Professional Documents
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Technical Report
TR-17 (Rev. C; 03-22-01)
(48-7-3)
19650 Pauling
Foothill Ranch, CA 92610-2610
Tel (949) 460-2100
Fax (949) 460-2300
Email: sales@balseal.com
www.balseal.com
Spinozastraat 1
1018 HD Amsterdam
The Netherlands
Tel +31 20 638 6523
Fax +31 20 625 6018
Email: sales@balseal.nl
www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 2 of 14
TABLE OF CONTENTS
1.0
Summary
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 3 of 14
12.0
Sources of supply
12.1
Hard anodizing
12.2
PTFE impregnation
13.0
References
The information, descriptions, recommendations and opinions set forth herein are offered solely for your consideration, inquiry, and verification and are not, in part or in whole,
to be construed as constituting a warranty, expressed or implied, nor shall they form or be a part of the basis of any bargain with Bal Seal Engineering. If any sample or model
was shown to or provided by Buyer/User, such sample or model was used merely to illustrate the general description and type of goods. Such use is not to be construed as a
warranty that the goods will conform to the sample or model. Furthermore, THE IMPLIED WARRANTY OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE AND ALL OTHER WARRANTIES, IMPLIED OR EXPRESSED, ARE EXCLUDED AND SHALL NOT APPLY. This document provides product options for
further investigation by Buyers/Users having technical expertise. The Buyer/User, through its own analysis and testing, is solely responsible for making the final selection of the
products and for assuming that all performance, safety and warning requirements for the application are met. It is recommended that Buyers/Users run evaluation testing under
actual service conditions to determine whether proposed Bal Seal products are suitable for the intended purpose. Nothing contained herein or in any of our literature shall be
considered a license or recommendation for any use that may infringe patent rights. (LE-17)
PATENTS: The items described in this report include products that are the subject of the following issued United States patents: 5,979,904; 5,994,856; 6,050,572; 5,984,316;
6,161,838 and others, as well as foreign patents or products where patents are pending. (LE-88G)
Copyright 2001, Bal Seal Engineering Co., Inc. U.S.A.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 4 of 14
1.0
SUMMARY
This report describes various coatings for aluminum, the processes, engineering properties, advantages,
disadvantages, and effect on the performance of BAL Seals in dynamic applications.
Aluminum alloys are used in applications requiring lightweight, corrosion resistance, and ease of
fabrication. Applications include controls, actuators, valves used in aircraft, marine environments,
transportation, food processing, and others. Aluminum and aluminum alloys, as compared to other
structural metals, have very low hardness, with low resistance to wear, abrasion and corrosion. A
surface coating can overcome thee disadvantages by providing a hard or corrosion resistant surface.
Hard anodizing of aluminum per MIL-A-8625C Type III is very effective at improving the hardness
and wear resistance by creating a very hard surface obtained by the electrochemical conversion of
aluminum-to-aluminum oxide. MIL-A-8625 Types I and II are for improvement of corrosion
resistance or application of a porous base for dyes, sealants or paint.
The main concern of this report is with ML-A-8625 Type III hard anodizing and its engineering
properties when used in contact with BAL Seals in dynamic applications. This report gives a brief
description of MIL-A-8625 Types I and II for information purposes only. It also describes an alodine
coating that leaves a conductive, corrosion inhibiting finish.
2.0
The basic reaction in all anodizing processes is the conversion of the aluminum surface to aluminum
oxide while the part is the anode in an electrolytic cell. The three anodizing processes are:
Type I chromic, in which the active agent is chromic acid;
Type II sulfuric, in which the active agent is sulfuric acid;
Type III hard anodizing processes, which use sulfuric acid alone or with additives.
The principal military specification, which covers the three anodizing processes, is MIL-A-8625,
anodic coatings for aluminum and aluminum alloys. The main difference in the three types of
processes is the thickness of the coating produced.
Type I produces a thin, dense, low porosity coating about 0.000050 inch, for enhancement of corrosion resistance.
