Professional Documents
Culture Documents
ABSTRACT
is necessary if s ~ e e l sare to be selected and used intelligently over the v.ery wide range of conditions of actual
service. The most innportant of these principles are outlined and illustrated; few specific applications are mentioned, although it is hoped that the discussion will be
found applicable to some of the current metallurgical
problems of the industry.
INTRODUCTION
In common with most of our basic industries, the
petroleum industry is a large consumer of steel; perhaps, on a tonnage basis, next in importance only to
the automobile and railroad industries. Steel is, without ,
doubt, the industry's most important structural material, and there is no phase of the vast and manifold
activities involved in petroleum technology in which
ferrous alloys in one form or another do not play a vital
part.
The growth and development of petroleum technology
has been rapid, particularly since the invention of the
internal-combustion engine and the exploitation of the
motor car. The crude equipment of the early days was
soon found inadequate for the demands put upon it,
and the introduction of iron and steel structures began
a t a n early date. Plain-carbon steel, in its various
grades, was employed during this period-largely because i t was the only material of its kind economically
available in the tonnages required. With the rapid ex-.
pansion of the auton~otive industry a corresponding
development occurred in petroleum technology; the increased demand for motor fuels and lubricants led to
the drilling of deeper and deeper wells and the opening
up of new oil fields-involving, in many locations, corrosive, briny waters and the more corrosive " sour "
crudes. At about the same time refinery methods were
undergoing radical changes a s a result of the development of various " cracking " processes, practically all
of which employ either higher operating temperatures
or pressures than previously had been found necessary.
This trend toward increasingly severe operating conditions, in both the production and refining divisions of
the industry, soon began to t a x the capacity of plaincarbon-steel equipment and to reveal its inherent limitations. The drilling of deeper wells demanded higherstrength
steels capable of being used in lighter sections
-
with resultant saving in weight; the " sour " crudes and
corrosive brines required materials with increased resistance to corrosion for both production and refinery
equipment; increased temperatures and pressures in
distillation processes demanded structural materials
which possessed not only increased resistance to oxidation and corrosion, but improved strength and resistance
to " creep " a t elevated temperatures.
Hence, for the past several years the engineers and
metallurgists of the petroleum industry have been
searching for; and adopting, structural materials which
are better suited to modern operating conditions than
carbon steel. These new materials are, of course, alloy
steels-many
of which have been so successfully employed in the automotive, railroad, and aviation industries. I t is not to be inferred t h a t plain-carbon steel
has no place in petroleum technology; on the contrary,
for many applications i t is eminently well suited to the
requirements, both from a n economic and a metallurgical standpoint. However, for certain purposes, alloy
steels have been found sufficiently better fitted to meet
the increased demands of present-day service a s to
justify their higher initial cost. That this trend toward
the introduction and use of alloy steels will be continued
and extended is allnost beyond question.', '"
'
iron-carbon alloys, a r e alloy steels-since they all con.tain some proportion of such elements a s manganese,
silicon, aluminum, chromium, nickel, copper, phosphorus,
etc., either a s impurities from the raw materials or a s
"residuals " from the furnace, ladle or mold additions
made during the finishing of the heat or the casting of
the ingots. With the exception of manganese and possibly silicon, these "residual " elements are present in
very small quantities-usually under 0.1 per c e n t a n d
their effects in a true alloying sense may be disregarded.
In certain instances, however, these "residuals," particularly when they a r e present in the form of oxides,
silicates, carbides, o r other non-metallic compounds,
may play an important r81e in determining the behavior
of the finished product, chiefly with respect to its characteristic grain size, hardenability, and response to heat
treatment; this aspect of the effect of very small quantities of certain special elements will be touched upon
later in connection with the discussion of hardenability
and heat treatment. Unless otherwise stated, the follow-
Alloying elements, properly so-called, a r e usually incorporated in steel for one or more of the following
reasons :
1. To increase resistance to chemical attack (corrosion) and to elevated-temperature oxidation
(scaling).
2. To improve mechanical properties a t atmospheric
temperatures through control of the factors which
influence hardenability and related phenomena.
3. To improve mechanical properties a t elevated or a t
low temperatures.
