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PAHANG
ANALYTICAL CHEMISTRY
COURSE CODE
BKF1243
LECTURER
EMAN N. ALl
FARHAN BINTI MOHD SAID
DATE
7 JANUARY 2015
DURATION
3 HOURS
SESSION/SEMESTER
PROGRAMME CODE
BKB/BKC/BKG
INSTRUCTIONS TO CANDIDATE:
1.
2.
3.
4.
This question paper consists of FOUR (4) questions. Answer ALL questions.
All answers to a new question should start on new page.
All the calculations and assumptions must be clearly stated.
Candidates are not allowed to bring any material other than those allowed by
the invigilator into the examination room.
EXAMINATION REQUIREMENTS:
CONFIDENTIAL
BKB/BKCIBKG/141511BKF1243
QUESTION 1
Percent K*
5.20
2
3
4
CONFIDENTIAL
BKB/BKC[BKG/14151/BKF1243
QUESTION 2
a) Steel which only contains Ag and Cu was analyzed by dissolving the steel in HNO3,
adding 10 3 in excess and weighing the mixture of A910 3 and Cu(10 3)2 formed after
filtering process. If the steel sample weighs 0.2175 g and the weight of precipitate
formed is 0.7391 g, determine the content percentage of steel (Ag, Cu).
(12 Marks)
b) Determine the pH of a solution prepared by mixing 0.250 mol of acetic acid and
0.100 mol sodium acetate and diluted to 500 ml. Then, calculate the pH when 10.0
ml of this solution is diluted to 500 ml?
Ka for acetic acid is 1.75x 10.
(11 Marks)
c) Determine [Hf] for a solution of pH 10.25.
(2 Marks)
QUESTION 3
Measurements based on light and other forms of electromagnetic radiation are widely
used throughout analytical chemistry one of which is spectroscopy method.
a) Define spectroscopy.
(2 Marks)
b) Absorption spectroscopy based on UV & Visible and JR radiation is one of the
most useful tools available for quantitative and qualitative analysis:
i) List the important characteristics of spectrophotometric that make it very
good tool in quantitative analysis?
(5 Marks)
ii) What are the qualitative applications for UV Visible spectroscopy?
(2 Marks)
iii) What kind of compounds can be identified using IR spectroscopy?
(2 Marks)
3
CONFIDENTIAL
BKBIBKC/BKG/141511BKF1243
iv) Why the AAS is currently the most widely used of all spectroscopy
methods?
(3 Marks)
c) The molar absorptivity for the complex formed between bismuth (III) and
thiourea is 9.32 X 10 3 LIcm. mol at 470 nm, the concentration is 1.07 X 10-5M.
Calculate:
i)
ii)
iii)
iv)
What is the conclusion from results obtained in (i), (ii), and (iii)?
(2 Marks)
Stationary phase.
(2 Marks)
ii)
Retention Time.
(2 Marks)
iii)
Selectivity factor.
(2 Marks)
CONFIDENTIAL
BKB/BKC/BKG/141511BKF1243
Band broadening.
(5 Marks)
ii)
Length of Packing
Flow rate
3.1
0.41
1.07
1.16
1.72
5.4
13.3
14.1
21.6
Calculate:
The number of plates from each peak.
i)
(2 Marks)
ii)
iii)
iv)
v)
vi)
The time required to separate the two species on the column in part (v).
(1.5 Marks)
END OF QUESTION PAPER
5
BKB/BKCIBKG/141511BKF1243
CONFIDENTIAL
APPENDICES
IV
xi
=1=1
N
IN
I
(xx)
1=1
= 1!
Ni
texp =
S
_x2x1
exp -
Xn -Xi
= xn - X11-1
Qexp
-
A = logT = _Iog L
PO
R
= 2AZ
WA
kA -
+ WB
2[(tR)B(tR)A]
WA+WB
tRtM
a = ( tR)B tM
(tR)A tM
N=
N= L/H
(R)1
(R)2
( tR)l
(tR )2
1/Ic:;- ( R)
(R)
BKBIBKC/BKG/141511BKF1243
CONFIDENTIAL
P. j. in O oterit Q
(Rtjt1 if Q
Number or
Observations
90% Confidence
959fci Ciimlidence
99% Confidence
3
4
S
6
7
0.941
0.765
o4)
0-56()
0507
0.970
0.829
(M I()
0.625
0.569
0.326
0.493
0.466
0994
0.926
O82I
0.740
0.680
0.634
0.598
9
10
IA
0.437
0.412