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Abstract
This paper presents the results of laboratory and field investigations on the influence of bleeding on minute properties
and steel corrosion in concrete. Test methods such as minute compressive strength test, minute tensile strength test and
minute diffusion test were performed in the laboratory to assess the effect of bleeding on minute properties of concrete.
In addition, electrochemical investigations were conducted both in the laboratory and in the field to determine the influence of bleeding on the rate of steel corrosion in concrete. The various test results indicate a strong agreement between the laboratory experiment and the field investigations. The upper layer of concrete affected by bleeding exhibited
weaker strength, higher permeability, lower concrete resistance, and higher oxygen permeability. Consequently, a higher
macrocell corrosion rate than the microcell corrosion rate prevailed in both the vertical and horizontal steel bar and the
corrosion rate was enhanced at elevated temperatures (20-40oC).
1. Introduction
The premature deterioration of reinforced concrete
member has become a major concern in many countries
throughout the world. According to the technical report
of the Concrete Society based in London, while concrete has proved to be an essentially durable material it
has not always been completely durable. Its performance depends not only on the exposure conditions but
also on the concrete quality, which can vary widely.
One of the factors mentioned that affects the quality of
concrete is bleeding. This phenomenon occurs as a result of adding a large amount of water into the concrete
mix to increase its workability. Bleeding of concrete is
caused by the segregation of water from the cement
paste. In the case of high segregation, suspended particles precipitate depending on their fineness and specific
gravity and the mix proportions of the concrete (Yonezawa 1988). As a consequence, concrete is weaker
and less durable at or near its top layer compared to
other parts. A study done by Wainwright and Ait-Aider
188
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
Item
Specific Gravity
Blaine Fineness, cm2/g
Loss on Ignition
SiO2 %
Al2O3 %
CaO %
MgO %
SO3 %
Fe2O3 %
OPC
3.16
3270.00
0.90
21.80
5.10
63.80
1.70
2.00
3.00
2. Experimental procedure
2.1 Materials and mix proportions
Ordinary Portland Cement (OPC) was used in the concrete mix. The physical and chemical compositions of
the OPC are shown in Table 1. The aggregates used
were natural river sand and crushed coarse aggregates.
Specific gravity, water absorption (%) and fineness
modulus of the sand were 2.59, 2.08 and 2.51, respectively. On the other hand, the specific gravity, water
absorption (%) and fineness modulus of the crushed
coarse aggregates were 2.61, 0.88, and 6.85, respectively. Deformed 16-mm diameter steel bars (SD 345)
conforming to the Japanese Industrial Standard (JIS)
were used. The iron, carbon, silicon, manganese, phosphorus and sulfur contents were 98.25%, 0.22%, 0.3%,
1.21%,
0.012%,
and
0.009%,
respectively.
Air-entraining agent and air-entraining water reducing
agent (JIS 6204) were used as admixtures. Except for
the control specimen, each of the concrete specimens
was admixed with a total amount of 10 kg/m3 of sodium
chloride. The mixture proportions of the concrete
specimens are summarized in Table 2.
2.2 Specimen layout
A total of seven (7) 30 cm x 15 cm x 150 cm reinforced
concrete specimens were prepared for the laboratory
investigation. Figure 1(a) shows the detail layout of the
specimen and the steel bars embedded in it. The steel
bars used in the said specimen are composed of vertical
and horizontal steel bars (Fig. 1(b)) formed by attaching
divided steel bars together using epoxy resin as the adhesive material. In order to measure in detail the mac-
3. Measurement methods
The measurement items considered in the investigation
to determine the influence of bleeding on minute properties and steel corrosion in concrete are briefly discussed below. In this study, the test methods (minute
compressive strength test, minute tensile strength test
and minute diffusion test) used to assess the minute
properties of concrete were based from the measure-
AE*1
(g/m3)
AEWRA*2
(g/m3)
Slump
Flow*3
cm
Bleeding
(%)*4
175
318
854
518
518
2226
3180
16.90
3.70
0.62
0.55
225
409
760
462
462
2863
4090
18.50
8.00
1.08
275
500
668
405
405
3500
5000
69.0
0.80
6.67
W, C, G, S refers to water, cement, gravel and sand, respectively. *1 AE- Air-entraining Admixture *2AEWRA- Air-entraining
Water-Reducing Admixture *3 Slump Flow *4JIS A1123
W/C
Water
(kg/m3)
Cement
(kg/m3)
Sand
(kg/m3)
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
30 cm
15 cm
Upper
150 cm
Epoxy
resin
Middle
60 cm
Lead wire
Each divided steel
bar was connected
8 cm using an epoxy
resin
5 cm
60 cm
Lower
189
8 cm
Concrete cover: 5 cm
Steel bars: Divided D16, SD345
con
Upper and bottom surfaces -of concrete were coated with epoxy resin
Concrete
Fig. 1 (b) Detail of connection of divided steel bars (vertical and horizontal steel bar).
