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Chemistry XII
CHAPTER # 01
PERIODIC CLASSIFICATION
DOBEREINERS CLASSIFICATION:
German chemist Johan W Dobereiner in 1829 made an attempt to classify elements. He observed
that some group of 3 elements (triad) showed similar physical and chemical properties.
STATEMENT:
The atomic mass and properties of the middle elements is approximately the arithmetic mean of the
other two elements.
SN
1
2
3
ELEMENTS
Lithium
Sodium
Potassium
ATOMIC MASS
7
23
39
ARITHMETIC MEAN
7+39=23
Although Dobereiners concept of triad provided background to seek further information for
classification of elements but it was rejected because all elements couldnt be arranged in such
triads.
STATEMENT:
Chemically similar elements reoccur in octaves when arranged in order of increasing atomic
weight.
Li = 7
Na = 23
K = 39
Be = 9.4
Mg = 24
Ca = 40
B = 11
Al = 27.3
C = 12
Si = 28
N = 14
P = 31
O = 16
S = 32
F = 19
Cl = 35.5
This law provided a basic that elements with similar properties arranged into groups (tabular form)
but noble elements were included so it was rejected
ADVANTAGES:
This law provided a basic for the classification of elements into group of elements having similar
properties.
This law provided a wider scope to arrange all known elements into tabular form.
Chemistry XII
DISADVANTAGES:
The periodic arrangement of element didnt included noble gases because the were not discovered.
STATEMENT:
Properties of elements are periodic function of their atomic weight.
Different curves and observed that elements with similar properties occupied similar
position in the curve.
2-
e.g. alkali metals occupy peak position halogen and acidic oxide occupy ascending position
in the curve.
3-
His classification couldnt receive proper attention because of two reasons worked only on
physical properties like brittleness malleability etc.
4-
Mendeleev proposed his classification in the same year with separable prediction of
discoveries.
5-
He arranged elements in 7 horizontal rows called period and 8 vertical columns called
groups.
6-
Chemistry XII
precedes
I (126.9)
The lanthanides a raise earth metals and actinides do not find any appropriate places in the periodic
table.
He did explain the cause of periodicity.
Certain chemically similar elements e.g. cu, au, pt are placed in different groups.
STATEMENT:
The properties of the elements are the periodic function of their atomic number
OR
Physical and chemist properties of the elements are the function of their electronic configuration
which varies with the increasing atomic number in a periodic manner
PERIODIC TABLE:
It is an arrangement in such a way that elements are arranged in the increasing atomic number and
elements have similar properties automatically fall in same group
Chemistry XII
MENDELEEVS PERIODIC
TABLE
It was based on the atomic weight
of elements
It failed to specify the position of
isotopes
It placed coinage metal with alkali
metals
It failed to explain the structure of
atom
SN
1
2
3
4
MODERN PERIODIC
TABLE
it was based on the atomic
number of elements
It has specified position of
isotopes
It placed coinage metal in and
alkali metal in IA
It explain structure of atom
PERIODS:
The horizontal rows from left to right in the periodic table are called periods. There are seven
periods in the periodic table which start from alkali metals and ends at noble elements.
PERIOD-1:
This period corresponds to filling up k-shell It is shortest period and contains only two elements H
and he with electronic configuration S and is respectively.
PERIOD-2:
This period corresponds to filling up L-shell it is first short period and contain 8 elements from Li
to Ne. In this period as occupy 2s and 2p orbital.
PERIOD-3:
This period corresponds to filling up M-shell. It is 2 nd short period and also contains 8 elements
from Na to Ar. In this period as occupy 3s and 3p orbital
PERIOD-4:
This period corresponds to filling up N-shell. It is 1st long period and contain 8 elements from k to
kr. n this period as occupy 4s followed by 3d and 4p orbital.
Chemistry XII
PERIOD-5:
This period corresponds to filling up O-shell. It is 2 nd long period and also contain 18 elements
from Rb to Xe in this period as occupy 5s followed by 4d and 5p orbital.
PERIOD-6:
This period correspond to filling up p-shell. It is longest period and includes 2 elements from sblock, 10 elements from d-block, 14 elements from f-block, and 6 elements from p-block. It starts
as start from Cs and ends at Rn in this period as start filling 4f orbital after 5d accommodates 1e.
PERIOD-7:
This period corresponds to filling up q-shell. It is incomplete period and includes 2 elements from
s-block, 10 elements from d-block 14 elements from f-block (Actinide). It starts from Fr and is
incomplete. In these period es starts filling 5f orbital after 6d accommodates 1e.
GROUP:
The vertical column from top to bottom in the periodic table is known as group. There are eight
group in the periodic table and these group are sub divided in to 2 groups or family or sub group A
and family or sub group B.
SUB GROUP A:
The normal elements are included in sub-group A. it includes IA to 5A and also known as
representative or typical elements.
SUB GROUP B:
The transition elements are placed in sub group B. It included IB to 5b.
PROPERTIES OF GROUP:
In a group of periodic table the elements contain same type of properties. They have same valence
shell configuration.
PROPERTIES OF PERIODS:
The properties of elements vary gradually from left to right. The number of periods also indicates
the total number of shell in all elements in the period.
TYPES OF ELEMENTS
CONFIGURATIOIN:
ON
THE
BASIS
OF
ELECTRONIC
This classification is based upon the type of atomic orbital which receive the last electron in its
atom.
There are two types of elements in the periodic table i.e. Representative and transition which are
further classified as S, p and d, f respectively.
Chemistry XII
REPRESENTATIVE ELEMENTS:
Elements of sub group A are called representative elements or typical elements. Metals, non
metals and metalloids are included some are paramagnetic some are diamagnetic S and P block are
included.
S-BLOCK ELEMENTS:
The incoming electrons enter the outermost s-orbital in the atoms of these elements. They have
valence shell electronic configuration ns1and ns2 and belong to the group IA and 2A respectively:
P- BLOCK ELEMENTS:
The incoming electrons enter the outermost p-orbital in the atoms of p-block elements. Their
valence shell configuration varies from ns2, np1 to ns2, np6 these elements belong to group 3A-3A.
NOBLE ELEMENTS:
Members of group 3a are known as noble elements or zero group found at the end of each period.
