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MAGNETIC PROPERTIES
The lanthanides are transition metals.
The magnetic moments of the transition metals ions are assumed to be due to
electron spin only; as the orbitals occupied by unpaired electrons are near the peripheries
of the ions, it is generally supposed that the orbital angular momenta are quenched by
external fields [3, 5].
From the very high values of the magnetic moments for Tb +3, Dy3+, Ho3+ and
+3
Er , it is clear that at least for these ions the orbital contributions must be taken into
account. Since the 4f quantum shells are well shielded from outside fields by the
electrons of the n=5 and n=6 quantum shells, this is a reasonable conclusion.
It is also clear that there is a minimum value for the magnetic moment of
trivalent ions such as Pb3+, Sm3+ and Eu3+. Agreement between observed and calculated
values is good, except for Sm+3 and Eu3+.
The magnitude of the separation between the adjacent states of a term indicates
the strength of the spin-orbit coupling, and in all cases, except Sm +3 and Eu3+, it is
sufficient to render the first excited state of the Ln +3 thermally inaccessible, and so the
magnetic properties are determined only by their ground state.
Ln
Ce
Pr
Nd
Pm
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Unpaired
electrons
1(4f1)
2(4f2)
3(4f3)
4(4f4)
5(4f5)
6(4f6)
7(4f7)
6(4f8)
5(4f9)
4(4f10)
3(4f11)
2(4f12)
1(4f13)
0(4f14)
Ground
state
2
F5/2
3
H4
4
I9/2
5
I4
6
H5/2
7
F0
8
S7/2
7
F6
6
H15/2
5
I8
4
I15/2
3
H6
2
F7/2
1
S0
* These are the values of e at room temperature. The values fall when the temperature is reduced.