4. To influence other special properties.
This order, used in what follows, was chosen for convenience of discussion-and
implies nothing a s t o the
relative importance of the several factors-which, indeed, differs from one application to another.
Corrosion
The effect of chrbmium, with or without, the addition
of nickel, in increasing the resistance of iron alloys to
many forms of chemical attack is too well known to
require extended discussion; its use is exemplified in
the wide variety of comnlercial stainless steels an.d other
ferrous alloys designed to possess increased resistance
to corrosion-ranging in chromium content all the way
from about 5-30 per cent, or higher in some instances.
In the absence of nickel these chronlium alloys are of
the so-called ferritic * type, i.e., they are magnetic a t
atmospheric temperatures-and, when they contain sufficient carbon, may be hardened by quenching from
* T h e constituents, ferrite nnrl n~ist~:nite,\\.ill be discossed
more f r ~ l l yi n n s u b s e r l ~ ~ e ns te c t i o l ~ .
TERISTJCS OF
ALLOYSTEEL
211
'
Oxidation
In general, the elements which impart corrosion resistance to iron alloys also contribute increased resistance to elevated-temperature oxidation, or scaling.
Chromium is particularly effective in this respect a s
exemplified in the high-chromium ferritic alloys containing upwards of 25-30 per cent chromium, and in
the various austenitic alloys carrying 25 per cent
chromium and 12 per cent nickel, or thereabouts. A
chromium .content even a s low a s 5 per cent results
in considerably increased resistance to corrosion and
scaling a s compared to plain-carbon steels; a s an
example of this, we have the 4-6-per-cent chroiniuin
steel now extensively employed in many oil refinerie'S.
As mentioned above under the subject of corrosion resistance, molybdenum, tungsten, titanium, columbium,
or other elements may be added to the oxidation-resistant alloys for certain specific effects. Copper has not
been widely exploited a s a n alloying element f o r increasing resistance to elevated-temperature oxidation, although i t undoubtedly contributes something in this
respect-and
several practical applications of copperbearing steels have been made with this feature in
mind.' Aluminum seems to be a n element which, when
present in sufficie~ltquantities, is effective in increas-'
ing oxidation resistance; but its practical application
has been more or less limited to the addition of aluminum to the surface of articles and parts subject to
exposure to high temperatures. Aluminum is one of
the more difficult alloying elements to incorporate satisfactorily into steel.
The mechanism of oxidation resistance is essentially
the same a s that of corrosion resistance; it undoubtedly
involves the formation of a tight, impervious, protective,
surface oxide layer which resists attack and protects
the metal beneath it. Indeed, oxidation or scaling a t
elevated temperatures is only a particular form of
chemical attack, and there is no reason for suspecting
that quite different mechanisms a r e involved in the processes of corrosion and oxidation of metal or in their
prevention.
The high-alloy stainless and' austenitic steels .have
been discussed first merely a s a matter of convenience;
but this arrangement does not imply that they are
necessarily of first importance.
'
'
'
a. Carbide
Distribution
-
With one or two possible exceptions, almost any alloying element which can be put into solution in austenite
can be expected to change the distribution of the carbide
in ferrite a s compared to plain-carbon steel. This
change is toward a finer dispersion of the carbide, and
it results in a n ilicrease in hardness and strength, with
less sacrifice of toughness and ductility, than is the case
with carbon steels. The nlechanism by which this effect
is accomplished need not be treated in detail here; it
will be sufficient for the moment to state that a t a given
slow, or moderately slow, rate of cooling from the
austenitic condition these elements retard the reaction :
Austenite+ferrite+carbide
h. Ferrite Properties
The ferrite matrix in which the carbides a r e imbedded
in the so-called pearlitic (defined later, p. 215) or in the
quenched and drawn steels is somewhat strengthened
and toughened by the presence of alloying elements in
solid solution. This solid-solution strengthening effect
is slight in comparison with that which can be obtained
through manipulation of carbide distribution a s outlined above. Silicon, nickel, aluminum, cobalt, copper,
manganese, and chromium are probably the elements
which are most effective i n bringing about this solidsolution type of strengthening of the ferrite; these elements a r e effective in this r61e only insofar a s they are
dissolved in the ferrite itself, and not combined with
the carbon in the form of a carbide.