They are colorless gases, uncreative (inactive) and diamagnetic and their electronic configuration is
exceptionally stable i.e. ns2, np6, with the exception of he (z = 2) i.e. ns2
TRANSITION ELEMENTS:
Elements of B-sub group of the periodic table are called transition elements. Only metals are
included. Both paramagnetic and diamagnetic are included d and j block are included.
D-BLOCK ELEMENTS:
The incoming last electrons enter the (n-1)d-orbital in the atoms d-block elements. Their valence
shell configurations varies from ns2,(n-1)d ns2,(n-1)d10. These elements belong to the group IB5B. They are also known as outer transition elements.
They consist of four transition series each series consist of 10 elements i.e.
1st transition series (sc-zn)
2nd transition series (y-cd)
3rd transition series (la-hg)
4th transition series (ac-)
F-BLOCK ELEMENTS:
The incoming last electrons enter the (n-2)f orbital in the atoms of f-block elements. Their valence
shell configuration varies from ns1,(n-1)d1,(n-2)f1-ns2,(n-1)d1,(n-2)f14.
These elements belong to group 3 b. They are also known as inner transition elements.
Chemistry XII
CHAPTER # 02
HYDROGEN
POSITION OF HYDROGEN IN PERIODIC TABLE:
Elements are arranged in the periodic table on the basis of their electronic configuration and to
some extent on the basis of their properties.
But there is no exact position of hydrogen in the periodic table. It has some resemblance and some
disresemblance with IA, 7A group.
DISSIMILARITIES:
123456-
Hydrogen is a gas but the elements of group IA are metals at room temperature.
Hydrogen exists as diatomic from while alkali metals exist as monatomic from.
Elements of group IA are electropositive in character they only form ionic compound while
hydrogen is electropositive as well electronegative, so it can form ionic as well as covalent
compound.
Alkali metals freely exist as caution in aqueous solution while H+ is not freely and exists as
oxonium ion H3O+
Hydrogen gains electron and form ve ion.
While IA group elements dont form ve ion.
DISIMILARITIES:
1-
Chemistry XII
DISSIMILARITIES:
123-
Electronic configuration of 7 a group ends on ns2 npo2 while hydrogen ends on ns.
Hydrogen contains 1 e in its valence shell while 7 a group contain 1 es
Monovalent negative ions of halogens i.e. cl-, Br- etc. exist freely in aqueous solution while
monovalent negative ion of hydrogen (H-) is incapable to exist in water. Since, H 2 is formed
immediately.
H-+H2O-----OH-+H2
45-
CONCLUSION:
From the above discussion, we conclude that position of hydrogen in the periodic table is still
unsatisfied and because of its simplest nature hydrogen shows different behavior.
4H* +4OH
4H* +4E- ------2H2
8
Chemistry XII
4OH- -----O2+2H2O+4E
2H2O -----2H2+O2
3h2+co
ACTION OF STEAM:
H2 gas is separated from mixture of water gas by heating it with more steam at 500c in the present
of Fe2O or Cr2O3
As a result co is converted in to CO2 and more hydrogen is produced.
H2+CO+H2O
FeO
CO2+2H2
CO2 is soluble in water and can be separated easily by dissolving it in water under pressure
BY LIQUIFICATION:
H2 gas is also separated from water gas by cooling it at -200c with the help of liquid air co
becomes liquid hydrogen is separated.
Traces of co further removed by passing it through Na oh which absorb CO
CO+ Na OH---------N C O O Na
Sodium format
CO+3H2
Chemistry XII
CO2 is separated by passing the mixture through water under high pressure, where by CO 2 will
dissolve in water and free H2 gas is obtained.
700c---------2H2+C
Carbon black is rubber, tire, ink pigment plastic and used typewriter ribbon, carbon paper etc
manufacturing.
ATOMIC HYDROGEN:
The product obtained by the dissociation of molecular hydrogen is known as atomic hydrogen to
dissociate molecular hydrogen 104k cal mol-1 bond energy is required.
BY ELECTRONIC DISCHARGE:
When electricity is passed through hydrogen gas at low pressure, atomic hydrogen is produced.
H2 electric discharge------ 2H
Imm-0.1mm pressure
PROPERTIES:
Atomic hydrogen is more reactive than molecular hydrogen. Its rxn take place at ordinary
temperature.
Chemistry XII
CL2+2H-----2HCL
STABILITY:
Atomic hydrogen is highly unstable they instantly combine to convert molecule.
USES:
12-
Some alloys of Ni, Cr, Al melts at 4000c-5000c for welding these alloys a flame of high temp is
required this flame is produced by Atomic hydrogen torch.
PRINCIPLE:
When hydrogen gas is passed through an electric are set b/w tungsten rods. It splits in to atomic
hydrogen which combines to convert molecular hydrogen release 104k.cal/mol/energy which
produces flame of 4000c-5000c.
NASCENT HYDROGEN:
The newly born hydrogen which is produced during chemical reaction is called nascent hydrogen.
OR
The hydrogen produced at the moment of its chemical production is called nascent hydrogen.
ATOMIC HYDROGEN:
123-
Zn+2HCl-----Zn cl+2 H
11
Chemistry XII
NASCENT HYDROGEN:
12-
BINARY COMPOUND:
The compound which is formed by the combination of two elements is known as binary compound.
CLASSIFICATION OF HYDRIDE:
On the basis of bond hydride are classified into following.
IONIC HYDRIDE:
The hydride which is formed by the transference of electron from metal atom to hydrogen atom is
known as ionic hydride.
Ionic hydride are formed by group I A and 2 A except Be and Mg.
They have salt like character so also known as salt like or saline hydride.
PREPARATION:
When hydrogen gas is passed through red hot alkali and alkaline earth metal, ionic hydrides are
formed.
2Na+H2------200c ---2NaH
Ca+H2-------200c----CaH2
PROPERTIES:
1234-
They are colorless, non-volatile salt like solids having high melting point.
They are sufficiently stable towards heat, stability decreases with increasing atomic masses.
They contain cubic structure.
They are insoluble in organic solvents but soluble in water with which they react and
produce hydrogen.
Ca H2+ H2O --------CA (OH) + 2H2
Na H + H2O---------Na OH + H2
USES:
12
Chemistry XII
COVALENT HYDRIDE:
The hydrides which are formed by mutual sharing of electrons is known as covalent hydride.
