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Article history:
Received 19 May 2015
Received in revised form 20 July 2015
Accepted 10 August 2015
Available online 14 August 2015
Keywords:
PEM fuel cell
CHP
Building cogeneration
a b s t r a c t
A simplied model of a polymer electrolyte membrane (PEM) fuel cell has been suggested for simulating
packaged commercial fuel cell systems. PEM fuel cell systems are used in building cogeneration applications because of their high efciency, low transmission loss and pollution, exible scalability, and low
noise. In conventional cogeneration applications, optimization techniques are utilized to size a system
and determine proper operational strategies using simulations. To evaluate the performance of a building cogeneration system, a fuel cell model should be concise but accurate to allow its implementation in
a whole-building simulation program. Some existing models are appropriate for building applications,
but they have some limitations in modeling when a commercial packaged fuel cell system is used. To
overcome these problems, a simplied fuel cell model is suggested for commercial packaged fuel cells by
adding some new variables and validating through experimental and published data. This model is relatively simple compared to other models but can be easily utilized in some limited cases with performance
predictions.
2015 Elsevier B.V. All rights reserved.
1. Introduction
Combined heat and power (CHP), which simultaneously generates heat and power, has been extensively used recently owing to
its high efciency [1]. In addition, when CHP systems are used at
a micro-scale or in a distributed manner (i.e., decentralized energy
generation), their efciency in terms of primary energy is maximized owing to their low transmission and heat losses [24].
Recently, among many applicants in micro CHP systems, fuel cell
systems have proved to be attractive in many aspects, including
the facts that they have high electrical efciency because of direct
conversion from fuel to electricity, low pollutant emissions, exible
scalability, and production of low noise during generation [4].
Numerous recent studies [514] have focused on the building cogeneration applications of polymer electrolyte membrane
(PEM) fuel cells (also known as proton exchange membrane fuel
cells) because they have high power density (small stack size), high
cogeneration efciency (sum of heat and power), and fast startup
time owing to their low operating temperature [4,15,16].
In general building cogeneration applications, PEM fuel cell systems generate power for buildings, and the recovered heat is used
for domestic hot water or heating. However, in the summer, the
Corresponding author.
http://dx.doi.org/10.1016/j.enbuild.2015.08.023
0378-7788/ 2015 Elsevier B.V. All rights reserved.
214
Nomenclature
a0 , a1 , a2 model coefcients
b0 , b1 , b2 model coefcients
BX
xed (bias) uncertainty
specic heat of water (kJ/kg K)
cp,w
LHVfuel lower heating value of fuel (kJ/kmol)
n
number of measured data
molar ow rate of fuel (kmol/s)
N fuel
p
number of predictors in the model
PAC,anc
parasitic AC power (kW)
PAC,net
net generated AC power (kW)
PAC,net,nom rated maximum power from manufacturer (kW)
PAC,net,rated rated power at part-load condition from manufacturer (kW)
PAC,PCU generated AC power after PCU (kW)
PAC,ref
generated AC power at reference condition (kW)
net generated DC power (kW)
PDC,net
P*
dimensionless power ()
P gen,start average power generation in startup mode (kW)
P use,start average power use in startup mode (kW)
PCU
power conditioning unit
PLR
part-load ratio ()
recovered heat (kW)
Q
Q fuel
caloric value of fuel (kW)
Q fuel,ref caloric value of fuel at reference condition (kW)
recovered heat at reference condition (kW)
Q ref
Q
dimensionless recovered heat ()
Q fuel
dimensionless caloric value of fuel ()
r0 , r1
model coefcients
random (precision) uncertainty
SX
Tw,in , Tw,out inlet/outlet temperature of stack cooling water
( C)
UX
overall uncertainty
V fuel
fuel volume ow rate (m3 /s)
(m3 /s)
molar volume of fuel (m3 /kmol)
water volume ow rate (m3 /s)
measured value
average value of measure data
predicted value by the model
Greek symbols
,
model coefcients
0 , 1 , 2 model coefcients
DC,net
electrical (DC) efciency of fuel cell
PCU
PCU efciency
density of water (kg/m3 )
w
in practice, the fuel cell model must be accurate but simple and
implementable in a whole-building simulation.
