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CONFERENCE ON
SELECTED TECHNOLOGY
for the PETROLEUM INDUSTRY
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NASA SP-5053
CONFERENCE ON
SELECTED TECHNOLOGY
for the PETROLEUM INDUSTRY
1 96 6
For sale by the Superintendent of Documents, U.S. Government Prin ting Office
Washington, D.C. 20402 Price $1.25
FOREWORD
Our nation's space program is both an illustration of the dynamic and growing
scientific and technical activity of the country and a prime mover in it. The
space program attacks, in an organized way, problems at the frontiers of
knowledge and know-how in science and engineering. This attack uses and
creates new information and new technology.
With the premise that most of the new technology derived from the space
program is applicable to other activities, topics of interest and potential value
to the petroleum industry were selected for this conference. The choice of
content was determined through a series of meetings between the NASA
Lewis Research Center staff and petroleum industry specialists.
ABE SILVERSTEIN
Director
Lewis Research Center
111
L_
---
---.~
---
CONT E NT S
PAGE
FORElf/ORD
111
INTRODUCTION
Walter T. Olson ____________________________________________ _
1.
II.
III.
IV.
V.
VI.
VII .
VIII.
IX.
COMBUSTION
Richard S. Brokaw, Frank E. BeIJes, Bruce J. Clark,
and Frank J. ZelezniL________________________________________
25
45
67
73
PUMP TECHNOLOGY
I. Irving Pinke!, Me!vin J. Hartmann, Cavour H . Hauser,
Max J. Miller, Robert S. Ruggeri, and Richard F. SoltiL__ ____________
81
103
125
TECHNOLOGY UTILIZATION
Breene M. Kerr, Melvin S. Day, George J. Howick,
Richard L. Lesher, and Howard L. TimmL__________ ______________
155
167
v
---~--
- --
Introduction
THIS
CONFERENCE
ON
SELECTED TECHNOLOGY
WALTER
T.
OLSON
SELECTED TECH
INTRODUCTION
II
Combustion
RICHARD
S.
BROKAW, FRANK
CLARK,
E. BELLES, BRUCE
AND FRANK
J.
J.
ZELEZNIK
HI
RESTLES
U RGE TO BE ON
THE MOVE,
be air, or as exotic a fluorine. Thi reactor differs from t hose used in the chemical-process
industries in two important way: (1) It is
adiabatic rather than i othermal; (2) thrust is
wanted, not chemica ls. Therefore, the reaction
product are exhausted through a nozzle to convert t he random t hermal energy of the hightemperature ga e into directed kinetic energy,
or thrust.
The optimum behavior of such a device can
be estimated by as uming that the fuel and oxidant mix perfectly and react in tantaneously to
give an equilibrium mixture of reaction products.
In t hi examp le, t hey are not merely carbon
dioxide and water; the high temperature also
produces molecule such as carbon monoxide,
hydrogen, and oxygen, rad icals like hydroxyl,
and t he atoms of hydrogen and oxygen. Thus,
t he fir t topic to be di cussed is the chemical
t hermodynamics of high-temperature gas mixtures, or how to calculate the composition,
properties, and ideal behavior of such mixtures.
Of cour e, this picture is oversimplified. In
practice, such a combu tion cham ber must be
FIG
RE
I- I.-Chemical t hermodynamic.
5
FIGURE
1-2.-Transport properties.
FIG RE
treme, if rates are fast enough, carbon monoxide and oxygen will combin e to form carbon
dioxide, as shown in the lower part of t he
figure. In thi case, additional chemical energy
is converted into thrust. To estimate accurately
the nature of t he exhaust requires high-temperature reaction rates-chemical kinetics. The use
of shock t ube to obtain such inform ation will
be discussed.
CHEMICAL THERMODYNAMICS
To simulate a chemical rocket t hermodynamically, assume first of all that the fuel and the
oxidant react at a con tant pressure and energy
and t hen the hot combustion gases expand adiabatically t hrough t he nozzle to convert thermal
energy into the directed velocity of the gas (fig.
1-1). Since the calculations for any thermodynamic process are similar, the combustion process can illl! trate the complexity of t he calculat ions. Thermodynamically, t he situation can be
illustrated with combustion as it occurs on a
kitchen range when a mixture of air and natural
gas, large ly methane, is ignited to produce a hightemperature flame containing the reaction products (fig. 1-6). In a simplified calculation, it
would be assumed that only carbon dioxide and
water are possi ble reaction products. However,
because of the high t emperature, a considerable
amount of dissociation takes place, and under
t hese conditions there are potentially many different reaction products, for example, carbon
monoxide; various low-molecular-weight hydrocarbons, such as acetylene and ethylene ; and
COMBU TION
FIGURE
!,
!
r
1--4.-Ignition.
F,GURE
2.
1-6.-Combustion process.
0.5
0.4
MOLE
0.3
FRACTION
ELECTRONSO.2
0 ,1
FIG RE
'.
M I N DUSTRY
TRANSPORT PROPERTIES
Transport propert ies, such as heat conductivity, vi cosity, and diffusivity of hi gh-temperature reacting gases are needed bot h to ca lculat e
heat transfer pertinent to cooling t he chamber
and in connection wit h the vaporization of propell ants (fi g. 1-2) . The kinetic theory of gases
promises to provide a way of computing these
30
25
20
INCREASE,
15
TEMP , OK
FIGURE
COMBUSTION
l
{
\
I
_
t:.H, dr
A..-At+ T D dT
dr
The total heat conductivity A.. is the sum of two
terms. The first is a frozen heat conductivity At,
which would be present as a result of collisions
even in the ab ence of reactions. The second
part is a resu lt of the chemical reaction. The
heat flux associated with the diffusion of the
atoms or monomer can be calculated; each atom
diffu ing carries half the heat of the reaction,
and the flux of atoms is simply a diffusion coefficient t imes the concentration gradient of the
atom. The heat conductivity is simply t his flux
divided by t he temperature gradient; the di mensions cancel conveniently.
A limiting maximum value for this change of
atom concentration with temperature can be calcul ated with t he assumption that the chemical
reaction rate, in other words, t he reversible dissociation, occurs so rapidly that, at every point
A
-- -P
FIGURE
~-
DPt:.H2 XAX A
(l+ XA:F
10
30
THERMAL
CONDUCTIVITY,
20
------------------o
300
350
400
450
TEMP, OK
FIGURE
tivity predicted in the ab ence of chemical reaction. It is about wh at would be expected for a
heavy gas uch as carbon dioxide. rrhe solid
curve has been calculated from the relation
shown in the preceding equat ions. The data
points repre ent measured values. At low t emperature, when the gas is predominantly nitrogen
tetroxide, the heat conductivity is low ; it ri es
through a maximum and then declines again a
the dissociation goes toward completion. The
effect is not small. As a matter fact, the heat
conductivity is 8 to 10 times what it would be
in the absence of reaction. Indeed, at the maximum, the heat conductivity is more like that
of a light gas, such a hydrogen or helium.
For nitrogen tetroxide, there is excellent
agreement between t heory and experiment.
The e computed propertie also do an excellent
job of correlating heat transfer from this same
reacting mixture in a more practical sort of configuration; for example, a turbulent pipe flow ,
or heat tran fer to a cylinder in a cross flow.
Al 0, of course, most practical ca es involve
much more complex gas mixtures. Hence, the
theory has been worked out for mixtures involving any number of chemical reaction . The equation involve exactly t he same terms, name ly,
diffu ivi ties, heat of reaction, and compositions
expre ed in mole fraction . The ideas are exactly the same, but there are so many terms that
a computer becomes useful. Indeed, this theory
has been used to calculate the properties for
a ystem of practical interest, namely, hydrogen-
.65
c p "I
.60
.55
o
.50
B
00
.45
.40
.2
.4
-'l
.6
I:J"
.8
1.0
11
COMB S TION
ATOMIZATION
For a rocket engine, the fuel and the oxidant
often start out as liquid. Liquid is sprayed
through an inj ector that consists of one or more
nozzles. Then t he pray of this reactant vapo rizes rapidly in the hot environment, and the
vapor burn as it mixe with the vapor of the
other reactant. High- peed motion pictures of
hydrogen -oxy gen combu tion at 20 atmospheres
in an -inch-long transparent rocket engine how
liqu id-oxygen jet silhouetted by back lighting
as they enter t he combu tion chamber. The
gases a re accelerating rapidly as t he oxygen vaporize and burns with hydrogen. Even though
oxygen is a cryogenic liquid , t he liquid state
persi t for con iderab le distance into t he combustion zon e. Photograp hs of other combustion
systems, for exampl e, hydrocarbon-oxygen and
ni trogen tetroxide-hydrazine combu tion, ,are
similar except for t he co lor of the rad iation.
Becau e it is very difficult to obtain photograph
such as the e, most of the photographic studi es
of prays and drops are taken under cold-flow
condition , that is, in the ab ence of combustion.
low-motion pictures of the sprays from different types of injector revcal qualitatively the
gross difference in t he pray from the different
inj ectors.
From a sin gle photograph, as for impinging
water jets as shown in figure 1-12, t he drops
in a particular ar a of t hi pray can be counted
and their size measured. Drops of similar sizes
can be grouped, as in figure 1-13, in t hi case,
for about 5000 drops of the spray. While drops
of 100 to 200 micron in diameter app ar most
frequently, a plot of the rna s distribution as
add ed show that mo t of the mass is concentrated in drop of about 1000 micron in diam eter. The
large drop mu t be vaporized to
FWURF.
12
ffiITl
NUMBER OF DROPS
MASS
NUMBER
OF
DROPS
20
1600
16
1200
12
MASS,
25
B
DROP DIAM, }l.
FIGURE
environmental conditions, such as different ambient pressures and gas velocities; for a variety
of fluids, such as water, glycerine, ethanol, heptane, or other hydrocarbons; and for a variety
of flow conditions, as different injector geometries, djfferent length-to-diameter ratios of the
hole, different diameter, and different flow velocities through these holes. The bibliography
lists a number of report on thi work. In making
tests of this sort, it wa found that the mo t important single criterion for producing small drops
is a mall orifice diameter.
V APORJZ ATION
It is possible to calculate the rate at which
drops of known size vaporize if the standard
equations for heat, mass flow, and momentum
transfer are used. The complexity of the proces e involved require a computer to make uch
calculations. The re ult of such a calculation
are illustrated in figure 1-14 for a single stationary drop of n-decane in a steady flow of
heated air. The drop is heated rapidly to its
wet bulb temperature while its radiu is decreasing as vaporization progres es. Experimental
points are also shown for both the temperature
720
.4
680
.3
DROP
TEMP , 640
OR
600
DROP
.2 RADIUS,
IN .
.1
b---~---L---L--~--~--~o
2
3
4
5
6
TIME , SEC
FIGURE
13
COMBU TION
__~__------~B~4~5~R~~~~~rn790FT/SEC
GAS
VELOCITY -
" DROP
VELOCITY
RADIUS
100
F T/SEC n----'~
FIG URE
IGNITION
In y st ems of the rocket type, atomiza tion and
vaporization occur in the pre ence of active
combustion so that a fl ame is a lways present t o
ignite the fu el-oxidant mixture. However , in
orne systems, this is not so. For example, in the
hypersonic ramjet illustrated in figure 1-4, fuel
inj ected into a upersonic heated airstream.
1.
II.
III.
IV.
H 2 +O:! ~ 2 OH
OH + H :! ~H 2 0+H
H+ 02 ~ OH + O
O+ H :! ~ O H+H
14
.3 0 F - - -......
.25
.20
MOLE
FRACTION .1 5
.1 0
.05
__________ L
0",'"_ - - _
H 2(EO)
F O (EO)
1-16.-Characteristics of hydrogen-oxygen ignition reaction for bydro!,en burning in air at 1 atmosphere and 1700 K.
FIGURE
10
~o
MOLE
-3
FRACT ION 10
10 - 4
TIME,
FIGURE
_ _ _ 0 _ _ _-
15
COMBUSTION
1000
- - CA L CU LA T ED (BROKA W )
o EXPER IMENTAL{G.E)
100
IGNITION
DELAY,
fL SEC
10
I~__L-__L-~~~__~__~
.00 1
10
1000
[H2J1[0~
1-18.-Hydrogen-oxygen ignition delays.
sure, approx imately 1 atmo phere.
FIGURE
Pre-
16
,~ COLD
HIGH-PRESSURE
HELIUM,
\
LOW-PRESSURE
;
I \
BURSTING
CO 2 -Ar MIXTUR:7 /
~~
/ -
DIAPHRAGM...i
l"SHOCK-WAVE
,//\DETECTORS
~'.
DRIVER GAS
'-SHOCK WAVE
~WINDOW
J]r----
4 .5-M ICRON
LR. DETECTORN" _ _ _
l .R EMISSION
MONOCHROMATOR
FIGURE
FIGURE
.14
~/- DISSOCIAT I ON
RATE CONSTANT
OBTAINED FROM INITIAL SLOPE
.12
LOGARITHM
OF
.10
DETECTOR
SIGNAL,
.08
VOLTS
CO 2 + M -+ CO + 0 + M
.06
.04
0
1- 22.-D ecay of infrared emission of carbon dioxide dissociation behind incident shock. Mixture,
0.10 carbon dioxide-O.90 argon; temperature, 3240
K; pressure, 0.4 atmosphere.
FIGURE
17
COMBUSTION
FIGURE
EXPANSION
WAVE?
DISSOCIATED MIXTURE
AT EQUILIBRIUM7
I
;'
/
1/
VACUUM "",,_Lf-rnn.r---.....",.-----".....,...----~.."
TANK ~.~~~~~~-----~--~
BLUE CO FLAME/ ,
I
//
I
/
BAND EMISSION 1
DIAPHRAGM /////
PHOTO- ,-..
PIERCERS-"
MULTI PLI ERyt=.::
CJ]
FIGURE
To tran late t hi sort of information into reaction rate constant, the logarithm of the detector vo ltage i plotted against t he time after the
hock passed the window (fig. 1-22). The initial
slope of the data is then directly related to the
dis ociation rate constant for the assumption
t hat the di ssociation in vo lves carbon dioxide
colliding with a molecule M to produce carbon
mon oxid e, oxygen, and M again. The linear period in figure 1-22 provides a reliable slope, and
then the data at later times deviate from that
straigh t line a the mixture approaches chemical eq uilibrium . Dissociation rate constants from
data of this kind have been obtained over the
temperature range from about 3000 to 5000
K and for variou mixture of carbon dioxide
and argon.
A revised apparatus to mea ure recombination rates i
hown in figu res 1-23 and 24.
Both a large vacuum tank and an extra diaphragm have been added to the other end of
the driver. Furthermore, the incident shock wave
i allowed to refl ect from t he wall at the end of
the tube before mea urements are recorded. The
refl ected hock is used for the recombination
studie because there is more time available behind t he reflected wave to achieve a known
chem ical equilibrium of partly di sociated gases.
The vacuum tank generates an expansion wave
that cool the hot equilibrium sample of gas by
adiabatic expansion and thus starts the recombination processes. Proper timing is achieved
with the diaghragm piercers, which allow the
hot ga e in the tube to flow in to the large
vacuum. Th e recombination reaction is followed
by ob ervation of the so-called carbon monoxide
flame-band em ission. This emi ion is the characteri tic blue light that is emitted from a mixture of ga e whenever carbon monoxide and
oxygen atom are both simultaneously present; it
een in the mantle of an ordinary gas flame. A
monochromator isolates t he proper wavelength,
and it i detected by t he photomultiplier.
A typ ical 0 cillogram i hown in figure 1-25.
The upper trace is a pres ure record at the end
of the tube; when the reflected wave arrives, the
pres ure suddenly jumps, levels off for a long
18
,REFLECTED SHOCKWAVE
,!
r EXPANSION WAVE
,
~-l
__~~..~~~~~____~PRESSURE
----LIGHT
20
INITIAL MIXTURES
0.03 COz-O.OI Oz-0.96Ar
0 .03 CO z -0.97 Ar
15
PHOTOMUL TIPLIER
SIGNAL,
10
VOLTS
FIGURE 1-26.-Flame-band intensity in equilibrium mixtures behind refl ec ted shocks. T emperature, 3000 to
3600 K; pressure, 8 to 22 atmosphere ; CO+O --7 CO ~
--7 CO 2 + hv.
[co] x [0] .6
([cO]X[o]lT'O .4
.2
,,
,,
",
'-
'- ...
"' ... ,
OBSERVED
",,(FLAME-BAND INTENSITY)
----------
o
FIGURE 1- 27.-R ecombinatioll of carbon monoxide and
ato mic oxygen during expa n ion of equilibrium mixture
of carb on dioxide, carbon monoxide, atom ic oxygen,
molecular oxygen, and argon. Starting conditions:
temperature, 3498 K; pressure, 8.66 atmospheres.
------~-
- - - - - --
19
COMBU TION
)
i
k,
co + 0 + M ~ cOz + M
kd
I 0 171=--.,....-_ __
--~
~ MAHAN
r CL YN E AND THRUSH
o
o
0 .03 CO 2-O.97 Ar
0.07 CO z -O.93 Ar
F IGL" RE
2800
TEMP , OK
FIGURE
20
.030
r------------------FROZEN
.025
both for combustion inefficiencies and for noz. zle inefficiencies such as friction. The discrepancy between kinetic calculation and corrected
data is not too serious since there is some uncertainty in making these corrections .
.020
OH MOLE
FRACTION .0 I 5
.010
o
KINETIC
.005
EQUILIBRIUM
FIGURE
460
EQUILIBRIUM
455
0
450
0
KINETIC
445
VACUUM
SPECIFIC
IMPULSE
440
435
430
425
420
4 .5
6.0
21
COMBUSTION
TEMP=296K
,,
,,,
,
>-e
40
,"
--- ..., ,
,,
....
,,
30
"
,
THERMAL CONDUCTIVITY
(CAL CM-1SEC-1 oK - 1)
20
thermal ignition in connection with the hypersonic ramjet engine has been di cussed, but spontaneous ignition occurs in diesel engines and
perhaps also in knocking gasoline engines.
F inally, chemical kinetics in terms of exhaust
nozzle losses have been discus ed, and it was
shown how shock tu bes can be used to obtain
reaction-rate data. But t he shock tube is a versatile too l for clean studies of high-temperature
phenomena and may be applicable to cracking,
isomerization, and other reactions.
10
>- f - - - - - - - - - - - - - - - -
BIBLIOGRAPHY
01
PRESSURE, ATM
F IGURE 1-32.-Effect of chemical reaction rate on t hermal cond uctivity of ni trogen tetroxide-ni trogen dioxide system. T emperature, 296 0 K .
t hat the rates are very slow. Note that, at atmospheric pressure, the experimental data are
very close to the equilibrium curve, but that they
fall away as the pres ure decreases. The solid
curve has been calculated from the theory we
have developed by using experimental rate constants determined by shock-t ube techniques and
also from acoustical measurements.
Chemical Thermodynamics
GORDON, SANFORD; a nd ZELEZNIK, FRAN K J . : A General
IBM 704 or 7090 Computer Program for Computation
of Chemica l Equilibrium Compositions, R ocket P erform ance, a nd Chapman-Jouguet D etonation . Suppl ement I-A igned Area-Ratio P erforma nce. NASA
TN D-1737, 1963.
M cBRIDE, BONNIE J.; H EIM EL, SHELDO~ ; EHLERS, J ANET
G.; and GORDON, SANFORD: Thermody namic Proper ties
to 6000 0 K for 210 Substances Invol ving t he Fir t 18
Element. NA A SP-300l, 1963.
ZELEZNIK, F'R.~ NK J .; a nd GORDON , SANFORD: A General
IBM 704 or 7090 Computer Progra m for Computation
of Chemical E quilibrium Compo ition , Rocket P erforma nce, and Chapman-J ouguet D etonation.
