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Chapter 5
Reactors
Type of Reactors
We have already learned the reaction orders
constants. In addition to this knowledge, in order
and estimate the performance of wastewater
processes and to design these, the knowledge of
necessary.
and rate
to analyze
treatment
reactor is
Type of Reactor
Batch Reactor
Bath Reactor
o The reactants are initially changed into a reactor (no input
and no output during the reaction)
o Well-mixed (the concentration of the reactant or products
is same throughout the reactor at any time)
o After a certain period (reaction time), the resultant
mixture is then discharged
o Unsteady state operation where the concentrations of
reactions and products change with time.
Qin
Cin
t (h)
V (m3)
Qout
Cout
3
Cin
V (m3)
Cout
t (h)
4
Q
Cin
Q
Cout
V (m3)
Cout
t (h)
5
X in
X out
Reaction
Rate of A
ACCUMULATED
IN OUT PRODUCED CONSUMED
Qout
(kg/m3)
C
V
(m3)
(kg/m3)
t (h)
dC
V
QC0 QC V r
dt
Accumulation
Inflow
Outflow
Disappearance
dC
0
dt
0 QC0 QC V r
V
C C0 k0 C0 k0T
Q
QC0
C0
C0
C
Q Vk1 1 Q k 1 k1T
1
V
T: Hydraulic retention
time
C0
C1
1 k1T
With respect to reactor 2
C2
1
C1 1 k1T
1
C
C
C1 C2 C3
. . ..... N N
C0 C1 C2
C N 1 C0 1 k1T
CN
1
C N 1 1 k1T
9
Solution:
dC
V
QC0 QC V r
dt
0 QC0 QC V r
C 80 coli/mL
10
dC
V
V r
dt
dC
r
dt
dC
k0
dt
C k0t C0
1
t C0 C
k0
dC
k 1C
dt
1 C0
t ln
k1
C
11
Solution:
Let C0 : Initial concentration of the color
C : concentration of color at any time t
C = 0.1 C0
C0
ln
kt
C
C0
ln
0.35t
0.1C0
2.30
t
6.6 days
0.35
12
dC
AS
QCx QCx x (r ) Ax
dt
Where Cx and Cx+x are substrate concentration at x=x and x=x+x
At a steady state dC/dt = 0
Q C x x C x
( r )
A
dx
x 0
Q dC
( r )
A dx
dC
Q
( r )
dV
13
Q dC
k0
A dx
A
dC k0 dx
Q
A
C k0 x const
Q
At x = x0, C=C0 Const=C0
A
C k0 x C0
Q
dC
Q
k0
dV
k0
dV
dC
Q
V
C k0 const
Q
At V=V0, C=C0 Const=C0
V
C k0 C0
Q
14
AL
Ce C0 k0
Q
V
Ce C0 k0
Q
Putting
V (variable) = V (reactor volume)
V
Ce C0 k0
Q
Ce C0 k0T
Ce C0 k0T
Or more directly, applying integrate!
15
Q dC
k1C
A dx
Ce
C0
dC
A L
k1 dx
C
Q 0
Ce
A
ln
k1 L k1T
C0
Q
Ce C0e
Ce C0e
k1T
k1
dC
Q
k1C
dV
Ce
C0
dC
k1 V
dV
C
Q 0
Ce
k1
ln
V
C0
Q
Ce C0e k1T
A
x
Q
16
17
odor from their waste. Assume that the ditch acts as a plug-flow
reactor. The odor reduction behaves as a first-order reaction, with the
rate constant k = 0.35 day1. The flow rate is 1600 L/d. How long must
the ditch be if the velocity of the flow is 0.5 m/s and 90% odor
reduction is desired?
Solution:
Ce C0e
k1
A
x
Q
T 6.58 days
C
ln
kT
C0
0.1C0
ln
0.35T
C0
L 2.8 105 m
18
CFSTR
V
C0 C (r ) T (r )
Q
The required HRT to obtained
effluent concentration of Ce
TCFSTR
(C0 Ce )
re
dC
Q
r
dV
The required HRT to obtained
effluent concentration of Ce
TPFR
C0
Ce
1
dC
(re )
20
Solution:
VCSTR
VPFR
Q C0
A C
Q C0
ln
k C
C0
2
C
VCSTR 2 1
1.44
VPFR
ln 2
21