A Study of the Performance of Oxidative Degradation and Crossing Linking of Metallocene Linear

Low D
Author :LiHaiLong
Tutor:ChengFengMei
School :Changchun University of
CLC :TQ320.721
TYPE :Masters thesis
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Year:2011
Abstract:
This plastic material and is closely related to peoples lives , but a lot of use of plastics has caused
serious environmental pollution problems . With the increasing awareness of the importance of
environmental protection , how to ensure the health of the environment in the development of plastic
products has become the subject of widespread concern of scientists . In this thesis, the degradation of
the plastic , designed to effectively solve the problem of plastic pollution and strive to achieve a
breakthrough in terms of new technology . Biodegradable plastic degradation pathway into
biodegradable , optical and chemical degradation three main degradation pathways between
synergistic , collaborative and coherent role . This paper will study focused on photodegradation , the
main method is a metallocene linear low - density polyethylene (m-LLDPE) as a parent material ,
respectively, was added in which three different kinds (CoSt, FeSt, FeDEC) and different the
proportion of the photosensitive agent , and the different samples obtained by detecting , in order to
understand the optical degradation characteristics of the m-LLDPE film . Through experiments , it can
be concluded : m-LLDPE film carbonyl index in the gradual strengthening of the role of light , with
the increase of the photosensitizing agent , showing a gradual upward trend . The visible light
sensitizer in the reaction of photooxidative degradation of the m-LLDPE film has played a role to
enhance the degradation efficiency . At the same time , the paper also discusses the irradiation
conditions, the amount of photosensitizer 60Co - gamma irradiation source exposure time, distance,
distance from the heart of the irradiation source and other factors impact on the performance of
polymer crosslinking . The experimental results show that : 60Co- -ray source irradiating the gel
content of the m - LLDPE increases, so that the increase in the degree of crosslinking of the mLLDPE , m - LLDPE crosslinking degree becomes large . Crosslinking can make the upper limit of
temperature mechanical properties and their use in the 1n-LLDPE improved , thus improving the
application range of the m-LLDPE and able to be closer to the market demand , the market potential is
huge , in terms of production is also more simple , solve the plastic pollution problem , and an
effective way to achieve sustainable development .