ASA
T N D-1454, 1962.
ZELEZNIK, FRANK J .; a nd GORDON , SANFORD: Equilibrium Computation for Mul ticomponent Plasmas.
NASA T N D-2806, 1965 .
Transport Properties
BAKER, CHARLES E.; a nd BROKAW , RICHARD .: Therma l Conductivities of Ordinary and I otopically Substituted P ola r Ga es a nd Th eir Equimolar Mixtmes.
J . Chern. Phy ., vol. 43, no. 10, 0 \ ' . 15, 1965, pp. 35193528 .
BROKAW. RICHARD S.: Correlation of Turbulent H eat
Transfe r in a Tu be fo r t he Di ociating System N 20,
P2N0 2 .
ACA RM E57K19a, 1958.
BROKAW, RrCHARD .: Th rm al Conductivity of Ga.s
Mix t ures in Ch mi cal Equ ilibrium II. J . C hern . Phys.,
vo l. 32, no. 4, Ap r. 1960, pp . 1005- 1006.
BROKA W, RICHARD .: Alignm ent Chart for Tran port
Prope rties, Vi sco ity, Th ermal Conductivity, and Diffu ion Coefficients for onpo la r Gases a nd Ga Mixture at Low D ensity. NASA TR R-81, 1960.
BROKAW, RICHARD S.: Approximate Fomulas for Visco ity a nd Therm al Conductivity of Gas Mixtures.
A A T D-2502, 1964.
22
Vaporization
DEJUHASZ, K ALMAN J ., ed.: Spray Li terature Abstract.
Vol. I , ASME, 1959.
D EJ UHASZ, KALMAN J .: Sp ray Literatu re Abst ract, Vol.
II . Dru ckerei Winter (H eidl eberg) , 1964.
I ' GEBO, ROBEIlT D.: Vapori zation Rat es and Drag Coefficients for I ooctane Sp ray in T mbu lent Air
treams. NACA TN 3265, 1954.
PR IEM , RICHARD J . ; a nd H ElOMA):).'. M ..IIlClS F.: Propell a nt Vap orization as a D esign Crit erion for RocketE ngine Combustion Chambers . K ASA TR R -67 ,
1960.
WIEBER, PAUL R. : Calculated T emperaLure Hi tor ie of
Vaporizing Dropl et to the Critica l Point. AIAA J. ,
voJ. 1, no. 12, D ec. 1963, pp. 2764-2770.
ignition
BELLES, FIlANK E.; and LA UVER, MILTON R.: Effect of
Concentration and Vibrational R elaxation on Induction P eriod of H ydrogen-Oxygen R eaction. ~ASA T~
D-2540, 1964.
Sprays
BITTKER, DAVlD A.: Effect of Ambi ent Air Velocity on
Atomization of Two Im pin O'ing Water J ets. NA A
TN D-2087, 1964 .
CLARK, BRUCE J . : Breakup of a Liquid J et in a T ransD -2424, 1964 .
verse Flow of Gas. N A A T
FOSTER, HAMPTON H .; and HElDMAN , M .~RCUS F.:
Spatial Cha racteri stics of W ater Spray Formed by
Two Impinging J ets at Several J et Velocities in Quie cen t Air. NASA TN D-301 , 1960.
HElD MANN, MARCUS F.; PRIEM , RICHARD J .; and HUMPHREY, JACK C.: A Study of Sprays Formed by Two
Impinging J ets.
ACA TN 3835, 1957.
Chemical Kinetics
INGEBO, ROBERT D.; a nd FOSTER, HAMPTON H.: DropSize Di t ribu t ion for Cro current Breakup of Liquid
J ets in Airstreams . NACA TN 4087, 1957.
I NGEBO. ROBERT D.: Drop- ize Distributions for Impinging-Jet Brea kup in Airstreams S imulating the Velocity
Condition in Rocket Combustors. NACA TN 4222,
1958.
MORHELL, GERALD; and POVI ELLI, FREDERICK P.: Brea kup of Vari ou Liquid J ets by Shock Waves and App li cation to R esonant Combustion.
ASA T
D2423. 1964.
- -- - - - - -- - -- _. -
=~-~~---
~----
23
COMBUSTION
---
_.._ -- - -
llll
Some Developments
in Aerospace
H eat Transfer
Problem Areas
A simplified diagram of a nuclear rocket is
given in figure II- I. The system is composed of
a propellant storage and pumping system, a nuclear reactor to add heat to the propellant, and a
nozzle or thrustor to expand t he heated propellant and provide a thrust velocity. Consider the
flow chart of the liquid propellant. The propellant starts as cryogenic hydrogen stored in the
tank at a t emperature of 420 F below zero.
FUEL EL EMENTS
4500F
LIQUID Hz TANK
-420- F
FIGURE
25
26
0000000000
FIGURE
....
FLOW
BOUNDA RY L AY ER
F ILLS PIP E SEGME NT
(a)
(b)
FIOURE
of
OME DEVELOPMENTS I
/~G A S
,~
SIDE
PREDICTE D
-,~ E X PE RI MENT AL
OL-__- L___________________
LENGTH
II-4.-Comparison of experimental and predi oted gas ide heat tran fer,
FIG U RE
l_
27
BOUNDARY
LAYER
HOT
GAS
FIGU RE
cili ty.
I.O. - - -- - - -- - - ----:-:U- - - - - - - - --.
5
I
.8
I
I
DIST ANCE,
.6
FRACTION OF
BOUNDARY LAY ER
THICK NESS
.4
ACCELERATING " )
I ',
NONACCELER ATING
(117 PO WER L A Wh
I
I
"
.2
I
I
"
't
,/
.2
.4
.6
.8
V ELOCI T Y RATIO, ulu s
FIGU RE
1.0
non-
28
\ TURBULENT EDDIES
///C/) '
W//~W<Y/'
STRETCHED
000~
FLOW.
EDDIES
,
G ~~//
0 O~///~~~
/ff//////////////////-
'~ N E G L E C TIN G
ACCELERATION
EFFECT
RELATIVE
RADIAL
MIXING
FIGURE
LIQUID H2 TANK
-420F
PUMP
FIG URE
II
29
PRESS UR E,
ATM
200
GAS
DENSITY,
LB/CU FT
40
12.8
rCRITICAL
\
.. PRESSURE
7
I
I
I
I
I
I
-440 -420 - 400 - 380 -360 -340
TEMP, OF
I
I
-320 -300
FIGURE
-420 F
II- IO.throat.
FIG RE
30
TRY
~DE
~SIDE~ ~
/'
SECTION
2 .0
HEAT FLUX RATIO,
CURV ED TUB E
1.5
STRAIGHT TUBE
In
/ - OUTSIDE
/'~ STRAIGHT
1.0 '-==---'--- - - - - - - -
r- GAS
HYDROGEN
I
I
SUPPLY
\
I
\
\
' - LIQUID
HYDROGEN
SUPPLY
FlGlRE
'
FLOW
5/16IN . 1.0. TUBE
R=4.5 IN.
A-A
FIGURE
FLOW
tube
31
Full-Scale Testing
Sin ce t here i a 2-to-l in crease in the coolant
heat-transfer coeffici ent at the throat because of
th e chann el curvature and a 2-to-l decrease in
the hot ga ide coeffi cient near the throat as
discu ed earli er, there i in total a 4-to-l a dvan tage over what was ori ginally predicted. These
measurements, however, were obtained under
laboratory conditions; con equent ly, there is
om e qu estion as to whether these lower nozzle
cooling requirements can be reli ed upon in fuIlscale hardware.
To better determine ju t how evere t he actual
cooling problem is, a te t program is pl ann ed
wit h t he use of a highly instrumented nozzle.
These t ests will be condu cted with a new facility
that is now under construction. Thi facility,
iIlu t rated in figure II- l3 , will be able to provide
cIo e simul ation to t he nuclear nozzle on both
the hot gas and coolant sid es. Simulation of
the hot ga side of the rocket nozzle is provided
by supplying t he research nozzle with heated
hydrogen gas. The gas is heated by a pebble
heater 28 feet high and 5t feet in diameter. The
bed is fill ed with 2t -inch -diameter graphite
ba ll s. H eatin g of t he bed i provided by electri cal induction heating of a graphite susceptor that
forms the wall of t he bed. The hydrogen gas is
upplied from an outside storage vessel. The
l_
HEAT
I
J-,;'''''!'Tr->''', EXCHANGER
t
FIGURE
32
, ICE LAYER
~##$~~
WARM
WATER
FLOW
\
"
~INSUL A TED
WALL
COLD
ALCOHOL
FLOW
\
..
\
"
/Wm#/~~
'- THERMOCOUPLE
FIGURE
Powerplant Components
It i expected t hat, in t he year to come, pacecraft will be larger and will be involved in
lon ger and more complex mission. Therefore,
they will require more and more on board electrical power. Power will be needed for such
thing as communications, operation of life-support equipment, and propui ion by various electrically powered means for flight changes and
33
FER
FIGURE
I
I
I
I
I
II- l7 .- N ucl ear-elec tri c space power generation
y tem.
FIGURE
I
I
34
SAME SCALE AS
(b)
VAPOR
TO
TURBINE
(0)
t
LIQUID METAL
FROM
RADIATOR
FIGURE
- - - - - - - - _. -
-- .
--
--
35
lQ)
(a ) ucleate boiling.
(b ) Film boiling.
FIGURE II- 19.- Appearance of nu cleate and fi lm boiling
regim es.
\
\
"-.....\
./
~ ,;.I~
' "
HEATED SURFACE
CONDENSING
EVAPORATIN G
SUPERHEATED LIQUID
Itt
\\\
'-
evaporation
MICROLAYER
heat-transfer
36
ILIa I ,
I SLUG I ANNULAR I
MIST
~.~,------~.-------/
BUBBL y J
NUCLEA TE
FILM BOILING
BOILING TRANSITION
POINT
VAPOR CONVECTION
HEAT
FLUX
FIGUHE
MIX TURE
OUT
L IQU I D
IN
II-24.-J et mixing of liquid and vapor to demon-tJ'ate two-phase insta biliti es.
F , GURE
_____.~_J
:'
LlQUID .J>
FIGURE
,
"~ SHAFT
37
Un table flow excursion in the boiler can lead
to serious difficulties in the space powerplant.
For examp le, liquid may enter the turbine and
damage the turbine blade. Con equently, this
problem i being pur ued along everal paths.
The mechanisms and the mathematics of such
flow in tabilities are being studi ed by u ing exten ions of analy es of pipe line dynamics. An
attempt i a lso being made to prevent the e instabili ties by various designs and devices.
One way to tabilize the liquid-vapor interface
in weightl es flight is to create an artificial gravity by rotating t he parts of the flow system t hat
undergo a pha e change. Figure II-25 shows
an apparatus in which boiling take place in a
rotating cup . The liquid enters at t he bottom of
the device through a hollow shaft. It pa ses
through a regulating valve and then sprays out
to the cy lindrical wall, where it form an annulus
of liquid. Th e liquid pas es up into the heated
zon e to replace t he liquid that ha boiled off.
At the liquid-vapor interface, vapor leaves the
liquid and flow toward the center of rotation and
then out the top of t he boiler. Pho tographs taken
through a window on top of the rotating cup
have shown that boiling can be quite stable at
conditions of 75 times Earth gravity and at a
heatin g rate of 250 watts per square inch
( ~1 2 0000 Btu/( hr) (sq ft)) . Under these condition , bubbles form at the heated urface and
quickly move inward through the liquid. At this
point the bubble break, and being quite numerous, t hey form a t hin zone of bubbly froth at the
interface. By increasing the rotation and generating 475 tim Earth gravity, the bubbling was
a lmo t entirely eliminated, but the boiler could
till t ransfer t he same rate of heating by vaporization only at the interface, which was then a
sharp teady boundary between clear liquid and
vapor. The maximum heat that can be transferred to water by poo l boiling at one gravity
is about 650 watts per square inch ; above t his
leve l film boiling ets in. However, at 400 Earth
gravit ie 40 watt per quare inch (30 percent
more) have been tran ferred, and only a few
patche of bubb les were actually formed in the
proce . Obviou ly, much higher heating rates
and higher gravities are possible and could be
very beneficial.
38
[XXXX~ ~
TWISTED TAPE
HELICAL SPRING
FIGURE
...
4 11//
- -'\'-' ....
SPRAY TUBE
0
0
...
~ ...
~:
( 0
NOZ ZLE
~~
-....;:
-----
serts.
Other ways of stabilizing a once-through boiling process are to design the stationary flow
tubes to impart a wirl to the fluid as it passes
through. Idea a to how this may be accomplished are shown in figure II-26. The boiler
tubes are shown with in erts such a twisted
tape, spiral ribbons, and helical wire springs to
pin the fluid, thereby throwing the entrain ed
liquid again t the tube wall, and allowing vapor
to flow down the center. Even a tube bend, a
wa hown in figure II-I (b) of th pace boiler,
will eparate the pha e in two-pha e flow. The
tube bend thus erves the dual purpose of relieving thermal stresse and aiding the boiling
proce .
Another technique to stabilize boiling, as
shown in figure II-27 , is to add an in ert such a
a short spray tube, a nozzle, or a conical plug
FIGURE
ID
space
39
~o CRITICAL
POINT
f-
INH3/
,
PRESSURE,
PSIA
, ,
/"
I I
I I
CH 3 0H/
I
100
I
, ," ,9,'
,
/'
,0
1,000
'
,I
, ,
,, , ,,,
/
I.'
~C 12H26
H2 0-.p " H
CS/~N
"1
II,
/1/
" I
1/ I
III
/I I
1000
TEMP. OF
,liI
II Pb
'I
I I
10,000
RE II-29.-Boiling pressure and temperature for conventional Auid and liquid metals.
FIG
BOILING
LlQUID)~S~~IE~
~,~""~""7"""""",,,,,........~
HEATED SURFACE
F IGU RE
40
Containment Materials
FIGURE
rrom
CAVITY
RAD IUS
l li;;Ii:lllllllj'I'I,lltili
SURFACE SUPERHEAT
FIGURE
BOILER
T U BE
INLET
HEAT I NG ELEMENT
HOT FINGER
FIGURE
tube.
41
Space Radiator
As was mentioned earli er, the radiator for a
a space power system can be of co lossal size.
In fact, even at high temperatures it rema in the
largest and heaviest component in the system.
This is illustrated in figure II-36 , which shows
a proposed design for an eight-man M ars mission. The radiator in t his case i t he ize of two
football fi elds ! Thi large ize arises because, to
generate a certain amount of power, the system
must reject a given amount of waste heat. Since
radi ation t o pace is t he only effective way of
doing this, look at the relations governing radiant
heat loss. These show that radiator area depends
directly on the heat rejected and the surface
radi ation properties, and inversely on the absolute surface temperature to the fourth power.
High temperatures near the material limits are
already being utilized, and surface properties are
chosen to be as clo e a possible to that perfect
r adiator , the blackbody. This does not leave
much room for fur ther reducing radiator area.
FIGURE
ci lity.
FIGURE
'?'\~~\~==ebic
\\
\~ PROPELLANT
\~ REACTOR
FIGURE
CREW CABIN ,
,,:
3l!t,
LANDING CRAFT ~
SYSTEM
42
rIG
r -- - - - - -
43
CONCLUDING REMARKS
In conclusion it should be poin ted out that
only a limited number of heat-transfer problems
have been discus ed that have required further
investigation for the development of space t echnol ogy. In t he di scussion two y t ems have been
chosen for purposes of illustration: the nucl ear
rocket engin e, and a space electri c power generation system . Al t hough the e are specific ystem .
their design requirements have led to many
problem that are of a basic nature. These includ e uch things as turbul ent heat tran fer with
large flow accelerations, flow of near-critical
flui I in curved chann el, solidification of a liquid flowing over a coo led surface, and the many
comp lexiti e of high-tempera ture forced flow
boiling.
It is hoped that thi di cu sion has provided
a good indi cation of the scope of heat-transfer
information which is avai la ble as a re ul t of
space programs.
BIBLIOGRAPHY
rLi sted in orde r of di scu s ion o f ubject matter in text.]
IEGE L, R.; AND AVINO , J. M.: An Ana ly i of th Tra nsient olidi fication of a Flowing W a rm Liquid on a
onvectively Cooled Wall. T o be Pre en ted at the
Third In ternationa l H eat Transfer Conference, Chicago . 111., Aug. 1966.
nnn
H ydrod ynamics of
Liquid Surfaces
OR TH E LA ST SEVERAL YEARS
W . OTTO
Lewis Research Centel'
EDWARD
a re noticeabl e. Typically, the effects of domi nant inertial forces a re t he shaping of liquids
in tanks, t he weight of the liquid, the hydrostatic pres ure of liquid columns, t he rise of
vapor bubbles in liquid due to buoyancy, and
the convection currents in liquids a a result of
heat inpu ts. Although t he surface tension for ces
are small in comparison with inertia force at
1 g, their effects are sti ll observable in the meniscus of liquids in contact with so lid bodies and
in the capill ary rise or depres ion in small di ameter tubes.
However, when a liquid or a system containing liquid and vapor i allowed to accelerate
freely in t he lo cal gravity field, t he inerti a forces
disappear and t he surface tension forces remain .
These forces are domin ant in determining the
equilibrium liquid confi guration and the liquid
configuration dynamics and playa larger role in
t he heat-transfer mechanics.
Early History
Th e history of the study of surface-tension
p henomena can be traced as far back as Leonardo da Vinci and Sir I saac Newton ; however,
it wa Young who first estab li shed the theo ry by
demonstrating how the principles of surface t ension and contact angle can be u ed to explain
a great many capillary phenomena. The theory
wa put on a firm math matical foundation by
Laplace and later Poi son. Further development were made by Gauss, who app lied the
principle of con ervation of energy to the system
and obtained not only t he equation of the free
surface but al 0 t he conditions of the contact
a ngle. Other early investigators include Dupre,
Rayleigh, Gibb , and Plateau, who ut ilized soap
45
--- .. - - - -
46
bubble and ot her device to determin e the equi librium configuration of liquid. Later investigation s were carried ou t by Langm uir and H arkin
in the nited tates and Ad am and Burdon in
England.
and
() =cos-
CTvs - CTls
(2)
( ymbols are defined in the appendix.) Equati on (1) i known a Youn g's equation. It i observed th at the contact angle () depends on the
magni t ud es of t he three urface-ten ion force .
When (CTrs- CTPs/CT"1 i between 0 and 1, t he con-
2CT
(3)
Thi expression is found everywhere in the literature and i imply derived by equating the surface-ten ion for ce acting a long a meridan circumference to a pres ure difference times the
circul ar area enclosed by thi s meridan circumference. If th e interface is not pherical, the
pressure drop is given by the more general equation
SOL
(4)
Dimensionless Parameters
0 <9
90 <9 <180.
< 90.
(a ) Wetting liquid,
(b)
onwetting liquid,
90 < fJ<180.
III- l.- Surface energy and con tact angle rela tion.
- -_.
- - -- . - - - -
47
flow and convection current characteristics, respectively, in different sized systems and also
define regimes of different behavior. Other dimen ionless parameters t hat have been found
u eful in the field of fluid mechanics are Grashof
number , Prandt l number, Froude number, Nu sselt number, Mach number, etc. These parameters are useful t o the t heorist in providing an
insight in to the ba ic behavior mechani sm and
to t he engineer as an aid in studying the behavior
of full-sized systems through the use of model s.
