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Materials.
Introduction:
Materials are important in everyday life because of their versatile structure
and properties. The properties of materials doesnt depend its shape and
side. Some prime properties of materials include electrical, mechanical
thermal and optical properties. Electrical behaviors of materials are diverse
so are uses in electrical applications.
Classifications:
Materials based on electrical properties classified into following types:
Conductors
Insulators
Semi-Conductors
In the first, one outermost band is partially filled with electrons. This
energy band structure is typified by some metals. e.g.: Copper
Second band structure also found in metals, there is an overlapping of an
empty and filled band. Magnesium has this band structure.
The final two bands are similar, one band (valence band) completely filled
with electrons is separated from an empty band that is conduction band
by an energy band gap lies between them.
The difference between two band structures is the magnitude of energy
gap for Insulator the energy band gap is wide whereas for
Semiconductors it is narrow.
Electrical Conduction:
= VA/I
Also,
= 1/ = /RA,
= conductivity of materials
P=IV=I2R
Conductors ,
Semiconductors,
Insulators.
Conductors > 107 (-m)-1
Semiconductors 10-6 -104
Insulators < 10-10
Resistivity in Metals:
Lattice vibrations and scattering center play a role in disrupting the mean
free path of electrons. In addition, crystalline defects and impurity atom
affect the conductivity. These scattering mechanisms act independently on
one another. Thus the effective resistivity of metals can be represented as
follows:
= t + i + d ,
t, i, d are the individual thermal, impurity and the deformation resistivity
respectively. This equation also known as MATHIESSENs EQUATION.
With increase of temperature, thermal vibrations increase so the resistivity,
and vice versa. In the same manner, with increase of either defects or
impurities, resistivity increases. For pure metals, the resistivity approaches
zero at absolute zero temperature.
Electron Mobility:
When an electric field applied, all the free electron should accelerate in the
direction according to the direction opposite to the field, which would give
rise in electric current that is continuously increasing with time. However,
some frictional force counter this acceleration from an external field and
constant the value of current. Because of this force the electron scattered by
imperfection in the crystal lattice.
This scattering phenomenon called resistance to the passage of an electric
current. Several parameters are used to describe the extent of this
scattering, these includes drift velocity and the electron mobility. The drift
velocity d is directly proportional to electric field.
d=e Ef
The constant of proportionality
e ,
Semi Conductivity:
Intrinsic Semi-Conduction:
Extrinsic Semi-Conduction:
Charge can also be conducted via ions - called ionic conduction. This may
occur either in conjunction with or separately from electronic conduction.
Several types of compounds show exceptionally high ionic conductivity.
Such phases fall into three broad categories: halide and chalcogenides of
silver and copper; oxides with -alumina structure; and oxides of fluorite
structure.
Ex.: La2CuO4 (Tc = 30 K), YBC compounds yttrium doped perovskite
structure, YBa2Cu3O7 (Tc = 92 K).
By properly engineering the point defects, it is possible to convert
ceramics into semiconductors. Ex.: Indium tin oxide (ITO).