Covalent hydrides are formed by group 3 A-7 A.
PREPARATION:
They can be prepared either by direct method or by indirect method.
DIRECT METHOD:
H2+ Cl2 sunlight--------2HCl
H2+ S
sunlight---------H2 S
INDIRECT METHOD:
CaC2+ 2H2O---------Ca (OH) 2+C2 H2
Hl4 C3 6H2 O-------2AL2O3+3CH4
PROPERTIES:
12345-
They are colorless gases or volatile liquid having low boiling point except water which has
high B.P due to presence of intermolecular hydrogen bond.
Hydrides of group 3 A and 4A are neutral
Hydrides of group 5A are basis.
Hydrides of group 6 A and 7A are acidic.
Stability of these hydrides decreases with the increase in size of non-metal atoms.
COMPEL HYDRIDE:
Hydride of group 3A are not stable so they combine with hydride of group I A and form such
hydrides in which all three types of chemical bonds i.e ionic, covalent and co-ordinate covalent
bond are present.
They arent binary so they are known as complex hydride.
They have general formula A B H 4
Where A= univalent ion = LI*, Na* etc
B=trivalent ion = B*3, Al*3
PREPARATION:
LiH+AlH3---------LiAlH4
NaH+BH3---------NaBH4
PROPERTIES:
1-
Chemistry XII
METALLIC HYDRIDE:
Hydrogen forms hydrides with transition metals, properties of these hydrides are apparently as pure
metals, therefore they are named as metallic hydride.
In there hydride hydrogen occupied interstitial spaces so they are also known as interstitial hydride.
PROPERTIES:
1234-
These hydrides are non stanchion metric no true chemical bond is present.
E.g. LaH2.75, VH 0.56
They are good reducing agent.
They hydride are used as catalyst in the hydrogenation rxn.
CH3 Cl +2H -----Ni----CH4+ HCl
POLYMERIC HYDRIDE:
Be and Mg of 2A group react with hydrogen form hydride with formula BeH2 and MgH2
respectively these hydride then polymerized to form (BeH2) and (MgH2) n. Therefore they are
known as polymeric hydride.
Their properties are intermediate between ionic and covalent.
ISOTOPES:
Atoms of same elements having same atomic number but different mass number
OR
Atoms that have same number of protons but different number of neutrons are known as isotopes
ISOTOPES OF HYDROGEN:
14
Chemistry XII
PROTIUM:
1.
2.
3.
4.
5.
DEUTRIUM:
1.
2.
3.
4.
5.
6.
TRITIUM:
1.
2.
3.
4.
5.
6.
CHAPTER # 03
S-BLOCK ELEMENT
DEFINITION:
The elements in which last electrons enters in ns orbital are called S-Block elements. The elements
of group IA and group IIA in the periodic table are S-Block elements the elements of group IA are
called alkali metals including the following elements Sodium (Na), Lithium (Li), Potassium (k),
Rubidium (Rb), Cerium (Cs) and Francium (Fr) the elements of group IIA are called alkali earth
metals Beryllium (Be), Magnesium (Mg), Calcium (Ca), Scandium (Sr), Barium (Ba) and Radium
(Ra) are the numbers of group IIA.
Why elements of group IA are called alkali metals?
The elements of group IA have ability to form alkalis their oxides and hydroxides are alkalis in
nature so they are called alkali metals.
Why elements of group IIA are called alkaline earth metals?
The elements of group IIA are exist as in oxides form in the earth and their oxides and hydroxides
are also are also alkaline in nature so they are called alkaline earth metals.
Chemistry XII
The regular variation in the properties of elements is known as Group trends for e.g. electro
negativity ionization potential atomic radii, hydration energy melting & boiling point etc. the group
trends in physical property are discussed below.
ELECTRO NEGATIVITY:
The tendency of an atom to although a shaped pair of electron towards itself is known as electro
negativity
IN GROUP:
In group as we make from top to bottom the electro negativity decreases due to increase in atomic
size.
Comparison between electro negativity alkali & alkaline
EARTH METALS:
Alkaline earth metals are making electro negativity as compare to alkali metals due to their smaller
atomic size and high nuclei charge
IONIZATION POTENTIAL:
The minimum amount of energy required to remove an electron from garners atom is called
ionization potential
IN GROUP:
Ionization potential decreases as use moke down the group because in group atomic size increases
and due to increase in atomic size the distance between nuclei and outer most electrons also
increases so the attraction between and outer most electrons becomes lower so the ionization
potential decreases in down the group alkali earth metals have high ionization potential as compare
to alkali metals because of lower atomic size and higher nuclei charge.
The second ionization enthalpy of alkaline earth metals are higher them first ionization enthalpy
because when first electron has been removed them nuclei charge an atom is increases and
interaction between nucleus and outer most electron is also increase so he second electron require
more energy for removed and hence the second ionization enthalpy is higher than the first in
alkaline earth metal.
ATOMIC RADII:
The distance from the centre of nucleus to the outer most shell is called atomic radius
IN GROUP:
As we moke from top to bottom in a group the atomic radii increases due to increase in number of
shells
16
Chemistry XII
Alkaline earth metals have smaller atomic radii as compare to alkali metals because of their high
nuclei charge.
IONIC RADII:
The distance from the centre of nucleus to the outer most electron in as atom is called ionic radii
alkali and alkaline earth metals are highly electro positive so they can easily from positive ion
(Lation) the size of the Lation (M +1) is less then as compare to the size of metal (M) the reason is
that when an atom loses electron then the number of electrons becomes decreases as compare to the
number of protons so the nuclei charge increases and now the attraction between nuclei and the
outermost electrons increases due to which the size of the ion because shrink.
Hydration energy:
The amount of energy released in the formation of hydrate of one mole of M+(g) ion is called
hydration energy
M+(g) + aq = [M(ar)]+ + Energy released
IN GROUP:
Hydration energy depends upon size of the atom as we moke down the group hydration energy
decreases because of increasing in atomic size alkaline earth metals are easily hydrate as compare
to alkali metals because of their lower atomic size and higher nuclei charge.