Two dimension Ie s parameters that are useful in t he field of capillarity are Bond number
Bo , the ratio of gravitational or acceleration
forces to capillary or surface-tension forces , and
Weber nu mber We, the ratio of pre sure or
inertia forces to urface tension for ces. These
parameters a re defined in terms of the physical
constants of the system as follows:
a-L
aL
(5)
aL
aL
= L pL
(6)
1000
INERTIA DOMINATED
100
(7)
(8)
The value of the Weber number will be empirical depending on the specifi c configuration.
Reynolds (ref. 1) has portrayed the various
hydrodyn amic regimes as a function of Bond
and Weber numbers as shown in figure 1II-2,
wh ich is taken from hi s work. This diagram
provides a useful means of visualizing the several
hydrodynami c regimes as defin ed by the several
dim ensionless parameters.
FACILITIES
Th e Lewi R e earch Center has utilized several zero -gravity facili ties to obtain various periods of zero-gravity time. A diagram of t he facilitie a nd a compari on of their times is shown
in fi gure 1II-3. Each of these involves the technique of free fall to obtain a zero-gravity, or
weightless, environment.
10
~~9J?~~%~~
17.
___ACCE
LERATION
OR GRAVITY - DOMINATED
.1
CAPILLARY
DOMINATED
.01
.001
FIGURE
.01
.1
10
100
III-2.-Hydrodynamic regimes.
1000
48
10-20 SEC
2 SEC
5 MIN
/ - ......
AJ2 AIRPLANE
:'
A
DROP TO WER
,
\
DUSTRY
using an experimentally determined Webe r number near 7, where L i again the radius. The
most significant aspect of figure III-4 is the low
acceleration, or g-level , required for interface
experiment in the 2- to 20-inch range (the most
de irable model range). Thi requirement also
implies that the initial di turbance be low. These
acceleration and disturbance requirements have
prevented succes ful u e of airplane facilities for
interface experiments even though their 15econd time range ha been very attractive.
AEROBEE ROCKET
1II-3.-ZeI'0-gravity facilities.
lo.oof
IN TERFACE 100
FORMAT ION I~
TIME, SEC
I
,~
. I'-------"""-~I
ACCELERATION 0-4
OR 9 LEVEL I
1010-8L-_ _-!-_ _-,l:--_ _--L_ _~
.1
FIGURE
49
fLOOR,
TEST PACKAGE
PRE-DROP POSITION
81"
I"
RELEASE
MEeHANIS ..
HOIST fOR LIfTING
TEST PACKAGE
ACTUAL DROP HEIGHT
85 fEET
61" FLOOR ,
CHEM ICAL
LABORATORY--" I
ENTRANCE GROUND
LEVEL
51" fLOOR :
EXPERIMENT ASSE MBLY
AND WORKING AREA
4 TK fLOOR'
M[CHANICAL fABRICATION
AND STORAGE AREA
2"D fLOOR :
CRYOGENIC
LABORATORY-----
ANNEX :
HYDROGEN
STORAGE
AREA
151
fLOOR
SAND STORAGE
HOPPER
(a ) Before test
drop.
- -
- - - . -- - --- - -
50
DUSTRY
. VACUUM PUMPS
STEEL CHAMBER-
.......
-'
........
.... ....
-.- ACCUMULATOR
,j
FIGURE 1II- 7.-400-Foot zero-gravi ty drop facili ty (per pective cutaway vi ew) .
- ---
-----. ----
51
the bottom of thi steel tube, and t he deceleration device, whi ch con ists of styrofoam, is
moun ted in a pocket near t he bottom of the steel
tube. Th e decelera tor roll in to pl ace a fter t he
experimen t i proj ected. E vacuation t o 10- 5 atmosph eres allows experiments to be conducted
wi thou t a drag hield ; howeve r, the accelerator
and decelera tor are designed t o accommodat e
the weight of a drag hi eld if de ired .
F IGU RE
FI GU RE
52
INTERFACE STATICS
Interface Configuration in Cylinders and
Spheres
DISTURBANCE THRUSTER
EXPERIMENT
TELEVISION CAMERAS
\
\
\
\
\
\
\
DISTURBANCE THRUSTER
\
\
\
!' . 'I!
The configuration of the liquid-vapor interface under weightle conditions has been studied
analytically by several investigators. Benedikt
(ref. 2) and Reynolds (ref. 1; Reynold having
indicated that he also found the calculations in
the work of Rayleigh) calculated exact solutions for the configuration of the interface between parallel plates as a function of the gravity
level or Bond number. From the e calculations
and the principle involved, they inferred the
configuration of the interface in other geometries. Li (ref. 3) u ed the principle of the minimization of the free surface energies to predict
the interface configuration in many geometries .
All these analyses indicate that the interface
~OCKET
FIGURE
Bo
X/L
(0 )
.8
Bo
.4
0,,
, ,
2 . 2"""'\ \
flL
22 "
.'
,
2L
(b)
X/L
FIGURE
53
configuration is primarily dependent on the contact angle and that during weightlessnes the
liquid vapor interface tend to a sume a constant curvature urface that intersects the tank
wall at the contact angle.
The results of the calculations for the configuration of the interface between two parallel
plates as obtained by Reynolds are presented in
figure III-ll. The calculations present the interface configurations for a relatively wetting liquid
(contact angle, 10) and a relatively nonwetting
liquid (contact angle, 140), each at a series of
Bond numbers from zero (true weightlessness)
to infinity (essentially repre entative of 1 g). At
a Bond number of zero, the interface is a surface
of constant curvature intersecting the wall at the
contact angle. The contact angle determine
whether the surface is concave or convex. The
increased distortion of the surface from its constant curvature configuration as Bond number
increases is apparent.
The results of the calculations for the two
dimensional ca e may be u ed to infer the configuration in three-dimensional geometries. Figure 1II-12 shows the predicted configuration for
cylinders and for spheres as a function of the
contact angle and for the volume fraction of
liquid in spheres. These predicted configurations
are for a Bond number of zero. Five general
configurations are shown for pheres ranging from
an imbedded vapor bubble for all fillings at zero
degree contact angle to an imbedded liquid mass
for all filling at the hypothetical contact angle
of 180. The curved line indicates the combination of contact angles and fillings at which the
interface i flat as depicted by the center diagram.
The diagrams on either side of center are generally representative of the configurations obtained for the combination of contact angles and
fillings in the surrounding area. The configurations predicted for cylinders do not show the end
effects that would be encountered in ta,nks with
normal ends. For tank with hemispherical ends,
the configurations may be inferred from the configuration for sphere .
Experimental verification of the predicted interface configurations has depended heavily on
a suitable zero-gravity facility. The author and
I-G
"'"
VAPOR
VAPOR
~ ~ Ll OU ID:z:: /.
(i)
18 0
160
140
120
100
8, DEG
80
o
20
o
I
(b)
I
I
20
40
60
80
PERCEN T VOLUME
I
100
FIGURE
10
cylin-
his colleagues conducted a series of experiments (ref. 4 and 5) in the NASA Lewis Research Center 2.3- econd drop-tower facility that
verified the predicted configurations. These experiments were conducted with liquids with three
different contact angles in spheres, cylinders,
and cone at several different fillings. The results
for the range of conditions can be represented
by figure III-12; however, photographs of several
--_._-- - -
54
SELECTED TECH
IVAPOR
~lIQUID
90," FULL
50'" FULL
n
v
.tl
",Q
Effect of Baffles
The analyses for defining the configuration of
the interface indicated a reduction of system
L_
in spheres.
energy a the interface changed from its normal gravity configuration to the zero-gravity configuration. Therefore, the study of the ability of
tank geometries, which provide appreciable
changes in surface energy to position the liquid
and vapor in acceptable configurations, appeared
promising. A simple configuration that probably
has occurred to mo t investigators in the field
and ha been suggested and analyzed by Reynolds (ref. 1) is a tube mounted over the pump
inlet concentric with the vertical centerline with
holes around the bottom to allow fluid transfer
- -- - - -
I
t
55
r
10~ FULL
VAPOR
~ LlOUID
90% FULL
50% FULL
... ~
(b)
(e
56
APPROACHING STEADY-STATE
ZERO-G CONFIGURATION
(a)
(b)
(e)
(d)
FIGURE
57
FIGU RE
INTERFACE DYNAMICS
58
ETHYL ALCOHOL
FORMATION
TIME .
SEC
CARBON
TETRACHLORIDE
'
.1 '---'--L...J...J'-LL.L"----L..L...I..J...llJ..U..,,--l.-LLJ....L.L.U.J
I
10
102
103
DIAMETER OF TANK. CM
III-18.-Effect of tank size and liqu id properties on interface form ation time in spheres afte r
entering zero gravity.
FIGURE
ETHYL ALCOHOL
FORMATION
TIME .
SEC
d: FORMA TION DISTANCE
tER'ACE
-
I-G
O-G
.0 I L--...L.L..Li..l..l.llL_L...l.-L.L..l..lll..l..:;---'--L.LL.L.ll.J..J
10
10 2
DIAMETER OF TANK . CM
FIGURE
DUSTRY
)'/2(~ )'/2(CD )
3/ 2
(9)
59
I~
liqUid
(0 Vapor blowthrough;
FIGURE
60
0
0
6
'Cl
D
0
100
0
0
2
4
8
16
4
4
4
4
LIQUID
DOUT
DTANK
0.'.1
.1
.l
.1
.2
.05
.1
.1
ETHANOL
METHANOL
CARB TET
FIGURE
INTERFACE
VELOCITY
ON TANK 10
CENTERLINE,
CM/SEC
10
AVERAGE INTERFACE VELOCITY, CM/SEC
FIGURE
61
of the acceleration field and position of the interface relative to the edge of the tube. The critical
diameter is hown as a function of the specific
surface tension a/p o The left axis intercept of
the solid line approximating the data is proportional to the critical Bond number and is computed as follows with figure III-23 as an example. The equation of the solid line that is drawn
at a slope of t i , after the critical diameter is
converted to centimeters,
a
D=0.184 [ pa(O.OI)
--------
J1/2
(10)
[ (2~'~~~)
J=-;aR2
= 0.84=BocriUcal
(11)
CRITICAL
DIAMETER,
MM
t
ACCELERA TlON
1II- 23.-Stability characteristics in vertical cylinder. Acceleration, 980.2 centimeters per second per
second.
FIGURE
I
j
62
10
t
ACCELERA TION
o
4
CRITICAL
DIAMETER.
MM
B O~I.l2
t
ACCELERA TION
0,
CM
FIGURE
specific surface tension of 28.28 cubic centimeters per second 2 , which is representative of
many propell ants. The data obtained at 1, 0.1,
and 0.01 g are shown. The critical acceleration
fo r vehicles of 100 to 400 inches in diameter
is indicated as 10- 6 to 10- 7 g.
Accelerations less than the cri tical value may
be encountered in situation of low residual atmospheric drag, solar pres ure, attitude control
di turbances, or crew movement . Re idua l drag
or solar pressure will re ult in a continuous
acceleration, which will distort the interface in
a generally predictable manner. The operation
of attitude controls or crew movement , however, cau e intermittent acceleration perturbations t hat may set up an 0 cillation of the interface. In high gravitational or acceleration fields
(high Bond numbers), the frequency of 0 cillation is determined by the gravitational or acceleration force . In a zero -gravity environment
(zero Bond number), the surface tension forces ,
the only remaining restoring force , determine
the frequency. The damping of the e oscillations is dependent on the viscosity for both high
and low Bond number situations. It will be important to avoid these frequ encies in attitude
control systems.
.
There is extensive treatment in the literature
concerning the dynamics of free surfaces but
only for the condition of an unbounded 'surface
10
6
CRITIC AL
DIAMETER,
MM
ACCELERATION
~~I-------r~----L--,6-~-,~~~~
SPECIFIC SURFACE TENSION / ACCELERATlON,u/ po , CM2
FIGURE
63
100
CRITICAL
DIAM, 10
MM
I G NOM
0.1 G NOM
0 .0 1 G NOM - -
ACCELERA TION
1
ACCELE RA TION
.Jld
I
i
g
I
I
I
I
I
I
I
I
()
I
.01
1- G EXPERIMENTS
SPECIFIC SURFACE TENSIONI ACCELERA TlON, "Ip. , CM2
FiGURE
III
vertica l
10- 2
ACCELERATION ,
G
10.....
10~
1 0~
10-7 '---'-----'---'---'-:---'--''---'"---'
.1
100
1000
DIAMETER , IN .
1II- 27.-In te rfacial stability as function of acceleration. Specific surface tension, 28 .28 cubi c centimeter per second .2
FIOU RE
r!l
ACCELERAT ION
.5
.4
ACCELERATION,
FROUDE
NUMBER , .3
V
(oR )"2
.2
CM/SEC
o
"
.1
NASA
HATTORI
GOLDSMITH
TAYLOR
NASA
e.
980
MASON
}
1II- 28.-P enetration velocity of ull age vapor during collection . Specific surface tension, 11.8 to 74.12
cub ic cen ti meters per second 2; radiu , 0.165 to 4.77
centimete rs; acceleration, 9.8 to 980 centimeters per
second per second .
FiG URE
64
CONCLUDING REMARKS
In ummary, the result of research concerning the dynamic behavior of the surface of a
liquid when influenced primarily by surface tenion force have been reviewed. Although our
research ha been directed primarily toward fluid
behavior and management problems in space
vehicles under zero-gravity condition , a great
deal of attention ha been given to scaling parameters involving fluid properties and ystem
geometry. The results are therefore widely applicable and can provide an insight into normalgravity fluid behavior in such capillary-dominated systems a small tubes, creen, porous
material , and similaJ." geometrie common to the
petroleum industry.
APPENDIX-SYMBOLS
a
Bo
G,K
D
F
Fa
Fc
Fi
FT
L
M
p
R
T
V
We
8
p
(Tt,
(Tv t
(Tvs
REFERENCES
1. REV OLDS, WILLIAM C.: Hydrodynamic Considerations for the De ign of Systems for Very Low Gravity Environments. R ep. No. LG-1. Stanford Univ.,
Sept. 1961.
l_._.
DUSTRY
2. BENEDIKT, E. T.: Epihydrostatics of Liquids in Vertical Tank . R ep. o. A G-TM-{j1-48, orair Div.,
North rop Corp., June 1961.
3. LI, TA: Hydrostatic in Various Gravitational
Field. J . Chern . Phy ., \'01. 36, no. 9, May 1, 1962,
pp. 2369-2375.
4. PETRASH, DONALD A.; ZAPPA ROBERT F. ; and OTTO,
EDWARD W. : Experimental Study of the Effects of
Weigh ti es nes on the Configuration of Mercury and
Alcohol in Sperical Tank.
ASA TN D-1l97 . 1962.
5. PETRASH, Do ' ALD A.; I USSLE, RALPH C.; and OTTO,
EDWARD W.: Effect of Contact Angle and Tank
Geometry on the Configuration of the Liquid-Vapor
Interface During VI eightle n s. NASA TN D2075, 1963.
6. CLODFELTER, ROBERT G.: Fluid Mechanics and Tankage Design for Low-Gravity Environments. R ep.
No. ASD-TDR..{l3-506, Air Force Systems Command, Wright-Pattel'Son AFB, Sept. 1963: (Availab le from DDC a AD-423554).
7. PETRASH , DONALD A.; NELSON, THOMAS M. ; and
OTTO, EDWARD W.: Effect of Surface Energy on the
Liquid-Vapor
Interface
Configuration
During
Weightle sne . NASA TN D-1582. 1963.
8. PETRASH, D. A.; and OTTO, E. W.: Controlling the
Liquid-Vapor Interface Under Weightlessness. Astronaut. Aeron., vol. 2, no. 3, M ar. 1964, pp. 56-{)1.
9. PETRASH, DONALD A.; NUSSLE, RALPH C.; and
OTTO, EDWARD W.: Effect of the Acceleration Disturbance Encountered in the MA-7 Spacecraft on
the Liquid-Vapor Interface in a Baffled Tank During
Weightlessness. NASA T
D-1577, 1963.
10. BENEDIKT, E. T.: General Behavior of a Liquid in
a Zero or Near Zero Gravity Environment. Rept:
o. ASG-TM-{j0-9Z6, Northrop Corp., May, 1960.
11. RAYLEIGH, LORD: On the Capillary Phenomena of
J et . Roy. Soc. (London), Proc., vol. 29, no. 196,
May 15, 1879, pp. 71-97.
12. SIEGERT, CLIFFORD E.; PETRASH, DONALD A.; and
OTTO, EDWARD W. : Time R e ponse of Liquid-Vapor
Interface After Entering Weightlessness. NASA
TN D-2458, 1964.
13. POVITSKlI. A. S.; and LYUBI , L. YA.: Emptying
and Filling Vessels in Conditions of Weightlessness.
Plan tal)' Space Sci ., vol. 11, 1963, pp. 1343-1358.
14. Nus LE, RALPH C.; DERDCL, J OSEPH D .; and
PETRASH, DONALD A.: Photographic Study of Propellant Outflow from a Cylindrical Tank During
Weightle. ne-s. NASA TN D-2572, 1965.
15. MA lCA , WILLIAM J .; PETRASH , DONALD A.; and
OTTO, EDWARD W.: Hydro tatic Stability of the
Liquid-Vapor In terface in a Gravitational Field .
NA A TN D-2267, 1964.
16. BRETHERTO . F. P.: Motion of Long Bubbles in
Tubes. J. Fluid Mech ., vol. 10, pt. 2, Mar. 1961,
pp. 166-188.
65
(London), Proc .. ser. A, vol. 200, no. 1062, F eb. 7.
1950, pp. 375-395.
21. GOLDSMITH, H. L.; and MASON, S. G.: Movement
of ingl e Large Bubbles in Clo ed Vertical Tubes.
J . Fluid Mech., vol. 14, pt. 1, Sept. 1962, pp. 42-58.
22. MASICA, WILLIAM J. ; and PETRASH , DONALD A .:
Motion of Liquid-Vapor Interface in R esponse to
Imposed Acceleration. NASA TN D-3005, 1965.
23 . MASICA, WILLIAM J .; and SALZMAN, JACK A.: An
Experimental Investigation of the Dynamic Behavior of the Liquid-Vapor Interface Under Adverse
Low-Gravitational Conditions. Presented at Symposium on Fluid Mechanics and H eat Transfer
Under Low Gravitational Condi tions sponsored by
the United State Air Force and Lockheed Missiles
and Space Company, Palo Alto, Calif., June 24-25,
1965.
ITV
Surface Physics
and Chemistry
W E USU ALLY K NOW T H EM are covwit h oxid es, oil film s, and adsorbed
ga e . Much of their behavior i di ctated by the
properties of the contaminants rather t han by
the structure of the substrate material. In some
instances, con tinual interaction between t he contaminants and t he substrate material cont rols
the urface behavior. Because most material s
are normally exposed to t he atmosphere, t he
engineering properties of con tamin ated surfaces
are those of importance. The interest in t rul y
clean surfaces has been of con cern mainly fo r a
few applications (e. g., cata lysis) and for study
of the fund amental a pects of surface chemistry
and physic .
Wi th t he advent of space exploration and
fligh t at very high a ltitudes, new interest in t he
propertie of clean surface ha developed. M ateri als and device must survive in new envi ronments-ul trahigh vacuu m, extremely reactive
gases, very high temperatures, very low t emperatures, microm eteoroids, and a wide variety of
radi ations.
Many problems under study here at Lewi
stem from our need to un der tand and t o cope
wi th t he e new environments. One program described in detail is t hat con cerned with bearings,
seal , and lubri cants.
The subj ect di cus ed in t his paper is one in
whi ch surface chemi stry and physic are u ed to
gain insight in to t he behavior of t he whole olid .
I mperfections pl ay a very important role in
the behavior of solids. Dislocations provide the
means by whi ch slip occurs. Vacancies and interstitia l atoms interact wit h dislocations and
modify t he ea e wit h which they can move.
