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New prospects
created by an old idea.
2
3
Fuel cells generate electricity from hydrogen and oxygen without any harmful
emissions and therefore in an extremely environmentally friendly way. Heat is
produced in varying amounts and, as a by-product, water.
Electrical
load
Reaction water
Hydrogen
Oxygen
Excess
hydrogen
Excess
oxygen
Anode
Cathode
Electrolyte
Source: HEW
350
BHPP
FC
300
250
200
150
100
50
0
NOx
CO
CHx
Comparison of emissions
Compared with established technologies block heat and
power plants (BHPP) or other power plants fuel cells (FC)
boast very low emission levels.
Efficiency
Theoretically
Fuel cell
Practically
Coal-fired plant
Gas turbine
Full load
80
SOFC-, MCFC-Combined-cycle power plant
70
6
7
60
SOFC, MCFC
50
40
PEFC
30
Gas turbine
Gas engine
20
10
0
0.01
10
100
300
1,000
Waste heat
exchanger
Fuel cell
Electrolyte
Special features
Applications
SOFC
Solid Oxide
Fuel Cell
Solid zirconia
MCFC
Molton Carbonate
Fuel Cell
Molten
carbonates
AFC
Aqueous
potash lye
High efficiency,
pure H2 and O2 only
Space operations,
defense
PAFC
Phosphoric Acid
Fuel Cell
Phosphoric acid
Limited efficiency,
corrosion problems
Stand-alone CHP
generation
Proton exchange
polymer
membrane
Vehicles, stand-alone
CHP generation
(small-scale)
Generator
Compressor
Turbine
Load
CO2
SOFC
H2O
CO
H2
O2
N2 , unconverted O2
and reaction gas
CO2
600 650 C
MCFC
H2O
CO
H2
60 120 C
CO32
O2
CO2
AFC
H2O
H2
OH
PAFC
160 220 C
20 120 C
H2
160 220 C
20 120 C
H2
H+
PEMFC
H+
O2
H2O
O2
H2O
O2
N2 , unconverted O2
and reaction gas
Electrolyte
Fuel gas
Anode
Cathode
Process
heat
34 %
57 %
9%
Hot
water
Space
heating
Water vapor
Water vapor
Shift converter
Fuel cell
Product water
Shift reaction
Total
Renewable energy
Electrolyzer outfit
Excess electricity
Industrial sources
Electrolyzer outfit
Reformer
H2
storage
Methods of
hydrogen recovery
Fuel cell
A variety of applications
Description of the
PEM fuel cell.
PEM fuel cells boast simple design
and uncomplicated manufacture.
6
1 Flow field plate
(fuel supply)
2 Hydrogen supply
3 Membrane electrode
assembly
4 Air supply
5 One fuel cell
pulled apart
6 Stack consisting of
several cells
Watts / liter
1,200
1,000
800
600
400
Development of
the power density
of PEM fuel cells
200
0
1989
1991
1993
1995
1997
The Berlin fuel cell project managed by Bewag is the first of its kind in
Europe.The project is the first to employ the PEM technology in the
200kW class in Europe.Three further plants are being installed as part of
a field test one plant in Switzerland was commissioned in fall 2000,
another plant in Belgium in spring 2001, and a fourth unit will take up
operation in the Netherlands in the second half of 2001.
Air
Start-up air
Off-gas
Gas treatment
Natural
gas
Air cooler
4 H2 + CO2
Reformer
Shift
converter
CO
converter
Fuel cell
250 kWel
Anode/cathode off-gas
Reaction water
Make-up water
Project description
400 V 3~
Project goals
With this project, the partners pursue the goal of
testing all qualities of the system in a comprehensive
measuring program. In addition to the usual measuring devices for temperature, flow and electric parameters, a gas chromatograph is used that allows to
judge the reformation and conversion rates of each
gas treatment step. These are some central functions
of the measuring program:
Evidencing operational safety
Electric efficiency (approx. 35 percent),
evidencing that the course is constant
Efficiency of each component reformer, stack
and inverter
Aging behavior and voltage drop
Part load behavior
Theoretical degradation (conversion of all existing
energies into heat) after 40,000 hours
Evidencing long-term functional security of the
stack and plant
Review availability and reliability
Transient and start-up behavior
Optimum linkage into power and heat supply
systems
Approval procedure
The technical review by the German Technical Control
Association TV Rhineland/Berlin-Brandenburg was
core to the approval process. The reviews comprised
individual testing of components and groups, safety
checks and functional testing. Tests are being carried
out in compliance with both the new European directive for pressure devices and the Canadian CSA (Canadian Standards Association) directive. Their aim is to
conduct, if possible, all tests that will later be required
for the ultimate serial product.
Steam
boiler
12.7 MWth
Hotwater
boiler
18.7 MWth
90
Max
heat
demand
25 MWth
60
30
75 C
Fuel
cell
230 kWth
Flow
85 C
0
0
65 C
Flow: max 70 C
Average temperature: 58 C
Return flow
75 C
3,094
5,279
7,500
hrs p.a.
12
13
Solutions for
tomorrows world.
Liberalization of the European power market has for many
companies thrown up the question whether energy supplies
in their usual form still tally with market developments.
Will investments in large-scale generation plant and extensive
distribution networks continue to pay back in future?
Future prospects
14
15
Electricity
Natural gas
Fuel cell
Heat
Fuel cell
Fuel cell
Heat
250 kWel
1 to 5 kWel
A rsum.
1897 Nernst for the first time applies yttrium-doped zirconium for a bulb
hk
sc
Pu
starts
e
le
al
in
Eichenstrasse /
Puschkinallee 52
Treptower Park
The project of Hessische ElektrizittsAG (HEAG), Darmstadt, and the Institute of Chemical Technology of the
Darmstadt Technical University
enjoyed financial assistance from the
Hessian Ministry of Environment,
Energy, Youth, Family and Health:
During the project term between 29
June 1993 and 28 April 1998, the fuel
cell generated an electric power output of 5,462,951kWhel and a thermal
output of 6,866,506 kWhth.
Bewag Aktiengesellschaft
Puschkinallee 52
D 12435 Berlin
E-mail bewag@bewag.com
Internet www.bewag.de
Phone
Fax
E-mail
Internet
Information:
+49 30 -267-111 38
+49 30 -267-1 03 13
innovationspark@bewag.com
www.innovation-brennstoffzelle.de
www.fuelcellpark.com
May 2001