A few researchers have developed simplied PEM fuel cell models for building applications. However, these models have some
limitations in practice because they are based on simple linear
assumptions [22,31] or a stack polarization curve without balance of plant [10,16,3237]. In response, a simple and empirical
fuel cell model for building cogeneration simulation was developed in the Annex 42 project of the International Energy Agency
[38]. The model was basically developed for a solid-oxide fuel
cell system [39] but was extended to a PEM fuel cell system
[40]. The Annex 42 model is concise but accurate; however, it
has been noticed that a more simplied model is necessary for
practical implementations. Specically, in real applications, residential fuel cells are available off the shelf, and only limited
parameters can be modied in this case without disassembling the
package.
In this present research, a simplied PEM fuel cell model is
suggested based on the Annex 42 model. The model aims at a commercial PEM fuel cell system in which the Annex model is difcult to
implement. With seven measurable variables (e.g., design capacity,
AC power), the model predicts power, heat, and fuel consumption of
a fuel cell system by mapping performance curves through regressions. Although this model is not as specic as that in Annex 42, it
can be applicable to commercial fuel cells because it is manufactured with preprogrammed capacity controls (i.e., less performance
variations and part-load mode operation). First, in this research, a
simplied PEM fuel cell model based on other fuel cell models [40]
is derived, and then the proposed model is validated by experimental measurements. The model is also validated by measurement
data acquired from open literature.
approach is to use performance-based modeling because commercial fuel cell systems are manufactured and preprogrammed in a
factory [27,39,47].
PDC,net
DC,net LHVfuel
=
2.1. Motivations
Our proposed model is based on the quasi-dynamic PEM fuel cell
model developed as part of Annex 42 by the International Energy
Agency [38,40]. This model is a simple but accurate empirical model
whose purpose is to serve as a general model to be integrated into
and interoperable among various building energy simulation programs, thereby enabling overall performance evaluation of building
cogeneration systems. Although this model is relatively concise
and can be integrated into whole-building simulation programs,
we found that some commercial fuel cell systems have limitations
with regard to this model.
In a commercial fuel cell system, all components of the system
are assembled into one package including balance of plant (e.g.,
reformer), and it is impossible to disassemble the whole package
and model each component owing to safety and security concerns.
Moreover, the system has preprogrammed capacity control algorithms because the use of dynamic capacity control on the fuel cell
in order to meet load changes is unnecessary in stationary applications. This is because the overriding design criteria in stationary
fuel cells are durability and stable operation [4850]. Thus, regardless of the fuel cells operational strategy (e.g., electricity-led or
heat-led operation), auxiliary heaters and thermal storage, as well
as electricity storage such as capacitors and batteries, are utilized
for handling variations in electricity and heat demand [21,51,52].
This is very common in any CHP design [15,32,53]. For this reason, a
typical capacity control algorithm for a commercial fuel cell aims to
regulate the current density [54] to meet the required constant AC
power by using a DC-DC converter and a DC-AC inverter [51,55,56].
Thus, many commercial fuel cells have preprogrammed capacity control algorithms (i.e., preset turn-down or part-load ratios).
Finally, the power and heat generation of commercial fuel cell packages sometimes differs from the design capacity (in laboratory)
after installation. Therefore, the simplied model aims at commercial fuel systems in which application of the Annex model is limited
and new parameters of part-load ratio and AC power output are
used.
(1)
In the Annex 42 model, the measured PDC,net and fuel consumption N fuel are used to estimate electrical efciency (DC,net , see Eq.
(2)). In addition, the model suggested that DC,net can be correlated
with a second-order polynomial in terms of PDC,net . However, when
we used a previously reported dataset [40], we found that 1 and 2
have relatively small values compared to 0 , and the relationship
between PDC,net and N fuel was almost linear. According to this correlation, we can conclude that the fuel consumption is a rst-order
function with respect to PDC,net because the lower heating value of
215
PDC,net
PDC,net
1
LHVfuel 0 + 1 PDC,net + 2 P 2
0
DC,net
(2)
PAC,net,rated
PAC,net,nom
(3)
PAC,net
PAC,ref
(4)
P = a0 + a1 PLR + a2 PLR2
(5)
(6)
(7)
216
1.2
Heat
0.8
Operating point
0.4
Power
0
0
0.4
0.8
1.2
1.6
Current density(A/cm2)
Fig. 1. General polarization curve of a single cell.