c. Carbide Properties
'
Intensive investigation of this phase of ferrous metallurgy is of rather recent origin, and all of the factors
are not yet thoroughly understood. I t is becoming apparent, however, t h a t the carbide-forming elements
molybdenum, tungsten, vanadium, titanium, chromium,
and combinations thereof a r e most effective in retaining
strength and. imparting creep resistance a t elevated
temperatures; this is entirely consistent with what has
been stated in the previous section on the tempering
behavior of the alloy carbides. It is reasonable to expect
that a steel which retains its hardness and strength
a f t e r tempering a t high temperatures would, by the
same token, possess high strength, hardness, and resistance to creep when actually used at these elevated
temperatures; high-speed steel, used f o r tools, is a
familiar and practical example of this type of behavior.
Manganese and nickel, a s incorporated in the austenitic
steels, a r e elements which contribute ductility, but very
little strength, a t elevated temperatures.
Low-Temperature Properties
An increasing amount of attention is being paid to
the properties of steels a t sub-zero temperatures; and,
since impact strength is a rather sensitive means of
detecting low-temperature embrittlement, i t is the property which is usually measured. All ferrous materials,
except possibly the austenitic chromium steels, become
more or less brittle if the temperature is carried low
enough; however, in the presence of suitable amounts
of nickel, chromium, manganese, zirconium, vanadium,
molybdenum, aluminum, copper, or certain combinations of these elements, the embrittlement range is
forced to lower temperatures and the steel is, in effect,
endowed with a wider range of sub-zero temperatures
over which satisfactory impact properties may be obtained.' The exact mechanism by which the alloy addition effects this improvement in low-temperature properties is not thoroughly understood a s yet, but appears
to relate to the ratio of the shear resistance to the inherent cohesion of the metal.''
4. ELEMENTS
INFLUENCE OTHER
SPECIAL PROPERTIES
The various esalnples of the addition of alloying elements to iron-base materials for the purpose of influencing some particular o r highly-specialized property are
too numerous to record in detail; only a few 'typical
cases will be mentioned. I n most of these instances the
alloy content .is relatively high in comparison with the
steels which we have been discussing in the foregoing
pages.
The effect of nickel on the thermal-expansion characteristics of ferrous alloys is well known, and is exemplified by alloys of the Invar and related types; likewise the magnetic and other elect~icalproperties are
materially influenced by large amounts of nickel as, for
example, in permalloy. Other elenlents which influence
magnetic and electrical properties are cobalt, tungsten,
transformation temperature, depending upon the particular element involved; moreover, such additions may
alter the carbon-solubility relationships considerablybut these effects will not be discussed in detail, except
a s they have a bearing on the practical aspects of the
subject a s i t is developed hereinafter. It will be noted
from Fig. 1 t h a t ferrite is.capable of dissolving only
very small amounts of carbon-a maximum of perhaps
? 1200J
7
I,'
5$ 1 0 0 0 .I
2
-1%' i
800
A L P H A / R O N S O L I D SOLUTIC
tf E R R / TEJ
-J1; Z
I'
PER C E N T CARBON
FIG. 1
O.O3-0.04 Per cent a t 1,350 deg. F. (730 deg. C.) and
only about 0.01 Per cent a t room temperature; whereas
austenite can dissolve upwards of 0.85 per cent carbon.
precipitates in the form of iron carbide (FesC), a glasshard compound. If the cooling from the austenitic condition is very slow, a s in furnace cooling, t.he austenite
+ferrite transformation will take place a t or near the
equilibrium transformation temperature, the carbide
will be rejected in a pattern of thin plates or lamellae
separated by ferrite, and the steel will be quite ductile.
This structure, a s viewed in the metallurgical microscope, is known to the metallographer a s " pearlite," and
is illustrated in Fig. 2. If the cooling from austenite is
somewhat more rapid, the austenite + ferrite change
will be depressed below the 1,350-deg.-F. (730-deg.-C.)
equilibrium temperature; in other words, the austenite
Fig. 2
are the carbide laminations rendered visible. A correlation between hardness and actual spacing of the carbide
plates in pearlitic steels has been made by 0.V. Greene,=
as illustrated in Fig. 5.
