Problem 1

Differential Vaporization at T = 229 oF

Pressure
(psig)
4140
3900
3600
3200
2800
2400
2000
1600
1200
800
400
170
0

Solution
Relative Oil
Gas/Oil
Gas
Oil
Volume
Ratio
Deviation Density
(bbl/STB)
scf/STB
Factor (z) (g/cc)
1.859
1404
0.616
1.790
1280
0.912
0.627
1.718
1144
0.890
0.639
1.640
992
0.872
0.653
1.571
855
0.863
0.667
1.511
733
0.866
0.679
1.456
621
0.875
0.962
1.405
516
0.889
0.704
1.356
414
0.910
0.717
1.308
318
0.938
0.730
1.251
213
0.968
0.746
1.210
142
0.986
0.757
1.079
0
0.791

0
Separator Tests

Gravity residual oil

34.100 oAPI

(@ 60oF)

Formation
Separator
Separator Stock Tank Stok Tank Volume
Pressure
Temperature
GOR
GOR
Gravity
Factor
o
(psig)
F
(scf/STB) (scf/STB) (oAPI)
(BoSb)
50
70
1144
36
37.9
1.694
100
70
1079
69
38.5
1.667
200
70
1007
135
38.5
1.666
200
70
911
262
38
1.687

(a)

P
T
API
Bo
Rs
o

0 psig
60 oF
34.1
1
0
0.857 g/cc

53.48108 lb/ft3

log(log oD +1 )=1 . 86530. 025086 API 0 . 5644 log(T )

log(log oD +1 )=1 . 86530. 025086 API 0 . 5644 log(T )

oD

1.034100067 cp

(at 60)

oD

0.299505593 cp

(at 229)

(b)

P
T

2400 psig
229 oF

B o = BoD
Bo

BoSb

1.354129 bbl/STB

R s = R sD
Rs
o
A=
B=
o

R sSb
R sDb

733*(1007+135)/1404

596.2151 SCF/STB

(c) Pb=

0.6793 g/cc
0.368111
0.581528

42.36794 lb/ft3
(Eq. B-55)
(Eq. B-56)

0.182597 cp

(Eq. B-54)

4154.7 psia

B o = BoDb
b

Bob
Rsb
ob
A=
B=
ob

(d)

1.511*1.666/1.859

BoDb

B o=
Bo
Rs

BoSb
= BoSb
BoDb
1.666 bbl/STB
1172 SCF/STB

0.616 g/cc
0.269887
0.479317

38.4384 lb/ft3
(Eq. B-55)
(Eq. B-56)

0.151431 cp

(Eq. B-54)

4600 psia

Vt
Vb

( )

BoSb

1.649173 bbl/STB
1172 SCF/STB

o
B

0.622285 g/cc
0.382528

38.83059 lb/ft3
(Eq. B-57)

0.157637 cp

(Eq. B-58)

Constant
Composition
Expansion Test at T =
229 oF
Presssure (psig)

Relative Volume

5000
4800
4600
4500
4400
4300
4200
4140
4110
4081
4007
3861
3648
3377
3097
2770
2458
2118

0.9825
0.9861
0.9899
0.9920
0.9941
0.9962
0.9985
1.0000
1.0021
1.0040
1.0093
1.0208
1.0399
1.0687
1.1075
1.1659
1.2441
1.3621

1825
1550
1216
920
667

1.5098
1.7070
2.0917
2.6855
3.6652

Problem 2
Pb
Rsb
s
T
API

3580 psia
1120 SCF/STB

2500 psia

0.84
156 F
39

Constants
Ao
9.73E-07 Bo
A1
1.672608 B1
A2
0.92987 B2
A3
0.247235 B3
A4
1.056052 B4