30 cm
10 cm
10 cm
10 cm
10 cm
80 cm
10 cm
10 cm
c =
P
A
190
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
the other side with Ca(OH)2. The chloride ion concentration at the saturated Ca(OH)2 side was monitored
everyday using an ion chromatography device. Since the
gradient of the chloride ion concentration is known, the
flux of chloride ion can be calculated using Eq. 3
t =
V cell
J = Q
(3)
(2)
3% NaCl solution
Specimen
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
J cl
D cl =
( C cl x )
(4)
Potentiostat
RE
WE
CE
Concrete
Epoxy resin
191
cell corrosion current density test, except that no frequency response analyzer (FRA) was used. As shown in
Fig. 6, the electrochemical measurement system consisted of a working electrode (reinforcing steel bar with
lead wire attached to it), counter electrode (steel plate)
and a reference electrode (Ag/AgCl). The limiting current density was measured by a potentiostat. Oxygen
permeability in the concrete specimens was calculated
using Eq. 5 (Nagataki et al. 1996):
dQ
dt
(5)
i lim
=
nF
K
pi S
(6)
i
192
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
Ii-1,i
Ii,i+1
RS
RS
RS
RS
RS
Concrete
Ammeter
Rp
i
i-1
Concrete
Epoxy resin
i+1
Rp
V
Rp
Rp
V
Rp
V
Rp
V
Electric
double
layer
Steel bar
I i -1 , i - I i , i + 1
(7)
Si
Vertical
(cm)
Verticaldistance
distance (cm)
160
140
120
100
80
60
0.62 (% Bleeding)
40
1.08 (% Bleeding)
20
6.67 (% Bleeding)
20
40
60
80
Minute compressive strength (MPa)
80
40
Upper (145 cm from base)
Middle (75 cm from base)
20
0
0
20
40
60
80
Vertical distance
Vertical
distance(cm)
(cm)
193
150
60
80
60
40
20
0
70
80
90
100
110
Vertical
Verticaldistance
distance(cm)
(cm)
Minute compressive
strength (MPa)
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
75
Above coarse
aggregate
Below coarse
aggregate
0
0.00
0.50
1.00
1.50
2.00
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
Vertical
distance(cm)
(cm)
Vertical distance
150
Specimen
Position
75
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
0
0
10
15
20
(10 cm /s)
Fig. 13 Minute chloride ion diffusion coefficient(W/C =
0.55, specimen).
Vertical
distance(cm)
(cm
Vertical distance
Middle
(75 cm)
Bottom
( 5 cm)
25
Upper
(145 cm)
Diffusion Coefficient
20.80
10.00
8.50
of Cl-8
2
(10 cm /s)
Period (years)
3.47
7.22
8.47
Period: Number of years for the chloride ion to reach
the steel bar
80
60
150
Vertical
Verticaldistance
distance (cm)
194
75
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
0
0
40
1000
2000
20
0
6.00
7.00
8.00
(10 /s)
Fig. 14 Minute chloride ion diffusion coefficient (existing
concrete member).