PAC,net + Q
= r0 + r1 PLR(Tw,in + Tw,in )
PAC,ref + Q ref
(8)
217
=
Q fuel
Q fuel
Qfuel,ref
(9)
= b0 + b1 PLR + b2 PLR2
Q fuel
(10)
V
LHVfuel
Q fuel = fuel
Vm
(11)
3. Model validation
Fig. 3. Structure of the simplied PEM fuel cell model.
218
Table 1
Fuel cell system summary.
Location
Type
Rated AC power
Rated heat
Balance of plant
Fuel
Capacity control
Table 4
Investigated test sets.
PLR
0.6
1
20 C
25 C
30 C
35 C
40 C
interval were used for the xed (bias) uncertainty (BX ) and the
random (precision) uncertainty (SX ), respectively:
Table 2
Measured variables and corresponding sensors used.
UX =
Measured variable
Sensor
Specications and
accuracy
1% of measure
value
Digital electricity
meter
(LD3410DR-040, LSIS)
T-type thermocouple
(MV2000, Yokogawa)
T-type thermocouple
(MV2000, Yokogawa)
Ultrasonic ow meter
(TFM 100, Taehung
M&C)
Gas meter
(G2.5L, Daesung)
Obtained from
supplier
(http://www.kogas.or.kr)
200 to 400 C
(0.15% + 0.7 C) of
measure value
200 to 400 C
(0.15% + 0.7 C) of
measure value
1% of measure
value
0.0254 m3 /h
1.5% of measure
value
Monthly average
LHV (kJ/m3 )
2% of measured
value
Table 3
Overall uncertainty of variables.
PAC,net
Q
Q Fuel
Tw,in
Tw,out
V w
Min 0.06 kW 0.19 kW 0.33 kW 0.72 C 0.73 C 0.0025 l/s
Max 0.15 kW 1.48 kW 2.00 kW 0.89 C 1.04 C 0.0028 l/s
V Fuel
0.0005 m3 /min
0.0025 m3 /min
BX2 + tSX
2
n
2
1 1
SX =
Xi X
n
n1
(12)
(13)
i=1
219
Fig. 5. Performance map of tested fuel cell. (For interpretation of the references to colour in this gure citation, the reader is referred to the web version of this article.)
CV (RMSE) =
i=1
n
ymeasured,i y predicted,i
y measured
np
2
100 [%]
(14)
i=1
MBE =
ymeasured,i y predicted,i
y measured (n p)
100 [%]
(15)
Table 5
Model coefcients of tested fuel cell.
Reference
conditions
Equations
Power:
8.72 kW
Power (Eq.
(5))
Heat + power
(Eq. (8))
P* = 0.2367 + 0.7575PLR
R2 = 0.9817
P Q = 0.1572 +
1.493PLR(0.0008274Tw,in
0.0809
+ Tw,in
)
Fuel (Eq.
(10))
Range of
model
R2 = 0.9992
Q fuel
=
0.1938 + 1.1913PLR
2
R = 0.9982
PLR: 0.6, 1
Heat:
7.59 kW
Fuel:
40.6 kW
Tw,in : 15.140.3 C
part-load ratio, the predicted AC power and fuel consumption values agreed well with the measured values (Figs. 6 and 7). The main
reason is that the algorithm for stack capacity control is based on AC
power, and the fuel consumption actually depends on the stacks
fuel demand. As a result, the model yielded CV(RMSE) values of
2.6% and 1.89% for power and fuel, respectively, and an MBE value
of nearly zero for both of these parameters.
The predicted and measured values of recovered heat were
compared (Fig. 8). The heat recovery model agreed well with the
measured data, and all tested data fell within the 10% error bound.
The error of the heat recovery model was noticeably larger than
that of the other variablesnamely, power and fuel. In fact, the
heat recovery model predicted the sum of power and heat, not the
heat itself, and thus the predicted heat included the error of the
power model. Furthermore, the uncertainties associated with the
measurements of heat were noticed to be relatively large. The main
reason for this is the poor sensor accuracy of the water temperature. Because the heat generation was estimated based on Eq. (6),
the errors of each variable were propagated with changes in temperature, leading to large uncertainties. In spite of the cycling and
large uncertainty, we observed that the 1 h average of produced
220
10
CV(RMSE) = 2.6%
MBE = 0%
PAC,net,measured [kW]
5% error bound
Reference
conditions
Equations
Power: 0.9745 kW
Power (Eq.
