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NATIONAL
CHEMISTRY OLYMPIAD
LOCAL SECTION EXAM
Prepared by the American Chemical Society Chemistry Olympiad Examinations Task Force
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
Distributed by the American Chemical Society, 1155 16 th Street, N.W., Washington, DC 20036
All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
Avogadro constant
Celsius temperature
centi prefix
coulomb
density
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
n
A
atm
u
NA
C
c
C
d
E
Ea
H
S
K
CONSTANTS
M
mol
h
P
k
Q
s
c
T
t
VP
V
V
R = 8.314 Jmol K
1
1
R = 0.0821 Latmmol K
1
F = 96,500 Cmol
1
1
F = 96,500 JV mol
1
h = 6.626 1034 Js
c = 2.998 108 ms
0 C = 273.15 K
1 atm = 760 mm Hg
Specific heat capacity of H2O =
4.184 Jg1K1
1
EQUATIONS
E Eo
1
1A
1
H
RT
ln Q
nF
k E 1 1
ln 2 a
k1 R T1 T2
o
H 1
ln K
constant
R T
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Cn
113
115
118
(Uup)
116
Lv
117
(Uut)
114
Fl
(Uus)
(Uuo)
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(281)
(272)
(285)
(284)
(289)
(288)
(293)
(294)
(294)
58
Ce
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Page 2
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
1. Benzene, C6H6, reacts with oxygen, O2, to form CO2 and
H2O. How much O2 is required for the complete
combustion of 1.0 mol C6H6?
(D) 12 mol
(A) Na
(B) Mg
(C) K
(D) Ca
(B) 0.432 M
(C) 0.508 M
(D) 1.02 M
(A) Cr(NO3)3
(B) Co(NO3)2
(C) Cu(NO3)2
(D) Zn(NO3)2
(B) TbSO4
(C) Tb2(SO4)3
(D) Tb(SO4)2
(B) II only
(C) Either I or II
(B) HCl
(C) HBr
(D) HI
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
Page 3
= A
= B
= C
(A) ABC
(A) A
(B) B
(C) C
(D) D
(B) ABC3
(C) AB4C6
(D) AB8C12
(B) 23.0 C
(C) 25.0 C
(D) 52.5 C
(B) Metallic
(C) Molecular
(B) E = q + w
(C) H = E + PV
(D) G = H TS
Page 4
H = 35 kJmol1
H = +20 kJmol1
H = +15 kJmol1
(B) 30 kJmol1
(C) 40 kJmol1
(D) 70 kJmol1
(A)
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
H2PO4(aq) + H+(aq)
(B) 13 days
(C) 19 days
(D) 32 days
33. What is the ratio Kc/Kp for the following reaction at 723 C?
O2(g) + 3 UO2Cl2(g)
(A) 0.0122
(B) 1.00
U3O8(s) + 3 Cl2(g)
(C) 59.4
(D) 81.8
(B) II only
(C) Either I or II
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
Page 5
(B) 0
(C) +2
(D) +4
3+
3+
E = +0.34 V
E = 0.13 V
III. Ag+(aq) +
Ag(s)
E = +0.80 V
Al(s)
E = 1.66 V
3+
IV. Al (aq) + 3 e
(D) 4
(A) Li
(C) 3
(B) Al
(C) S
(D) As
I.
(B) 2
(B) Na
(C) K
(D) Rb
(B) Be
(C) B
(D) C
(B) Cl
(C) Br
(D) I
(A) I and II
(B) I and IV
(A) n = 5 n = 2
(B) n = 1 n = 2
(C) II and IV
(C) n = 3 n = 4
(D) n = 3 n = 1
(B) Pb(NO3)2
(C) ZnCl2
(D) In(NO3)3
E = +0.799 V
Page 6
II. I3
(A) I only
(B) II only
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
(C) T-shaped
(D) zigzag
(B) 1.5
(C) 2.0
(D) 2.5
(B) 1
(C) 0
(D) 1+
(B) alkyne.
(C) alcohol.
(D) aldehyde.
CH3CH2CH2CH(CH3)CH3
(A) Identical
(B) Stereoisomers
(B) Amide
(C) Amine
(D) Ketone
(A) I only
(B) II only
(B) C5H12
(C) C6H10
(D) C6H12
(B) Glucose
(C) Cellulose
(D) Chitin
END OF TEST
Property of ACS USNCO Not for use as USNCO Local Section Exam after March 31, 2015
Page 7
Olympiad 2015
USNCO Local Section Exam
KEY
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
B
A
D
C
B
A
C
C
D
A
B
B
A
B
A
C
D
B
B
B
A
D
B
A
C
B
C
C
B
D
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Answer
A
D
D
C
C
C
B
B
D
A
A
C
A
D
D
B
B
A
C
B
A
B
D
D
A
D
C
D
C
B