195
Total corrosion
Total
corrosionrate
rate(mm/year)
(mm/year)
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
75
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
0
0
0.025
0.02
0.015
0.62 (% Bleeding)
0.01
1.08 (% Bleeding)
0.005
6.67 (% Bleeding)
0
0
2
4
6
Rate of oxygen permeability
-11
(10
150
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
Vertical
distance(cm)
(cm)
Vertical distance
150
50
100
50
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
0
0
0.005
0.01
0.015
100
Gap
150
mol/cm /s)
Concrete
Vertical distance
Vertical
distance(cm)
(cm)
0.03
Vertical
Vertical distance
distance (cm)
Vertical distance
distance (cm)
Vertical
(cm)
150
100
50
0.62 (% Bleeding)
1.08 (% Bleeding)
6.67 (% Bleeding)
0.005
0.01
0.015
0.005
0.01
0.015
196
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
Percentage bleeding
Lead wire
Lower steel
150
150
100
50
150
Upper steel
100
50
100
50
0.01
0.02
0.03
0.01
0.02
0.03
0.01
0.02
0.03
Vertical
distance
Height
(cm) (cm)
70
70
70
60
60
60
50
50
50
40
40
40
30
30
30
20
Temperature
10.2
22.2
31.4
10
20
Temperature
10.2
22.2
31.4
10
0
0
0
0.002
0.004
Microcell
Microcell Corrosion
corrosionRate
rate
(mm/year)
(mm/year)
0.002
0.004
Macrocell
MacrocellCorrosion
corrosionRate
rate
(mm/year)
(mm/year)
20
Temperature
10.2
22.2
31.4
10
0
0
0.002
0.004
Total
TotalCorrosion
corrosionRate
rate
(mm/year)
(mm/year)
Fig. 21 Microcell and macrocell corrosion rate distribution (existing concrete member).
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
k = A exp E a
RT
(8)
where k = rate constant, A = frequency factor, Ea = activation energy, R = ideal gas constant, T = temperature.
If we take the natural logarithm of the above equation
ln k = ln A Ea
RT
(9)
we get
1
ln k = Ea + ln A
R
(10)
0.06
Bleeding
% Bleeding
Ratio
0.62%
1.68%
1.08%
6.67%
0.05
0.04
0.03
0.02
0.01
0
10
20
30
40
50
197
0.004
Position
Upper
Middle
Lower
0.003
0.002
0.001
0
0
Temperature ( C)
10
20
30
40
Temperature (oC)
-1
Bleeding
% Bleeding
Ratio
- 1.2
0.62%
1.68%
1.08%
6.67%
- 1. 4
- 1.6
- 1.8
-2
- 2.2
- 2.4
3.1
3.2
3.3
3.4
1/Temperature x 1000
(1/K)
Fig. 23 Arrhenius plot (specimen).
3.5
-2.0
Position
Upper
Middle
Lower
-2.5
-3.0
-3.5
-4.0
3.2
3.3
3.4
3.5
3.6
198
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
5. Conclusion
The conclusions derived from the results of the laboratory and field investigations that were performed can be
summarized as follows
1. Bleeding significantly influences the minute properties of concrete. This is bolstered by the following
results obtained in laboratory and field investigations,
to wit:
The minute compressive strength of concrete
taken near the upper layer particularly on the
concrete specimen affected by high bleeding was
weaker by almost 50% compared to the strength
of concrete taken in the bottom layer. The minute
compressive strength of concrete along the horizontal direction was also 36% weaker than that
of concrete taken in the inner layer.
The tensile strength of the mortar aggregate matrix taken above the coarse aggregate was 34%
higher than the mortar aggregate matrix taken
underneath it.
The chloride ion diffusion coefficient in the upper layer of the concrete was 59 % higher than
the rate of chloride ion diffusion coefficient in
the bottom layer.
Variations in the quality of the concrete (in the
upper, middle and bottom layers), as a result of
bleeding have great influence on concrete resistance, on the same order as oxygen permeability.
Concrete resistance in the upper layer is 40-53%
lower than the bottom layer. On the other hand,
the rate of oxygen permeability at the upper layer
is 38% higher than in the bottom layer.
In general, concrete affected by bleeding has weaker
strength, higher permeability, lower concrete
resistance and higher oxygen permeability at or near
the surface layer.