a1
a2
a3

4.33E-01
2.12E+00
4.76E-01

Pr
Rsr
Rs

0.698324
6.80E-01
7.61E+02 SCF/STB

0.022339
-1.00475
0.337711
0.132795
0.302065

Co
C1
C2
C3
C4

0.725167
-1.48548
-0.164741
-0.09133
0.047094

Problem 3
Pb
Rsb
s

3580 psia
1300 SCF/STB

P
T

4500 psia
210 oF

0.87

API

STO

41

0.823864

Constants for a

Constants for guess po

Ao
A1
A2
A3
A4
A5

-49.89300
85.01490
-3.70373
0.04798
2.98914
-0.03569

Co
C1

52.8
-0.01

po

39.8

po
a

41.207988 lbm/ft
3
24.746733 lbm/ft

po

3
41.208014 lbm/ft

Target

2.70E-005

p =

1.86

lbm/ft3

T =

-5.13

lbm/ft3

or =

37.94

lbm/ft3

Problem 4
Pb
Rs
g

3600 psia
1500 SCF/STB

P
T

3200 psia
210 oF

0.87

API
or

STO

43
lbm/ft

36.50

STO
Bo

0.814607

3
50.807022 lbm/ft

1.87715

(Eq. 11-5)

Plus derivation of the equation

Problem 5
Trial Bubble Point Pressures
1500
1400
1300
Comp
C1

mj (lbm)

Mj

zj

nj=mj/Mj

zjKj

zjKj

zjKj

16.043

0.062332

0.3748

0.858703 0.907601 0.963834

nC4

58.123

0.06882

0.4138

0.074427 0.071294 0.068607

C10

5 142.285

0.035141
0.166293

0.2113
1.0000

0.001143 0.000944 0.000784

0.934273 0.979839 1.199096

pb is between 1400 and 1300 psia

-0.219257
-0.020161

100
D

VLE at

P=
T=
zj

pb

500 psia
100 oF

ng
xj

yj

5.909

0.7515

0.1531

0.9045

0.4138458

0.174

-0.4522

0.5473

0.0951

0.2113185
1

0.00115

-0.2993
0.0000

0.2996
1.0000

0.0003
1.0000

0.3748357

nC4
C10

psia

9.19509

yj - xj

Comp
C1

Kj

1390.805

0.295091

Pressure
(psia) KC1

KnC4

KnC10

1500

2.291

0.180

0.00541

1400

2.421

0.172

0.00447

1300
1200
1100
1000
900
800
700
600
500
400
300
200
100
14.7

2.571
2.746
2.952
3.199
3.500
3.877
4.361
5.006
5.909
7.263
9.519
14.029
27.530
185.576

0.166
0.160
0.156
0.153
0.152
0.153
0.156
0.162
0.174
0.194
0.231
0.309
0.552
3.359

0.00371
0.00309
0.00259
0.00218
0.00185
0.00161
0.00141
0.00124
0.00115
0.00111
0.00113
0.00131
0.00200
0.01037

Problem 6
Calculation of Stock Tank Gas-Liquid Equilibrium
Pressure
(psia)
pST =

TST =

0 psig

60 oF

zjKj =

Trial ng = 0.7119191

zj/Kj =

yj - xj

xj

yj

Mj

1300
1200
1100

164.021

0.5220

0.0032

0.5252

16.043

1000

0.4138458

1.766

0.2051

0.2678

0.4729

58.123

900

0.2113185
1.0000

0.00252

-0.7271
0.0000

0.7290
1.0000

0.0018
1.0000

142.285

800
700
600

1.249

500
400
300
200
100
14.7

zj

Comp
C1

0.3748357

nC4
C10

Kj

62.21

1500
1400

g =

Calculation of Stock Tank Liquid Density

Lj

Comp
C1

zj

Mj

Mass

0.0032

16.043

0.051

nC4

0.2678

58.123

15.565

36.425

0.427

C10

0.7290
1.0000

142.285

103.724
119.341

45.023

2.304
2.731

14.7 & 60oF

3
Density of C3+ =
43.68 lbm/ft
W1 = 4.3E-04
W2 = 0.0E+00
3
Density of STO =
43.66 lbm/ft

Gravity of STO =

70.6

Molar mass of STO =

119.3

Volume

83.94

API
lbm/lbm.mole
o

KC1

KnC4

KnC10

2.291
2.421

0.180
0.172

0.00541
0.00447

2.571
2.746
2.952

0.166
0.160
0.156

0.00371
0.00309
0.00259

3.199

0.153

0.00218

3.500

0.152

0.00185

3.877
4.361
5.006

0.153
0.156
0.162

0.00161
0.00141
0.00124

5.909
7.263
9.519
14.029
27.530
185.576

0.174
0.194
0.231
0.309
0.552
3.359

0.00115
0.00111
0.00113
0.00131
0.00200
0.01037

164.021

1.766

0.00252

TWO-STAGE SEPARATION CALCULATION

pR =

TR =

1400 psia

100 oF

Step 1: Calculation of Separator Gas-Liquid Equilibrium

pSEP =
Trial ng =
Comp
C1

TSEP =

105 psig

zjKj =

0.4465
mj (lbm)

