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Department of Civil and Environmental Engineering, UAE University, P.O. Box 17555, Al Ain, Abu Dhabi, United Arab Emirates
b Department of Electrical Engineering, UAE University, P.O. Box 17555, Al Ain, Abu Dhabi, United Arab Emirates
Received 28 February 2005; received in revised form 5 June 2005; accepted 5 June 2005
Available online 1 September 2005
Abstract
The main aim of this study is to demonstrate the ability to determine the water content and salinity of a producing oil well by analyzing
captured time domain transmissometry (TDT) pulse signals by the newly developed coplanar waveguide (CPW) probe using eigendecomposition technique. The proposed technique characterizes the captured signatures by a number of eigenvalues calculated by autoregressive
modeling and singular value decomposition methods. To demonstrate the proposed method of analysis, crude oil samples obtained from Al
Bab oil reservoir, Abu Dhabi Emirate, UAE, were used. The physicochemical properties were first determined as functions of formation water
content and salinity and then samples were prepared for their use with the CPW probe for signal detection in the TDT mode of operation.
Transmitted signals were analyzed using eigendecomposition technique and the most significant eigenvalues were identified based on their
power. Multivariate statistical analysis was then performed and the regression analysis resulted in a system of linear equations that best
described the system. Actual and predicted results are in agreement, indicating a good performance and versatility of the developed system
for wide range of formation water content and salinities in the tested crude oil.
2005 Elsevier B.V. All rights reserved.
Keywords: Time domain transmissometry; Coplanar waveguide; Eigendecomposition; Eigenvalues; Oil reservoir; Water content; Salinity; Multivariate statistical
analysis
1. Introduction
Extracted fluids from producing oil wells are mixtures of
crude oil, water and sediments. Crude oil and water form
emulsion, which can be encountered at many stages during
drilling, producing, transporting and processing of crude oil,
and in many locations such as hydrocarbon reservoirs, well
bores, surface facilities, transportation systems and refineries.
It is important to know the water content in oil emulsions
for controlling and improving process at all operation stages.
The proportion of the various constituents varies dramatically
depending on the geologic formation from which the fluid
is produced and the stage at which the formation is in its
Corresponding author. Tel.: +971 3 713 3698/4297;
fax: +971 3 762 3154.
E-mail address: Mohamed.a@uaeu.ac.ae (A.M.O. Mohamed).
0924-4247/$ see front matter 2005 Elsevier B.V. All rights reserved.
doi:10.1016/j.sna.2005.06.014
134
Table 1
Physicochemical properties of ADCO Bab crude oil
Property
ASTM method
20 C
Specific gravity at
API gravity at 15 C
Kinematic viscosity at 40 C
Total acid number
Asphaltene content
0.8672 gm/cm3
31.67
6.3 cSt
0.9537 mg KOH/g oil
0.2%
D287
D287
D445
D974
D6560
Anions (ppm)
Sodium 54000
Calcium 15000
Magnesium 1791
Strontium 880
Potassium 1275
Chloride 155000
Bromide 850
Sulfate 993
Phosphate 90
135
Fig. 2. A drawing of conventional probe structure for within flow measurements (top), and the developed printed-circuit planar probe (bottom).
136
Fig. 5. A plot of the generated pulse used in the measuring system as captured
on the oscilloscope: r , f , and are rise time, fall time, and signal width at
50% of the amplitude.
Fig. 3. A drawing of CPW transmission line showing all geometrical and
material parameters.
137
Fig. 7. API gravity of water Bab crude oil emulsions, effect of water content
and salinity concentration on the emulsion density.
Fig. 8. Total acid number of water Bab crude oil emulsions, effect of water
content and salinity concentration on the emulsion acidity.
(4.59)
(1)
(23.17)
where WC is the water content as a weight percent; is a function of salinity concentration as a percent and API gravity as
degree. The numbers in parentheses below the coefficients
are the values of the corresponding t-tests, which test the
significance of the respective regression coefficients.
The analysis of variance (ANOVA) F-test is found to be
268.45, with 2 and 15 degrees of freedom, the fitted regression
model explains (R2 = 97.3%, R2 (adjusted) = 96.9%).
Based on Eq. (1), water content can be determined from
the knowledge of salinity of formation water and API gravity of the crude oil. This requires that additional experiments
should be conducted to determine these properties. Keeping in mind that reservoir conditions are always changing
in terms of water formation salinity, one needs to utilize or
develop other techniques that would be able to provide real
time monitoring of water content and salinity from a producing oil well.