Type II coatings range from 0.0001 to 0.001 inch. This acts as a better base for dyes, paints, and
pigments due to greater thickness and higher porosity than Type 1 coatings, Though both Types I and
II are used for decorative purposes in architectural structures or household items, automobile trim, etc.
The coating thickness produced by Type III processes range from 0.0005 to 0.0045 inch, with the
typical thickness being 0.002 inch. The added thickness and weight of Type III coatings provide a wear
and abrasion resistant surface. Figure 1 shows a comparison of properties produced by the three types
of anodizing.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 5 of 14
3.0
An alodine coating provides a corrosion resistant film where low resistance contacts are required. The
alodine is a chemical conversion coating formed by the reaction of chemicals on the surface of
aluminum or an aluminum alloy. Military specification MIL-C-5541 covers chemical conversion
processes for military weapons systems. MIL-C-5541 Class 3 is specifically intended for electrical
and electronic applications.
Where an application requires a conductive finish, such as along the seam of an EMI shield, an alodine
or chromate coating should be used. An anodized surface will not work in this application because it
leaves an insulating ceramic surface.
An alodine coating results from the treatment of aluminum or aluminum alloy parts nonelectrolytically with an aqueous solution, producing a protective coating on the metal surface. The
abrasion resistance of the alodine coating is very low.
4.0
The basic process for producing anodic coatings on aluminum consists of making the treated part the
anode in a bath containing an electrolyte such as sulfuric acid. The current density that passes through
the part is regulated in order to overcome the passivity of the metal and cause oxidation of the metal
surface. The surface metal is thereby converted to ceramic (aluminum oxide). As the oxide layer is
formed, it penetrates the surface and expands outward because of the increased volume of the surface
material as it takes on oxygen.
5.0
Hard anodizing produces a hard, wear- and abrasion-resistant coating of aluminum oxide on the
surface of aluminum alloys. Hard anodizing of aluminum increases hardness and wear resistance of the
part.
6.0
BAL Seal performance is substantially improved when in contact with harder mating surfaces. An
anodized surface results in lower friction, and less wear to the seal material and the shaft or bore
surface.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 6 of 14
6.1
Hardness
As the hardness of the mating surface increases, the adhesive force between the metal and the seal
decreases, resulting in lower friction and less BAL Seal wear.
6.2
Surface finish
Improving the surface finish of the hard anodized surface reduces abrasion of the BAL Seal. Hard
coatings are capable of obtaining excellent finishes by honing.
6.3
A dry film lubricant reduces friction, adhesion, and seal wear. Dry lubricants are introduced into the
hard anodized aluminum in two ways: (1) by bonding and (2) by impregnation or infusion.
6.3.1 Bonding
Molybdenum sulfide or graphite are bonded onto the aluminum surfaces.
6.3.2
Impregnation or infusion
PTFE is impregnated into the aluminum alloy during the hard anodizing process.
7.0
In engineering, the primary purpose of a hard anodized coating is to improve the hardness and wear
resistance. However, one should consider all coating properties for their effect on a particular
application.
7.1
Nature of film
The film coating produced on the surface of hard-anodized aluminum parts is aluminum oxide
produced by electrochemical oxidation at the metal surface. The film is integrally bonded to the base
metal, and has an amorphous (non-crystalline) structure.
7.2
Hardness
Indentation tests cannot determine accurate hardness values because of the soft aluminum substrate.
Scratch tests show the surface hardness to be between 7 and 9 on the Mohs scale, equivalent to 60 to
65 Rockwell C.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 7 of 14
7.3
Wear resistance
Comparable to that of hard chrome plated steel, or cyanide hardened mild steel. The graph in Figure 3
shows results of wear testing on various materials as compared to hard anodized aluminum.
7.4
Adherence of coating
The film is strongly adherent to most aluminum alloys, especially those containing magnesium. The
poorest adhesion is on the alloys containing zinc. For best coating adherence, use alloy 6061-T6.
7.5
Coefficient of friction
Hard coatings have a lower coefficient of friction than the metal substrate. Friction can be further
reduced by the application of a dry film lubricant bonded to the surface. Hard anodized surfaces
running in contact with PTFE-based BAL Seal materials will eventually become impregnated with
PTFE, reducing the running friction between the anodized surface and the seal.
