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Abstract
A mathematical model for simulation of gasification processes of solid fuels in atmospheric or pressurised bubbling fluidised beds
incorporating bed and freeboard hydrodynamics, fuel drying and devolatilization, and chemical reaction kinetics is presented. The model
has been used to simulate four bubbling fluidised bed gasifiers, described in literature, of different scales from atmospheric laboratory
scale up to pressurised commercial scale, processing brown coal, peat and sawdust. The gasifiers have been operated within a wide range
of parameters using air, airrsteam or oxygenrsteam as gasification agent, operating with or without recirculation of fines at operating
pressures up to 2.5 MPa. The simulation results for overall carbon conversion, temperature and concentrations of gaseous species agree
sufficiently well with published experimental data. q 2001 Elsevier Science B.V. All rights reserved.
Keywords: Gasification; Pressurised fluidised bed; Biomass; Coal
1. Introduction
The traditional approach necessary to establish commercial plant technology is based on comprehensive experimental investigations, progressing from a laboratory scale
test unit to a pilot scale plant, before building a full-scale
commercial demonstration plant. For process optimisation,
an extensive investigation of the plant behaviour depending on various operating parameters is required for each
scale up step. To support this optimisation procedure,
mathematical models are helpful to reduce the temporal
and financial efforts. Pre-condition is a reliable simulation
tool, which includes the mathematical formulation of all
important chemical and physical processes by describing
their dependency on operating parameters and their interdependencies.
As an extension of former works that have been carried
out in the field of bubbling and circulating fluidised bed
combustion at the Institute of Energy Technology of the
University of Siegen, a comprehensive model for pressurised bubbling fluidised bed gasification reactors is presented. The model includes bed and freeboard hydrodynamics, kinetic models for drying and devolatilization, and
for chemical reactions. The comparison between experi-
)
Corresponding author. Tel.: q49-271-740-2107, q49-271-740-2634;
fax: q49-271-740-2636.
E-mail address: S.Hamel@et.mb.uni-siegen.de S. Hamel..
2. Model description
The presented model is the result of an advanced development based on the works on atmospheric bubbling fluidised beds for coal combustion w6x, sewage sludge combustion w7x, and on works on atmospheric and pressurised
circulating fluidised bed plants w8,9x. The development of
the model, the applied formulas and the mathematical
solution procedure have been reported in detail w10x.
Therefore, the sources of the applied submodels are referenced and only a short description of the main features is
given here.
2.1. Cell model
The gasifiers and other required components, as for
example, the cyclone and connection pipes, are divided
into a number of in-series arranged discrete balance segments, so-called cells. According to the two-phase theory,
0032-5910r01r$ - see front matter q 2001 Elsevier Science B.V. All rights reserved.
PII: S 0 0 3 2 - 5 9 1 0 0 1 . 0 0 3 5 6 - 4
106
Table 1
Considered chemical reactions
D HR
Reference
R2
R3
R4
R5
1
2
2
O 2y
CO q
y 1 CO 2
Fc 2
Fc
Fc
C q H 2 O CO q H 2
C q 2 H 2 CH 4
C q CO 2 2CO
CO q 1r2 O 2 CO 2
y393.5 - DH R - y110.5
in kJrmol C
q131.4 kJrmol C
y74.9 kJrmol C
q172.5 kJrmol C
y283 kJrmol CO
R6
R7
R8
R9
R10
R11
H 2 q 1r2 O 2 H 2 O
CH 4 q 3r2 O 2 CO q 2 H 2 O
CO q H 2 O H 2 q CO 2
CH 4 q H 2 O CO q 3 H 2
Tar q O 2 CO q H 2
Tar q H 2 O CO q H 2 q CH 4
y241.9 kJrmol H 2
y519,4 kJrmol CH 4
y41.1 kJrmol CO
q206.3 kJrmol CH 4
D HR - 0
D HR ) 0
No.
R1
Chemical reaction
Cq
107
108
case of sawdust, several literature sources and own experimental results are used to estimate the product yields. A
detailed description of the evaluation of the available
literature data is given in Ref. w10x.
Reactor height
Freeboard B
Simulation no.
Fuel a
Pressure
Fuel feed
Primary air feed
Secondary air feed
Steam feed
ERc
Recirculation of fines
Fuel properties
W
A dry.
VM daf.
C dry.
H dry.
O dry.
N dry.
S dry.