(5))
P* = 0.082 + 1.2194PLR
0.221PLR2
R2 = 0.9988
P Q = 0.0125 +
0.6907PLR(0.01519Tw,in +
0.1953
)
Tw,in
Heat + power
(Eq. (8))
Fuel (Eq.
(10))
0
0
10
Range of
model
Heat:
0.1538 kW
R2 = 0.9981
Q fuel
= 0.1456 +
0.6162PLR + 0.2348PLR2
2
R = 0.9993
PLR: 0.251
Fuel:
0.2941 kW
Tw,in : 16.159.1 C
PAC,net,predicted [kW]
1
CV(RMSE) = 1.43%
MBE = 0%
50
40
Qfuel,measured [kW]
PAC,net,measured [kW]
0.8
CV(RMSE) = 1.89%
MBE = 0.32%
30
5% error bound
20
0.6
0.4
5% error bound
0.2
0
0
10
0.2
0.4
0.6
0.8
PAC,net,predicted [kW]
0
0
10
20
30
40
50
Qfuel,predicted [kW]
3
CV(RMSE) = 1.08%
MBE = 0.01%
2.5
10
Qmeasured [kW]
Qfuel,measured [kW]
CV(RMSE) = 5.12%
MBE = -0.2%
1.5
1
5% error bound
0.5
0
0
0.5
1.5
2.5
Qfuel,predicted [kW]
0
0
10
Fig. 10. Fuel model validation with experimental data from [40].
Qpredicted [kW]
Fig. 8. Heat recovery model validation with experimental data.
heat was relatively constant. The CV(RMSE) value of this model was
5.12%, and this value was within the acceptable range [64].
3.5. Model validation on literature data
The simplied model was also validated based on data from the
literature [40]. The coefcients of the simplied model (Eqs. (5), (8)
2
CV(RMSE) = 3.2%
MBE = 0.01%
CV(RMSE) = 3.2%
MBE = 0.01%
1.6
Qmeasured [kW]
221
1.2
Mode
Duration
time
Values
Description
Start-up
3h
P use,start : 2.4 kW
Electricity
consumption
Electricity generation
in the fuel cell
0.5 h
Start-up
0.8
5% error bound
P gen,start : 5.3 kW
Start-up
3h
V fuel,start : 0.00018055 m3 /s
Shut-off
2h
Gas consumption in
start-up mode
At least 2 h is required
to start after shut-off
0.4
0
0
0.4
0.8
1.2
1.6
Qpredicted [kW]
Fig. 11. Heat recovery model validation with experimental data from [40].
AC power is generated according to the preprogrammed partload ratio, and the fuel is consumed accordingly. As a result, the
CV(RMSE) values were 1.43% and 1.08% for power and fuel modeling, respectively, which were within the acceptable range of less
than 5% [64]. In addition, the MBEs were almost 0% for both models.
These results also indicate that it is acceptable to directly predict
AC power rather than the DC power.
Fig. 11 compares the measured and predicted values of the heat
recovery model. Unlike the power and fuel models, the recovered
heat was affected by the temperature of the stack cooling water,
and scattered data were observed. The heat recovery model was
quite accurate and yielded an acceptable CV(RMSE) value of 3.2%
(<5%) and an MBE of nearly 0%.
that, it generated approximately 2.65 kWh of electricity and consumed 0.85 m3 of fuel for 30 min. Not shown in Fig. 12, the system
also consumed electricity because it did not generate electricity
during this period. In both modes, the system consumed 2.4 kW on
average. These values are summarized in Table 7.
The operational characteristics of the system in part-load
change mode are shown in Fig. 13. As shown in Fig. 13a, 610 kW
change mode takes 20 min, and 106 kW change mode takes 5 min.
In addition, shutoff mode takes less than 10 min to stop consuming
fuel and generating electricity. However, the manufacturer prevents the fuel cell from being turned on again for 2 hours from
shutoff mode for safety reasons (cool-down time). Both part-load
change and shut-off modes are completed in 1020 min. The experimental results of startup, part-load change, and shutoff modes are
similar to the data in [60].