Vacancie , interstit ial atoms, and impurity atoms
scatter electrons as t hey mi grate through a crys-
S ered
U RFACES A
A. LAD
L ewis Research Center
ROBERT
I
I
68
KLYSTRON
OSCILLA TOR -,
~ CRYSTAL
DETECTOR
"- WAVEGUIDE
RECORDER
FIG
RE
tus.
9.l = 2 .0385
911= 2 .0032
-H
FIGURE
rr
69
SURFACE
0=
0=
M++
0=
M++
0=
M++
0=
0=
M++
M++
0=
M++
0=
M++
0=
M++
0=
M++
OW
M++
0=
M++
0=
M++
0=,,<+
M++
h~
0=
/\e
0=
Fe++
0=
M++
0=
( a)
SURFACE
0=
0
0=
M++
0=
M++
0=
M+ +
0=
0=
M++
M++
0-
M++
0=
M++
0=
M++
0=
M++
0-
M+ +
0=
OW
M++
0=
M++
0=
M++
M++
0=
M+ +
0=
Fe+
0=
(b)
FIGURE
1.2
-7SC
00
VIVo
AND
6k/6k o
0
30C
.2
8
6
10
12
14
16
IS
20
TIME, HR
FIGURE
70
I - I
M+ +
0=
M++
0=
M++
0=
M++
M++
0=
M++
0=
M++
0=
, \Ix = 2.0015
0=
M++
0=
M++
0=
0=
M++
0=
M++
M+ +
0=
M++
0=
0=
M++
10 GAUSS
F IGU Il E
~-
/ - 9y =1 . 9990
CJ
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
FIGU RE
F IGURE
~ lIx
=2 .0029
10 GAUSS
F IGURE
neti c pecies and created a new one, it can be concluded that the new site i as shown in figure
IV-8. The CO2 molecul e ha taken the electron
from the S' center, and it resid e on the O2
mol ecul e. The CO:! molecule i hown as hav ing
ch anged from t he usua l lin ear configuration to
the nonlinear form becau e t he EPR spectrum
observed i ju t the one reported in the li terature
for t he nonlinear CO. ion , whi ch can be generated in olid sod ium fo rmate by y-irradi ation.
This work illu t rates the u efulne s of EPR
in defining t he detail ed stru cture of an adsorbed
mol ecul e on a surface active ite. It ugge ts
that a tool i now 'available which migh t help
the understandin g of t he mechani m of catalysis
in new ways. Other methods, uch as gas adsorption, of neces ity yield inform ation on the
average behavior of large numbers of molecule
and large area of urface.
In tere t in t he interaction of solid urface
wi th ga es led to examin ation of other sy tems.
One was carbon monoxide (CO) on MgO . The
ad orbed CO molecul e plays an important rol e
in the.. Fischer-Tropsch process for the producti on of hydrocarbon from CO and hydrogen.
Experiments at Lewis showed that some of the
ad orbed CO form a paramagnetic pecies.
The ana lysi of the spectrum yielded information
71
which will aid in the understanding of CO adsorption, whi ch has been previously studied extensively by infra red pectro copy.
Attention is presently directed toward the' iden tification of the state of ad orbed oxygen on
magnesium oxide a nd on th e semiconductor zinc
oxide. This info rmation is pertinent to the understanding of the interaction of surface oxide layers with atmospheric oxygen and to the process
of oxidation itself.
Other work in progres at this center should
also be mentioned. M ethods are being tudied
for preparation of the high purity carbide and
nitride of metals like titanium and zirconium .
These material a re of in tere t becau e t hey are
among the highest melting materials known.
The nature of the chemical bonding in t hem is
unusua l. In order to study it, it i nece ary to
have higher purity mate ri a l than is commercially
available. Another intere tin g property of these
refractory compounds is t heir high electrical and
thermal condu ctivity; it is almost as high as for
metals. Th eir state of chemical bonding, whi ch
is neither ioni c nor metallic, might make th e
pure material interestin g to inve tigate as catalysts.
Another investigation i concern ed with diffusion in oxides. Figure IV-9 shows how atoms or
ions move in magn esium oxide. The ions move
by changing places with vacant site in the la t tice. In th e case of oxygen ions, bot h the num-
--~----
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
0=
M++
FIGURE
M+~=
0=
M++
Magnetics and
Superconductivity
HE
LAST
DECADE
vices whose capabili ties are dependent on lowtemperature operation. Typical of such devices
a re masers (very low noise level radio frequency
amplifiers) and cryo tron s (very hi gh speed
counters for computers) . The development of
elegant and unique low-temperature electrical
gadgets has somewh at over- hadowed t he considerable gains which have been made in t he
overall technology for t he operation of electrical
gear at low temperature as a means of overall
power savings.
It is well known that the electrical resistance
of most conductors decreases with decreasing
temperature. What is not so well known is t hat
advances in the knowledge of materi al properties
at low temperatures and the development of effi cient refrigeration techniques can be combined to
give substantial savings in t he overall power
consumption of much common electri cal hardware. The kind of changes in electrical resistivity which occur with temperature is illu t rated
in fi gure V - I. Good conductors such as copper
or aluminum show a decrease in lectri cal resistance of four or five orders of magnit ude between
room temperature and temperature near absolute zero. Absolute zero is defined here a that
temperature at whi ch all gross motion of t he
atoms cea es. There is a distinct leveling off of
the re istance at very low temperatures, and
there is a residual resistance of most materi als
close to absolute zero. There i a class of material s, known as supercondu ctors, which show a
sharp drop in resistance at very low temperatures. Lead and tin are two such materials. In
fact , there are now an enormous number of
ELECTRIC AL
3
RESIST ANCE , 10
ARBITRAR Y
UNITS
10 2
r RESIDU AL
;' RESIST ANCE
I 0 1 I+.
...~.;r-----
FIGURE
._-
_._-----
74
POWER IN, PI
REFRIGERATOR
POWER PR
POWER OUT,
PO, A CONSTANT
REFR IGERATOR
TO COOL
LOAD
FIGU RE
M INDUSTRY
ways in the lattice and interferes with the motion of the current carryin g electrons. As the
temperature decreases, the atomic motion decrea e and t he electrons pa more easily through
the lattice. The residual resi tance merely refl ects
the fact that impurities and stres es tend to di order the lattice structure.
Figure V-3 illustrates what can be expected
of good conductor such as copper or alumi num. A re istance ratio is plotted as a fun ction
of temperature. The re istance is normalized simply by dividing by the room temperature resi tance.
The most evident characteri tic of the curve
shown is that most of the change in resistance
occurs at low temperature. Thi i a expected,
for according to theory, resistance varies linearly
with temperature at high temperature and a
the cube of the temperature at very low temperatures. The overa ll re ult is that the mo t
significant decreases in resistance occur below
100 R , and therefore most cryogenic app lications will occur below thi temperature.
The va lue of the re idual re i tance shown
here lie some five order of magnitude below
t he normal room temperature re i tance. Thi
value is extremely sensitive to material purity
and stress. A value such a hown here can
only be achieved with extremely high purity, perhaps 99.999 percent, and fully annealed mate-
RESISTANCE
RATIO, R/ RN
R N , RESISTANCE AT
ROOM TEMP, 72 F
500 532
I
-460
FIGU RE
TEMP, OF
72
r---
75
rial . Le
pure or stressed materials would
have much higher re idual re istance and might
only be three 01' four ord er of magni tud e below
room temperature resistance.
M agnetoresistance is probably a new t erm to
many people, and it is a function of the magnet!c
field in which the conductor lies. Since magnetIc
fi elds a re generated by electrical currents, it is
impossible to build an electrical device which
doe not produce a magnetic field , and many
large devices such as electrica l generators produce quite large field. Magnetore istance is only
ign ificant at low temperatures, but it can result
in very large effects. To vi ualize how magnetoresi tance produces its effect, con ider the sim ple picture of the lattice stru cture but fi ll ed
with magn etic fi eld lines. Since the current carrying electrons tend to be tied to the magnetic
u eld lines , t his also interfere with their ready
pa age through the lattice stru cture.
D etail ed studies have been made of the magnetore i tance of a large number of conductor,
and ome typical results are shown in figure V--4.
The particular data hown here are for aluminum
and copper at 15 R. It i evident that aluminum
is much better than copper for all ca es where
the magnetic fi eld is sign ificant, and ip fact alu minum shows an interesting characteri stic called
"saturation "; that is, a bove a fie ld of about
20000 gauss there is no furth er increa e in magnetoresistance. This is extremely advantageou
when high field are desired or merely exist.
Now consider the application of what has been
di cu ed. Given a device which wa tes considerab le electrical power at room t emperature
16
MAGN ETO
12
RESIS TANCE,
ARB ITRARY 8
UNITS
COP PER
AL UMINU M
100,000
FIGURE
in
magnetic
12
POWER
.8
RA TlO , LOAD+
REFRIGERA TION AT T 4
LOAD AT To
TEMPERATURE
FIG U RE
76
FIGURE
V-.Q.-Cryogenjc magnet.
,S PACER-CARRIER
,...- COOLANT
PASSAGE
~~N,<~,-
AINLESS-STEE~~
ST
SPACER BARS ~-
"
I
,,
, ~~y-
"-
INSULA TING-GLASS ,I
SCRIM RIBBON ----'
/
ASSEMBLED /
WINDING ---'
STAINLESS-STEEL
')(
//
BACKING CHANNEL...../
~
L ALUMINUM
CONDUCTOR
V-7.-Construction of
cooled aluminum magnet.
FroURE
coils
of
cryogenically
77
NORMAL CONDUCTOR
CURRENT
O R
-460 F
TC
TEMPERATURE
FIG U RE
MAGNETIC
FIELD
-460F
FIGURE
TEMPERATURE
78
SELECTED TECH
MAGNET IC F IELD
NORMAL
CONDUCTOR
SUPERCONDUCTO R
WEAK FIELD
STRONG
FIELD
1001-----..
F L UX
EXCLUDED,
PE RC ENT
HC I
HC2
APPLIED MAGNET IC FI E LD
-----------
79
200 AMP
F IGU RE
500 AMP
V- l4.-Current capacity .
FIGU RE
V- 15.-Superconducting magnet.
80
SELECTED TECH
FIGURE
FIGURE
Vll
Pump Technology
J.
1.
J.
MAX
MILLER, ROBERT S.
RUGGERI, AND RICHARD F. SOLTIS
A TTEN'I'ION
FOCUSED
IN
THIS
D1 CUSSION
PAYLOAD
FUEL TANK
OXIDIZER TANK
FIGURE
82
TANK
PUMP BLADES
FIGURE
FIGURE
VI-3.-Pump cavitation.
83
PUMP TECHNOLOGY
----)
fl(
{I
FIGURE
FIGURE
VI-5.-Centrifugal pump.
...
centrifugal pump .
- - -- - - - - -
84
FIGURE
/:
/jUTFLOW
'NFLOW;/
\ DIRECTION
- /
f OF ROTATION
f'~
DIRECTION
OF ROTATION
FIGURE
VI--8.-Pump blades.
rotor, it is often advantageou to u e an axialflow pump, which can be easily staged. The axialflow pump (fig. VI-7) , which is also used in
modern rocket engines, consists of a succe ion
of rows of rotor blades and stator blades. The
rotor blades, all of which are mounted on the
same rotating drum, do work on the fluid being
pumped, and the stator blades turn the flow
into the desired direction for the next rotor stage.
Although the pres ure rise per stage of the axial
pump i Ie than that of a centrifugal tage, the
ease with which successive stages can be added
to the axial-flow type allows a more compact
high-pre sure pump .
PUMP-FLOW ANALYSIS
Before the di cus ion of the manner in which
cavitation degrades pump performance and the
approach to design that i used to achieve a high
degree of cavitation tolerance in pumps, it may
===,====(~->~
.. --
FIGURE
--------
85
PUMP TECHNOLOGY
FIGURE
tion.
FLOW
A mentioned previou ly, the presence of extensive amounts of vapor (cavitation ) in the
pump limits pump performance. This problem
of cavitation and its effect on pump performance
become increasingly more critical as the fluid
entering t he pump app roaches the near-boiling
condition. In order to illustrate the effects of
cavitation on flow conditions a bout pump blades,
blade pressure distribution with and without
cavitation are compared in figure VI-12. The
( b)
PRESSURE '.
FIGURE
;/~
-'
--
VAPOR
PRE SSU RE
(b)
(a)
oncavitating.
FIGURE
86
horizontal dashed line represents the vapor pressure of the incoming fluid. If t he inlet pre sure
i sufficiently high, the blade surface pressures
are everywhere greater than the liquid vapor
pressure. However, if inlet pressure is reduced
sufficiently, local pressures on the suction surface
of the blade are reduced to the fluid vapor pressure, and cavitation occur . Because the pre ure
on t he uction surface of the blade cannot be
less than t he vapor pressure of the liquid immedi ately adjacent to the vapor cavity , a "loss in
blade force result . Thi loss corre pond to the
reduced area of the pressure distribution di agram,
as illustrated by th e right-h and di agram of fi gure
VI-1 2.
As inlet pressure is further reduced, the cavitated region on the suction urface of t he blade
grows until the flow adj acent t o the vapor cavity
can no lon ger follow the sharp curvature at t he
down tream end of t he vapor cavity, as illustrated by t he right-hand di agram of fi gure VI- 13.
As noted in t he figure, t he flow separates from
t he bl ade, and a large part of the highly desirable
suction i lost. The presence of cavitation causes
a decrease in blade pressures on the lower surface because of disturbed flow in the channel
between blades, as was the case for separated
flow wi thout cavitation (fig. VI-l1 ) . The
greatly reduced area of the pressure diagram is
FIOu RE
''''"u"
PRESSURE
RISE
F IGU RE
87
PUMP TECHNOLOGY
INDUCERS
The problem of pumping from low-pressure
tanks (i. e., near-boiling fluids) has been alleviated to a large extent through the design of a
prepumping stage, which operates satisfactorily
even under conditions of extensive cavitation.
uch a prepumping stage i called an inducer.
A typical inducer i presented in figure VI-16.
The three exceptionally long blades are mounted
on the hub in a manner approximating a helix.
Inducer are generally located immediately upstream from the main pump and rotate on the
same shaft as t he main tage rotor. A typical
inducer-axial-flow-pump combin ation is shown
in figure VI-17 and the pres ure ri e through the
various tages i illustrated schematically in figure VI-18. The inducer i only required to produce a pressure rise sufficient to allow the first
axial-flow stage to operate free of cavitation.
(
I
Y
\
FIGURE VI-I6.-Inducer.
88
FIGURE
I
I
PRESSURE
I I
I I
I I
I I I
I I
I I
I I
VZ2Z?Z22ZZ222~
ctt1!:::)
I2 Z222Z222Z2ZZ ~
VI-lB.-Pressure rise
inducer.
FIGURE
In
(a)
FIGURE
oncavitating .
(b) Cavitating.
89
PUMP TECHNOLOGY
PRESSURE
RISE
FIGURE
I
I
I
WITH INDUCER
.......
WI THOUT INDUCER
FIGURE
FIGURE
FIGURE
VI-21.-Cavitating inducer.
and req uires about 9000 horsepower . The pressure ri e across t he pump i equivalent to raising
the hydrogen to a heigh t of over 50 000 feet.
The techni cal sophi t ication of t hi pump can be
rea lized from t he fact that the 9000 horsepower
is absorbed in useful work by a pump rotor
that is about 8 inche in diameter and inches
long.
An axial -flow rocket pump for handling liquid
hydrogen i hown in figure VI-23. This pump,
developed for an advanced 1.5-million-poundthrust engine, consists of an inducer and everal
axial-flow tages and i a bout 17 in ches in diameter. It pumps 65 000 gallons of liquid hydrogen per minute to a pressure in excess of 1500
90
I NLET PRESSURE -
FLOW""
FIGURE
L_-
91
PUMP TECHNOLOGY
,~ INLET
PRESSURE
INLET PRESSURE )
COOLED LlQUID/
,//
...L _ _
1 - - -- - - - - - 1 -
VAPOR PRESSURE
'- INLET LlQUID - - - - , B
VAPOR PRESSURE ~
COOLED LIQUID
j..L
.-i _ _
...
...
(a)
(b) ==:zz:Zfu:ZZ1Z1
FIGU RE
Vapor-pressure drop=K
(1)
G:gL ~~)
r'
(PL~ L
U"
(2)
FLOW
FIGURE
92
FLOW ......
PRESSURE
_..----__
fL--__-.'--.........
--
--~t
FLOW .......
PRESSURE
FIGURE
FIGURE
VI-27.-Venturi.
P\C ) 0.'
L
UO .8S
(3)
93
PUMP TECHNOLOGY
16
12
MEASURED
v.P. DROP, 8
FT OF
LIQU ID
o FREON
11 4
o LIQUID NITROGEN
o WATER
4
PR ED ICT ED V .P.
300
TABLE
Liquid
Freon 114
Freon 114
Freon 114
Freon 114
itrogen
Freon 114
itrogen
Temperature,
of
Flow
velocity,
ft/sec
6
28
59
79
-320
78
-320
32
32
32
32
32
44
42
Measured
vaporpressure
drop,
ft of liquid
0.9
1.8
5.1
8.5
8.8
10.2
12.5
LIQUID
/"
HYDROGEN \ '
"
WA T ER
130
PREDICTED
v.P. DROP,
130 \
FT OF
LIQUID
lO t-
WATER
LIQUID
NITR~GE N
II
r METHYL
\ ALCOHOL
ME~ANE
II
II
0~7~5~~45~0~-~3~2~0--~18~0---~2~59~-~4~2~3---~4~18
TE MP, OF
94
'
/
/
r:- rr
PRESSURE
RISE,
FT OF
LIQUID
1;;0
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
180 275
Vapor-pressure drop
UO. 85
250 75
- - - METHYL ALCOHOL
-----WATER
13
15
16
17
VI-31.-Pump
methyl alcohol.
performance
FIGURE
with
water
and
LIQUID
HYDROGEN
-418 F
,--------,--------
PRESSURE RISE ,
FT OF LIQUID
LIQUID
HYDROGEN
-423 F
=K(;: ;L 1~)
WATER
75 F
120
160
FIGURE
which uses the exponent of 0.5 and 0.85 established in the venturi study. This equation was
then used to predict the inlet pressure requirements (for the same small los in pre sure ri e)
for 275 0 water and 180 0 and 200 0 F methyl
alcohol. The predicted values, hown by the
solid symbol , are in good agreement with the
experimental re ults.
The vapor-pressure-drop equation predicted
a large drop in vapor pressure for cavitating
liquid hydrogen as compared with room-temperature water (fig. VI-30), Figure VI-32 shows
the performance of a pump operated at the same
flow conditions in both water and liquid hydrogen. As anticipated from the cavitation-cooling
studies, the margin of inlet pres ure above vapor
pressure at which the pump performance declined
is much lower for the liquid hydrogen than for
the cold water. For the same rotational speed
and flow rate, the analysis also predicted that
an increase of only 50 F in liquid-hydrogen
temperature (from -423 to -418 0 F) would
enable satisfactory operation of this pump at
zero margin of inlet pres ure above vapor pressure, that is, with the incoming liquid at its
boiling point. Thi predicted point is indicated
by the solid symbol. When the pump was operated under the e conditions, pump performance
was su tained when the hydrogen entering the
inlet was boiling, as indicated by the olid line.
Measured and predicted pump performance are
thus in good agreement.
INSULATED
TANK - .
