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Abstract
Lead-free (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3x%CeO2(BCZTxCe) piezoelectric ceramics have been prepared by the traditional ceramic process and
the effects of CeO2 addition on their phase structure and piezoelectric properties have been studied. The addition of CeO2 significantly improves
the sinterability of BCZT ceramics which results in a reduction of sintering temperature from 1540 8C to 1350 8C without sacrificing the high
piezoelectric properties. X-ray diffraction data show that CeO2 diffuses into the lattice of BCZT and a pure perovskite phase is formed. SEM
images indicate that a small addition of CeO2 greatly affects the microstructure. Main piezoelectric parameters are optimized at around
x = 0.04 wt% with a high piezoelectric coefficient (d33 = 600 pC/N), a planar electromechanical coefficient (kp = 51%), a high dielectric constant
(er = 4843) and a low dissipation factor (tan d = 0.012) at 1 kHz, which indicates that the BCZTxCe ceramics are promising for lead-free practical
applications.
# 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Keywords: A. Sintering; C. Piezoelectric properties; Dielectrics; Lead-free ceramics
1. Introduction
It is well known that lead zirconate titanate (PZT) ceramics
have widely been used for piezoelectric actuators, sensors and
transducers due to their excellent piezoelectric properties close
to the morphotropic phase boundary (MPB) between rhombohedral and tetragonal. Nevertheless, they are not environmental
friendly for their lead oxide toxicity. With recent growing
demand of global environmental protection, many researchers
have greatly focused on lead-free ceramics to replace the leadbased ceramics [13].
The newly discovered lead-free Ba(Zr0.2Ti0.8)O3
x(Ba0.7Ca0.3)TiO3 ceramics by Liu and Ren have attracted
great attention due to the excellent piezoelectric properties
(with d33 = 350650 pC/N) [411]. A d33 of 650 pC/N is
obtained for the composition of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3
(BCZT) by optimizing sintering temperature at 1540 8C [9].
However the optimal composition with high d33 value is
* Corresponding author. Tel.: +86 773 2291 957; fax: +86 773 2290 153.
E-mail address: cuiyerang@126.com (Y. Cui).
2. Experimental
Using conventional solid-state reaction technique BCZT
ceramics and CeO2 (x = 00.1 wt%) doped BCZTxCe
ceramics were prepared. Systems were prepared by using a
two-step method. Raw materials of BaCO3 (99.8%), CaCO3
(99.0%), ZrO2 (99.5%), and TiO2 (99.9%) were weighed and
mixed in a centrifugal mill, as well as wet-homogenized with
ethanol for 8 h. The obtained powders were dried in an oven,
and then calcined at 1250 8C for 2 h. Different amounts of CeO2
0272-8842/$36.00 # 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
doi:10.1016/j.ceramint.2012.02.063
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Fig. 2. SEM images of the BCZTx%CeO2 ceramic sintered at 1350 8C: (a) x = 0.00, (b) x = 0.02, (c) x = 0.04, (d) x = 0.06, (e) x = 0.08 and (f) x = 0.1.
Fig. 3. The piezoelectric constant d33 and the planar electromechanical coefficient kp of the BCZTx%CeO2 ceramics.
Fig. 4. The dielectric constant er and the dielectric loss tan d of the BCZT
x%CeO2 ceramics.
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Acknowledgments
The authors wish to acknowledge the financial support of the
National Nature Science Foundations, grant No. 51102056, and
Guangxi Nature Science Foundations, grant Nos.
2010GXNSFD013007, 2011GXNSFB018008.
References