Professional Documents
Culture Documents
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
A
C
C
A
A
A
B
B
21.
22.
B.
1. What is the concentration in moles/L? (not sure to. Tinry ko lang isolve. Wala akong sagot nung
exam.)
23. Given: = 3.7; l = 200 mm; c = 183g/ml ; MW = 372.45 g/mol
24.
C=
100
lc
100 (3.7 )
(2 dm)(183 g/ml)
25.
C = 1.0109 g per 100 mL
26.
C = (10.109 g/L) (1mol/372.45g)
27.
C = 2.7143 x 10-2 mol/L
28. Formula:
- []20D = (liquid) l represents the length of the polarimeter tube; d is the density of the sample =
ld
100
lc
10000
7. Congealing point vs. freezing point. (di ko sure ung tanong dito)
55.
Congealing temperature is the temperature at which the liquid passes into the solid
phase upon cooling while freezing point is the temperature at which the solid phase is at equilibrium
with the liquid phase.
56.
[Melting point is the temperature at which the solid coalesces and is completely melted.
The melting point and the freezing point are of the same temperature. Both solid and liquid phases
are present at this temperature.]
8. What are the limits for boiling point determination using Method III (BP 2007 / USP30)?
57.
Lower limit is the temperature at which the first drop of condensate leaves the condenser
while the upper limit is the temperature at which the last drop of distillate evaporates from the
condenser regardless of adhering droplets on vessel walls.
9. Allowable range for temperature of ignition: 425 + 25C
58.
400C - 450C
59.
Allowable amount of sample to be used:
60.
Formula: Weight = 10 / L
where L is the mean value of the limits
61.
10/L = 10/(20%)
62.
L = 0.5 grams
63.
Constant weight is achieved when when successive weighing agrees to +0.25mg per g of
sample.
10. Pretreatments done in alcohol content determination:
64. A. Talc clarifying agent
65. B. Dilute sulfuric acid, Sodium hydroxide TS neutralizes the solution
66. C. Zn or Na2S2O3 solution followed by a few drops of NaOH removes interfering color of
iodine
11. Sp.gr. = Wtsubstance / Wtwater
67.
= (10.339g 5.478g) / (10.484g 5.478g)
68.
= 0.9710
69. From the alcoholimetric table, %w/w = 18.77 and %w/v = 23
12. Water Determination Method IA, Direct titration (Karl Fischer Titration) reagents and uses,
equations
70. I2 OA; 1 reagent
71. SO2 RA; 1 reagent
72. Pyridine, C5H5N complex formation
73. Methanol solvent for the complex formed
74.
I2 + SO2 + 2H2O 2HI + H2SO4
75.
C5H5NI2 + C5H5NSO2 + C5H5N + H2O 2 C5H5NHI + C5H5NSO3
76.
C5H5N+SO3- + CH3OH C5H5N(H)SO4CH3
13. What is the % water of the sample? Does it conforms to the official requirement (OR: not more
than 4.0%)?
77. Given:
78.
88.36 ml titrant
79.
1.48 ml KFR per 100 ml titrant
80.
9.51 ml KFR consumed
81.
0.1518 g sample
82. Formula:
83.
%W = F(X - XR)
84.
R = Vol. of KFR consumed / 25
85.
F, KFR < 1% = 2 (18.02/230.08)(W/V)
86.
87.
(I tried. Pero Di ko alam isolve. sorry.)
88.
F = 2 (18.02/230.08)(W/V)
89.
F = 2 (18.02/230.08)(0.1518g/9.51ml)
90.
F = 0.00250033
91.
92.
X = 88.36 ml
93.
94.
95.
96.
97.
98.
99.
100.
101.
102.
103.
104.
X = 5 ml
R = Vol. of KFR consumed / 25
R = (1.48 ml KFR per 100 ml) / 25
R = 0.0592 per 100 ml
%W = F(X - XR)
%W = (0.00250033)[(88.36ml) (5ml)(0.0592 per 100 ml)]
%W = 0.22018906
105.
RAVCs part: LIMIT TESTS
1. a. Effect of introduction of analyte as a solvent contaminant
106.
false negative result will be observed since the amount of analyte decreases due
to its action as a solvent contaminant.
107.
b. Effect of introduction of contaminants from reaction of the solvent
108.
false positive result will be observed since contaminants from the vessel joins
and acts as analyte in the analysis.
2. Applications / Advantages and Limitations of Acids
109.
3. What is microwave decomposition? Give 2 equipments.
110.
Microwave decomposition is a process of decomposing substances with the use of lights
found in the microwave region which offers high temperature, speed, reduced interference, and
reduced operator time. Equipments include (1) vessels for moderate-pressure digestions, (2) highpressure microwave vessels, (3) atmospheric pressure digestions, (4) microwave ovens, (5)
microwave furnaces.
4. What is Schoniger Method? Draw the set-up.
111.Schoniger Method is combustion of organic compounds in the presence of oxygen in a sealed
container.
112.
5. Complete the table.
113.
114.
Method
Article
of
Analysis
118.
Arseni
119.
123.
124.
128.
Chlori
129.
133.
Iron
138.
Phosp
143.
Sulfat
115.
Princi
ple
Involv
ed
116.
Chemical
Reactions
117.
120.
121.
122.
125.
126.
127.
130.
131.
132.
134.
USP 30
Method I
(Marsh
Test)
BP 2007
(Gutzeits
Test)
USP 30
& BP
2007
USP 30
135.
136.
137.
139.
BP 2007
140.
141.
142.
144.
USP 30
& BP
2007
145.
146.
147.
148.
6. Heavy Metals USP 30
149.
Compare and contrast Methods I-III
Visible
Result
150.
7. Lead vs Mercury Method I Limit Test
151.
Both use dithizone as reagent to form a colored complex.
152.
Lead violet chloroform layer (neutralized by ammonium citrate)
- Differentiation test: formation of white precipitate with potassium cyanide
153.
Mercury green chloroform layer stabilized by acetic acid (acidic; pH 1-3); red
organic layer
8. Heavy Metals BP 2007 - Thioacetamide
154.
Compare and Contrast Methods A-F
155.
156.
157.