At a certain critical rate of cooling from the austenitic
condition, and a t all faster rates, the carbide i s not
rejected at the time of the austenite +ferrite reaction, but is retained in solid solution a t temperatures
even a s low as atmospheric; the austenite +ferrite
transformation does take place, however, in these
quenching treatments-and,
since alpha-iron is relatively incapable of dissolving carbon under equilibrium
conditions, this solid solution formed on quenching is
Fig. 3
Fig. 4
Hardness
Cooling
Figure
Product
Rate
No.
2 . ........ .Very slow ........... .Very coarse pearlite. ........... 5
163
3 . .........Slow ................ .Medium coarse pearlite. ........ 15
207
4. ........ .Moderately rapid ..... .Fine pearlite .................. 38
363
Structural Differences Resulting When the Same Steel Is Cooled at Different Rates, with Consequent Differences
in Actual Transformation Temperature (Original Magnification 2,500X ; Picric-Acid Etch).
FIG. 2, 3, AND 4
will be under-cooled; the carbide will .precipitate in
the form of thinner and more closely-spaced plates than
in the instance of slow cooling, due to the fact that the
rejection takes place a t a lower temperature; the steel
will be harder, stronger, and less ductile a s compared
to the very slowly-cooled product. The structure is of
the pearlitic type, but of a fine variety, as illustrated in
Fig. 3. At still faster rates of cooling of the austenite,
the transformation and accompanying rejection of carbide is depressed to still lower temperatures with increased closeness of spacing of the carbide plates and
consequent hardening and strengthening of the metal
with decrease in its ductility. The microstructure is
still of the pearlitic type, but of such a degree of fineness that i t is not completely resolved by lenses of the
highest power; a n example of this very fine pearlite is
shown in Fig. 4, and i t is seen that only in a few places
1
1
unstable, or super-saturated, and carbide tends to precipitate from i t on the slightest provocation. This
unstable solid solution of carbon in alpha-iron, which
is known to the metallographer a s " martensite," is the
chief constituent of fully-hardened steel; i t is glass-hard
and brittle, and its microscopic appearance is shown in
Fig. 6. At intermediate cooling rates, mixtures of the
two structures (pearlitic and martensitic) may be
formed as a result of part of the transformation taking
place a t the higher temperatures (to pearlite) during
cooling and part a t the lower temperatures (to martensite) ; this is known as the " split transformation."
The foregoing discussion of the effect of cooling rate
upon the gamma + alpha transformation and the resulting pearlitic and martensitic structures is well
summarized in Fig. 7, taken from one of E. C. Bain's
publications.
higher the tempering temperature, the coarser the particles of carbide and the softer and more ductile the
steel.
I t should be apparent from the foregoing discussion
that the existence of the two forms of iron and the
action of carbon in forming the hard carbide, Fe3C, a r e
of almost equal importance in giving rise to the useful
properties of steel. Without the 'two allotropic forms
of iron-gamma and alpha, austenite and f e r r i t e w e
could not vary a t will the distribution of carbide in the
ferrite matrix and thereby attain the wide variety of
mechanical properties which make ferrous materials
so valuable; on the other hand, without carbon we
Microstructure of Two Steels of Approximately the Same Carbon Content, Both Furnace-cooled from 1,600 Deg. F.,
Showing Influence of Alloy Addition (Original Magnification 1,000 X ).
FIG. 8 AND 9
""
Shallow-Carbon Steel.
Medium-Chromium Steel.
Deep-Chrome-Nickel Steel.
Deeper Hardenability Contributed by Alloying Elements.
(E. C. Bain)
FIG. 10
7 8 9 1 0 / / / Z
PER CENT AAL LOYING ELEMENT, N/,CR.MN
TABLE 1
Effect of Alloying Elements on Tempering Behavior
Analysis of Steel
I
Carbon
(Per Cent)
0.36
0.32
0.35
0.32
0.41
Chromium
(Per Cent)
Molybdenum
(Per Cent)
0.56
0.56
2.11
5.06
5.08
...
...
...
