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Group -1 Name_______________________________________Id.no._________
1
pH
7
[3]
0
0
10
20
30
40
50
60
indicator
methyl violet
0.0 - 1.6
methyl orange
3.1 - 4.4
bromothymol blue
6.0 - 7.6
phenolphthalein
8.3 - 10.0
[1]
(f)
2.
Write an expression for Ksp for calcium hydroxide, and state its units.
Ksp =
(ii)
units ............................................
25.0 cm3 of a saturated solution of Ca(OH)2 required 21.0 cm3 of 0.0500 mol dm3
HCl for complete neutralisation.
Calculate the [OH(aq)] and the [Ca2+(aq)] in the saturated solution, and hence
calculate a value for Ksp.
[OH(aq)] = .................................
[Ca2+(aq)] = ................................
Ksp = .........................................................................................
(iii)
How would the solubility of Ca(OH)2 in 0.1 mol dm3 NaOH compare with that in
water?
Explain your answer.
..................................................................................................................................
..................................................................................................................................
[6]
(a) Hydrogen fluoride, HF, behaves as a weak acid in water, with Ka = 5.6 104 mol dm
Calculate the pH of a 0.050 mol dm3 solution of HF.
pH = ....................................... [2]
(b) Gaseous ammonia and hydrogen fluoride react together to give solid ionic ammonium
fluoride.
NH3(g) + HF(g)
(i)
NH4F(s)
H = 147 kJ mol1
(ii)
Draw dot-and-cross diagrams (outer shells only) describing the bonding in the three
compounds involved in this reaction.
NH3
(iii)
NH4F
HF
piperidine
Suggest why this answer differs from your answer in (c)(ii).
.............................................................................................................................................
.............................................................................................................................................
(iv) How would you expect the basicity of piperidine to compare to that of ammonia?
Explain your reasoning.
.............................................................................................................................................
.............................................................................................................................................
[5]
(d) 20.0 cm3 of 0.100 mol dm3 HCl was slowly added to a 10.0 cm3 sample of 0.150 mol dm3
piperidine. The pH was measured throughout the addition.
(i) Calculate the number of moles of HCl remaining at the end of the addition.
pH = .....................
(iii) On the following axes, sketch how the pH will change during the addition of a total of
20.0 cm3 of 0.100 mol dm3 HCl. Mark clearly where the end point occurs.
14
pH
7
0
0
10
15
20
pH at which
colour changes
0-1
3-4
11 - 12
13 - 14
_______________________
[6]