7.6
Corrosion resistance
The hard coating is inert and resists attack from atmosphere, humidity, and salt spray environments.
Dry film lubricants enhance the corrosion resistance of the coating by filling the pores and forming a
protective film on the surface. Sealants are not recommended because the sealing process reduces the
hardness and wear resistance.
7.7
Coating porosity
The electrolytic solution used in hard coating has a solvent effect on the coating such that the porosity
of the coating increases as the processing time increases. Certain alloying elements in the substrate
(such as copper) increase the coating porosity.
7.8
Coating ductility
Hard anodized coatings are very brittle with very low ductility and fatigue strength. A hard anodized
surface will crack readily under impact loads or high flexural stresses.
7.9
The thick oxide coating has a different coefficient of thermal expansion than the aluminum substrate.
As a result, the coating develops fine hairline cracks after removing the parts from the cold processing
bath and allowing them to warm to ambient temperature. This phenomenon, known as crazing, appears
to have no detrimental effect on other properties of the coating.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 8 of 14
8.0
When designing parts to be hard anodized and preparing parts before coating, the following important
points should be considered
8.1
Hard anodized coatings are not like electrodeposited coatings since the coating is not all built-up above
the surface. A combination of penetration into the substrate surface and growth outward from the
surface occurs. Half the coating thickness is buildup, and the other half is penetration. For example, a
shaft with a 0.500-inch outside diameter anodized with a 0.002 inch per side coating will measure
0.502 inch on the outside diameter after coating, and not 0.504 inch as in electrodeposited coatings.
8.2
The quality of the hard anodized coating improves with the quality of the surface finish before coating,
because of the method of coating growth. The surface finish will roughen slight to moderate amounts
during coating, depending on the prior surface finish and the coating thickness. For example, a finish
of 2 RMS before coating will roughen to approximately 4 RMS after applying a coating thickness of
0.002 inch. Approximately 0.0005 inch of coating thickness should be allowed for machining after
coating to obtain the desired finish, normally by honing.
8.3
Anodized coatings grow perpendicular to the surface from the treated surface. Therefore, a void will
occur on all sharp corners and edges. Thicker coatings accentuate the defect and the coating has a
tendency to crumble at these points. To obtain a uniform coating, all edges and corners should be
broken with a 0.005 to 0.050 inch radius.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 9 of 14
8.4
When coating a straight piece of aluminum, cracks will form in the coating because of the expansion of
the substrate under normal processing conditions. When coating small radius parts, the number of
cracks increases because of the radial growth of the coating.
8.5
Hard coating solutions have extreme throwing power or ability to coat surfaces in hard-to-reach
places such as small bores or deep blind holes. The coating thickness will vary from the open end of a
bore to the closed end of a blind hole. To obtain a more uniform coating it would be necessary to use
auxiliary cathodes and agitation of the bath inside deep recesses.
9.0
All aluminum alloys can be hard anodized by one process or another. Results will vary with certain
alloys, depending on composition and temper. For BAL Seal applications, however, try to specify one
of the three wrought alloys shown in Figure 3.
9.1
Select the alloy for a specific application based on strength and other properties required and the
anodizing characteristics of alloy. The chart in Figure 3 shows mechanical properties of three wrought
aluminum alloys.
9.2
Alloys low in copper or silicon such as 6061-T6 give the best results in anodizing. Alloys such as
7075-T6, used when higher strength than 6061-T6 is required, anodize almost as well. The presence of
zinc in alloy 7075 lowers the adherence strength of the coating. Alloy 2024-T6 produces a less wear
resistant coating with lower corrosion resistance, lower hardness, and higher porosity due to the high
copper content. As the purity of the alloy approaches that of pure aluminum., the coating properties of
density and hardness increase, and the roughening of the surface finish decreases.