...
1.88
Analysis of Steel
h
Chro+um
(Per Cent)
Carbon.
(Per Cent)
0.36
0.38
0.37
...
...
.3.60
4.48
r
'
. .
Carbon
(Per Cent)
0.36
0.33
0.35
0.32
...
0.59
.
Molybdenum
(Per Cent)
Chromium
(Per Cent)
...
1.94
2.02
...
Molybdenum
(Per Cent)
...
...
0.52
5.06
'
Rockwell C :
33.9
41.6
45.7
47.0
51.3
Converted Brine11
321
401
444
.
461.
.
495
'
A . S . Z M. G R A I N S I Z E N U M B E R
.
.
220
MATERIALS
111. THE HEAT TREATMENT OF STEEL
is to be construed a s applying only to medium- or highcarbon steels in which there is considerable carbon for
effective combination with the carbide-forming elements.
. .
To Stabilize
Ferrite
Chromium
Tungsten
Molybdenum
Vanadium
Silicon
Phosphorus
Aluminum
Titanium
Zirconiunl
Tin
To Increase Hardenability
.To Strengthen
Ferrite
Manganese (strong)
Chromium (strong)
Silicon (strong)
Nickel (moderate)
Molybdenum (moderate)
Tungsten (moderate) .
Aluminum (moderate)
Vanadium (nloderate)
Copper (moderate)
Titanium (weak)
.
Cobalt (weak)
Zirconium (probably
weak)
Phosphorus ?
Nitrogen ?
Oxygen ?
Manganese (strong)
Silicon (strong)
Nickel (strong)
Cobalt (strong)
Aluminum (strong)
Chronliuln (moderate)
Copper (moderate)
Molybdenum (weak)
Tungsten (weak)
Vanadium (weak)
Titanium (weak) .
Zirconium (weak)
Phosphoru's ?
Nitrogen ?
Oxygen ?
To Increase Resistance
to Corrosion
Chromium
Copper
Nickel
Aluminum
Silicon
Molybdenunl
Tungsten
To Increase Resistance to
Oxidation (Scaling)
Aluminum
Silicon
Nickel
Copper
Molybdenum
Tungsten '
TABLE 2
A. High-Alloy Steels
Ferritic Type
Straight-Chromium Stainless Alloys *
(SAE 51,000 Series)
12-14 per cent chromium; 0.25-0.40 per cent carbon
11.5-18 per cent chromium; 0.12 per cent carbon (maximum)
25-30 per cent chromium
4-6 per cent chromium
27 per cent chromium; 3.5 per cent nickel; 1.5 per cent
molybdenum
High-Speed Steels
18 per cent tungsten; 4 per cent chromium; 1 per cent
vanadium
12.5-21 per cent tungsten; 4 per cent'chromium; 0.75-2.0
per cent vanadium; 3.5-13 per cent cobalt; 0.40-0.80
per cent molybdenum
8 per cent molybdenum; 2 per cent tungsten; 4 p e r cent
chromium; 1per cent vanadium
9.5 per cent molybdenum; 3.5 per cent chromium; 1.25
per cent vanadium
High-Silicon Trunsfornzer Steel
4 per cent silicon (low-carbon)
Pernzunent Magnet Steels
Containing various combinations of:
Carbon
(0.40-1.20 per cent)
Manganese
(0.10-4.8 per cent)
Chromium
(0.20-10.0 per cent)
Tungsten
(5.0-9.0 per cent)
Cobalt
(13.0-40.0 per cent)
Molybdenum (2.0-4.0 per cent)
Special 'Tool and Die Steels
Containing various combinations of carbon, chromium,
tungsten, molybdenum, manganese, vanadium, silicon,
cobalt
'
An excellent classification and summar of typical properties of the stainless steels and a l l o ~ shas been published by Wright and
Luger (see bibliography, p. 225, reference 14y.
