reversal test for Class I data in the Quebrada La Porcelana section.
Class I, site-mean orientation data cluster in two antipodal groups and pass
the reversal test (projection of the southern circle of condence shown by
the gray circle). The mean declination for the normal sample is 148 with a
mean inclination of 2368 and a 95 78. For the reversed sample, the mean
declination is 1898 with a mean inclination of 388 and a 95 58. The data
suggest a clockwise rotation on the order of ,12 ^ 68. Mean normal and
reverse directions are within 9.58 (g c) of antipodal, providing a positive
reversal test (Class B; MacFadden and McElhinny, 1990).
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
687
Fig. 6. Plot of Virtual Geomagnetic Pole (VGP) latitude of the paleomagnetic sites versus their stratigraphic level. Lithostratigraphic units are shown on the
left. Polarities are abstracted to the standard black and white magnetic polarity scale on the right. Reversals are placed halfway between adjacent sites with
opposite polarities. The I and II refer to growth strata intervals.
688
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
Age (Ma)
Top of El Simbolar
Tss-El Simbolar
TsmTss
TsiTsm
Base of Tsi
Top of Tranquitas Formation
Base of Tranquitas Formation
p1
, 1.2
4.24.3
, 6.2
, 8.1
. 8.1
?
5. Regional correlation
Our results and those presented by Hernandez et al.
(1999) demonstrate that the entire Terciario Subandino is
temporally equivalent to the Jujuy Subgroup farther to the
south (Fig. 9). The Terciario Subandino at Quebrada La
Porcelana is younger than 8.1 Ma. At Arroyo Gonzalez,
200 km to the south (Fig. 1), the base of the Guanaco
Formation was shown to be not older than 9.0 Ma (Reynolds
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
689
Fig. 9. Chronostratigraphic correlation of the Oran Group between and within the normal subduction region and the Transition Zone (Fig. 1). Question marks
indicate levels for which no numerical ages exist. The basal age of the Ro Piedras section was modied by Reynolds et al. (2000). Lithostratigraphic units in
both areas exhibit a diachronous depositional history with younger contact ages in the east. This temporal framework demonstrates that Neogene strata in the
Sierras Subandinas are contemporaneous with Jujuy Subgroup strata in the Transition Zone and are younger than the Metan Subgroup strata except for minor
overlaps.
S de Cinco Picachos
S a Pescado and S a de
Pintascayo
S a Baja de OranS a Bermejo
S a de RamosS a de San
Antonio
Age (Ma)
, 8.2
, 6.9
4.23.6
, 2.5
6. Interpretation
6.1. Local implications
Given the uniform weathered appearance of Tranquitas
strata across the region and the diachronism expressed in the
basal ages of the Terciario Subandino between Ro Iruya
and Quebrada La Porcelana, we suggest the presence of a
disconformity at the basal contact with the Tranquitas
Formation. Other possibilities that might explain the altered
appearance of the Tranquitas Formation and the poor quality
of the paleomagnetic results from the unit across the region
are as follows: (1) a regional thermal event that altered the
magnetic minerals or (2) migration of hydrocarbons or other
uids through the strata. We suggest that the Tranquitas
beds were deposited in response to the initial uplift of the
690
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
Fig. 10. A hydrocarbon generation age model based on the sediment accumulation rate shown in Fig. 8. About 250 m of repeated strata were
removed to give the plot the proposed 0.5 mm a 21 steady-state accumulation history. The 4-km-long vertical dashed line is the assumed hydrocarbon generation depth. It extends from the base of the Los Monos source
horizon to its intersection with the modied sediment accumulation plot.
The best t occurs at ,3.8 Ma, suggesting this age for the initiation of
hydrocarbon generation and migration.
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692
Acknowledgements
We wish to thank the many people and institutions that
assisted us on this project. YPF provided personnel and
logistical support in the eld, including YPF geologists
Alfredo Disalvo, Luis Constantini, and Alberto Schultz.
David Gonzalez (YPF and XR Exploracionistas Regionales,
s.r.l.) was superb as the chief eld assistant and guide.
Laboratory funding was provided by American Chemical
SocietyPetroleum Research Fund awards PRF#24348B2 and PRF#28363-B8 to Reynolds. Ricardo Domnguez
milled the paleomagnetic samples at the Universidad
Nacional de Salta, Argentina. William Harbert (University
of Pittsburgh) contributed much insight to the paleomagnetic analysis. Robert Graham conducted most of the
analyses at Pitt.
Appendix A. Analytical procedures 40Ar/ 39Ar dating
Samples of tuffs LP 19A and LP 26 weighing 23 kg
each were disaggregated in a blender, washed thoroughly
in tap water, and sieved to remove ne material (,125 mm).
Biotite and sanidine were separated from the remaining
coarse fraction using standard heavy liquid and magnetic
techniques. Additional cleanup was accomplished by
hand-picking under a binocular microscope to achieve a
nal purity of .99%. Aliquots of the separates weighing
,3 mg each were packaged in Sn foil and sealed, together
with other unknowns, in evacuated quartz tubes. Packets
containing monitor mineral GA-1550 biotite (97.9 Ma;
McDougall and Roksandic, 1974) were spaced evenly
throughout the tubes to record the vertical variation in
neutron ux within the irradiation container. CaF2 and
K2SO4 were also included in the irradiation package to
monitor neutron-induced interferences due to Ca and K,
respectively. The samples were irradiated for 3 h in position
L67 of the Ford Reactor at the University of Michigan.
The 40Ar/ 39Ar analyses were conducted in the geochronology laboratory at Lehigh University. Argon was
extracted from the samples by fusing them in a doublevacuum tantalum resistance furnace at 1350 8C. The
evolved gases were puried using a cold nger cooled to
liquid-nitrogen temperature and SAES getters operated at
room temperature and 400 8C. The argon isotopes were
analyzed in a VG 3600 noble gas mass spectrometer operated in the static mode. An electron multiplier with an overall sensitivity of ,5 10 217 mol Ar mV 21 was used to
measure the argon beams. The total blank contribution
from the furnace and extraction line was ,3 10 215 mol
40
Ar.
The measured isotopic ratios were corrected for line
blank, mass discrimination (0.51% amu 21), radioactive
decay of 37Ar and 39Ar, neutron-induced interferences on
K and Ca, and atmospheric contamination. Uncertainties
in the ages are reported at the 2s level and incorporate
691
692
J.H. Reynolds et al. / Journal of South American Earth Sciences 14 (2001) 681692