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Chapter 6
Paper 1
Answer all questions. Each question is followed by four options, A, B, C and D. For
each question, choose one answer only.
1)
2)
C Aluminium
D Hydrogen chloride
Zinc plate
Copper
plate
Silver
plate
Lead plate
iron plate
Iron plate
3)
Iron plate
Iron plate
The diagram below shows the apparatus that is used to electroplate iron nail with copper.
What can be observed at the copper plate and the iron nail at the end of the experiment?
Copper plate
Iron nail
A
Thinned
Brown solids are deposited
B
Thickened
Brown solids are deposited
C
Thinned
Gas bubbles are released
D
Gas bubbles are released
Brown solids are deposited
4)
A dilute copper(II) chloride solution is electrolysed using carbon electrodes. Which of the
following occurs at the anode and cathode respectively?
Anode
Cathode
A Copper metal is deposited
Oxygen is released
B Oxygen is released
Copper metal is deposited
C Chloride is released
Oxygen is released
D Oxygen is released
Copper metal is deposited
5)
Sodium sulphate solution is electrolysed using carbon electrodes. What is the product
formed at the cathode and anode respectively?
Cathode
Anode
A Oxygen
Hydrogen
B Sodium
Oxygen
C Hydrogen
Sulphur dioxide
D Hydrogen
Oxygen
6)
7)
The diagram below shows the apparatus arrangement for the electrolysis of the dilute
lead(II) nitrate solution.
C Oxygen
D Hydrogen
8)
The voltmeter shows a reading of 1.1 V. What is the possible reading of the voltmeter if
the zinc plate is replaced with a lead plate?
A 0.7 V
C 1.2 V
B 1.1 V
D 2.1 V
9)
The diagram below shows the apparatus set-up that is used in an electrolytic process.
Electrolysis is carried out on a dilute nitric acid by using platinum electrodes. The gas
that is released at the cathode
A turns lime water cloudy
B lights up a glowing wooden splint
C bleaches a moist red litmus paper
D produces a pop sound with a lighted wooden splint
11)
During the electrolysis of a copper(II) sulphate solution using copper electrodes, the ions
that are attracted to the cathode are
A hydroxide ions
B hydrogen ions
C copper(II) ions
D copper atoms
12)
13)
When a copper plate is placed into dilute hydrochloric acid, no reaction occurs. This is
because
A hydrogen is not a metal
B the mixture needs to be heated
C copper is more electropositive than hydrogen
D hydrogen is more electropositive than copper
14)
Which of the following equations represents the reaction that occurs at the negative
terminal of a mercury cell?
A Pb Pb2+ + 2eB Pb2+ + 2e- Pb
C Zn Zn2+ + 2eD Zn2+ + 2e- Zn
15)
Paper 2
Answer all the questions.
Structured question
The diagram below shows the apparatus set-up that is used to study the electrolysis of dilute
potassium chloride solution.
(a) (i)
(ii)
(b) (i)
(ii)
Use the words anode and cathode to label the diagram above.
Write the formula of the ions that move to the anode and cathode of the
electrolytic cell in the table below.
Anode
Cathode
(c) State the observation at the anode and cathode of the cell.
_______________________________________________________________
(d) (i)
Name gas X.
__________________________________________________________
(ii)
(iii)
(e) If 36 cm3 of gas X is collected at the end of experiment, calculate the number of
molecules of gas X that is collected.
[Molar volume = 24 dm3 at room conditions; NA = 6.02 x 1023 mol-1]
(f) State the ratio of the volumes of gas X and gas Y that are collected.
_________________________________________________________________
Essay question
(a) You are given two electrolyte solutions as listed below.
Explain why the product collected at the anode of the cell is different but the product
collected at the cathode of the cell is the same, if both the electrolyte solutions are
electrolysed using carbon electrodes.
(b) A student wants to purify an impure copper plate by the process of electrolysis.
Design an experiment in the laboratory to purify the impure copper plate.
Your answer should include the following:
Materials and apparatus needed
Diagram of the apparatus set-up
Procedure of the experiment
Observation
Chemical equation involved
Paper 3
Answer the question.
A student carried out an experiment to study the potential difference between two
different types of metal. The apparatus set-up that is used in the experiment is shown
below.
Before the experiment
(a) Fill in the table below by stating the observation and inference involved in the
experiment.
Metal plate
Zinc
Iron
Observation
Inference
(b) The student repeated the experiment by replacing the iron metal with copper metal,
aluminium metal and magnesium metal.
Metal pairs
Negative terminal
Positive terminal
Voltage / V
Zinc iron
Zinc
Iron
0.4
Zinc copper
Zinc
Copper
1.1
Zinc aluminium
Aluminium
Zinc
0.8
Zinc magnesium
Magnesium
Zinc
1.4
Action to be taken
(i) Way to change the manipulated variables
(c)
(d)
If the experiment is repeated by using lead metal to replace iron metal, predict the
possible reading recorded by the voltmeter.
Answers
Paper 1
1
B
2
C
3
A
4
B
5
D
6
B
7
C
8
A
9
B
10
D
11
12
13
14
15
C
A
D
C
B
Paper 2
Structured question
(a) (i) Positively charged ions
(ii) Electrical energy to chemical energy
(b) (i) Anode: On the left side; Cathode: On the right side
(ii) Anode: Cl- and OH-; Cathode: K+ and H+
(c) Anode: Colourless bubbles are released
Cathode: Colourless bubbles are released
(d) (i) Oxygen
(ii) Insert a glowing wooden splint into the test tube. The wooden splint lights up.
(iii) 4OH- 2H2O + O2 + 4e(e) Number of moles of gas X = 36 = 0.0015 mol
24000
Number of molecule of gas X = 0.0015 x 6.02 x 1023
= 9.03 x 1020 molecules
(f) 1 : 2
Essay question
(a)
Dilute sodium chloride solution
Product collected at
the anode
Explanation
Oxygen
Product collected at
the cathode
Explanation
Hydrogen
(b) Material: Impure copper plate, pure copper plate, copper(II) sulphate solution
Apparatus: Battery, connecting wires with crocodile clips, ammeter, rheostat, beaker
Procedure:
- Impure copper plate is used as the anode
- Pure copper plate is used as the cathode
- Copper(II) sulphate solution is used as the electrolyte
- The circuit is completed by allowing the electric current to flow through the
electrolyte
Observation:
Anode: Impure copper plate dissolves / is corroded/ is thinned
Cathode: Pure copper plate is thickened / brown solids are deposited
10
Chemical equations:
Anode: Cu Cu2+ + 2eCathode: Cu2+ + 2e- Cu
Paper 3
(a)
(b)
(c)
(d)
Metal plate
Zinc
Observation
Dissolved
Iron
Inference
Zinc loses electron to form
zinc ion
Copper(II) ion receives
electrons to form copper
metal
11