ELECTRODE POTENTIAL:
The difference of potential created between a metal and solution of its salt is called electrode
potential it is the measure of a tendency of an electrode to lose (or gain) electron. The elements
which have higher value of redaction potential they can easily reduced and are oxidizing agent
while these elements which have lower values of reduction potential they can easily oxidized and
are reducing agents.
Alkali and alkaline earth metals have very low reduction potential values so they act as a powerful
reducing agent. Alkali and alkaline earth metals cannot be used in voltaic cells because their
reduction potentials are very lower and they are powerful reducing agents they reduced the water
present in voltaic cells
Chemistry XII
Alkali and alkaline earth metals reacted with halogen and forms halides
2Na + Cl2 2NaCl
Mg + Cl2 MgCl2
Reaction with hydrogen:
Alkali and alkaline earth metals reacted with water and forms their hydrides
2Na + H2 2NaH
Ca + H2 CaH2
Reaction with nitrogen:
Alkali and alkaline earth metals reacted with nitrogen and forms nitrides
6Na + N2 2Na3N
3Mg + N2 Mg3N2
Reaction with water:
Alkali and alkaline earth metals reacted with water and produces hydroxides of them
2Na + H2O 2NaoH + H2
Ca + H2O Ca (OH) 2 + H2
Reaction with oxygen:
Alkali and alkaline earth metals directly combine with oxygen and producing a variety of oxides
(O-2), peroxides (O-22) and super oxides (O-12) the type of product depends upon the type of metal
and temperature.
2Na + O2 2Na2O (sodium peroxide)
2Na + O2 Na2O2 (sodium peroxide)
Na + O2 NaO2 (sodium superoxide)
Ba + O2 BaO2 (barium peroxide)
2Ba + O2 2Bao (barium oxide)
EXTRACTION OF METALS:
The alkali metals:
Alkali metals are very reactive metals so they do not occur in nature in free state they are obtained
from their compounds
Chemistry XII
Downs cell is made up of steel lined with fire bricks anode is made up of graphite and iron cathode
is surrounded by it the two electrodes are separated by a cylindrical iron gauze diaphragm this
diaphragm prevents the mixing of produced Na and Cl 2 when electricity is passed through the
mixture of formed NaCl CaCl2 NaCl ionizes to give Na+ and CeNaCl Na+ + ClCl- discharge at anode in the form of chlorine gas (Cl2)
At anode:
Cl- le- + Cl
Cl + Cl Cl2
At cathode sodium (Na+) discharge and produces sodium metal (Na) due to it low density it rises up
and stored in the inverted through in the molten state
At cathode:
Na+ + le- Na
Over all reaction:
2Na+ 2Cl- 2Na + Cl2
PURIFICATION:
NaCl so obtained contains impurities such as calcium and magnesium these impurities and
removed by treating brine with Na2CO3 and NaOH to participate these metals
19
Chemistry XII
USES OF NaCl:
123-
PREPARATION:
NaHCO3 can prepared by Ammonia Solvay process in this process first ammonia reacted with CO2
and H2O to give NH4HCO3 and the NH4HCO3 combine with NaCl and produces NaHCO3
NH3 + CO2 + H2O NH4HCO3
NH4HCO3 + NaCl NaHCO3 + NH4Cl
FROM Na2CO3:
NaHCO3 can be prepared by treating saturated sodium carbonate with carbon dioxide Na2CO3 +
H2O + CO3 2NaHCO3
USES:
1234-
Chemistry XII
The source of CO2 is limestone when lime stone is heated CO2 is produced
CaCo3 CaO + CO2
Ammonia:
Ammonia is resourced from the solution of NH 4Cl, left after the removal of NaHCO 3, NH4Cl reacts
with Ca (OH)2 to give ammonia
CaO + H2O Ca (OH)2
2NH4Cl + Ca (OH)2 CaCl2 + 2H2O + 2NH3
Ammonization of brine
Carbonization of Ammoniated brine
Conversion to Sodium carbonate
AMMONIZATION OF BRINE:
In this step saturated solution of NaCl i.e. brine is mixed with ammonia in ammoniating tower until
the solution becomes saturated.
Chemistry XII
In this process mercury is used as a cathode so the same vapors of mercury escape from the
industry and contaminates sea water.
CHEMICAL PROPERTIES:
1-
Sodium hydroxide (NaOH) is a strong base reacted with acid to from salt and water
22
Chemistry XII
Sodium hydroxide (NaOH) reacts with ammonium salts on heating and librates ammonia
NH4Cl + NaOH NH3 + NaCl + H2O
3-
4-
When participated hydroxides are amphoteric they re-dissolve in excess of NaOH forming
complex ion e.g.
Zn+2 + 2OH Zn(OH)2 (amphotenic hydroxide)
Zn(OH)2 + 2OH (Zn(OH)4)-2 (complex ion)
USES:
1234-
PREPARATION:
Mg + H2SO4 MgSO4 + H2
MgO + H2SO4 MgSO4 + H2O
Mg(OH) + H2SO4 MgSO4 + 2H2O
MgCO3 + H2SO4 MgSO4 + H2O + CO2
The hepta hydrated magnesium sulphate (MgSO4.7H2O) is known as Epsom salt. It is soluble in
water. When heated crystalline Epsom loses water forming anhydrous magnesium sulphate.
MgSO4.7H2O MgSo4.H2O + 6H2O
MgSO4.7H2O MgSO4 + 7H2O
2MgSO4 2MgO + 2SO2 + O2
USES:
(i)
(ii)
Chemistry XII
PREPARATION:
CaSO4 can be prepared by following reactions.
(i)
CaCO3 + H2SO4 CaSO4 + CO2 + H2O
(ii)
CaCl2 + Na2SO4 CaSO4 + 2NaCl
PROPERTIES:
(i)
(ii)
(iii)
USES:
(i)
(ii)
(iii)
REACTIONS:
(i)
When bleaching powder is reacted with water it liberates chlorine gas (Cl2).
24
Chemistry XII
USES:
(i)
(ii)
(iii)
25
Chemistry XII
CHAPTER # 4
P-BLOCK ELEMNTS
DEFINATION:
The elements in which last electrons in nP orbitals are called P-Block elements.
The general configuration valence of P-Block elements is ns2, 2p1 to ns2, np6. The elements of group
IIIA to VIIIA are called P-Block elements. Out of these elements, 10 elements are metals and 20 are
non-metals.