- TRANSPARENT
HOUS ING
.-,- VIEWING
6
FIGURE
WINDOW
CAMERA
VI-33.-Hydrogen-pump te t arrangement.
f
I
I
95
GENERATOR
HEAT
SOURCE
F!G\'I~E
CAVITATION
FIGURE
D~MAGE
96
FIGURE
FIGURE
,,- VIBRATOR
"
,,
SPE CI MEN
,,
SURFACE
FIGURE
,,
--_.- - - - -
~---
97
PUMP TECHNOLOGY
surface of the 0.5-inch-diameter circular specimen, which is submerged in liquid and cau ed to
vibrate at high frequency. On each upstroke,
vapor bubbles are formed near the surface of the
pecimen. These bubbles collap e with hi.gh
energy on the ensuing down troke. The devICe
provides a practical method for making rapid,
accurate , and detailed mea urements of the rate
of weight loss for a given material.
The cavitation erosion rate for a number of
materials, tested over a range of conditions, are
presented in figures VI-39 and VI-40. Rate of
weight los in milligrams per hour is plotted a
a fun ction of exposure time in hours. The curve
of figure VI-39 is for 304L stainless teel te ted
in 80 F water; the curve of figure VI-40 is for
316 stainless steel tested in 400 F liquid sodium.
The curves are imilar in that the damage rate
is small initially, ri es sharply, and then falls off
to a constant, steady-state rate. Compari ons
between various materials are made in the teadystate zon e. The damage rate differs for the various materials. In water, for example, soft aluminum i eroded by cavitation about 60 times
faster than stainless steel. The resistance of several refractory alloys, TZ if, T-222 , and columbium 132M has been studied in liquid sodium.
These alloy maintain their strength at the high
temperatures of interest in space power systems.
In 400 F sodium, the resi tance of these materials to cavitation damage (ba ed on steadystate values) i comparable with that of 316
stainles steel. Stellite 6B, a cobalt-base alloy, is
remarkably resistant to damage. After 14 hour
432
1100-0 ALUMINUM - -
60
CAST IRON--
40
RATE OF
WEIGHT
LOSS,
MG/HR
MOLYBDENUM -
30
RATE OF
WT LOSS.
MG/HR
30
20
0' '''----o---c>-
FIGURE
INCO 300M _
1020 MILD
STEEL~,
410SS===
TIME , HR
1_-
40
20
FIGURE
50
98
SELECTED TECH
2520-
031655
~ TZM
RATE OF
15-
T-222
WT LOSS ,
MG/HR
10-
rn
JLti
1000 F
=1500
f}J
FIGURE
FLOW INSTABILITY
Cavitation can cause pump damage in an entirely different manner; it can lead to flow instabilities, which produce strong pre ure fluctuations in the pump. The e pressure fluctuations
can vibrate some of the pump parts to failure.
Photographs of flow oscillations induced by
cavitation in a pump inducer (operating in water)
were obtained by use of the arrangement shown
in figure VI-42. The inducer was enca ed in a
transparent hou ing, and nylon tufts attached to
the housing wall were used to indicate local flow
direction. A photograph howing the arrangement of tufts and inducer blading is also shown
in the figure. Under normal flow conditions, the
tufts ahead of the rotor indicate flow directly into
the inducer. Tufts in the rotor area indicate the
flow turned in the direction of inducer rotation.
Flow 0 cillation that can occur with cavitation
are pre ented in figure VI-43. With the inducer
DU TRY
INDUCER
''- TRANSPARENT HOUSING
FIGURE
99
PUMP TECHNOLOGY
ROTATION
ROTATION
IN FLOW
operated at de ign conditions. Velocity distribution can be controlled by varying the hub contour, blade heigh t and thickne s, circumferential
spacing, and blade curvature.
In a pump of poor design, the flow velocity
may drop to zero or even become negative on
t he high-pre sure side of t he flow passage, as
shown in figure VI-46. A negative velocity means
that the local flow is opposed to the main tream
direction. The e local flow reversals produce a
whirling eddy, which disturbs the flow , as indicated by the marked distortion of the streamlines. Unfortu nately, the e eddie are un stable.
Eddies are continually generated, grow as they
move outward through the blade passage, and
are then washed down tream to produce a rhythmic fluctuation in pump delivery pressure and
flow rate. Such 0 cillations can bu ild to destructive magni tud s in purnps and associated plumbing sy tem .
100
OUT FLOW
~, ,
ROTATION
"
,,
,,
\
':)\I
,
ROTATION
\
\
,
,
I
I
I
\
I
I
I
\
\
I
I
I
I
I
I
I
I
I
IN FLOW
CONCLUDING REMARKS
The foregoing discussion of the role of cavitation in defining pump performance t reats one
phase of NA A work on high-performance
pumps. Companion work includes tudies on the
design of high pressure-rise blading for centrifugal and axial-flow pump and high-work turbines for driving these pumps. These studies
make ex ten ive u e of the compressor and turbine techno logy developed earlier for jet engin es.
Mo t of this work is documented in NASA reports dating from 1958.
Pre ent NA A work on rotating machinery
extends from large components for aircraft jet
engines to mall, high-speed t urbin e and compre or suited for turbogenerated electrical
power sy tern in pace that u e gase such a
argon and neon a the working fluid. The high
efficiencies attained in t urbine and compressors
ranging in size to one a small as 3 inche in
diameter represent a new advance in the technology of these machine. The wide range of
information developed should include many areas
of interest to the machine de igners who erve
the petroleum indu try.
BIBLIOGRAPHY
Pumps and Inducers
CROUSE, J AMES E.; M o TGOMERY, J OH C.; AND OLTIS,
RICHARD F.: In ve tigation of the P erformance of an
Axial-Flow-Pump Stage D e 19ned by the Blade-Element Theory- Design and Overall P erformance. A A
T N D--591, 1961.
CROUSE, JAMES E.; OLTIS, RICHARD F.; AN D M o TGOMERY, J OHN C.: Inve tigation of the Pertormance
of an Axial-Flow-Pump Stage D igned by the BladeElement Theory-Blade-Element Data. NASA TN
D-1I09, 1961.
HARTMANN, MELVIN J. ; AND BALL, CALVIN L.:
ew
Problems Encountered with Pumps and Turbines.
Proceedings of the NASA-U ni versity Conference on
the cience and Technology of Space Exploration,
Vol. 2, NASA SP-lI, 1962, pp. 23-35.
OSBORN , WALTER M .: Noncavitating and Cavitating
P erformance of a Liquid-Fluorine Pump D esigned by
Stream-Filament M ethod. NASA TM X - 722, 1963.
SANDERCOCK, DONALD M .; SOLTIS, RICHARD F.; AND
A DERSO , DOUGLAS A.: Cavitation and oncavitation
P erformance of an 80.6 0 Flat-Plate H elical Inducer at
Three Rotational Speeds. NASA T
D-1439, 1962.
OLTIS, RICHARD F.: Some Visual Observations of Cavitation in Rotating Machinery . NASA TN D-26 1,
1965. (Technical Film uppl ement C-239 availabl e
on reque t.)
SOLTIS , RICHARD F.: A ' DERSON, D OUGLAS A.; AND
SANDERCOCK, DONALD M. : In ve tigation of t he P erform ance of a 7 0 F lat-Plate H elical Inducer .
A A
T D-1I70, 1962.
101
PUMP TECHNOLOGY
Cavitation
JACOBS, ROBERT B.; MARTIN, KENNEn'H B. ; AND HARDY ,
RI CHARD J.: Direct M easurem ent of
et Po itive
Suction H ead. R ep.
o. 5500,
ation a l Bureau of
Sta ndards, July 18, 1957.
R UGGERI, ROBElRT S.; AND GE~DER, THOMAS F.: Cav itation and Effective Liquid T ension of Nitrogen in a
Tunn el Venturi.
ASA TN D-2088, 1964.
STAH~, H . A.; AND 8TEPANOFF, A. J.: The rmodynami c
A peets of Cavitation in Centrifugal Pumps. ASME
Tran ., vol. 78, ov. 1956, pp . 1691- 1693.
WILCOX, W. W .; ME G, P. R., AND DAVIS, R. L.: P erforman ce of an Indu cer-Impell er Combination at or
Cavitation Damage
K ULP, ROBERT S.; AND ALTIERI, JAME. V.: Cavitation
D a m age of M ech a ni cal Pump Impe ll ers Operating in
Liquid M etal Space Power Loops. 1 ASA CR-165,
1965.
THIRUVENOADAM, A. ; PREISER, H. S.; AND R DY, S. L.:
Cav itation D a m age in Liquid M eta l . T ech. Prog.
R ep . 467-3, Hydronalltics, Inc. (NASA CR-54459),
1965.
vnn
A ERO
PACE
APPLICATIONS
Lubricants,
Bearings,
and Seals
require
lubrication
FILMS IN LUBRICATION
PAYLOAD
FUEL TANK
ox 1DI ZER
TANK
PUMP
THRUST CHAMBER
FIGURE
Hydrodynamic Films
Posit ive surface sepa ration by hydrodynamic
film s precludes surface damage due to sliding
contact. Thi widely used principle is illustrated
in the hydrodyn amic journal bearing schematic
drawing (fig. VII-2). For purposes of illu str ation, the clearance between the journal a nd t he
bearing ha been exaggerated. Typi cal clearances
are of t he ord er of 0.001 inch per inch of diameter.
Under the action of a load W, t he journa l i
di placed 0 that the bearing center and the
journal center are no longer coincident. The r esul t is a film of nonuniform t hi ckness. A the
journal rotates, fluid is dragged into the converging portion of the film because of the vis103
104
LIF T
MOTION
SLIDER
WEDGE
ANGLE
(EXAGGERATE.,)
VII-3.
examp le of a hydrostatic film i t he 12-inchdiameter flat-plate bearing shown in figures VII4(a) and (b) . By app li cation of lung pressure
alone, 100 pounds i upported and floated freely
acros a flat surface.
Hydrostatic Films
In app lications where the fluid vi co ity i
very low or whcre there i not uffi cient relative
motion to develop adequate load supporting pressure, hydrostatic bearings can be u ed. In hydrostatic bearings, t he film i developed by external
pump pre urization and, therefore, can be u ed
to upport surfaces having no relative motion.
The fi lm again i u ually several thou andth of
an inch thick. Film thickne s is a function of
external pump capacity, load, and surface fl atne . Many fluids besides oil can be u ed in
hydrostatic lubrication becau e t he load capacity does not depend on fluid vi co ity . !~ graphic
//~ BEARING
FILM PRESSURE ~ /
FIGURE
105
VII-4.-Hydrostatic bearing.
FIGURE
t
106
(0)
(b)
~~~~~~~~~
~
CARBONS
(WITH ADDITIVES)
~ LEADOXIDE
(e)
- - - - - - - - - - - . ..
-400
TEMP, OF
FIGU RE
107
MASS WELDING
OF SPECIMENS
COEFF OF
FRICTION
10
15
20
TIME, MIN
Vacuum Lubrication
In vacuum it i difficult to maintain the surface films needed for lubrication because lubricant evaporate and surface oxide films, which
were present originally, do not reform when worn
away. The types of surface failu re that occur
in vacuum are imilar to those ob erved in most
convention a l lubri cation when protective film
are disrupted. As an example of the importance
of the oxide film, figure VII- shows friction
measurement made with SAE 52100 (a common bearing teel) slidin g on SAE 52100 in
vacu um.
As the protective oxides were worn away,
friction increased and complete surface welding
occurred. The friction coefficient obtained in
vacuum i 10 to 100 times that normally found
with metals sliding in air, and the extent of fail ure is greater in vacuum ince complete surface
welding and cata trophic surface damage occur
more readi ly becau e protective oxide film do
not reform. From both a fundamental and practical tandpoint, therefore, friction and wear
experiments in vacuum provide a severe test of
the utility of solid materials to be used in liding
contact.
FIG U RE
108
SELECTED TECH
1. 6
,,-;;,. '
~
....~"'r
..->..'? .-
CU BIC ON
1. 2
CU B IC ~/
FRIC T ION
WEAR
RATE,
CM 3/C M
'-,__
COEFF OF
.8
HE XAGONAL ON
CO MP LET E
WELD IN G
"-"'- 4 xI0- S
HEXAGONAL?
.4
--'-- 4 xI 0 - 11
1200
.8
.6
CO EF F OF 4
FR ICTION'
.2
8e
f c
a
1.62
1. 63
r
I
109
.8
' ........
.6
COEFF OF
FRICTION
.4
Ti- AI
ON 440-C
.2
---------Ti-Sn
ON 440- C
-
1.61
1.60
-- ----
_----- Ti-Sn
LATT I CE 1.59
RATIO,
c/o
1.58 ~-~-~:____;:7_-~-~
FIGURE VII-13.-Friction and lattice ratio (cia) for titanium alloy . Load, 1000 grams; sliding velocity, 390
feet per minute; pres llre, 10- 10 millimeter of mercury.
Studies have al a shown that the cobalt hexagonal form can be stabilized over greater temperature ranges by alloy additions of tungsten
and molybdenum. Thi cry tal structure stabilizing principle i potentially u eful in many fields
besides aerospace. As an example, in the medi cal fi eld, Vitallium (a cobalt-base alloy) has
been found compatible with the human body
and is used in artificial human joints such as the
ball and socket of the hip. NASA tudies have
shown a significant difference in friction and wear
between the Vitallium alloy and a hexagonally
stabilized cobalt-molybdenum a lloy. The coefficients of friction were 0.22 for Vitallium and
0.15 for the NASA developed cobalt-molybdenum alloy. Further, the wear wa much greater
for the Vitallium than for the cobalt-molybdenum alloy. In this tudy, both alloys (Vitallium
and cobalt-molybdenum) were lubricated with
heptane in order to exclude oxygen and preclude formation of surface reactant films. (The
synovial fluid of animal joints could not be used
as the lubricant because it decomposes on contact with air.) Since the cobalt-molybdenum
alloys have lower friction than Vitallium and are
chemically similar, these cobalt-molybdenum al loys may provide artificial joints of improved
friction and wear characteristics.
,,
~ INNER
RACE
,,
,fB ALLS
,I
- ---------,--- ----
I
FIGURE VII- 14.-Ball bearing components.
llO
A L UMINUM
SHR OUD
FIGURE
111
(a)
(b)
cage.
FIGURE
112
111ill
RACE
CUT
FROM
TUBING
FORGED
RACE
'L STRESSEO
REGION
113
,
.6
RELATIVE
LIFE
.4
.2
.1
.06
SOFTER BALLS
. 0~5
~~~~~~~~-L~~~-L~~L-
F I GU RE
80
60
40
BEARINGS
FA IL ED, 20
%
10
8
6
4
2~
1 --------~--------I~
OO -------I~
OOO
FIGURE
DRY
CONTACT
LUBRICATED
CONTA CT
STRESS,
S
CONTACT
'----r"---+------..,.----!---'':--- - - - - - - - - WIDTH
FIGURE
dis-
114
Ut ilization of all these t echniques in the manu facture of rolling bearings and proper lubricant
selection should resul t in a bearing life of at least
10 t imes greater th an that of a decade ago.
FLUID
GAS BEARINGS
In pi te of all the advances made in solid
lubri cants, protective film s, and improved bearing materi als for use in difficult environments,
bearing t hat operate in solid contact between
running part have li mited life. This limited life
is uita ble for many machines, bu t when extra
long bearing life at hi gh temperature is required,
fluid film bearing mu t be used. Fluid film bearing , such as a journa l bearing, can utilize a gas
as well as a liquid as the lubricant to provide
a film of eparation between t he haft and t he
bearing.
One pace related application for gas bearing appears in turbdgenerator electric power
systems in which hot argon is used to drive the
turbine. in ce t he turbine operate at 1700 F ,
it would be extremely diffi cult t o u e an oil to
lubricate t he journal bearin g adjacent to t he
turbine. The use of t he proce fluid (in t his
ca e, argon gas) as the bearing fluid eliminates
the complexity of a separate lubrication system
and the need for eal to prevent contamination
of t he argon wit h oil.
The use of ga a t he bearing lu bri cant has a
number of advantage including low friction, low
noi e, cleanliness, and tolerance to rad ioactivity.
115
FLAT TO
DE TERMINE
WHIRL FREQUENCY ~" ,
JOURNAL
CENTER ORBIT
X
CA PACITANC E
PROB E
BEARING
FIGURE
whirl.
________J
116
../~ SHOE
_ _ _ _ 0 _ __
,,
" SEAT
(ROTATING)
: LNOSE
(NONROTATING)
l plSTON RING (SECONDARY SEAL)
-----~~~-------
117
Sealing Gap
Pressure Balancing
Pre sure balancing i illu t rated in figure VII30, which shows the forces acting on a cylindri-
NOSE PIECE
,SEAL SEAT
(a ) Pressure loaded .
Compensating Pressure
Positive gap control is obtained by having the
sealing gap perform as a hydrostatic thru t bearing. As shown in figure VII-32 , the seal design
is similar to figure VII-31 except that a recess
and a eries of orifices have been added to the
nosepiece face. Some of the leakage through
the seal takes place through the orifices arranged circumferentially around the seal. The
(
118
SELECTED TECH
leakage flow through the orifices produ ces a pressure drop from sealed pressure P i to the recess
pressure P' and the sealing gap height i controlled by com pen ation in reces pre sure P'. The
mechanism works in the following way: If the
gap is closed down for ome reason, the leakage
out i reduced , t hat i , the pre ure drop in
the orifice i low becau e of leakage flow ; t herefore, recess pressure P' will increase, approaching sealed pre ure P i' and produce a net retoring for ce to maintain design gap height.
Similarly, if the gap opens beyond the de ign
point, the inverse proces take place. In effect,
the gap is maintained by automatic compensation in the rece s pressure P' . The designer can
select t he operating seal gap height t hrough
proper selection of the rece and orifice izes.
\
j
HO USING - ,
SEAT
FIGURE
1
1
I
Wear Effects
Using the smallest closing load that can maintain th in film separation in a seal is important.
When contact occur , wear and wear particle
size increase with load. The wear particles can
ea ily be larger than the normal sealin g gap.
Thus, wear particles between t he surfaces can
increa e the thicknes of the leakage gap. Ironically, if, in an attempt to reduce leakage, the
sp ring force is rai ed, an increase is obtain ed in
both wear and wear particle ize; hence, leakage
will be increased.
LOW PRESSURE ,
Po
,r r - - - --
--,l',.-----,
SEAT
~,.-----
-- -- - f----
'-L-r-S_H_A_F~ ~ ~~~---.-r~
__
FIGURE
__
Vibration Effects
osepiece vibration also causes ealing gap
variations. The gap change can be very rapid
and nonuniform around the circumference. Studies have shown t hat t he predomin ate motion
was a "rocking" of the seal no epiece and that
t he force due to rocking were very high. As
an example, figure VII-33 hows the wear pattern of a ea l nosepiece which was run in liquid
nitrogen for 3 minutes at 10 000 rpm. The
nosepiece profile before and after te t i hown
with the horizontal cale enl arged. Wear of
0.004 inch ha occurred in t he 38 minutes of
operation. Of interest here is the cone-shaped
wear at the outer edge, which i due to t he rocking-type vibration. While mo t of the wear is on
the outer edge, the vibration impacts have caused
ome chippin g from the inner edge also. This
wear is in to lerable. This damaging vibration can
be eliminated through the u e of damper in
contact with the nosepiece outer diameter and
through the u e of improved no epiece frict ion
materia ls which do not excite the vibrations when
rubbing occurs with the seal seat.
119
BELLO W S~
'- P ROFILE
AFT ER
TEST
1/
II
/'
ENLARG E D VIEW
NOSE'~~'~21
FIGURE VII-33.-N ose-piece wear due to seal vibration.
for a liquid fluorine centrifugal pump was required. Fluorine i one of the most corrosive of
known chemical . Early eals for fluorine pumps
used carbon nosepieces, which had been used
successfully in liquid oxygen. Attempts to run
these seals resulted in pump failure and severe
fires, which were traced to fluorine reaction with
the nosepiece carbon of the seal.
