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Paragraph 2
The Chemistry
1869 Hunt in Scientific Paper 1953 Van Arsdale Hydrometallurgy
First stage reactions:
Molecular Formula
Cu2O + FeCl =
CuO + FeCl2 + H2O
Cu2Cl + FeO
CuCl2 + Fe(OH)2
Second stage reactions:
Cu2Cl + 3FeO =
Balanced Equation
Cu2 + FeCl + Fe2O3
3Cu2+O2-(s) + 2Fe2+Cl2-(aq) + 3H2O
Final Result:
2CuCl (aq) + Cu2+Cl2-(aq) +
3Cu2O + 2FeCl =
Fe(OH)3(aq)
2Cu2Cl + 2Cu + Fe2O3
(Errors for cuprous chloride & ferrous chloride
traced back to atomic weight errors.)
Cu
31.71
31.7
63
63.4
1876
Hunt &
Douglas
31.75
Fe
27.18
28
----
56
28
55.85
Cl
35.47
35.5
35.5
35.5
35.5
35.45
8.01
16
16
16
Element
1840
Graham
1858
1869
Cannizzaro Medeleev
Modern
63.55
Hunt &
Douglas
(1876)
Formula
Cu2O
Cu2O2
Hunt &
Douglas
(1869) Patent
oxides of
copper/red
oxides of
copper/black
Cu2Cl
FeO
dichloride of
copper
protochloride
of iron
ferrous oxyd
F2O3
ferric oxyd
FeCl
iron
oxychloride
chlorid of
sodium
Hunt (1869)
Scientific
Copper
Article
cuprous oxyd
Other Hunt
& Douglas
(1869)
Terminology
suboxide
oxidum
cuprosum
cuprous
chlorid
cupric chlorid
protoxide
ferrous
chlorid
ferrous oxyd
iron
dichloride
ferric oxyd
chlorid of
sodium
oxychloride
of iron
common salt
chlorid of
sodium
Modern
Latin
System
Names
cuprous
oxide
cupric oxide
cuprous
chloride
ferrous
chloride
ferrous
oxide
ferric oxide
sodium
chloride
Modern
Stock System
Names
copper (I)
oxide
copper (II)
oxide
copper (I)
chloride
iron (II)
chloride
iron (II) oxide
iron (III)
oxide
iron (III)
oxychloride
sodium
chloride
T. Sterry Hunt
Their Careers
Douglas CV
Hunt CV
Roasting
furnace
Leaching tanks
Precipitation
tanks
Solution
recovery
Patent #
Name
Patentee
Title of Patent
(solvent/product)
Extraction
Method
1869 86.754
H&D
iron precipitate
1874 151,763
D, H, S
iron precipitate
1880 227,902
H&D
1887 364,174
H&D
iron precipitation
or filter
1893 506,985
iron precipitation
or filter
1896 563,144
Electrolysis
1900 664,537
Electrolysis
iron precipitation
or filter
Hydrotechnology
Hydrometallurgy vs. Hydrotechnology.
Shared idea place ground ore in a solution in
order to manipulate desired metal.
Leach.
Precipitate.
Electrolysis.
Float off top.
Reflections
Low-grade metal mining is on defensive today.
Low-grade metal mining is humanitys way ahead.
Considering historical perspectives is one way to
maintain dialogue.
Hydrometallurgists have a burden to be creative in
solving known problems.
Investors take a risk, but must balance return with
safety for workers and the environment.
Conclusions
The Hunt & Douglas Copper Process worked.
It is an early instance of scientific insight leading
to business opportunity.
Ahead were decades perfecting the necessary
engineering and methods:
-non-selective mining,
-overall mine/plant scale of operation,
-particle sizing and sorting.
Blind alleys and dead-ends helped find the way
ahead for overcoming the low-grade challenge.