GROUP TRENDS:
IN P-BLOCK ELMENTS:
The regular variation in the properties of elements is known as group trends.
The group trends in physical properties are discussed below.
26
Chemistry XII
ELECTRONEGATIVITY:
The tendency of an atom to attract a shared pair of electron towards itself is known as
electronegativity.
IN GROUP:
The electronegativity of P-Block element decreases in down the group due to increase of atomic
size.
IN PERIOD:
The electronegativity is increases as we move from left to right in the period due to decrease in
atomic size.
IONIZATION POTENTIAL:
The amount of energy required to remove an electron from gaseous atom is called ionization
potential.
IN GROUP:
The values of ionization potential decreases in down the group except (IIIA). Ionization potential
depends upon atomic size and shielding effect of inner energy level. As the atomic size and
shielding effect increases down the group so ionization potential decreases.
IN PERIOD:
Ionization potential of P-Block elements increases as we move from left to right in the period. This
is due to lower atomic size and low shielding effect creates greater force of attraction between
nucleus and electron. Hence greater will be ionization potential.
27
Chemistry XII
PROPERTIES:
(i)
(ii)
(iii)
(iv)
(v)
Chemistry XII
USES:
The aqueous solution of boric acid act as a mild antiseptic and used as an eye-wash.
Boric acid is also used in glass industry.
BORAX: Na2B4O7.10H2O
Borax is known as sodium tetra borate decahydrate. It is a salt of pyroboric acid.
PREPARATION:
(i): FROM BORIC ACID:
Borax can be prepared from boric acid by the following reactions.
4H3BO3 + 2NaOH Na2B4O7 + 7H2O
4H3BO3 + Na2CO3 Na2B4O7 + 6H2O + CO2
(ii): FROM COLEMANITE:
Colemanite (Ca2B6O11) is an ore of borex when colemanite is boiled with concentrated solution of
Na2CO3, borax is produced.
Ca2B6O11 + 2 Na2CO3 2CaCO3 + Na2B4O7 + 2NaBO2
PROPERTIES:
(i)
(ii)
(iii)
Action of heat
USES:
(i)
(ii)
29
Chemistry XII
Chemistry XII
Chemistry XII
Al+3 + Al Al + Al+3
PROPERTIES:
(i)
(ii)
(iii)
(iv)
CHEMICAL PROPERTIES:
(i): ACTION ON AIR:
Aluminium is not affected by dry air at ordinary temperature but moist air forms a thin film of
oxide on its surface.
If aluminium is heated strongly in air, it forms Al2O3.
4Al + 3O2 2 Al2O3
(ii): ACTION OF ACIDS:
Aluminium reacts with HCl and dil H2SO4 to form H2 gas.
2Al + 6HCl 2AlCl3 + 3H2
2Al + 3H2SO4 Al2(SO4)3 + 3H2
Concentrated H2SO4 reacts with aluminium to give SO2 and Al2 (SO4)3
2Al + 6H2SO4(conc) Al2(SO4)3 + 6H2O + 3SO2
Nitric acid (HNO3) does not react with aluminium due to formation of protective layer on the
surface of metal. HNO3 is a strong oxidizing agent and it serve only to thicken the protective oxide
coating.
(iii): ACTION OF ALKALIES:
Aluminium reacts with alkalies and forms aluminate and liberates H2 gas.
2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2
2Al + 2KOH + 2H2O 2KAlO2 + 3H2
(iv): ACTION OF HALOGEN:
Aluminium reacts with halogens to form halides.
2Al + 3Cl2 2AlCl3
2Al + 3Br2 2AlBr3
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Chemistry XII
USES:
(i)
(ii)
(iii)
ALUM:
Double sulphates of monovalent and trivalent metals containing 24 molecules of water of
crystallization are called Alum.
FOR EXAMPLE:
K2SO4.Al2(SO4)3.24H2O
K2SO4.Cl2(SO4)3.24H2O
(NH4)2SO4.Cr2 (SO4)3. 24H2O
(NH4)2SO4. Al2(SO4)3. 24H2O
33
Chemistry XII
PREPARATION:
Potash alum is prepared by mixing the solution K 2SO4 and Al2(SO4)3 in equimolar quantites. The
solution is evaporated to saturation and allowed to cool. As a result of this crystals of alum are
formed.
K2SO4 + Al2(SO4)3 + 24H2O K2SO4.Al2(SO4)3.24H2O
PROPERTIES:
(i)
(ii)
(iii)
It is crystalline acid.
It is soluble in water.
At 200C it forms porous mass called burnt alum or phul-phitkari.
USES:
(i)
(ii)
(iii)
(iv)
ALLOTROPY:
Two or more forms of same elements having same chemical properties but different physical
properties are called allotropes and this phenomenon is called Allotropy.
DIAMOND:
Diamond is a crystalline form of carbon.
34
Chemistry XII
PROPERTIES:
(i)
(ii)
(iii)
(iv)
(v)
STRUCTURE:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
GRAPHITE:
Graphite is another crystalline form of carbon.
PROPERTIES:
(i)
(ii)
(iii)
(iv)
(v)
STRUCTURE:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
35
Chemistry XII
In greater each carbon is Sp2 hybridized and fourth electron of each carbon forms the delocalized bonds. Due to delocalized -bonds, graphite conduct electricity while in diamond each carbon is
Sp3 hybridized and each carbon atom utilizes its four unpaired electrons in the formation of four
covalent bonds. These bonding electrons are localized so, diamonds do not conduct electricity.
LEAD PIGMENTS:
Lead (Pb) forms various types of pigments which are used to give the proper to paints etc. Some of
them are discussed below.
(i)
White lead pigment.
(ii)
Red lead pigment.
(iii)
Chrome Yellow pigment.
(iv)
Chrome Red pigment.
(v)
Turners Yellow pigment.
Pb3(OH)2.(CO)2
PREPARATION:
BY DUCH PROCESS:
In this process a mixture of the vapours of acetic acid and steam is passed into the chambers
containing lead sheets until the corrosion of lead is complete. By passing the mixture of CO2 and
vapours of acetic acid through this corroded lead, the white lead is formed on the surface of lead
sheets. This product is scratched and collected.
