Section 9.4.1 Much of the work of chemists involves
monitoring the reactants and products of reactions and managing reaction conditions.
Outline the role of a chemist employed in a named
industry or enterprise, identifying the branch of chemistry undertaken by the chemist and explaining a chemical principle that the chemist uses.
Burhan Gemikonakli is a plant chemist at Qenos, a major
Australian manufacturing company that makes ethylene from ethane and then polymerises it to polyethylene. Burhans role at Qenos has several components: - Monitoring the quality of the ethylene/propylene products from the plant to ensure that they meet the requirements for the next stage of manufacture (in particular determining the nature and amount of impurities present). - Monitoring waste water from the Qenos complex to ensure that it meets environmental requirements (such as pH, suspended solids, sulfate, grease, hydrocarbons) before it is discharged; and - Collaborating with process engineers at the cracking furnace (ethane to ethylene) to adjust operating conditions in order to optimise product yields. As a chemist in the central laboratory, Burhan is not so much concerned with the hour-by-hour monitoring of products and wastes; rather his job is to check that the equipment works properly, to calibrate instruments from time to time, train shift workers in the use of the instruments, carry out occasional analyses to ensure the reliability of the results and solve problems that may arise. The efficient operation of plants as complex as those at the Qenos site requires regular routine monitoring. In addition there needs to be skilled chemists available to oversee this, and solve problems that occur Burhan is one of those chemists. The branch of chemistry that Burhan mainly works in is analytical chemistry the part of chemistry concerned with determining what substances (and how much of each) are present in materials. Many of Burhans analyses use gas chromatography. This is a technique in which a mixture is vaporised into a stream of helium that flows over a stationary phase which can be
solid, or a liquid coated on the surface of the solid. The
stationary phase can be a finely divided solid packed in a long thin tube or columned called gas-solid chromatography, or it can be a liquid coated on the walls of a long thin glass capillary tube, called gas-liquid chromatography. The chemical principles involved are adsorption (for gassolid chromatography) and solubility (for gas-liquid
chromatography).
If the stationary phase is solid, then the components of the mixture
adsorb on to it (stick to the surface) to differing extents, pass through the column at different rates and so are separated. A device at the end of the column detects each substance as it passes out of the column and measures it quantitatively. If the stationary phase is a liquid, then the components of the mixture dissolve in it to differing extents. The more soluble a substance is in the stationary liquid, then the slower that substance moves through the column (tube). Hence a separation is effected and the detector measures the amount of each component as it emerges from the column. Polarity of the molecules is often
a key factor in GLC separations: if the stationary phase is a polar
liquid, then the more polar a component of the mixture to be analysed, the greater is its solubility and so the more slowly it moves through the column. The rate and the volume of the substance that emerges through the column is quantitatively measured and hence used to detect the presence of anomalies in the gas.
Gather, process and present information from secondary
sources about the work of practising scientists identifying: o A variety of chemical occupations o A specific chemical occupation for a more detailed study Variety of Chemical Occupations: 1) Environmental chemists: These chemists are employed by a wide variety of organisations, including mining companies, the EPA (Environmental Protection Agency) and the local government. Environmental chemists have developed expertise in analytical chemistry during their training. They collect, analyse and assess environmental data from the air, water and soil. Water resource authorities and air quality management authorities employ environmental chemists who monitor water and air samples for pollutants. Environmental chemists have strengths in analytical procedures and instrumental analysis. Following their analysis, environmental chemists write concise reports about their investigations. 2) Metallurgical Chemists: have a high-level knowledge of metals, alloys and ores and their reactions. Metallurgical chemists specialise in all aspects of the use and development of metals and alloys in our technological society. In mining companies they design and monitor methods of extracting metals from ores. They investigate ways that metals could be combined with other materials such as polymers of ceramics. Metallurgical chemists are also employed in industries such as metal manufacturing and chemical engineering. In production-based industries, the metallurgical chemist will be involved in optimising plant performance and developing new procedures. Industrial Chemist in a Crude Oil Refinery -
An industrial chemist studies and applies the physical and
chemical property of substances (e.g. B.ps). The industrial chemist improves the quality of the product (i.e. maximise the purity of each fraction (e.g. petrol in a car C 8H18). Monitor the unsatisfactory process of a chemical.