3.1.2. Total acid number
Depending on oil source, additive content, refining procedure, or deterioration in service, petroleum oil may exhibit
certain acid or alkaline (base) characteristics. Data on the
nature and extent of these characteristics may be driven from
the products neutralization number or total acid number as it
is commonly known. The effect of water content and salinity
on the acidity of water oil emulsions is shown in Fig. 8. It
was observed that the total acid number decreases with the
138
Fig. 9. Measured response for the first transmitted signal of the constructed
TDT system for various water contents at constant salinity of 17% in ADCO
Bab crude oil.
value). The results were further analyzed by plotting the variations of the maximum signal amplitude with water content
as shown in Fig. 10. The linear relationship between the maximum amplitude the water content of the emulsion indicates
the decrease of maximum amplitude with increase of water
content due to the increase of the overall bulk conductivity
of the fluid. This coupled with the fluid changing back and
forth from oil continuous to water continuous. If the flow is
oil continuous the conductive water droplets are generally
isolated from one another. If the flow is water continuous
the conductive droplets are all touching each other, which
increases the overall bulk conductivity. This is in agreement
with the diffuse ion layer which indicates that for the same
concentration, as the water content increases the dielectric
constant increases leading to a decrease of the amplitude of
the transmitted signal [21].
3.2.1.2. Eigendecomposition analysis. Captured signals can
further be analyzed by different methods such as Fourier spectral analysis [22,23,9], power spectral analysis [22,23] and
eigendecomposition [10,2427]. Unlike Fourier decomposition, which partitions signals based on harmonic frequency
using parametric sines and cosines, eigendecomposition partitions signals by their strength using adaptive non-parametric
Fig. 10. Relationship between the maximum amplitude response for the
first signal of the constructed TDT system and water content percentage at
constant salinity of 17%.
Fig. 12. Variation of calculated magnitude of eigenvalues (order of the eigenvalues E1 E5 ) for various water content and constant salinity of 17%.
Fig. 13. Measured response for the first transmitted signal of the constructed
TDT system for various salinity concentrations and constant water content
of 50 wt.% in ADCO Bab crude oil.
Fig. 14. Relationship between the maximum amplitude response for the first
signal of the constructed TDT system and salinity concentration at constant
water content of 50 wt.%.
139
Fig. 16. Variation of calculated magnitude of eigenvalues (order of the eigenvalues E1 E5 ) for various salinity concentrations and constant water content
of 50 wt.%.
140
Fig. 17. (a) A three-dimensional plot for the variations of the first eigenmode
with respect to water content and salinity concentrations. (b) Predicted threedimensional plot for the variations of the first eigenmode with respect to
water content and salinity concentrations.
(55.84)
(2)
(15.13)
Fig. 18. (a) A three-dimensional plot for the variations of the second eigenmode with respect to water content and salinity concentrations. (b) Predicted
three-dimensional plot for the variations of the second eigenmode with
respect to water content and salinity concentrations.
(47.84)
(3)
(11.48)
where E2 is the second eigenmode of the transmitted signal, WC the water content as a weight percent, and salinity concentration as a percent. The observed significance
levels (p-values) of the above t-test are all <0.0001, indicating that all regression coefficients are highly significant
and cannot be dispensed with. Furthermore, the analysis
of variance (ANOVA) F-test is found to be 1210.84, with
2 and 45 degrees of freedom, which indicates that the
regression model is highly significant overall (the corresponding p-value is less than 0.0001). In fact, the fitted
regression model explains about 98.2% of the observed
variations in amplitude (R2 = 98.2%, R2 (adjusted) = 98.1%).
Also, the coefficient of variations is found to be small
141
Acknowledgement
The study was supported by a research grant provided by
the Research Affairs of the United Arab Emirates University.
References
Fig. 19. (a) Predicted of water content versus measured water content at
various salinity concentration. (b) Predicted of salinity concentration versus
measured salinity at various water content.
(s/mean = 0.02030/0.4985 = 4.07%). Based on Eq. (3), the fitted surface is shown in Fig. 18(b).
To determine the water content and salinity concentrations in terms of (observed values of) the first and second
eigenmodes, Microsoft Excel was used to solve the system
of linear equations such as Eqs. (2) and (3). For both water
content and salinity variations, the predicted values are plotted against the actual values in Fig. 19(a) and (b), respectively.
Upon comparing the actual and predicted values, it turned out
that the proposed method was very successful in predicting
both water content and salinity concentration.
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Biographies
A.M.O. Mohamed earned his M.Eng. in 1983
and PhD in 1987 from the Department of Civil
Engineering and Applied Mechanics, McGill University, Montreal, Canada. From 1987 to 1998,
Dr. Mohamed was employed by McGill University, and was the associate director of the
Geotechnical Research Centre (GRC) and a faculty lecturer in the Department of Civil Engineering. In 1998, he joined the Department of Civil
and Environmental Engineering, UAE University
where he is currently a professor of Civil Engineering & the Advisor of the Associate Provost for Research Affairs
Sector, UAE University. Dr. Mohamed is currently the president of