2Pb + 2CH3COOH + 2H2O [Pb(OH)2.Pb(CH3COO)2] + 2H2
3[Pb(OH)2.Pb(CH3COO)2] + 2H2O + 2CO2 2[2PbCO3.Pb(OH)2] + 6CH3COOH
OR
2PbO.PbO2
PREPARATION:
It is prepared by heating lead monoxide (litharge) in a revolving furnace with excess of air at about
450C.
36
Chemistry XII
6PbO + O2 2Pb3O4
PREPARATION:
(i)
OR
PbCrO4.PbO
PREPARATION:
It is prepared by heating lead chromate with NaOH.
2PbCrO4 + 2NaOH Pb2CrO5 + Na2CrO4 + H2O
PREPARATION:
It is prepared by boiling the solution of NaCl with litharge (PbO).
5PbO + H2O + NaCl 2NaOH + PbCl2 +.4PbO
Chemistry XII
PHYSICAL PROPERTIES:
(i)
(ii)
(iii)
(iv)
STRUCTURE OF HNO3:
CHEMICAL PROPERTIES:
Chemical properties of HNO3 are divided into following types.
(i)
Acidic properties
(ii)
Oxidizing properties
(iii)
Nitrating properties
Chemistry XII
OXIDIZING PROPERTIES:
HNO3 is strong oxidizing agent. The oxidizing properties of HNO3 is due to instability of its
molecule and presence of nitrogen in its highest oxidation state of +5.
2H+1N+5O-63 2NO3 + H2O + [O]
Chemistry XII
O + HNO3 O + H2O
AQUA REGIA:
The mixture of 1 part by volume HNO3 and 3 points by volume HCl is called Aqua Regia.
3HCl + HNO3 2H2O + NOCl + ZCl
Aqua regia dissolve certain noble metals like gold(Au), Platinium (Pt) etc due to liberation of
nascent chlorine.
REACTION OF AQUA REGIA WITH GOLD (Au):
Au + 3HCl + HNO3 AuCl3 + NO + 2H2O
REACTION IF AQUA REGIA WITH PLATINIUM (Pt):
3Pt + 4HNO3 + 12HCl 3PtCl4 + 4NO + 8H2O
RHOMBIC SULPHUR:
PREPARATION:
Rhombic sulphur is prepared by dissolving ordinary sulphur in CS 2 carbon disciplide and then the
saturated solution of sulphur in CS2 is filtered nd filterate is allowed to evaporate at room
temperature. After evaporation of CS2 Rhombic sulphur are obtained.
PROPERTIES:
(i)
(ii)
(iii)
(iv)
(v)
40
Chemistry XII
STRUCTURE:
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
Rhombic sulphur consists of sulphur atoms in S8 molecules giving eight membered ring.
Each S8 molecule has the form of puckered rings.
In each puckered ring four sulphur atoms lie in one plane in other four atoms lie in
another plane.
Each sulphure is linked to another by single bond in some ring.
The S S bond distance is 2.12A and S S S bond angle is 105.
There puckered ring unite together by vander waals forces of attraction.
These rings unite with one another and form the crystal of rhombic sulphur.
MONOCLINIC SULPHUR:
PREPARATION:
It is prepared by melting ordinary sulphur in a dish and allowing is to cool slowly until a crust is
formed on the surface of another sulphur. The crust is pierced in two places with a glass rod and the
liquid portion is drained out through on the holes on removing the crust, the long needle shaped
crystals of monoclinic sulphur are formed on the sides of the dish.
PROPERTIES:
(i)
(ii)
(iii)
(iv)
STRUCTURE:
(i)
(ii)
(iii)
PLASTIC SULPHUR:
PREPARATION:
This is non crystalline allotrope of sulphur. When ordinary sulphur is heated carefully and slowly. It
melts at 113C to a pale yellow liquid on further heating at 444.6C sulphur boils. If molten sulphur
is passed into cold water, a soft rubber like mass is obtained called plastic sulphur.
PROPERTIES:
(i)
(ii)
(iii)
(iv)
41
Chemistry XII
STRUCTURE:
The plastic sulphur is composed of long chains of sulphur atoms coiled up.
CHEMICAL PROPERTIES:
(i)
H2S is a weak acid and dibasic acid, it produces two ionizable H+ ion.
Chemistry XII
H2S is strong reducing agent because S-2 ion loses its electrons readily to form sulphur
atom and hence reduces other substances.
FOR EXAMPLE:
2FeCl3 + H2S 2FeCl2 + S + 2HCl
REACTION WITH HNO3:
U2 + H2S 2HCl + S
REACTION WITH HNO3:
2HNO3 + H2S 2H2O + 2NO2
REACTION WITH H2SO4:
H2SO4 + H2S SO2 + S + 2H2O
REACTION WITH H2O:
H2O2 + H2S 2H2O + S
STRUCTURE:
The molecule of H2S is non-linear. The angle between H S H is 92.2 and the bond distance
between S and H is 1.34A.
43
Chemistry XII
PHYSICAL PROPERTIES:
(i)
(ii)
(iii)
H2SO4 is colorless, odourless, viscous oily liquid, often known as oil of vitriol.
It is hygroscopic and corrosine in action.
Its boiling point is 338C.
CHEMICAL PROPERTIES:
The chemical properties of H2SO4 can be divided into following types.
(i)
(ii)
(iii)
Acidic properties
Oxidizing properties
Dehydrating properties
44
Chemistry XII
Sulphonating properties
Chemistry XII
H2SO4 has great affinity for water so it removes the elements of water from other compounds. This
type of reaction is called as dehydration reaction.
C12H22O11 + H2SO4(conc) 12C + 11H2O + H2SO4
Sugar
H2C2O4 + H2SO4 CO + CO2 + H2O + H2SO4
Oxalic acid
HCOOH + H2SO4(conc) Co + H2O + H2SO4
Formic acid
C6H12O6 + H2SO4(conc) 6C + 6H2O + H2SO4
Glucose
USES:
(i)
(ii)
(iii)
(iv)
(v)
STRUCTURE OF H2SO4:
The molecule of H2So4 has tetrahedral structure as shown in the figure.
CHLORINE:
Chlorine is manufactured by two different methods in industries which are described below.