Since fluorine was, obviously, too active chemically for the safe use of carbon materials in
seals, attention was turned to election of material such as metal fluorid es which are compatible
wit h fluorin e. Frictional qualities of t hese materials were checked running together in liquid
fluorine. These experiments showed that nickel
fluoride appeared to have promise for providing
a protective layer with low fric tion. Accordingly,
a nickel-bonded titanium carbide cermet that
would form nickel fluorid e reaction films was
studied in friction and wear experiments in liquid fluorin e. D ata from tho e experiments in
oxygen and fluorine (fig. VII-34) gives a compari on of two potentially useful material combinations. The graphitic carbon material, which
was not run in fluorine, is one of t he best materi als for use in liquid oxygen and i given as a
standard for comparison. The nickel-bonded car-
I>:H
10-9
LIQUID OX YGEN
- 297" F
~ LIQUID FLUORINE - 30 6 F
10- 10
RID ER WEA R,
IN 3 /FT OF
SLI DING
10-
11
10-12
10- 13 L---L=.t.......---""=
COE F F OF
FRI CTION
C
ON
Cr
PL ATE
AI 2 0 3
ON Ni
BONDE D
TiC
FIGURE VII-34.-Friction and wear of potential seal materials. liding velocity, 2300 feet per minute; load,
1000 gra ms.
120
SELECTED TECH
LOW
PRESSURE,
NOSE,
Po
SUMMARY
In summary, the influence of extreme environments on operation of bearing and seals has
been described. These environments include (1)
low and high temperature, (2) vacuum, and (3)
contact with fluids chemically active toward the
bearing and seal materials. There are additional
area and environments, which were not discu ed, but which are of equal importance. Some
of these are (1) the nuclear radiation effect
(both neutron and gamma) on the lubrication
DUSTRY
BIBLIOGRAPHY
General
BISSON, EDMOND E.; AND ANDERSON , WILLIAM J .: Advanced Bearing Technology. NASA SP- 3 , 1964.
Bo DI, ARNOLD A.: Physical Chemistry of Lubricating
Oil . Reinhold Publishing Corp., 1951.
BoWDEN , F. P.; AND TABOR, D . : The Friction a nd
Lubrica tion of
olid . Clarendon Press (Oxford) .
Part I , 1950, P a rt II. 1964.
RABINOWICZ, ERNEST: Friction and W ear of M aterials.
John Wiley & Sons, In c., 1965.
HAW, MILTON C.; AND MACKS, E. FREID: Analysis and
Lubri cation of Bearing. McGraw-Hill Book Co., Inc.,
1949.
Wlf.COCK, Do AI.D F.; .~ ND Boo 1'lR, E. RICHARD: Bearing
Design and Application. McGraw-Hill Book Co., Inc.,
1957.
~
j
BUCKLEY, DoNALD H.; JOHNSON, ROBERT L.; AND BRAINARD, WILLIAM A.: Influence of Entrained Gases and a
H alogen Additive on Boundary Lu brication of Four
Oils at Temperatures to 1000 F. NASA TN D-2686,
1965.
HADY, \VILLIAM F.; ALLEN, GORDON, P.; AND JOHNSON,
ROBERT L.: Wear and Friction of Mechanical Carbon in Liquid Oxygen as Influenced by Transfer
Film. ASLE Tran ., vol. 6, no. 3, July 1963, pp. 201208.
JOHNSON , ROBERT L.; GODFREY, DOUGLAS; AND BISSON,
EDMOND E.: Friction of Solid Films on Steel at High
Sliding Velocities. NACA TN-1578, 1948.
J OHNSON, R . L. ; SWIKERT, M . A.; AND BUCKLEY, D . H.:
High Temperature Lubrication in Reactive Atmos-
r \
I
I
pheres. Carro ion , vol. 16, no. 8, Aug. 1960, pp. 101-
104.
JOH NSON, R . L.; AND SLINEY, H. E.: Ceramic Surface
Films for Lubrication at T emperatu res to 2000 F .
Am. Ceram. Soc. Bull. vol. 41, no. 8, Aug. 1962, pp.
504-508.
LOOMIS, WILLIAM R.: Evaluation of Five BearingSeparator Materials and Polyphenyl Ether Lubricant for Use in Space Power Generation Systems.
ASA T D-2663, 1965.
SLINEY, H. E.: D ecomposition Kinetics of Some Solid
Lubricants Determined by Elevated-Temperature xray Diffraction T echniques. Proceedings USAF Aerospace Fluid a nd Lubrica nts Conference, P .M. Ku,
ed., Southwest R esearch Institute, 1963, pp. 350-364.
SLINEY, HAROLD E.; STROM, THOMAS N.; A D ALLEN,
GORDON P. : Fu ed F luoride Coatings as Solid Lubricants in Liquid Sodium, Hydrogen, Vacuum, and Air .
NASA T D-2348,1964.
Vacuum Lubrication
BOWDEN , F. P.; AND YOUNG, J . E.: F ri ction of Clean
M etals and the Influence of Adsorbed Films. Proc.
Roy. Soc. (Lond on), Ser. A, vo l. 208, no. 1094, Sept. 7,
1951, pp. 311- 325.
BUCKLEY, DON ALD H .; A D JOHNSON, ROBERT L.: Friction and Wea r of Hexagonal Metals and Alloys as
Related to Structure and Lattice P a rameters in Vacuum to 10-'0 Millimeter of M ercury . Paper No. 65LC-18, ASLE, 1965.
BUCKLEY, DONALD H.; AND J OHNSON, ROBERT L .: Influence of Mi crostructural Inclu ions on Friction and
Wear of Nickel and Iron in Vacuum to 10-9 MilliD-1708, 1963.
meter of M ercury . NASA T
BUCKLEY, DoNALD H.; AND JOHNSON, ROBERT L .: M echanism of Lubrication for Solid Carbon Materials in
Vacuu m to 10- 9 Millimeter of Mercury. ASLE
Trans., vol. 7, no. 1, J an. 1964, pp. 91-100.
BUCKLEY, DONALD H. ; AND JOHNSON , ROBERT L .: Friction and Wear of Nickel-Aluminum Alloys and Some
Sulfur-Modified Steels in Vacuum to 10- 9 Millimeter
of M ercury. NASA TN D-2307, 1964.
121
BUCKLEY, DoNALD H.; AND JOHNSON , ROBERT L .: Influ ence of Crystal Structure on Friction Characteristics
of Rare-Earth and Related Metals in Vacuum to
10-'0 Millimeter of M ercu ry. NASA TN D-2513,
1964.
B CKLEY, DONALD H .: Influence of Order-Disorder
Tran form ation on Friction Characteri tics of Copper-Gold Alloys in Vacuum. NASA TN D-2985, 1965.
BUCKLEY, DONALD H .: Influence of Crystal Orientation
on Friction Characteristics of Titanium Single Crysta ls in Vacuum . NASA TN D-2988, 1965.
MORRAL, F. R.: Cobalt Alloys as Implants in Humans.
Paper presented at the ASTM/ASM Symposium on
M etal as Surgical I mplant M ateria ls (Detroit, Mich.l,
Oct. 1965.
- - ').
\
122
NEMETH, Z.
.; AND ANDERSON, W. J. : Effect of Air
and Nitrogen Atmospheres on the T emperature Limitation of Liquid and Solid Lubricants in Ball Bearings. Lubrication Eng., vol. 11, no. 4, July-Aug. 1955,
pp. 267-273.
NEMETH, Z. N.; AND ANDERSO " W. J.: Im'estigation of
Temperature Limitation of Variou Lubricants for
High-Temperature 20-Millimeter-Bore Ball Bearing.
ACA TN-3337, 1955.
EMETH, ZOLTON N.; .~ND ANDERSON, WiLLIAM J .:
Temperature Limitations of Petroleum, ynthetic, and
Other Lubricants in Rolling-Contact Bearings. SAE
Trans. vol. 63, 1955, pp. 556--566.
TAYLOR, K. M.; SIBLEY, L. B.; AND LAWRENCE, J. C.:
Development of a Ceramic Rolling Contact Bearing
for High Temperature Use. Paper No. 61 LUB-12,
ASME,l961.
WILSON, DoNALD
.. Evaluation of Unconventional
Lubricant at 1200 0 F in High-Speed Rolling Contact
Bearings. Paper No. 61-LUBS-9, A ME, l961.
Gas Bearings
CASTELLI , V.; AND ELllOD, H. G.: Solu tion of the Stability Problem for 360 Deg. Self-Acting, Gas Lubricated
Bearings. J . Ba ic Eng., vol. 87, no. 1, March 1965,
pp. 199-212.
123
LUDWIG, LAWRENOE P.; STROM, THOMAS N . ; AND ALLEN,
GORDO P.: Gas Ingestion and Sealing Capacity of
H elical Groove Fluid Film Seal (Viscoseal) Using
Sodium and W a ter as Sealed Fluids. NASA TN
D- 3348, 1966.
M CGREW, J. M .; A D M cH UG H, J. D.: Analysis and
T est of t he Screw Seal in La minar and Turbulent
Operation. J. Basic Eng., vol. 87, no . 1, M arch 1965,
pp . 153- 162.
M UIJDEJtMAN, E. A.: Spiral Groove Bearings. Philips
R es. R ept. Su ppl., no. 2, 1964.
vnnn
J.
TABLE
Cryogenic
fluid
Boiling
point,
of
Oxygen
Nitrogen
Neon
Hydrogen
Helium
-297
-320
-411
-423
-452
Freezing
point,
of
-362
-346
-416
-434
-----
H eat of
vaporD ensity, ization,
lb/cu ft Btu/ lb
71
51
75
4.4
8.5
92
86
37
194
10
FREEZING POINT ~
[ BOILING POINT
~METHANE
~~~~nOXYGEN
~FLUORINE
~NITROGEN
BNEON
[SjHYDROGEN
BHELIUM
ABSOLUTE -400
ZERO
-300
- 100
200
TEMP . of
FIGURE
126
800
700
VACUUM
600
SPECIFIC
IMPULSE,
LB-SEC/LB 500
400
CHEMICAL BIPROPELLANTS
\
I
I
[
I
\
VIII-2.-Rocket
liquids.
FIGURE
performance
of
NUCLEAR
cryogenic
V;;
L_~-
CRYOGENIC PROPELLANT
APPLICATIONS
A number of cryogenic fluids can be used as
propellants (fig. VIII-2).
ASA is presently
using two of the e fluid s in large quantities,
namely, liquid hydrogen and liquid oxygen. Their
aerospace use are described to convey an im-
500
WASHINGTON
MONUMENT
400
HEIGHT,
SATURN :l[
300
FT
200
100
MAN
o L---~----~~----~~------~~--
FIGURE
that
127
pression of the present size and extent of operations using t hese fluid s. The relative sizes of
two vehicles that use liquid hydrogen and liquid
oxygen as propellant are illustrated in figure
VIII-3 . The Atlas-Centaur vehicle is 110 feet
high ; the Saturn V vehi cle, which will someday
carry man to and from the Moon is 365 feet
hi gh. hown for compari on are Man (app rox.
6 ft high) and the Washington Monument (555
ft hi gh). The Atlas-Centaur vehi cle became operational in 1965, while the Saturn V vehicle will
be flown for t he first t ime in 1967.
The Atlas-Centaur vehicle, shown in figure
VIII-4 at lift-off, i the first United States vehi cle to use liquid hydrogen a a propel Ja nt. A
chematic dra wing of t hi vehi cle is shown in
figure VIII-5. The Atlas, or first stage, burns
li quid oxygen and kerosene and u e three engines with a tota l of approximately 390 000
pounds of thru st. The econd stage, which is t he
Centaur, burns liquid hydrogen and liquid oxygen a propell ants and u e two 15 OOO- poundthrust engines. The amount of cryogenic pro pelIant consumed by both stages i 2.5 tons of
liquid hydrogen and 102 tons of liquid oxygen.
The atu rn V v hicIe is compo ed of three
stages, as shown in figure VIII- 6(a). The fir t
stage, -Ie (fig. VIII-6( b)), burns liquid oxygen and kero ene similarly to the Atlas first
stage. The five engine, with a total thru t of
7 500 000 poun ds, that a re used in this stage
make it the ation 's most powerful boo ter. The
second tage, -II (fig. VIII-6( c)), uses liquid
hydrogen and liquid oxygen as propellant . The
liquid oxygen consumed weighs five times more
than t he liqui d hydrogen ; however, because of
the low den ity of liquid hydrogen , the hydro gen tanks are much larger than the liquid oxygen
tanks. In this stage, the hydrogen tank i insulated with a honeycomb-type insulation that i
bonded to t he outside of the tank wa ll. F ive
200 OOO-pound-thrust engine with a total tage
thrust of 1 000 000 pounds are used. Th e
-IVB third stage (fig. VIII-6 (d )) a l 0 use
liquid hydrogen and liquid oxygen. The upper
tank tores t he liquid hydrogen and the lower
tank , the liquid oxygen. In this stage, a foam in-
.~~
Jr
F I GURE
VIII-4.-Atlas-Centaur launching.
128
daily requirements necessary to support development of this vehicle requires 22 trailer loads of
liquid hydrogen, 76 trailer load of liquid oxygen,
and 26 trailer loads of liquid nitrogen.
1I-T11111&~i!ll-
LI QUID
HYDROGEN
....
.... ,
.... ....
/
/
/
/
FIGURE
129
r4 11 TONS
LIQUID OXYGEN
~--~~"""~~'-~--~\--~~:I~~~~--------~~~
// /'
:::K~~---_
(0)
(el
(b)
(d)
FIGURE VIII-7.-Atlas-Centaur
Kennedy.
la unch
pad
at Cape
F1GURE VIII-B.-Saturn S-IV stage ground test facility .
130
F IGU RE
FIGU RE
F IGURE
unjacketed
liquid-hydrogen
131
10
fl ow line
FIGURE VIII-15.-Liquid-hydrogen
temperature joint.
FIGURE VIII-13.-5000-Pound-per-squal'e-inch
tor.
g~ s
regula-
bayonet-type
low-
132
SELECTED TECH
TABLE
700
10
8
6
CONDUCTIVITY,
BTU/HR-FT _oF 4
~oo
Owner
Location
Government
Linde
Linde
Air Products
Air Product
Air R edu ction
(b)
100L I
-400
TEMP, of
'30
"30
60
30
30
6
L
o
Capacity,
tons/day
I
-200
Total 186
o
On tandby after Jan. 1966.
(b) Copper.
VIII-17.-0ring
plications.
I fIGURE
133
VIII-3.-Cost
0/
Electric Power
Energy
content,
Btu/lb
Liquid hydrogen
Liquid oxygen
Ga oline
Hydrogen-oxygen
fu el cell b
Hydrogen-air
fu el cell b
Gasoline engine c
and generator <I
Equivalent
energy
content,
kW-hr/ lb
52000
. . ....
15.2
.
. ....
18000
5.27
. . ....
.. ....
. ....
,
.....
. .....
., ....
." . . .
. .. . ..
. . , ...
"0.24
. .... .
......
0.0365
. .....
. .....
.0202
. .. . ..
......
.0228
0 tax.
Efficiency, 65 percent.
c Efficiency, 35 percen t.
d Efficiency, 95 percent.
IOO-=-_ _ _ _ _~
I-GAL/HR PLANT. /
80
60
COST, OOLLARS/GAL
40
20
FIGURE
r 66-GALlHR
\ PLANT
134
I N DUSTRY
F IGU RE
INN ER BA G:
HYPALO N- NYLONAI - MYLAR
/
,
r OUTER BAG :
VINYL-CO ATED
NY LON
AI R
BLOWER -
~---------- 9 2 F T ----------~
F I GURE
M any materia l characteristic change drastically at low temperature; for examp le, two important change occur when tru ctural materials
are cooled to cryogenic temperature : they tend
to become stronger and brittle.
The popular structural materials undergo various in crea e in yield strength at low temperature
(fi g. VIII- 22 ) .
The materi als shown are 301 tainle
teel.
(70 percent cold reduced), a u ed in t he Centaur vehi cle; a titanium a lloy t hat i currently
being inve t igated for propellant-tank applica tion ; an aluminum alloy t hat is used on t he
Saturn S-II and -IV vehicles ; and 304L annealed
stain Ie steel, whi ch i often used for ground
storage app lications. The 301 tainle s steel increa ed abou t 50 percent in yield strength between room and liquid-hydrog n temperature ,
the titanium alloy increa ed about 100 percent,
and the a luminum alloy and t he 304L tainless
steel in crea ed much les .
The ot her property change i the tendency of
t he material to become bri ttle, that is, the materi al cannot defo rm pI a tically. It may be st rong,
but it cannot accommodate stress concentrations
FIGURE
-I
135
250XI0 3
200
FRACTURE
YIELD
0 .02,,/
150
150
./
.06
.----- ----
100
/'
/'
PSI.jiN
PSI
."... < ,
.,/
TOUGHNESS ,
STRESS,
--/'
THICKNESS,
IN.
50
100
AI ALLOY [2014-T6h
\
~
~ ~ ,r ~04L SS [ANNEALED)
50~ /1
100
TEMP , OF
FIG GRE
FIGU RE
tress
on
t.
'.0;
.,
""~"
"",.
'--
"
-: -
..
'~
. . :-.'
.,'
!:.--_.,
. ,
1>-"
-
-- . -
, #....
. ~." . . . .
"
.
.-
FIGURE
136
sufficient toughness for it thickness can be important. Figure VIII-26, for example, hows a
result of failure to provide adequate toughness.
The fragment seen in figure VIII-26 are from
a 22-foot-di ameter steel pressure vessel, which
failed in the hydrostatic proof test; in t his case,
the ve el failed before yield stres was reached.
This failure was an example of bri ttle fracture
at room temperature caused by a flaw in the
longitudinal weld , as indicated by t he arrows.
The fl aw which caused this failure was approximately 2 inche long (fig. VIII-27). The
fracture toughness of the weld for thi material
wa low, even at room temperature, and t he
flaw propagated in a brittle mann er. The chevron
markings on t he right side of the material point
to the fracture origin . These markings on the
fracture faces were used to identify t he point of
failure initiation. This large fl aw was undetected
by both careful and repeated X -ray and ultrasonic inspections. Current nondestructive inspection techniques are not adequate to assure identifi cation of all significant flaws.
The cau e of failure of t his ve el is shown
graphically in figure VIII-28. The stress at fracture u is related to the fl aw size and fracture
toughness by t he equation
Kc
u = --;====::;::;::;::::<::;;<
v~a+~
,
CHEVRO N
MARKINGS
STRESS.
CT
FLAW SIZE, a
I
I
137
INITIAL
FLAW ~,
( FLAW GROWTH
CRITICAL FLAW
STRESS.
PROOF STRESS
CT
I
I
- - j l- - - - 0 r '\
OPERATING
I ,r Dp
FLAW SIZE. a
FIGURE
--
_., ...
_-_ ..
--.-----------------------~
138
\
\
STRESS,
u
PROOF STRESS
-~ ~~
i~,
STRESS
I ,,{...
I
1 -,r Oc
FLAW SIZE,
- -IOOCYCLES
DUSTRY
FIGURE
250x 10 3
- - YIELD
200
150
"-
""- ........
- - ALLOWABLE
........
[ SAI-2 .SSn Ti
-....:(:-.....
STRESS,
PSI
100
50
-.--,-----.---~--~--~/
OL_~4~0~O--~3~OO---o~--~-~-~~-TEMP, of
VIII-31.-Effe ct of temperature on yield and allowable trength for 3000-pound-per-square-inch presure-vessel application .
FIGURE
FIBERGLASS
COMPOSITE .