The default time steps for whole-building simulation programs
such as EnergyPlus [45] and TRNSYS [37] are 15 and 60 min, respectively. Thus, only generation/consumption of electricity and fuel in
startup mode must be considered in annual simulation. However,
the time required by shutoff mode must be considered even though
there is no fuel consumption.
10
0.06
10
0.04
6
4
Warm up period
0.02
8:26
8:47
9:08
9:29
9:50
10:11
10:32
10:53
0.07
Electricity
Fuel
Electricity
Fuel
0.06
8
0.05
6
0.04
0.03
4
Warm-up period
0.02
2
0.01
0
5:46
6:07
6:28
6:49
7:10
Time
Time
(a) 6 kW start
(b) 10 kW start
Fig. 12. Transient characteristic start mode.
7:31
7:52
0
8:13
0.06
0.06
Electricity
Fuel
0.045
0.04
7
0.035
Electricity
Fuel
13:03
13:09
13:15
13:21
0.03
0.05
8
0.055
Mode change (6 to 10 kW)
0.055
0.05
8
0.045
0.04
7
0.035
0.03
0.025
13:27
15:00
15:06
Time
15:12
15:18
222
0.025
15:24
Time
(a) 6 kW to 10 kW
(b) 10 kW to 6 kW
Fig. 13. Transient characteristic part-load change mode.
Required electricity
Required heating energy
Hot water temperature
Hot water flow rate
Time step information
Building
surface
model
Building
system
model
Building
airflow
model
Net electricity
Net fuel consumption
Hot water temperature
Heat
recovery
model
Auxiliary device
Fuel
model
In fuel cell:
Generated electricity
Generated heat
Fuel consumption
Fuel cell
operational schedule
or
control algorithm
Thermal storage
constraints for safe
operation in fuel cell
(e.g., min and max
temperature in
thermal storage)
Thermal or electric
storage model
Thermal
Storage
energy
balance
Fuel cell
Auxiliary
cooler
Auxiliary
boiler
Net electricity
Net heating energy
Temperature change in storage
Electricity changes in battery
Electricity
battery
energy
balance
hot water information (if heating is implemented by hot water circulation with a fuel cell system). The fuel cell model then estimates
electricity and heating energy generation in the current time step
by using Eqs. (4)(11) based on the fuel cells control algorithm.
In general, schedule-based fuel cell operation (grid-connected) is
used in stationary applications for reliable operation. In most cases,
there are mismatches in electricity and heating demand between
the building and the fuel cell system. Thus, models for the electricity battery (if it exists) and thermal storage are necessary. In
these models, the net required electricity from the grid and heating
energy from the auxiliary boiler are estimated. Moreover, the temperature changes in the thermal storage must be calculated because
the performance of the fuel cell is affected by this factor. Finally,
there might be minimum or maximum constraints for hot water
temperature (stack coolant) in the fuel cell system. If a fuel cell auxiliary cooler or heater is installed for these reasons, the energy used
in these devices is added to the net electricity and heating energy
demand, and some information such as hot water temperature is
transferred to the next time step.
223
10
8
6
4
2
0
-2
9 10 11 12 13 14 15 16 17 18 19 20 21 22 23
-4
-6
-8
Start-up mode
-10
6 kW mode
10 kW mode
Time [hr]
Electricity demand (building) [kW]
41
40
39
38
37
0
-2
9 10 11 12 13 14 15 16 17 18 19 20 21 22 23
36
-4
35
-6
34
-8
33
-10
32
Time [hr]
Heating demand [kW]
Table 8
Comparison of different fuel cell models for building cogeneration.
Model
Modeling method
Applications
Limitations
Dynamic
models
[30,41,44]
Physical model
based on
electrochemistry
TRNSYS [37]
Annual simulation
and control
Annex 42 [40]
Physical model
based on
electrochemistry
Empirical model
Modeling
difculties and
interoperability
with building
simulation
program
Model is limited to
the stack
Present study
Empirical model
Annual simulation
and control for
general fuel cell
system
Annual simulation
and control for
commercial fuel
cell package
Steady-state
model, each
component should
be modeled
Steady-state model
and limited to the
commercial
package
224
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