46
Chemistry XII
CHEMICAL REACTION:
NaCl Na+ + ClREACTION AT CATHODE:
Na+ + 1e- Na
Na + Hg Na / Hg
2Na / hg + 2H2O 2NaOH + H2
REACTION AT ANODE:
Cl- 1e- + Cl
Cl + Cl Cl2
47
Chemistry XII
PHYSICAL PROPERTIES:
(i)
(ii)
(iii)
(iv)
CHEMICAL PROPERTIES:
Chlorine is very reactive. It readily combines with various metals and non-metals. The reactions of
chlorine can be divided into following types.
(i): OXIDATION RECTIONS:
Chlorine is oxidizing agent because it has ability to gain one electron and oxidizes most of the
substances.
FOR EXAMPLE:
Zn + Cl2 ZnCl2
Cu + Cl2 CuCl2
2P + 5Cl2 2PCl5
H2 + Cl2 2HCl
(ii): ADDITION REACTION:
Chlorine directly combines with certain compounds to form addition products such reactions are
called addition reaction.
CH2 CH2 + Cl2 CH2 CH2
|
|
Cl
Cl
CO + Cl2 COCl2
SO2 + Cl2 SOCl2
(iii): SUBSTITUTION REACTION:
Chlorine replaces one or more atoms from other compounds such reactions are called as
substitution reactions.
H2S + Cl2 2HCl + S
2KI + Cl2 2KCl + I2
CH4 + Cl2 CH3Cl + HCl
48
Chemistry XII
IMPORTANCE:
(i)
(ii)
(iii)
(iv)
It is used in the manufacture of various organic compounds like CCl4, CHCl3 etc.
Chlorine is used as bleaching agent.
It is used in sterilizing of drinking water and disinfecting drainage.
It is used for the preparation of PVC.
CHAPTER # 5
D-BLOCK ELEMENTS (TRANSITION ELEMENTS)
INTRODUCTION:
The elements having partially filled or f-orbital in any common oxidation state are called Transition
elements
They are called for 2 reasons firstly their position in the periodic table in-between the and p-block
elements and their properties are transitional between s-block elements, Which are highly reactive
and strong electropositive elements forming ionic compounds, p-block elements, Which from
largely covalent compounds, secondly, they show variable valiancy.
The s-block elements consist of three series each These are:
12345-
49
Chemistry XII
Copper ores are found at saindak, zhob, pishin, laralal, in baluchistan in north waziristan agency,
gilgit dir and chitral.
50
Chemistry XII
COLOUR:
The compounds of transition elements including ionic and covalent are colored except Zn, Which is
while, since electron are not be pounded d-orbital of Z +2. The color of transition elements is due to
promotion of elements from one d-orbital to another, which posses small energy difference. The
energy required to do this is obtained by absorbing the light of a particular wavelength in invisible
of electromagnetic radiation.
The five d-orbital are oriented differently in space, an electrons (s). which is are close to legend will
be repelled and hence the energy of such orbital will be raised relative to the other. T he degenerate
3d-orbital is therefore destroyed.
According to crystal field Theory (C F T), An octahedral field, split five degenerate d-orbital into
two sets with different energies as follows:
1. A higher energy pair d2Y2 and d2 z1 designated as Cg.
2. A lower energy trio, dxy, dyz and d1 designated as I2g.
In many cases, the energy different between two sets (Eg and I2g) of orbital is equivalent to a
wavelength in the visible rehion. Thus by absorbing visible light an electron may be able to move
from lower energy set (I2g) to higher energy set (Eg) of d-orbital. In doing so some of the
component wavelength of white light is absorbed. So the remaining component wavelength of the
reflected or transmitted light gives an excess of the other color of the spectrum-particularly blue, so
it give blue color in its compounds.
The color of a transition metals ion as associated with:
a) An incomplete 3d level (between land 9 electrons)
b) The nature of legends surrounding the ion.
MAGNEYIC PROPERTIES:
Most of the compounds of transition elements are paramagnetic as they are attracted by magnetic is
generally caused by the presence of unpaired electrons spin in the valence shell of the atom.
Elements such as Fe, Co and Ni are ferromagnetic2 i.e strongly attracted in the magnetic in the
field and therefore they can be magnetized.
51
Chemistry XII
Chemistry XII
For example:
Diammine curprous ion {Cu(NH3)2}in which central atom is cuprous ion (Cu) and the ligand is
ammonia (NH3) which are two in number, therefore co-ordination number of this complex is two
Co-ordina
tion group or ligands (generally called lewis bases) are sub-divided into two main group.+
POLY OR MULTIDENTATE:
It contain two or more electron-pair donor atoms in a molecule or an ion i.e it can from bonds
through two or more atoms of its molecule, for example: (BIDENATATE)
The ligands that can form two bonds with its atom or that contains two donor electron pairs. Such
as:
H2N CH2 CH2-NH2 and COO
(Ethylene diammine)_
COO
TRIDENTATE:
It contains three donor of electron pair. Such as:
H2N-CH2-CH2-NH-CH2-CH2-NH2
(Dithylene thiamine )
CHELATING AGENT:
The poly or multidentates are also called chelating agent they from quit stable complex. When
chelating agent forms a ring structure on co-ordination with a central metal atom, is called chelae
compound which means crabs claw the term chelae is derived from Greek word chelae means claw
for ample nickel dim ethyl glyoximate chalets are stable and highly colored compounds.
34-
In simple ionic compounds (salts) the action is named first and then the anion.
In a complex whether anion action or neutral species, ligands are named first in alphabetical
order, and metal atom is named second the perefixes di-tri-tetra-etc(or prefixes bis-tristetrakis-pentakis-etc for ligands having Greek prefix) are used with the name of ligands
when more than one ligands of the same of kind occurs with in the complex ion.
The name of the anion ligands are modified to endin o for example floure (F)-cholro (Cl)
bromo (Br) iodo (!) cyno (CN) nitro (NO2) nitrato (NO3) hydroxo (OH2) amido (NH2)
oxalate (C2O4) carbonate (CO3) Oxo (O2) and sulphato (sO4)
The name of neutral legends usually remain unchanged there are however several important
exception which are water ammonia and carbon monoxide water (H,O)is called aqua,
ammonia and carbon monoxide (CO 32-)as carbonyl.