HTW pressurised
gasification plant w39x
HTW demonstration
plant w39x
14.5
0.6
LU
RB
2.5
3377
airrH 2 O b
O2
RB
2.5
6859
O 2 rH 2 O b
2.75
BE
RB
1.0
25,769
O 2 rH 2 O b
0.337
yes
0.268
yes
0.238
yes
3.7
0.25
KU1
RB
0.5
46.9
51.8
30.1
6.8
0.33
no
16.9
11.41
53.42
61.5
4.1
21.8
0.68
0.51
15.8
8.31
52.7
62.9
4.03
23.3
0.88
0.58
12.4
12.1
53.38
61.1
4.4
20.7
0.7
1.0
11.8
4.3
53.0
63.8
4.6
26.2
0.8
0.3
KU2
RB
0.5
41.4
51.6
37.5
9.0
0.40
yes
KU3
RB
0.5
41.4
51.4
46.5
6.8
0.44
yes
KU4
RB
0.7
49.0
62.2
42.8
11.3
0.41
yes
KU5
FP
0.5
68.8
43.8
49.5
0.31
no
KU6
FP
0.5
65.5
60.7
21.9
15.5
0.29
no
KU7
FP
0.5
61.6
53.3
31.9
5.4
0.32
no
KU8
FP
0.5
63.7
48.1
46.9
0.37
no
11.7
11.9
11.8
16.1
4.3
68.4
54.5
5.6
33.6
1.8
0.25
14.8
15.9
18.5
Reactor height
Freeboard B
Simulation no.
Fuel a
Pressure
Fuel feed
Primary air feed
Secondary air feed
Steam feed
ERc
Recirculation of fines
3.7
0.25
KU9
FP
0.7
76.3
62.7
35.7
18.7
0.30
no
3.65
0.158
LPA
FP
0.1
11.2
12.5
0.26
no
Fuel properties
W
A dry.
VM daf.
C dry.
H dry.
O dry.
N dry.
S dry.
16.2
4.3
68.4
54.5
5.6
33.6
1.8
0.25
K10
FP
1.0
62.5
65.2
34.0
27.0
0.29
no
K11
FP
0.5
45.0
51.4
27.7
6.5
0.40
yes
K12
FP
0.4
26.5
38.9
10.4
7.9
0.43
yes
K13
FP
0.5
50.2
47.0
41.6
7.6
0.41
yes
K14
SD
0.4
42.8
39.1
11.6
2.9
0.28
no
K15
SD
0.4
40.0
37.6
22.3
12.8
0.39
no
15.5
15.7
16.0
16.1
11.3
0.2
83
50.2
6.1
43.4
0.1
0
5.9
15.2
5.2
68.4
54.3
5.7
33.1
1.5
0.2
LPB
FP
0.1
10.3
10.4
1.1
0.25
no
LPC
FP
0.1
11.7
12.5
3.5
0.32
no
LPD
FP
0.1
10.7
12.9
0.26
yes
LPE
FP
0.1
9.8
13.0
0.29
yes
10.7
15.2
8.4
8.4
m
m
MPa
kgrh
N m3 rh
N m3rh
kgrh
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
m
m
MPa
kgrh
N m3 rh
N m3 rh
kgrh
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
wt.%
109
Fig. 2. Comparison of the different scale up levels of the simulated fluidised bed gasifiers including the preferred cell structure.
cation of low grade fuels, peat and waste wood at operating pressures from 0.4 up to 1.0 MPa. A detailed description of the reactor, the operating parameters and the
experimental results are reported in Ref. w2x. Experimental
results of the gasification of peat in the atmospheric laboratory scale gasifier are described by Leppalahti
and Kur
kela w1x. The data necessary for simulation of this two
gasifiers are taken from the literature sources mentioned
above.
The original measurement data of the HTW pressurised
gasification plant and of the HTW commercial scale
demonstration plant are provided by the company Rheinbraun and its engineering partner Krupp-Uhde. The HTW
Fig. 3. Calculated results in comparison with experimental data of airrsteam gasification of the HTW pressurised gasification reactor simulation no. ALUB
according to Table 2..
110
4. Simulation results
The simulation results of temperature and gas concentrations depending on the reactor height are displayed
exemplary for run number ALUB see Table 2. in Fig. 3 for
the HTW pressurised gasification reactor. To represent the
complete calculated results, the cells of the connection
pipe between cyclone and reactor see Fig. 2. and the
cyclone cells itself are appended vertical at the top of the
reactor cells see left sketch in Fig. 3..
Comparisons of the average freeboard temperature, the
overall carbon conversion and the molar fractions of CO,
H 2 , H 2 O and CH 4 in product gas are shown in Fig. 4af.
For the two laboratory scale gasifiers w1,2x, only one data
point for the freeboard temperature is published. Therefore, in Fig. 4a, the average value of the calculated free-
Fig. 4. Comparison of the predicted average freeboard temperature, the overall carbon conversion and the CO, H 2 , H 2 O and CH 4 concentrations with
measured data.
5. Conclusion
A previously developed mathematical model w10x for
bubbling fluidised bed gasifiers is used to simulate four
gasifiers of various scales. A wide range of operation
modes is tested using air, airrsteam or O 2rsteam ER s
0.230.44., processing brown coal, peat and sawdust,
operating either with or without recirculation of fines,
operating with or without secondary gasification agent
supply at pressures up to 2.5 MPa. Simulation results of
the present model agree sufficiently well with the experimental data represented by overall carbon conversion,
freeboard temperature and the concentrations of individual
gas species.
111
Acknowledgements
The authors gratefully acknowledge the financial support from the Ministry of School, Science and Research of
Nordrhein-Westfalen Project-No. IV A 4- 9021.1. and
from the German Research Foundation DFG-Project No.
KR 892r9-1..
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112
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