9.3
Die case or sand cast alloys are generally not recommended, because of their higher porosity and nonuniform surface composition, which results in coatings with excessive porosity. For best results, use
heat treatable wrought alloys T4 to T6 temper.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 10 of 14
9.0
To achieve good results with hard anodizing, a high level of quality control must be maintained
throughout the stages of surface preparation, processing, and finishing. Some of the points to watch are
as follows:
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 11 of 14
TYPE I
Chromic Acid
.00005 - .0003 in
.001 - .007 mm
Minimal Roughening
Hardness Increase
Wear Resistance
Porosity of Coating
Corrosion Resistance
Minimal
Poor
Very Low
Good
TYPE II
Sulfuric Acid
.0001 001 in
.002 - .025 mm
Minimal to Slight
Roughening Increase
Moderate Increase
Minimal Increase
Medium to High Porosity
Good (excellent when
sealed)
Colorless to Yellowish Gray
Poor
Good
Good
Thicker,
more
porous
coating makes better base
for paint or dye.
Thickness of Coatings
TYPE III
Hard Anodize
.0005 - .0045 in
.012 - .114 mm
Slight to moderate roughening
File Hard (60 65 Rc)
Excellent
High Porosity
Good
Light to Gray to Brown or Black
Figure 2
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 12 of 14
Tensile Strength:
(psi)
at 75F
300F
Yield Strength:
at 75F
(psi)
300F
Elongation Percent
Brinell Hardness with 500 Kg
load,
10 mm ball
Density
grams/cc
lb/cu.in.
Chemical
Si
Composition
Fe
Typical
Cu
Analysis
Mn
Mg
Cr
Zn
Ti
Others max
Aluminum - min
Machinability
Corrosion Resistance
Anodic Coating Quality
Special Features and
Applications
6061-T6
QQ-A-225/8
AMS-4150
45,000
30,000
7075-T6
QQ-A-225/9
AMS-4122, 4123
83,000
25,000
2024-T4
QQ-A-225/6
AMS-4119, 4120
68,000
45,000
21,000
21,000
73,000
21,000
47,000
36,000
12
95
11
150
20
120
2.70
0.098
0.4 0.8
0.7
0.15 0.40
0.15
0.8-1.2
0.15-0.35
0.25
0.15
0.15
95.85
Fair
Excellent
Best density and wear
resistance
Lowest cost, most versatile
alloy. Has very good corrosion
resistance, but fair strength.
General-purpose application.
2.80
0.101
2.81
0.102
0.5
0.7
1.2 2.0
0.30
2.1 2.9
0.18 0.40
5.1 6.1
0.20
0.15
86.75
Good
Fair
Good, but less wear resistance
0.5
0.5
3.8 4.9
0.30- 0.90
1.2 1.8
0.10
0.25
--0.15
90.90
Excellent
Poor to Fair
Poor, due to high Cu
content
Good strength with very
high fatigue resistance but
lowered corrosion
resistance. Used in
aircraft structural
components.
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 13 of 14
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl
TR-17 (48-7-3)
Rev. C / 03-22-01)
Page 14 of 14
13.0 REFERENCES
Metals Handbook, American Society for Metals
Military Specification, Anodic Coatings for Aluminum and Aluminum Alloys, MIL-8625
Military Specification, Coating, Anodic, Hard, for Aluminum and Aluminum Alloys Mil-C-60536
Military Specification, Coatings, Anodic, Conventional for Aluminum and Aluminum Alloys MIL-C-60539
Mechanical Engineers Handbook, Lionel S. Marks
WADC Technical Report 53-151, Study of Hard Coating for Aluminum Alloys, F. G. Gillig, Cornell Aeronautical
Laboratory, Inc., Wright Air Development Center
Military Handbook, MIL-HDBK-132(ORD), Department of the Army Technical Bulletin TB-700-801D-1, Protective
Finishes
Use or disclosure of data contained on this sheet is subject to the restrictions contained in the disclaimer located in the Table of Contents of this report.
Bal Seal Engineering Co, Inc. Foothill Ranch, CA USA 92610-2610 Tel: 949 460-2100; Fax: 949 460-2300 Email: sales@balseal.com Web: www.balseal.com
Bal Seal Engineering Europe, B.V. Amsterdam, The Netherlands Tel: +31 20 638 6523, Fax: +31 20 625 6018 Email: info@balseal.nl Web: www.balseal.nl