200
150
( TITANIUM
ALLOWABLE
STRESS , PSI
100
50
ALUMINUM
FIGURE
139
Fiber Glass
Other promising materia ls for fa brication of
cryogenic tanks are t he fi ber- glass-fi lam nt woun d composites. Figure VIII- 32 how t he
same allowable stre curves fo r titaniu m and
aluminum as in figure VIII- 3l, wi t h the addition
of a curve for the fi ber-glass composite. T he fi berglass composite has an in creasin g usable strength
leve l wit h decreasing temperature, wi t h a leveling
off or slight redu ction near liquid-hydrogen tem perature. This in crease in trength and t he low
den ity of the material make gl ass-fib er-fi lament-woun d composites attractive fo r cryogeni c
pre ure vessel. Not only doe the materi al
t rength in crease markedly wi th decrea e in t emperature, but also the fracture t oughness remains
hi gh because of t he nature of the constru ction.
The structural characteristi cs of a fil amentwound pressure ve el are illustrated schematically (fig. VIII-33 ) by the wa ll cross section
where t he hoop and t he longitudin al load-carry~
ing fil amen ts are shown embedded in a matrix of
l~w-modulus mat erial, usually a resin or a plastIC ma teri a l. The inherent high fracture t ou ghness of this structure arise from the fact th at
fr acture of a single load-carrying fil ament is
arrested by the matrix material wit hout propagating to an adj acent fil ament. The matrix materi a l in t his type of structure is forced t o undergo
large strains in localized areas between the fi laments, and, a a resul t, some local cracking of
the resin occurs. The leakage paths indicated in
th e sc hematic di agram are developed in this way.
y/
STRESS
/ I r MAX
I
ELASTIC STRAIN
STRAIN
FIGURE
VIII-34.-Elastic tra in .
Thi leakage problem is present at all temperature levels and requi res the use of an impermeable lin er. These fil ament-wound vessels are
li ght, strong, and tough, but t hey leak. Obtaining
an effective liner is thus a prerequisite t o t he use
of fi ber gla s for a pre sure vessel.
The fiber gl ass, whil e strong, has a low elastic modulu , whi ch results in a large amount of
stretching of the vessel wall during pressurization .
Thi st ret ching requires a fl exible liner that can
follow t he wall. At room temperature, usually
no problem is presented ; a lin er can be made
from rubber or ot her ela tomeric materia l. At
cryogenic t emperatures, however, the elastomers
lack t he needed fl exibility, and other materials
mu t be used .
The elastic strain capabilities of several possible liner materi als are compared wit h fiber glass
in table VIII-4. The elastic strain illu trated in
figure VIII- 34, is t he maximum ' elon gation a
materi al can withstand without a permanent set
due t o plastic flow . At room temperature, t he
elastomeric materi al , such as rubber, are more
than adequate to ati fy the lin er requirement .
TAB tE
M ateri al
FIGURE
yes eJ.
pres ure
Gla fi bers
E lastomers
T efl on
Myla r
Stainle s steel
Al um inu m
2.7
,...,0
1.6
1.3
.6
.5
140
While T eflon and Mylar are also adequate, tain Ie s steel and aluminum do not have the necessaryelongation. At liquid-hydrogen temperature,
however, the elongation of glass fib er i 2.7 percent and that of the elastomers drops essentially
to zero. The two polymeric materials, T eflon
and Mylar, can elongate only about one-half as
much as the glas fiber. he elongation of tainless steel and aluminum are only about one-fifth
of that required. The inability of the e materials
to match the strain of the fiber glass requires
de ign innovation if they are to be u ed for
pre sure-vessel liners.
ASA is currently investigating three different
cryogenic liner concepts (fig. VIII-35). The first
approach i to use a corrugated metal liner, which
is essentially a two-dimensional bellows, in a
fiber-gla tank (fig. VIII-36). The liner shown
was made of 3~-mil stainless steel and was manufactured over a plaster mandrel. A fiber-glass
FroURE
",-FIBERGLASS
CORRUGATED METAL
~~CORRUGATION
ADHESIVEL Y BONDED
METAL FOIL
WlZ//(/zz/Z/V
-
evT2r.?/...-:/...,/
.....,/
....,/
....,/....,::/"72/~-5t
:: /
, ADHESIVE
-'~FOIL
. r fIBERGLASS
~~METAL
FIG URE
FIGURE
VIII-35.-Liner concepts.
VIII-36.-Corrugated liner.
WALL
I
I
141
VIII-38.-0verwrapped metal
(Cour tesy Aerojet General Corp.)
FIGURE
tank
section.
CRYOGENIC INSULATION
Storing and transporting cryogenic fluids normally require tank insulation. In special cases,
this insulation is provided by a buildup of frost
on a bare tank.
The lift-off of an Atlas-Centaur vehicle from
the pad at Cape Kennedy is shown in figure
VIII- 39. The white portion of the Atlas, which
is the lower stage, is frost covering the bare liquid-oxygen tank. Ice can be seen falling off
FIGURE
142
LIQU I D
PLASTIC FOAM
LIQU ID
TANK WALL
OUTER WALL
LI QUID
LIQ UID
OUTER WALL
TER WALL
143
VIII-44.-Machine winding of multilayer insu lation on large tank . (Courtesy Linde Di v., Union Carbide Corp.)
FICURE
VIII-45.-Machine winding of multilayer insulation on small tank. (Courtesy Linde Div., Union Carbide Corp .)
FIGURE
THERMAL CONDUCTIVITY .. 01
BTU IN.lHR FT2 OF
L.-_-
--
__ - MULTILAYER
INSULATION
FWtlRE
144
SELECTED TECH
1000
100
INSULATION
THICKNESS,
IN.
10
r PLASTIC FOAM
1/10:
, EVACUATED
FIBERGLASS
1/10:
, EVACUATED
I \ MULTILAYER
\ I/IQ
\
--rBOILOF!
/ RATE,~.
r PER DAY
.1 ~'------'_'---''--'---''---'--_'--_ _
FIGURE
for lO-foot-
DUSTRY
FIGURE
~ POWDER
----"-<---
MUL TILAYER
224 GALS
OF TANK LENGTH
DAILY EVAPORATION LOSS
INSULATION WEIGHT PER
3%
135 lB
0 .7%
10 LB
FOOT OF LENGTH
FIG URE
FIUURE
145
RATE OF HEAT
TRANSFER .
BTU/ HR-FT 2
FIGURE
GLA SS PAPER
SINGLE
ALUMINIZED MYLAR
GLASS FABRIC
F IGU RE
40 percent reduction in the rate of heat transfer, or propellant boiloff rate, occur when silver
reflective shields (reflectivity, 0.98) are used in stead of alu minum (refl ectivity, 0.965) .
orne of the spacer materials in current use
are shown in figure VIII-53. ingle a luminized
Mylar (t mil thick), a reflective shield, is also
a spacer. Wrinkling the aluminized Mylar resul ts in only point contacts between adjacent
layers. Glas paper (about 3 mil thick) and
glass fabric are also used as spacer. All these
DOUBLE
' .....-ALUMINUM ---~
SINGLE
ALUMIN IZED MYLAR
ALUMINIZED MYLAR
materials are used to eliminate olid conduction
paths through the insul ation.
Some of t he newer spacers that are now being
inve tigated (fig. VIII-54) are silk net, open
cell foam (about 20 mils thick), and two combinations of net and foam .
ALUMINUM FOIL
For atisfactory u e, howeve r, shields and
FIGURE VIII-51.-Multilayer in ulation reflective hields. r spacers must be integrated int o a system designed
146
for a particu lar application. Several such systems proposed for aerospace application to a
liquid-hydrogen tank are shown in figure VIII55. The basic design of these systems is irifluenced strongly by two consideration . Fir t, advantage mu t be taken of the vacuum of space,
so that the low thermal conductivity previously
de cribed can be obtained. Obtaining a vacuum
u ually present no problem, however, ince the
multilayer system can be vented to pace. Conden ation of air and moi ture within the in ulation mu t be prevented during prelaunch, however, and the insulation itself mu t be prevented
from being blown off the tank during the a cent
into the vacuum of pace. econd, a metal vacuum jacket, uch as is used on ground equipment,
is too heavy to use during prelaunch and a cent.
The two ystems on the left in figure VIII-55
have a sublayer that provides a temperature at
the base of the multilayer insulation which is
above liquid-nitrogen temperature. Dry nitrogen gas is used on the ground to purge the multilayer. In the upper left of the figure, the sublayer is helium-purged fiberglass. The sublayer
in the lower left is a passive layer of sealed
po lyurethane foam. In the upper right, a heliumpurged multilayer blanket mounted directly on
the tank wall is used. On the ground, dry nitrogen gas surrounds this in ulation. Finally, in
the lower right, a relatively thick layer of compre ed multilayer in ulation contained within a
lightweight flexible barrier, or vacuum jacket, is
used. Thi system i continuously evacuated on
SILK NET
NET BETWEEN
FOA M STRIPS
FIGURE
NET BETWEEN
FOAM BUTTONS
EX IBLE
IMPE RMEAB LE
FIB ERGLASS
BATTING
BARRIER ~,
ULTILAYERS ~'"
PUR GED
~_M"m"""
~
i
SEAL ED
SECONDARY
INSULATION-'
PASSIVE
FIGURE
XIBLE
IMPERMEABLE
BARRIER
EVACUATED
SHINGLE
BUTTON
.... PROPELLANT
...,
SIDE
VIII-56.-Multilayer
methods.
FIGURE
in ulation
attachment
147
VIII- 57.- T ank wi th shingled mul tilayer insul ation. (Courte y Lockheed Missiles and Space Co .)
FIGU RE
l<'IGU Il E
F A B R IC
F UZZ Y P I LE
F IGU IlE
148
SELECTED TECH
1.2
PER of
---- --e
.8
.4
-----
~b4k50~==~==~~~-~30~0~~:~~
~80
,
He
H2 Ne
N2 O2
TEMP. of
ROOM TEMP
FIGURE
CRYOGENIC INSTRUMENTATION
Common to all cryogenic ystem i the need
for in trumentation. Some of the components
which mu t be controll ed and moni tored are
seen in figure '/III-50, which shows a nuclear
rocket y tern The liquid-hydrogen propellant
tank, pumps for the liquid hydrogen, turbine for
driving the pump, flow line, valve, and rocket
engine all require in trumentation .
The principal cryogenic mea urements are as
might be expected: the common ones of temperat ure, pressure, flow rate, and quantity of
propellants. It has generally been necessary, however, because of the low temperatures with which
we are working, to extend the operating range
of exi ting commercia l in trumentation.
For cryogenic temperature measurements, three
ba ic type of ensor are u ed. Their sensitivity
characteristics strongly influence the useful range
of each type. Thi characteristic is demonstrated
F IGU RE
SEMICONDUCTOR
RE SISTORS
METAL
RESISTORS
THERMOCOUPLE
PROBES
FIGURE
by figure VIII-51. The ensitivity of the metalli c re i tance sensor limits t heir useful range to
temperatures warmer than that of liquid hydrogen. The ensitivity of semiconductors limits
their u efulne to temperatures colder than that
of liquid nitrogen. Obviou Iy the thermocouple
i no match' in sensitivity to resi tance sensors.
Some commercially available cryogenic temperature sen ors are shown in figur e VIII-52.
The em iconducto r re istor are usually either
germanium or carbon. The germanium sensors,
of which two types-a screw-in type and an
immersion type-are hown, have good repeatability , but unfortunately their pre ent poor inter-
149
PRESSURE
GAG E
ROOM TEMP
'1",1111,11,1111111,_:
1'1,,',',1111111111111111<
~~
VIII-63 .- Cryogenic fluid prec lire measu rement.
Conventional pre ' ure-gage in tallation.
FIGURE
changeabilit y requires that each sensor be calibrated throughout its intended temperature range.
A carbon semiconductor shown next to the
germanium sensor is a compo ite carbon resistor
like t he ones u ed in radio and television sets.
As a temperature sen or, it uffer from poor
stability; that is, its calibration will change wi th
u age.
The metal resistan ce temperature' sensors are
primarily platinum. Shown are two immersion
types, a cementable- urface type and a welda ble-surface type. In general, platinu m enSOl'S are preferred for cryogenic temperature mea,
surements wherever po sible becau e of t heir
excellent repeatability and calibration accuracy.
At the upper ri ght of figure VIII- 62 is hown
a thermocouple. In spite of its low sen itivity,
it has app lication at cryogeni c temperature, primarily because of its small size. (The sensin g
element is the small junction at t he very end of
t he wires.) Chromel-con tantan is preferred to
copper combinations because t he th erm al conductivity of copper, a previou ly hown, is very
high at cryogenic temperatures. The high conductivity could cause a high heat input to the
mea uring junction and give an erroneou measurement.
Th ermocouples usuall y have t he fastest response to temperature changes because of t heir
small mass. However, all t he en ors hown tend
to have a faster response at cryogenic t empera-
ture t han at room temperature because the specifi c heat of t he ensor material decreases wi th a
decrease in temperature.
At t he bottom of figure VIII-62 are shown
t hree pro bes in which the sen or element is protected against vibration and high flow velocities
by a t ube. Th e lower probe is also seal ed to
protect the element against high pressures.
The mea urement of low temperature requires
several con iderations. This is also true for the
measurement of cryogenic fluid pressure. The
princip al problem is t hat most conventional pressure tran du cer eit her will not work in the
cryogeni c environment or are highly temperature
sensitive. However, convention al transdu cers
can be u ed to measure cryogeni c fluid pressures
if they are kept at essentially room temperatures.
As hown in figure VIII-63, t he gage may be
kept near room temperature by means of a long
pressure t ube. The cryogenic liquid flows into
t he tube and boils, t hus filling the tube wit h warm
gas, which acts a a t hermal barrier between the
measuring diaphragm and t he cryogeni c liquid.
The disadvantage of such an install ation is t hat
t he combination of liqui d and gas in t he tube
causes a reduction in frequency response. This
type of installation will give a respon e of only
abou t 10 cycle per econd. For measuring t ranient pressure, gage especially designed for cryogenic temperatures must be used.
Figure VIII-64 shows an application requiring
such a transducer. H ere, following the high-fre-
FIGURE
150
VIII-65.-Commercially
pressure transducers.
FIOURE
available
strain-gage
quency pressure fluctuations within a liquidhydrogen pump, casing is de ired. For such an
application, a fiu h-mounted transducer is required. The cold, pul ating cryogen contact the
sensing diaphragm of this transducer directly.
This type of installation can follow pressure oscillations at frequencies of everal thousand cycles per second.
These ca es are only two example of how
transducers can be applied to the measurement
of cryogenic pre sure. In actual practice, many
types of pressure-measuring devices are required
to meet the various vehicle and test-stand appli cations.
Figure VIII-65 show
ome commercially
available pres ure transducers, here, all of the
train-gage cIa s. These units are generally used
on ground test tands. The transducers on the
right are gage-type units and the one on the bottom right i a partly diassembled absolute unit.
The four units on the left are differential pressure
units.
The cutaway in the lower left of figure VIII-65
illustrates one of the transducers designed for
measuring small differential pressures at high
average system pre ure. This transducer i just
one example of those avail able on today's commercial tran ducer market. The full-scale differential range can be 5 pounds per square inch
or less and can resolve pressure differences in the
order of 0.05 pound per square inch while
operating at a nominal pressure level of 3500
pound per square inch. In addition, these unit
are designed for use with corrosive fluid and
------------------------11..------- __________________
'- INSULATION
FIGURE
~I
I
151
There are other type of flow-measuring devices ui table for cryogenic fluid s. Turbine meters , which are also volumetric type, have come
.
into widespread use in t he la t few year . FIgure
VIII-57 shows some typica l turbine meters with
a cutaway view. The meter consists of a free
turbine, straightening vanes, and an externally
mounted electric pickup which senses turbine
speed.
Figure VIII-58 show some typical calibration
results that were obtained when turbine meters
were calibrated on water, liquid oxygen, and
liquid hydrogen. A perfect meter is represented
by the traight line passing through the origin.
In the actual case, bearing friction is present so
that t he turbine does not tart un til fluid force is
sufficient to overcome the friction. As the flow
rate is fur t her increased, the friction al forces are
overpowered and the meter follows t he ideal
curve. Because of it low density, con iderably
higher flow rates of liquid hydrogen than liquid
oxygen or water are required to overcome the
frictional forces, and the meter does not approach
the ideal curve until a bout midrange.
Th e useful range in water and liquid oxygen
is from about 10 to 1 a compared with 2 or 3
to 1 for liquid hydrogen . Experience has hown
that, for liquid oxygen app lications, a water calibration will assure an accuracy of better than
2 percent over t he upper nine-tenths of the range.
For a hydrogen meter calibrated on water, the
2-percent accuracy will app ly on ly to about the
upper half of the meter range. If an accuracy in
t he order of 1 percent i required, the turbine
100
ROTOR SPEED,
50
,. OF FULL RANGE
AND LO ,
50
VOLUME FLOW RATE , % OF RATED
FIGURE
VIII...{i7.-Turbine I owmeters.
100
FLO~
F I GUR~~
152
FIGURE
DUSTRY
FIGURE
FIGURE
153
I
FIGU RE
I
I
I
FIGURE
LH2
CAPACITANCE
PROBE --- __ _
ensor.
----
CONCLUDING REMARKS
L0 2
CAPACITANCE
PROBE -- -p;-_ _~
//"
.- MIXTURE RATIO
VALVE
L0 2
,/!
/
I
I
I
'+---+L.;f>-...,,--+-"\
PROPORTIONAL
FIGURE
thi way have found widespread use in the aerospace industry, both for ground storage and for
flight applications. For example, as shown in
figure VIII-73 , the Centaur vehicle uses such
capacitance probes in the propellant utilization
I
I
llX
Technology
U tilization
T cal
J.
S.
DAY,
G EORGE
HOWICK , RICHARD L.
L ESHER, AND HOWARD L. TIMMS*
NASA H eadquarters
156
lAA
,
j
Fro RE IX-I.-STAR
journals.
and
IAA
ab tracting-indexing
JI
157
source, per onal author, report number, accession number, and contract number. Separate
cumulative index issues are pu~lished quarterly
and annually. Thus, STAR and it indexes provide the user with both an announcement tool
for maintaining current awareness of developments in his field and a retrospective searching
tool for bringing him elf up to date on a specific
matter at any point in time.
By arrangement between NASA and the American Institute of Aeronautics and Astronautics,
that society's publication, International Aerospace Abstracts (IAA) , is issued in coordination
with STAR with no overlap or duplication. IAA's
worldwide coverage of scientific journals, books,
and open meetings complements STAR's worldwide coverage of the report literature. The two
publications thus provide comprehensive access
to current literature on aerospace science and
technology. More than 50000 items a year are
announced in these two journals.
The Department of Defense and its contractors
are the largest single source of documents in
STAR, almost a third (fig. IX-2). Documents
of foreign origin (mostly Soviet) total about the
same. The ASA-sponsored input, about a fifth
of the total at present, is growing with the rising
flow of contractor reports into our central collection.
The portion of foreign input into IAA is even
greater than that of STAR, more than 40 percent, as shown in figure IX-3. This perhaps
reflects the European tradition of publishing in
the learned journals rather than in report literature.
Note then the large number of items of foreign origin fed into the NASA information system for use not only in our national aerospace
programs but also through the regional di semination centers for use by United States industry.
NASA Publications
~
._---- -----
NA1A " NO
CONllACTOU
11"
OTHH GOV 'T
ACi[NCIUANO
CONT~ACTOtS
""
o r"'E~ 'OIIHGN
1~
~NCE
USSR AND
SOV IO 8l OC t(
CiHM,ANY
1.97"\0
lo SS
19>
,,!fAIN
1. 1l
ITA LY
1.11
~. 9J
FIGURE
u.s.