Role of chemists: The role of chemists is to monitor/manage the
production process. 1) Safety ignition of the fuel/air mixture 2) Time efficient max yield in the shortest amount of time 3) Cost and Yield The specific tasks of the chemist: The industrial chemist ensures that the crude oil is heated to the correct temperature so that it fully vaporises and then rises through the fractionating tower appropriately. This ensures that vapour reaches correct height in the tower so that it is at a temperature that causes it to condense back into a liquid. Contamination of the fraction with other compounds needs to be avoided. Chemical principles used: A chemical principle is a statement that connects a large number of facts and concepts. The properties of elements are periodic in nature. Solids have sharp melting and boiling points. The greater the molar mass of the molecule the stronger the dispersion forces between the molecules. The weaker the dispersion forces between covalent molecules, the more easily the molecules are separated from one another - furthermore, the lower the mp and BP The further away from the source of heat, the cooler the object becomes. Explanation: The Bp principle: The smaller in mass a gaseous molecule is (for a fraction of crude oil), the lower the temperature at which the molecules change state from gas to liquid (condense). Molecules with a smaller mass have dispersion forces between the molecules due to the random movement of electrons, which will form temporary dipoles which will bring about the potential for uneven distribution of electrons. Therefore, with less mass will form weaker dispersion forces due to the lower probability regarding the number of dispersion forces that can occur at any one time. Hence at higher temperature, there is sufficient heat energy to overcome these forces of attraction and keep the molecules separated as a gas. The particles move faster with more K e at higher temperature therefore, dispersion forces are less likely to occur (they are moving too fast). As the gaseous molecules move up the tower, they lose energy sufficiently such that dispersion forces can form between them. This results in the vapour condensing as a liquid.
Identify the need for collaboration between chemists as they
collect/analyse data. Collaboration is an essential aspect of all data collection and analysis. In any given situation, a wide range of chemists, each with varying degrees of knowledge and expertise can aid in data collection. This is because certain chemists will be aware of efficient collection methods in their respective fields and this can make the overall data collection process efficient. Furthermore, by allocating varying positions and responsibilities for those in the group, reduces the pressure and workload of each individual. This allows for all group members to meet target dates for data collection, hence increasing the overall efficiency of the process. In terms of analysis, varying
knowledge and degrees of expertise allows for deeper analysis
to occur. Furthermore, with discussions and collaborations, ideas and theories can be discussed and debated this leads to new understanding and hence greater knowledge for all involved. Furthermore, by allocating analysis to those chemists specialised in the respective fields involved, it reduces the pressure on others who are unable to analyse due to their lack of knowledge. These individuals could be used for other areas where they are skilled. This creates an overall efficient system where regular collaboration ensures efficacy in both data collection and data analysis.
Describe an example of a chemical reaction such as
combustion where the reactants form different products under different conditions and thus would need monitoring. Combustion is a reaction in which hydrocarbons are combusted in the presence of oxygen. The products from this reaction vary quite considerably, and hence monitoring is required. When there is excess oxygen relative to the amount of hydrocarbon being combusted, the end products formed are carbon dioxide and water. This is desirable as neither of these two substances are regarded as pollutants. Note: CO2 is not a pollutant despite its effect in global warming. However, when oxygen is restricted moderately or severely, carbon in the form of soot (C(s)) and CO(g) can be produced.
Carbon Monoxide is a toxic compound that binds with the
haemoglobin in the body with 200 times greater affinity than oxygen. This makes it difficult to breathe and can lead to anoxia (oxygen deprivation of the brain). Carbon in the form of soot is carcinogenic which means it causes cancer due to its highly pollutant and toxic nature. Furthermore, it builds up within the engine which increases wear and tear during the combustion process this is costly as engine parts need to be replaced more frequently. Not only this, but other substances such as nitrogen are also present in the combustion chamber. Due to the highly exothermic nature of the combustion process, the temperatures within the combustion chamber will easily exceed 1000 degrees.
This will facilitate the reaction between nitrogen and oxygen to form nitrogen monoxide and then nitrogen dioxide.
Nitrogen dioxide is a brown gas that forms a layer of
photochemical smog which leads to the production of ozone. It also irritates the eyes, nose and throat (mainly the respiratory tract) and can make it difficult for asthmatics and sufferers of emphysema to breathe. Sulfur is also a major impurity within the fuel and will readily be converted into SO2 within the reaction chamber. This needs to be monitored as SO2 leads to acid rain, as well as being an odourless gas that increases breathing difficulties (more so than NO2). Furthermore, Lead, from engines is also released into the atmosphere during the combustion process. Lead is associated with brain damage and hence its monitoring is essential for overall well being of society. The EPA (Environmental Protection Authority) monitors these substances and heavily fines companies that exceed the legal limit. As a result, companies employ environmental chemists to monitor the release of these substances from their products. It has been found that: 1) To lower CO production: the engine needs to operate at high speed with a maximum oxygen intake. 2) To lower NO2 production: the engine needs to operate at low speeds, with lower temperatures and a high oxygen intake. 3) In order to lower C production: the engine speed must be high and the oxygen intake must be at a maximum. Besides pollution, a further consideration for monitoring combustion is to ensure energy efficiency of the process. Although it is not possible to obtain 100% of the chemical energy from an exothermic reaction such as combustion of petrol, incomplete combustion produces considerably less useable energy than complete combustion. Therefore automotive engineers work collaboratively with chemists from the petroleum industry to continue to develop engines that produce more power and less harmful pollutants.