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| A3 |
1
The word any, used as a subscript, refers to any solubility parameter,
Hansen, Hildebrand, Hoy, etc.; or disperse, polar, or hydrogen bonding.
A3 1
2
It is this authors belief that the linear blend rule was chosen on the
basis of two factors: (1) Simplicity of calculation when personal
computers and spreadsheets hadnt yet been invented, and (2) that the
form of the blend rule wasnt signicant when the values of the solubility
parameters were similar.
3
To combine the three solubility parameters, one uses Equation 2.6.
503
Appendix
A3
Equation A3-1, for four components, and energy associated with any type of intermolecular force, can be restated
as Equation A3-2.
X
Total Energyany blend m1 Eany 1 m2
Eany 2 m3 Eany 3
m4 Eany 4 .
A3 2
dany blend
dany blend
s
m1 Eany 1 m2 Eany 2 m3 Eany 3 m4 Eany 4 .
Vmblend
s
Total Energyany blend
Molar Volumeblend
sP
Eany blend
Vmblend
A3 3
504
2
Total Energyany i Vmi dany i
A3 5
A3 6
dany blend
A3
Appendix
s
m1 Vm1 fd1 g2 m2 Vm2 fd2 g2 m3 Vm3 fd3 g2 m4 Vm4 fd4 g2 .
Vmblend
A3 7
vi ri
Mi
mi P v
ri
i
Mi
A2 6
M
r
dany blend
Equation A3-8 can be simplied (fortunately), for a fourcomponent blend, to Equation A3-9, by performing algebraic manipulations (canceling the molecular weights and
densities) in each of the terms in the numerator and
recognizing that the two terms in the denominator are the
inverse of one another (both are the blend molar volume),
and so cancel.
The blend rule for any solubility parameter used in this
book is Equation A3-74.
q
X
A3 7 (or) A3 9
dany
vi di 2
The point of this Appendix is to recognize that the
HSP blend rule, Equation A3-9, is an energy summation (balance)dfor any of the three types of cohesive
u
v r
M
v 2 r2
M2
v 3 r3
M3
v 4 r4
M4
1
1
u
1
d1 2
d2 2
d3 2
d4 2
u
u
M1
r1
M2
r
M3
r3
M4
r4
2
u
t
P v i ri
P v i Mi
Mi
ri
A3 8
dany blend
X
v 1 d1 2 v 2 d2 2 v 3 d3 2
v4 d4 2 or Equation A2-7
for four components
A3 9
4
An answer to the question of whether or not the energy balance as
Equation A3-1 is valid for so-called ideal uids and non-ideal uids is
beyond the scope of this book.
505