2. Bleeding significantly influenced the macrocell and
microcell corrosion rates in the reinforcing bars.
Concentration difference in the upper layer of the
concrete due to bleeding causes higher rates of
corrosion in the vertical steel bars. Hence, due to the
trapping of bleed water under the horizontal steel bars,
gaps formed leading to the development of crevice
corrosion cell. The greater the area of the formed gap
the greater the rate of corrosion. Generally, macrocell
corrosion prevailed over microcell corrosion both in
vertical and horizontal steel bars.
3. The intensity of corrosion in concrete was generally
enhanced at elevated temperatures. This was
consistent with the theoretical expectation that
corrosion should increase with temperature.
Furthermore, the graphical relation between
temperature and corrosion rate, using the data derived
from the laboratory and field investigation is in full
agreement with the Arrhenius equation. Thus we can
state the principle that the logarithm of the corrosion
rate is linearly related to the reciprocal of the absolute
temperature.
References
Alexander, M. G., Mackechnie, J. R., Ballim Y. (2001).
Use of durability indexes to achieve durable cover
concrete in reinforced concrete structures. in
Materials Science of Concrete, Vol. VI, Mindness, S.,
and Skalny J. eds. The American Ceramic Society,
483-511.
Bentur, A., Diamond, S. and Berke, N. S., (1997).
Modern Concrete Technology 6 Steel Corrosion in
Concrete, Fundamentals and Civil Engineering
Practice. E & FN Spon (Chapman & Hall).
Bentur, A. and Odler, I. (1996). Development and
nature of interfacial microstructure in interfacial
transition zone in concrete. Maso, J.C. ed., RILEM
Technical Committee 108-ICC Report. Great Britain:
E & FN Spon (Chapman & Hall), 8-44.
Concrete Society (1984). Repair of Concrete Damaged
by Reinforcement Corrosion. London: The Concrete
Society, Report 26.
Jggi, S., Bhni, H. and Elsener, B. (2001). Macrocell
corrosion of steel in concrete Experiments and
numerical modelling. Eurocorr 2001. Riva di Garda,
Associazione Italia Mettalurgia, Milan.
Kropp, J. and Basheer, L. (2000). Assessment of the
durability of concrete from its permeation properties:
A review. P.A. M. Basheer Ed. Fifth CANMET/ACI
International Conference on Durability of Concrete,
Barcelona 65-79.
Melchers, R. E. (2002). Effect of temperature on the
marine immersion corrosion of carbon steels. NACE
International, 58(9), 768-774.
Mehta, P. K. and Monteiro, P. J. M. (1993). Concrete:
Structure, Properties & Methods. 2nd ed. New
Jersey: Prentice Hall.
Miyazato, S., Otsuki, N. and Kimura H. (2001).
Estimation method of macrocell corrosion rate of
rebar in existing concrete structures using
non-destructive tests. East Asia-Pacific Conference
(EASEC 8), 2, 531-542.
Nagataki, S., Otsuki N., Hisada, M. and Miyazato, S.
(1996). The experimental study on corrosion
mechanism of reinforced concrete at local repair
part. JSCE Proceedings, 544(32), 109-119.
Nolan, E., Basheer, P. A. M. and Long, A. E. (1995).
Effects of three durability enhancing products on
some physical properties of near surface concrete.
Construction Building Materials, 9(5), 267-272.
Mohammed, T. U., Otsuki, N., Hamada, H. and Yamaji,
T. (2002). Chloride-induced corrosion of steel bars
in concrete with presence of gap at steel-concrete
interface. ACI Materials Journal, 99(2), 149-156.
Tsuru, T., Maeda, R. and Haruyama, S. (1979).
Application of the alternating method to corrosion
monitor in local corrosion. Technology of Corrosion
Prevention , 28, 638-644.
Wainwright, P. J. and Ait-Aider, H. (1995). The
M. A. Baccay, T. Nishida, N. Otsuki, J. Hamamoto and K. Chin / Journal of Advanced Concrete Technology Vol. 2, No. 2, 187-199, 2004
199