58'!>
_ _---'f---~NCE
G ERMANY
3'1>
O THER FOREIGN
11'1>
USSR
15'1>
JAPAN
BR iTAIN
10'1>
ITALY
2.1
1.5
POLAND
1.3
NETHERlANDS
CZECHOSLOVAKIA
1.0
1. 0
23 O THER COUNTRIES
4.4
FIGURE
158
J
I
-----~--------------~~-
159
TECHNOLOGY UTILIZATION
NbS- 12422
I)f I
'lytCH
.
~
FIGURE
is through a Selective Dis emination of Information Program-- ASA/ SDI. SDI is a computerbased system for notifying individual scienti ts
and engineers of new reports and journal articles
of value in their own particular work. This system illustrates the many possibilities that arise
from computer speed, capacity and flexibility in
manipulating data.
SDI can be compared with a library run in
reverse: a library in which people as well as
acquisitions are cataloged. A new reports and
articles are received, they are matched to the
interests of individual users.
In SDI, the user's information needs are cataloged on magnetic tape as lists of words or
phrases describing each man's particular interest ; these lists are called user profiles. The
document appear on another tape as lists of
indexing terms describing their contents, called
document profiles; this is the same NASA tape
index to new acquisitions that has already been
prepared for other uses. The computer then compares user profiles with document profiles. When
a predetermined degree of imilarity between a
man's in terests and a new document is found,
the man is sent a citation of the report and
instructions on obtaining the full report.
SDI is currently serving 500 NA A scientists
and engineer and 200 Air Force personnel. Although it is still under development and too early
to make a formal evaluation, the volume of
documents reque ted by participants in the SDI
program has risen as much as 300 percent over
their pre-SDI patterns. Eventually the program
will be operated on a decentralized basis at the
variou NA A Centers, and perhaps by major
contractors.
In the meantime, variation of the pre ent
program, such as tandardized profiles and simplified announcement formats, are being tested
which should be able to serve many more users.
Numerous case histories of technology transfer
can be cited to illustrate the usefulness of this
system .
160
cour e, actively up ported and aided t he development of a civilian nuclear electric-powergenerating industry; it has helped develop industrial and biomedical uses for radio isotopes; it
has helped to create many other civilian u e for
nuclear technology. Recently the Atomic Energy
Commi ion al 0 began to introduce commercial
industry to the nonnuclear technology developed
by the Atomic Energy Commi ion in the cour e
of its nuclear re earch and development programs. The laminar flow clean room , now fairly
common in the electronics and in trument indu tries, i an example of uch econdary utilization of Atomic Energy Commission technology.
Another examp le i the development of extremely
advanced mechanical centrifuge technology, incorporating "quantum jump " in the art of making bearing and eal. uch advances, nece sary
for the continued improvement of nuclear technology, obviously have many potential applications out ide the nuclear indu try. The focal point
for obtaining uch new knowledge from the
Atomic Energy Commis ion is its Office of Industrial Cooperation at Argonne National Laboratory.
The Smithsonian Institution and the National
Science Foundation al 0 have obligation to
diffuse new knowledge throughout the economy.
One outgrowth is the cience Information Exchange (SIE) , located within the Smith onian
In titution and supported largely by funds from
the National Science Foundation. This is not a
technology transfer program in the same ense
a are the programs of ASA and AEC, rather
SIE is a regi try of current ongoing research
ta ks supported by Federal and non-Federal
grant. SIE can tell a scientist or engineer who
el e i working in his field. The scienti t or engineer can write to SIE and describe the specific
field of interest. In return, SIE will provide him
with one-page definition of all the work in that
field that has been reported to SIE. For each
of these tasks, IE can provide the name of the
supporting agency, the title of the project, the
names, titles, and locations of the principal investigator , the name and address of the in titution conducting the research, a 200-word ummary of the work under way, the starting date
for the research, the planned conclusion date,
rI
161
ence span a broad pectrum of science and t echnology , are a ble t o under tand and interpret
the problems of indu trial firm s and to screen
and identify relevant information from NA A
scient ific and t echnical information resources.
Selective Dissemination
A ba ic service provided to industrial fir m
part icipating in ARAC is the Select ive Di semination Service, a "current awareness effort " based
on the specific technical intere ts of each firm .
E very 2 week newly received NASA computer
tapes containing everal t hou sand citations of
techni ca l reports and journa l art icles aresearched.
E ach member firm has several "interest profiles"
which have been developed t hrough a cooperative effort of company and ARAC engin eers and
cientists. Th ese profiles refl ect th e company 's
special areas and activities.
ARAC assigns a techni cal staff member to
each profile. Thi provide a con t inuous manto-man contact between techni cal people in each
company and ARAC engineer and scient i ts.
E ach p rofile is tru ctured for compu ter search
by the ARAC specia list and is machine matched
against t he indexed de cript ion of every new
report. Ci t ations of document that appear to
match profile intere ts a re screened and evalu ated
by t he ARAC technical man before they are
ent to cienti ts and engineer in each member
firm.
In terest profiles serve t he purpo e of main taining cont inuous and current awareness of particip ating firm s in relevant area of cience and
t echnology. E ach profile is dyn ami c and can be
ea ily modified a intere t and needs change.
ARAC is ident ifying and sending out over 13 000
abstract every 2 week in respon e to matchin g
with more t han 300 profiles.
Th e ystem combine th e economy and
peed of computerized information retrieval with
per on alized processing by competent t echnical
people wor kin g toward t he needs and interests
of indu t ri a l firm s.
Full copies of reports of intere t can be supplied by return mail in microfiche form (4- by
6-in. microfilm sheet ) for tho e companie with
Retrospective Searches
The R etro pective Search Service is set up to
fo cus on specific problem or areas of interest to
member firm. ARAC st aff pecialist take a
problem- olving approach to retrospective
searche . Th ese problem-oriented searches cover
the ent ire NASA fil e containing more than 200000
reports.
Search requests are studied and prepared for .
compu ter search by an ARAC technical man
whose background and experience closely parallels the subj ect a rea of the problem. Typically,
t he company scient ist or engineer is contacted by
phone before t he search is made to ensure that
the ARAC specia list under tands the problem
and all relevant detail .
R esults of each compu ter printout are carefull y screened and evaluated before results are
sent to the company. Interpretation and assessment of re ul ts are made whenever po sible.
The compu ter i used as a t ime-saving device.
All I"e ul ts pa s throu gh hum an hands and a technical mind before goin g out t o the request er.
earch problem may range from t hat of
seeking a part icul ar materi al wit h specified characteri tics to a tate-of-t he-art type search on
an area of technology such a fluid amplifiers.
On one earch for the Cummins Engine Company of Columbus, Indiana, on bearing technology, a ASA report was identified which provided the basis for Cummin to completely
reprogram their computer program used in
bearin g design for t hcir di esel engines.
.The Selective Di semin ation and R etrospective
Search Services complement each other. Ongoing
need and interests are met through elective
di semination. P art icular problem are handled
in depth a retro pective searche. Th e e p roblem can be converted t o in tere t profiles, or incorporated in exi ting profi les if a company eeks
t o main tain a current awareness in the area in
t he fu ture.
The importan t consideration is a clear-cut
understanding of company needs and interests
_ _ _ _ _ _ _ 0 _ _-
...- - -
162
- -- - - - - -- - - --
by ARAC scientists and engineers. These service provide a mechani m for meeting these
needs once they are identified and understood .
The close operating relation between ARAC and
participating firms is the all-important element
in succe ful results.
- - - - - - - - - - - . - -- -- -
_._- - - - - -
INDUS'l' RY
TECHNOLOGY UTILIZATION
163
normally requires only a minimal amount of
effor t. P art of t he coordinator' job is t o establish mul tiple receipt points within the company ;
attemp ts to funn el a ll ARAC ser vices to only on e
point are typically unsuccessful. To make ARAC
ervices effective, direct con tact i needed between ARAC technical people and those in the
company. Thus, ARAC operating procedures
have purposely been kept flexible to accommodate various in tern al operatin g plans.
ARAC activity with member firm s has moved
up exponentia lly for t he pa t 21- years. Those
comp ani es t hat have gone into t he program on
a positive bu t rea listic basis have cont inued to
expand t heir use of the services, and t his app li es
to nearly every firm. Over 90 percent of t he
init ial member firms are wit h us after nearly
3 years. The oil and ga in dustry is represented
in ARAC by Cit ies Service Company, In corporated; Kerr-MeGee Oil Industries, Incorporated ;
So cony Mobil Oil Company , Incorporated ; and
T exa Ga T ransmission Corporation.
H ere i an example of t he problem-solving
approach taken in ARAC. This example, as
well as the other example in t hi s text, are cited
wit h written approval of the companies concern ed. In ARAC all personnel sign a secrecy
agre ment t o protect t he in terest of all member
firms. Every request is handled on a completely
p roprietary basi .
The T exas Gas Transmission Corporation was
evalu atin g t he u e of gas-turbine-driven . compressors as power sources for system exp ansion
program in tead of con ventiona l reciprocating
gas engin e unit . The main component of the
gas t urbine compressor is a tandard jet aircraft
engin e widely used in civil and milit ary aviation.
The company asked ARAC for information and
data pertaining t o t he life expectancy of t hese
gas turbines und er condi t ions of tatic cont inuous
use.
A search of NASA literature yielded no directly relevant result, so ARAC next contacted
several specialized inform ation sources. WrightP atterson Air Force Base had been engaged in
testin g t he type of jet engine in question for
many years, and , alt hough t hey had no data
relatin g to static con tinuous conditions, they did
164
DUSTRY
ADDITIONAL INFORMATION
More information on the NASA T echnology
Utili zation Program can be obtained from
T echnology t ilization Division
Code T
National Aeronautics and Space Administration
Washington, D. C. 20546
Patent !icen e and waiver information may be
obtained from
Assistant General Counsel for Patent Matters
Code GP
National Aeronautic and Space Administration
Washington , D . C . 20546
STAR's (Scientific and Technical Aerospace Report) emimonthly i sues and cumulative ind ex
i sue are available postpaid from
uperintendent of Documents
United State Government Printing Office
Washington, D . C. 20402
(Semimon thly is ue: $33/yr; $2.25/copy ($42
and $2.50, foreign). Cumul ative in dex i ue:
$30/ yr ($35, foreign); single copy price varies
with page length.) IAA (International Aeropace Abstracts) is pubJi hed semimonthly and
avai lable from
American Institute of Aeronautics and Astro nautics, Incorporated
750 Third Avenue
New York, N. Y.10017
(Semimonthly is ue: $25/yr ($33, foreign). Cumulative index vo lume: $25/ yr ($33, foreign )) .
165
TECHNOLOGY UTILIZATION
166
SELECTED TECH
DUSTRY
Durant, Oklahoma
T echnology Use Studies Center
Southeastern State College
Pittsburgh , Pennsylvania
Knowledge Availability Systems Center
University of Pittsburgh
--------------- - ------
_~_J
1
I
AUTHORS
WILLIAM J . A N DERSON is Chief, Bearing Branch, at
Lewis. H e joined the taff of the Research Center in
1950. A native of Brookly n, Mr. Anderson attended
Ma sachusetts I n titute of T echn ology where he received
a B.S. degree in mechanical engineering in 1950 . . In 1957,
Ca e Institute of T ech nology awarded him an M .S . degree in aeronautical engi neering. H e ha specialized in
bearing and lubrication problems in spacecraft a nd aircraft propulsion and auxili ary power sy t m .
FRANK E. BELLES is H ead, Kinetics ection, at Lewis. H e
join,ed the Re earch Center in 1947. A native of Cleveland , Mr. Belle attend ed Western R eserve Un iversity
wh ere he received a B.S . in 1947. In 1952 he received an
M .S. degree in physical chemistry from Ca e Institute of
T echnology. Mr. Belles ha peciali zed in combustion
and detonation, high- temperature chemistry, and is currently working on chemi cal kin etic studi es by shock-tube
tec hniques.
EDMOND E. BISSON is Assi tant Chi ef, Fluid System
Components D ivision, at Lewis. H e joined the Lang ley
Resea rch Center in 1939 and tran ferred to Lewis in 1943.
In 1955 he wa appointed to hi pre ent po ition where
he directs much of NASA's research effort in lubrication
and bearin gs. Born in Ea t BalTe, Vermont, Mr. Bi son
\Va graduated wi th hon ors fr om the Un ive r ity of Florida
in 1938 with a B.S . deg ree in mechani cal engineering and
recei ved his Profes ional D egree of M echani cal E ngineer
from the University of Florida in 1954.
RICHARD S. BROKAW is Ch ief, Phy ical Chemi try
Branch, at Lewis. H e joined the R esearch Center in
1952. Dr. Brokaw is responsible for research in chemi cal
the rm odynam ics a nd eq uilibri a in gases, chem ical kin etic
and tran po rt properties in ga es, and fund a menta l of
ro cket combustion . H e received his B.A. degree in 1943
at warth more College and his M .A. (1949) and Ph .D
(1951) fr om Princeton University.
EDMU N D E. CALLAGHAN is Assistant Chief, Electromagnetic Propul ion Division, at Lewis. H e joined t he
staff of the Re. earch Center in 1944. Mr. Callaghan, a
native of Brooklyn, attend d Rensselaer Polytechn ic
In titute wh ere he received his B.S. degree in aeronautical engin eering in 1943. His research pecialties include
work on icing problem , heat tran fer, noise, turbulen(;e,
cryogenics, a nd magnetics.
BRUCE J. CLARK is an Aero pace T echnologist, Chemis-
Michigan, Mr. Clark attended the Uni versity of Michigan wh ere he received B.S . and M .S . degrees in chem ical
engineering in 1947 and 1949 and an M.A . degree in
mathematics in 1951. Mr. Clark has specialized in elementary co mbustion processes and i currently working
on the breakup characteristics of sp rays.
MELVI N S. DAY is Director of the Sci ntific and T echnical In formation Divi ion, N ASA. A native of Maine, he
wa gradu ated from Bates College in 1943, worked as a
chemi t, and served in the U.S . Army during World
W ar II. In 1947 he joined the Atomic E nergy Commission, later erving a Director of AEC' T echni cal Information Service. Mr. D ay joined NASA in 1960.
ROBERT W . GRAHAM is H ead, Experim ental S ction,
Fun damental H eat Transfer Branch, at Lewi . Dr.
G ra ham joined the R eseal'ch Center in 1953. H e has
specialized in fluid mechani cs of turbom achinery a nd in
heat transfer research as app lied to rocket engine cooling. Dr. Graham graduated wi th honors fr om Case
Institute of T echn ology wi th a B.S. degree in mechani cal
engin eering in 194 . H e is al 0 a graduate of Purdue
Un,iversity, receiving an M.S. degree in 1950 and a Ph.D.
in 1953.
VERNON H . GRAY i
167
~
r
168
Physics Branch, at Lewi . Dr. Howell joined the R esearch Center in 1961. H e attend ed Ca e Institute of
T echnology where he received a B.S . degree in ch mical
e ngineering in 195 , an M. . degree in nuclea r engineering in 1960, and a Ph.D . in engineering in 1962. H e has
p cialized in thermal radi ation heat tran fer and boiling
heat transfer and i current ly working on heat transfer
in radiative y tern .
GEORGE J . HOW ICK is Chief, T echnology Utilization
Divi ion, ABA. H e came to ASA in 1965 from Midwe t Re earch Institute wh ere he wa involved in projects that exa mine and in terpret the economic im plications of new tech nology. H e is a form er a ociate editor
of Sleel Magazin e.
ROBERT l. JOHNSON is Chief, Lubrication Branch, at
Lewis. H e joined the taff of the Re earch Center in
1943. A native of Gla gow, he attended Mon tana State
College where he received a B.S. degree in mechanical
engineering in 1942. His experience include 22 years of
fund a mental and app lied resea rch on lubrication problem for aerospace device.
W I LLIAM L. JO N ES i H ead, Ro cket Cooling Section, at
in chemistry in 1939, a n M . . degree in physical chemistry in 1941 , and a Ph.D. in inorganic chemi try in 1946.
Dr. Lad ha specialized in mass pectro copy of hydrocarbon , olid tate phy ics and ch mi try, and su rface
chemi try and i currently working on chemi try and
phy-ic of the urfac of ioni c cry ta ls.
RIC H ARD l. LESHER
D eputy A i ta nt Admini trawr
for T echnology tilization, NASA. H e is re pon ib le for
the admini tration and control of NASA' R egional Disemination Progra m. A native of Chambersburg. Pa.,
Dr. Le her wa edu cated in busine and economic, receivin a B.B .A. degree from Univer ity of Pi ttsburgh,
M .. from Pennsy lvania State, and D .B .A. from Indiana
Un i,-er ity . Prior to Jornrng ASA , he er'ved on the
facul tie of Ohio tate Univ r ity a nd the University of
Georgia.
LAWRENCE P. LUDW IG i H ead, ea l Unit, Lubrication
Branch, at Lewi . H e joined lhe staff of the R e earch
Cente r in 1962. A na tive of Racine, Wi consin , Mr. Ludwig attend ed Marquette Univer ity where he received a
B .S. degree in mechanical engineering in 1948. In 1957
he r ceived an M .. degree in mechanical engin ering
from Wi consin University . Mr. Ludwig ha pecializE'd
in fri ction, wear, and flu id dynami c and i currently
working on contact a nd hydrodynami c eal resea rch.
MAX J. MILLER is a R esea rch Enginee r, Fluid Sy tern
Components Division, at Lewi . H e join d the taft of
the Resea rch Center in 1962. A native of Griswold,
Iowa, Mr. Mi ller attended Iowa State Univer ity where
he received a B.S. degree in mechan.i cal engin eering in
1962. He has specia lized in axial flow and centrifugal
rocket pump and is currently working on pump analy i computer programs.
DONALD l. NORED i Chief, Liquid Rocket T echnology
Branch. at Lewis. H e joined the R e earch Center in 1958.
Mr . Nored received hi B .. d gree in chemical engineering from T exas Technologi ca l College in 1955. At Lewi
he ha worked on advan ced propul ion facili ty de ign
a nd operation, high energy ro cket engine, and v ~ hicle
systems studie .
WALTER T. OLSON is A ' istant Director, Public Affairs,
BREENE M . KERR i
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169
AUTHORS
staff of the R esea rch Center in 1944. A native of Christoph 1', Illinois, Mr. Ruggeri attended Tri- tate College
wh ere he received a B.S. degree in aeronautical engin eering in 1944. Mr. Ruggeri has specialized in a ircraft deicing and aerodynam ics and is cunently working on
cavitation research.
ROBERT SIEGEL i H ead, Analytical ection, at Lewis.
Dr. Siegel joined the R e earch Center in 1955. A native
of Cleveland , he attended Case Institute of T echnology
where he received B.S. and M .S. degrees in mec hanical
engineering in 1950 and 1951. In 1953, Massachusetts
Institute of T echnology awarded him an Sc.D . in mechani cal engineering. Dr. Siegel has pecialized in fluid
dynamics and heat t ran fer and i currently working on
boiling in reduced gravity, solidification of flowing liquids, Bnd heat transfer in rectangul ar channels.
DONALD H . SINCLAIR is an Aerospace Engineer, Instrument Operations Section, at Lewis. H e joined the
Langl ey R esearch Center in 1947 and transferred to
Lewi in 1948. A native of Cleveland, Mr. Sinclair attended Yal e University wh ere he received a B.S. degree
in mechani cal engineering in 1945. In 1956 he received
a B.S. degree in electri cal engineering from F enn College.
Mr. inclair ha pecialized in in truments and i currentl y working on cryogeni c temperature mea urement.
GORDON T. SMITH is an Aero pace Engineer, Fluid
* u.