Mj

nj=mj/Mj

Maria Barrufet
These are either given
to you or you must
evaluate them from
correlations...

80 oF
zj/Kj =

8.58

399.91

zj

Kj

yj - xj

xj

yj

16.043

0.0623325

0.3748

22.5

0.7604

0.0354

0.7957

nC4

58.123

0.0688196

0.4138

0.35

-0.3790

0.5830

0.2041

C10

5 142.285 0.0351407
0.1662928

0.2113
1.0000

0.00053

-0.3814
0.0000

0.3816
1.0000

0.0002
1.0000

Next ng =

g =

0.4465

Maria Barrufet
target to be zero
changing ng (cel

0.851

Step 2: Calculation of Stock Tank Gas-Liquid Equilibrium

pST =
Trial ng =

TST =

0 psig

zjKj =

0.2345

60 oF
7.00

zj/Kj =

319.33

Comp
C1

zj

Kj

yj - xj

xj

yj

Mj

0.0354

170

0.1471

0.0009

0.1480

16.043

nC4

0.5830

1.7

0.3506

0.5008

0.8514

58.123

C10

0.3816
1.0000

0.0012

-0.4977
0.0001

0.4983
1.0000

0.0006
1.0000

142.285

Next ng =

0.2345

g =

1.794

Step 3: Calculation of Stock Tank Liquid Density

Lj

Volume

29.111

36.425

0.799

70.896
100.021

45.023

1.575
2.374

Comp
C1

zj

Mj

Mass

0.0009

16.043

0.014

nC4

0.5008

58.123

C10

0.4983
1.0000

142.285

Density of C3+ =
lbm/ft3
42.13
W1 = 1.4E-04
W2 = 0.0E+00
lbm/ft3
Density of STO =
42.12

Maria Bar
These are e
to you or y
evaluate th
correlation

Gravity of STO =
Molar mass of STO =

78.0
100.021

API
lbm/lbm.mole
o

Step 4: Calculation of Gas-Oil Ratio

RSEP =

948.4

Scf/STB

RST =
R=

275.7
1224.1

Scf/STB
Scf/STB

2138 { ngl sto

RSP=

n L1 n L2 M STO

2138 { n g2 sto
RST =

nL2 M STO

2138 { n g2 sto
RST =

nL2 M STO

Step 5: Calculation of Reservoir Liquid Density

Lj

Volume

24.054

36.425

0.660

30.067
60.135

45.023

0.668
1.328

Comp
C1

zj

Mj

Mass

0.3748

16.043

6.013

nC4

0.4138

58.123

C10

0.2113
1.0000

142.285

Density of C3+ =

lbm/ft3
40.75
W1 = 1.0E-01
W2 = 0.0E+00
po =
lbm/ft3
34.86
p =

0.94

lbm/ft3

T =

-1.78

lbm/ft3

or =

34.02

lbm/ft3

Molar mass of STO =

60.1

lbm/lbm.mole

Step 6: Calculation of Formation Volume Factor

Bo =

1.757

RB/STB

B ob =

M oR STO
M STO oR nL1 nL2

Maria Barrufet
Study questions are hidden in coment
cells. Make sure you study al for the test

Maria Barrufet
These are either given
to you or you must
evaluate them from
correlations...

Maria Barrufet
target to be zero, by
changing ng (cell b9)

Maria Barrufet
These are either given
to you or you must
evaluate them from
correlations...

2138 { n g2 sto
RST =

nL2 M STO

2138 { n g2 sto
RST =

nL2 M STO

STO

nL1 nL2
R