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Group
Group-I
Physical
Group-II
Inorganic
Unit
Title
Marks
Part-A
Part B
Part C
II
III
10x1 mark
8x2 mark
8x3 mark
Part D
Total
IV & V
11x5 mark
Solution
1,2
Electrochemistry
Chemical kinetics
Surface chemistry
Total of Group-I
41
36
19
11
10
20,21,22
10
23,24
25,26
Coordination compounds
32
28
Total of Group-II
Group-III
Organic
Hours
10
11
27
28
12
29
13
30
31
11
36
14
28
8
15
32
33
12
13
Amines
14
Biomolecules
15
Polymers
16
47
41
120
105
Total of Group-III
TOTAL
16
10
34
35
36
37
5
4
17,18
41
10
10
15
35
105
MAX.MARKS.70
Instructions :
i. The question paper has four parts. All the four parts are compulsory
ii. PART A carries 10 marks , each question carries one marks.
PART-B carries 10 marks . each question carries two marks
PARRT C carries 15 marks . each question carries three marks
PART-D carries 35 marks . each question carries five marks
iii) write balanced chemical equations and draw diagrams wherever necessary
iv) use log table and simple calculators if necessary
(use of scientific calculator is not allowed)
PART-A
I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES ONE MARK 1X10=10
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15. How does Acetyl chloride react with Anisol in presence of anhydrous aluminum chloride
catalyst. Write the chemical equation of the reaction.
16. What are the effects of the electron withdrawing and electron donating groups on acidity of
carboxylic acids
17. What are antacids? Give an example.
18. What are food preservatives ? Give one example
PART C
III ANSWER ANY FIVE OF THE FOLLOWING EACH QUESTION CARRIES THREE MARKS
15
5X3=
(3)
(2)
(4)
(1)
H2 S oxidation
(2)
(2)
V ANSWER ANY FOUR OF THE FOLLOWING . EACH QUESTION CARRIES FIVE MARKS
4X5=20
32. a. Explain SN1 mechanism by taking tertiary butyl bromide as an example
b. What is Wurtz Fittings reaction ? Give an example
(3)
(2)
33. a. How is phenol manufactured by cumene process. Give the chemical equations of the reaction
involved .
(3)
b. How do you prepare ethanol by using the Grignard Reagent?
34. a. How is Benzol chloride converted into benzaldehyde ? Name the reaction
(2)
(3)
b. Write the chemical equation for the reaction between dilute NaOH and acetalhyde, mention the
name of the product formed .
(2)
35. a. Explain how is Hinbergs reagent is used to distinguish the primary, secondary and tertiary
amines
b. Write the chemical reactions involved in the conversion of aniline into phenol
36. a. What are carbohydrates ?and how are they classified ?
(2)
(3)
(2)
(3)
(2)
Scheme of Valuation
Q.N
O
VALUE POINT
MARK
S
Two
Invertase
A=XeF6 or Xenonhexaflouride
A mixture containing two enantiomers in equal proportions will have zero optical
rotation.
Acetaldoxime
10
Uracil
1
PART -B
11
Formula d=zM
-------a3 NA substitution with correct answer(10.5 x 103 kgm-3)
OR
10.5 g cm-3
1
12
13
protection)
1
14
Lanthanides
1.Binding energies of 4f es are higher
Actinides
1. Binding energies of 5f es are
Lower
2. They do not form complexes easily
complexes
ANY ONE SUITABLE ANSWER
15
16
17
18
Ex: Table salt, sugar, vegetable oils, OR any other suitable example
PART-C
19
Al2O3. +x H2O.
20
4NO + 6H2O
500k,9bar
2NO + O2
2NO2
1
1
21
(i)
Statement
2KClO3 Mno2 2KCl + 3O2
22
(i)
1
1
(ii)
23
24
Availability of d- orbitals
25
26
Diamagnetic
dsp2 Hybridisation
(i)
(ii)
(iii)
1
1
PART -D
27
(a) Up to a = 4 /3 OR r=
1
28
Substitution:
M2 = 1000 x 1.8 x 2.53
0.88 x 90
M2 = 58 g mol-1
[ NO UNIT DEDUCT ONE MARK]
(c) Ideal solution
Hmix =0
Vmix =0
1
1
30
(a) RP
Rate = - d[R] = k[R] OR
dt
d[R] = - kdt
[R]
Integrating euation
Ln[R] = -kt+I --------------------(1)
To calculate I :
T=o, R=[R]0
ln[R]o =-kxo+I
OR
ln[R]0=I
substitutionequation (1)
ln [R] = -kt + ln [R]0
Rearranging
Ln[R] = - kt
OR
[R]0
K= 1/t. ln [R]0
OR
[R]
K= 2.303 log10 [R]0
t
[R]
(b) Order of reaction is one and molecularity is two or more than two
1
1
1
31
FeCl3 + 3H2O
Hydrolysis
AS2 S3 +3H2O
Fe(OH)3 + 3HCl.
1
1
PART-V
32
1
(a)
Step-1
+ Br -
+OH - fast
(CH3)3 COH
(b) Alkylhalide reacts with anyl halide gives alkylarenes when treated with
sodium indry ether
1
2
(a) Explanation
33
OR
Step wise reaction carries
(b) HCHO+ CH3 Mg Br CH3CH2OBr
Methanal
CH3CH2OMgBr + HOH CH3CH2OH+Mg(OH)Br
Ethanol
34
(a)
H2
Pd-BaSO4
Benzoyl
chloride
Rosenmund reduction
Benzaldehyde
Ethanal
3-Hydroxybutanal
(ALDOL)
CH3-CH=CH-CHO
But-2 enal
2
35
(a) Hinsbergd reagent reacts with 1 amine gives a product which is soluble in
alkali
(b) Hinsbergs reagent reacts with 2 amine gives a product which is insoluble
in alkali
Hinsbergs reagemt doesnot react with 3 amine
C6H5NH2 + NaNO2+2HCl 273-278 k C6H5N2+Cl- + NaCl + 2H2O
C6H5N2+Cl- + H2OC6H5OH + N2 + HCl
1
1
1
1
1
36
1
37
1
1
1