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GHEMTSTRY
tI
PU 2014-2015
Max. Marks
Board Preparatory - 02
Duration
Date
Instructions
PART . A
Answer ALL of the following (answer ach question iuone word or one setrtenee)
Wbat is anisotropy?
2015
[10x]=101
ib
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I.
houn
g.
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Class
9.
Given,
R-C:N
ia
ik
solutes.
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PART. B
Answer any FIVE of the following (each question carries 2 marks)
[5 x 2 = 10]
11, Niobium crystallizes in a body centered cubic stucture. Its density is
8.55 g em-3. Calculate the atomic
radius of niobium (Atomic mass:93).
II.
12. calculate the ernf of the cell in which the following reaction takes place.
,Ni(s) + 2Ag* (0.002
M + Ni* (0.160 M)+ 2Ag(s)
Standard errf ofthe cell = +1.05 V.
13. What is a zero order reaction? Give an example.
14. What are interstitial compounds? Why transition melals form interstitial
compounds?
(ili) apiAc
22- Describe the followjng
with,respect to halogen
family.
following
;,* ilffiffi,*
*.
ouu," ,r,* #
lanthanidt
24. Compare
"i,urr"t*
I3l
I3l
::ffiHi:rrrsnetic.
ia
(i)erecnonic#ililfctinidesT#;:.,ffi;I.*.
Ji;:,;i:i
ib
(i)
"f,"*.*
;;".
ik
(ii) Explain
--
marrs)
co
tr'"i'*iL
g.
PART. G
(each question carries
3
lo
i"*;-
r;the
basis of varence
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1T*"
28. (a)
5 marrrs)
[3x5=15]
;;;;#
3#l;J},*.T]":T*::"::T:i{:i)^morecurar
.,
(ea"ffil,;i..rries
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t21
?:r::'x;:#
rv..e shows
rxuw) a oepressron
depression n
in freezrng
freezngpoint equal to
l.62 "C. Calculate the
,r'j'::'":1-: 1^t^:::,1:,zene
of
the
acid
in
solurion
if it exists aq
solution.
ntution.GivenK.^r.r.--:::1'li-:.11sociatio,n
iGiven Kr of benzene ii +.g
as rrimcrc
dimers in
f n U *"i;.
(b) What is reverse osmosis?
How is it usefiit
13l
2e. (a)
}:il::""
determination of srandard
erectrodepotentiar of zinc
erecrode using
l"l Define
ft)
expression
(i)
threshold en..gy
aod
,", , ,
--l
S cm_l. Calculate
sthndardrr.;1
*lrr"r* Oon*""
"** r*lnoo""'""'
l3l
al
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,, j:]
l*"ll the mechanism
(b) Desoibe
of enzyme catarysis.
iroti"r*.
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121
rl
carries 5 marks)
32' (a) lVrite the organic product
formed in the forowing reactions.
1g4y
acetone
heat
>
*'
3a' @)
443
K.
*r:m"#fTT*",1,jtr'-Y
ib
I{zSO+ at
(b) Explain Kolbe,s reaction.
121
lo
(ii)PCC
(iii) Excess conc.
nucreophilic substirution
g.
:::lilrwhv
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co
cH3CrLCHrcl +
+ CH3C}I2-CI ACI'
-
(i)
(ii)
[4x 5=201
romura
"lt*
TJJ
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ik
;
ffi H[:J'f,,:,*T:l1*,y1]1:,,rd;';;*il'#r""jHHl;ff
rornrs a ketone c with acetvt
ctro.iil;;.;:T,;H;fff;:,;
H"T,trf3;l'::
Identify,\
B and C.
Given
CH, - CHO
Kor{+orhy'm gryor
--IEL:M!--r 1
!b)
, y . What are X and y?
35' (a) Distinguish primary' secondary
and tertiary amines with
Hinsberg reagent- Give equations.
(b) Give the preparation of erhanamine
ia
12)
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12)
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