53
Chemistry XII
The charge of the central metal ion is indicated by a roman numeral in parenthesis
(1,2,3,4,etc)
Following the name of the metal, an oxidation state zero is indicated by (o) when the
complex is either action or a neutral species. The central ion is written is its English named
followed by the oxidation state (the charge number) in roman numerals in parenthesis e.g
nickel (o), iron (2) copper (1) etc. when the complex ion is anionic the suffix-ate is added
often to the stem of the Latin name for the metal (except mercury) e.g ferrate, stannate,
aurate plum bate etc. the formal oxidation state is again show by roman numeral in
parenthesis for example:
{Ag(NH3)2}Cl
{Co(en)2BVr3}Cl
{Co(en)3}NO3)3
{Co(H2O)6}SO4
{Co(NH3)3(NO2)3}
{Co(NH3)4(H2O)Cl}Cl2
{Co(NH3)5 Cl}Cl2
{Co(NH3)6 Cl3
{Co(NH3 Cl}Cl2
{Cr(H2O)5 NO3)3
{Cr (H2O)6}NO3)3
{Cr NH3)4CI3 ]CI
METALLURG OF COPPER:
OCCURRENCE:
Copper occurs both in free and combined state in combined state the chief ores are:
1. Chalcopyrite or copper pyrite
2. Chalcocite or copper glance
3. Cuprites or red copper
(CuFeS2)
(Cu2 S)
(Cu2O)
54
Chemistry XII
(C u S)
{CuCO3. Cu(OH)2} Bright green
{2CuCO3 Cu(OH)3} deep blue
Cu2O
Cu3FeS3
Copper is used in making wires and cables for electrical conduction its conductivity is
appreciably lowered by traces of impurity.
it contains traces of silver gold and platinum which from a value able mud in electrolytic
cell make the process economically feasible.
55
Chemistry XII
Silver nitrate or lunar caustic is prepared when silver metal is dissolved in cold or hot diluted
HNO3 and resulting silver nitrate solution is evaporated and allowed to crystallize
2Ag + 4HNO3 ----------- 2AgNO+2H2O
As such transparent large rhombic crystals or stick of AgNO3 are formed.
PHYSICAL PROPERTIES:
AgNO3is readily solube in water it is also soluble in organic sol-vents such as C 2H5Opyridine etc. it
is called lunar caustic because it corrodes the skin and produces black spots on it its melting point is
2I20 C and decomposes at 4500 C giving NO2 and O2gases and leaving Ag metal.
2AgNO3 ------------ 4500C
Ag + 2NO2 +O
CHEMICAL PROPERTIES:
RECTION WITH Noah:
AgNO3When related with Noah first forms very unstable silver hydroxide
(AgOH) which decomposes to stable blackish brown silver oxide (Ag2 O ).
AgNO3 + Noah ---------AgOH + NaNO3
2AgOH
--------- Ag2O + H2O
PREPATION:
1. It is industrial, by reacting metallic copper with dilute H 2SO4 in the presence of air
2Cu+2H2SO+O
2 CuSO4+2H2O
56
Chemistry XII
PHYSICAL PROPERTIES:
It is very poisonous substance. It is readilty soluble in water but in insoluble in alcohol and can be
precipitated from its aqueous solution by addition of C2 H5 OH
CHEMICAL PROPERTIES:
HEATING:
Crystalline CuSo4 5H2O is blue in color which loses four of its molecules on heating at about 100c
the fifth molecule is also on heating at about 250C and slowly changes in to colorless powered
form or anhydrous CuSO4 the anhydrous salt decomposes into CuO and SO 3 on strong heating at
about 736C.
CuSO4 4H2O----------CuSO4+5H2O
Blue (hydrated) --------- color (anhydrous)
CuSO2---------------- CuO+SO3
USES OF CuSO4:
It is use in copper plating in electric in cells, in making green pigments, containing copper ebonite
as modern dying dyes and with milk of lime to kill fungus. It is used as timber preservative it is
used as calico in printing trade.
57
Chemistry XII
PROPERTIES:
It is lemon-yellow crystalline solid substance. It melts at 968.30 it is isomophous with K2SO 4. It is
very soluble in water and gives a yellow colored alkaline, which changes to orange-red on addition
of H2SO4 due to formation of dichromate ion.
2CrO4+2H*------------------CrO2+H2O
(Chromate ion) yellow
(dichromate ion) orange-red
Potassium chromate converts to dichromate in the presence of carbon dioxide.
2K2Cr4+CO2------------------K2Cr2+K2CO3
If forms precipitate of lead chromate with lead ion and barium chromate with barium ion.
CrO4+Pb2*--------------PbCrO4
CrO4+Ba2*--------------BaCrO4
USES:
K2CrO4 is used a laboratory reagent, especially as an oxidizing agent and indicator. It is used to
prevent the corrosion. It is used for the preparation of pigment, such as chromate yellow and
chrome red which is used for painting letterboxes.
PHYSICAL PROPERTIS:
58
Chemistry XII
It is orange-red crystalline solid. It melts at 3960. It is moderately soluble in cold water and easily
soluble in hot water giving an orange color in solution. The color changes to yellow on addition of
an alkali due to the formation of chromate.
K2Cr2O7+2KOH--------------2K2CrO4+H2O
CHEMICAL PROPERTIES:
REACTION WITH H2SO4:
It gives red needle-like crystal chromate oxide (CrO3) when its cone solution reacts with cone
H2SO4
K2Cr2O7+2KOH----------------2K2CrO3+2KHSO4+H2O
AS OXIDIZING AGENT:
It acts as a strong oxidizing agent in the present of H 2SO4 and oxidizes ferrous (Fe2*) salt to ferric
salts (Fe3*
6FsO4+K2Cr2O7+7H2SO4---------3Fe2 (So4) +K2SO4+Cr2 (So4) + 7H2O
It also liberates iodine from potassium iodide in the presence of H2SO4.
6Kl+K2Cr2O7+7H2SO4-------------4K2SO4+Cr2 (SO4) +7H2O
USES:
It is as powerful oxidizing in the volume analysis of ferrous ion it is used for the preparation of
chromium compounds such as chrome alum chrome red which are used as pigment it is used the
preparation of acetaldehyde and ethyl alcohol. It is used industrially in the tanning of leather in the
preparation of electrolyte used in chrome plating, and as a source of pure chromium.
59