TABLE 3
B. Low-Alloy Steels
(Total alloy content generally less than 5 per cent)
TABLE 3-Continued
Nickel-Ckromiz~mSteels
1.00-1.50 per cent nickel; 0.45-0.75 per cent chromium
SAE 3100 series:
1.00-1.50 per cent nickel; 0.60-0.90 per cent chromium
SAE X3140:
1.50-2.00 per cent nickel; 0.90-1.25 per cent chromium
SAE 3200 series:
3.25-3.75 per cent nickel; 1.25-1.75 per cent chro~nium
SAE 3300 series:
2.75-3.25 per cent nickel; 0.60-0.95 per cent chromium
SAE 3400 series:
Molubdenum Steels (Cr-Mo; Cr-Ni-Mo; Ni-Mo)
0.50-0.80 per cent and 0.80-1.10 per cent chromium: 0.15-0.25 per cent molybdenum
SAE 4100 series:
0.50-0.80 per cent chromium; 1.50-2.00 per cent nickel; 0.30-0.40 per cent molybdenum
SAE 4340:
0.60-0.90 per cent chromium; 1.50-2.00 per cent nickel; 0.15-0.25 per cent molybdenum
SAE 4345:
1.65-2.00 per cent nickel; 0.20-0.30 per cent molybdenum
SAE 4600 series:
3.25-3.75 per cent nickel; 0.20-0.30 per cent molybdenum
SAE 4800 series:
Chromiztm Steels
SAE 5120:
0.60-0.90 per cent chromiun~
0.80-1.10 per cent chromiunl
SAE 5140 and 5150:
SAE 52100:
1.20-1.50 per cent chromium
I
CI~romiz~m-Va?xadiu?n
Steels
0.80-1.10 per cent chromium; 0.15 per cent vanadium (minimum)
SAE 6100 series:
T7~ngsten Steels (Chromium)
SAE 71360:
3.0-4.0 per cent ch+onlium; 12.0-15.0 per cent tungsten
SAE 71660:
3.0-4.0 per cent chromium; 15.0-18.0 per cent tungsten
SAE 7260:
0.50-1.0 per cent chromium; 1.5-2.00 per cent tungsten
Silicon-Manganese Steels
0.60-0.90 per cent manganese; 1.80-2.20 per cent silicon
SAE 9200 series:
Miscelluneous Low-Alloy Steels Comn~nerciall~
Ayailable *
1. Copper-cl~romium-silicon-phosphorus
steel (" Cor-Ten ")
0.30-0.50 per cent copper; 0.50-1.50 per cent chromium; 0.50-1.00 per cent silicon; 0.10-0.20 per cent phosphorus; 0.10 per cent carbon
2. Manganese steel (" Man-Ten ")
1.25-1.70 per cent manganese; 0.35 per cent carbon; with or without 0.20 per cent copper
3. Silicon steel (" Sil-Ten ")
0.20-0.30 per cent silicon; 0.70-0.90 per cent manganese; 0.40 per cent carbon; with or without 0.20 per cent
copper
4. Manganese-copper-nickel-molybdenum steel (" Double Strength ")
0.50-1.00 per cent manganese; 0.50-1.50 per cent copper; 0.40-0.80 per cent nickel; 0.20 per cent molybdenum
(maximum)
I n two grades, with carbon 0.12 per cent (maximum) and 0.30 per cent (maximum)
5. Copper-bearing steel
0.15-0.30 per cent copper; carbon usually under 0.15 per cent
6. Copper-molybdenum steel (" Toncan ")
0.40 per cent copper (minimum) ; 0.05 per cent nlolybde~lum(minimum) ; carbon usually under 0.05 per cent
7. Chromium-manganese-silicon steel
0.30-0.70 per cent chromium; 0.90-1.50 per cent manganese; 0.60-0.95 per cent silicon; 0.35 per cent carbon
(maximum)
8. Chromium-manganese-molybdenum steel
0.60-0.90 per cent chromium; 1.20-1.50 per cent manganese; 0.25-0.40 per cent molybdenum; 0.25-0.40 per
cent carbon
9. Chromium-molybdenum-silicon steel
1.50-2.00 per cent chromium; 0.60-0.80 per cent molybdenum; 0.45-0.75 per cent silicon
In two grades, with carbon 0.15-0.20 per cent, and 0.35-0.45 per cent
10. Carbon-mblybdenum steel
0.30-0.80 per cent manganese; 0.40-0.60 per cent molybdenum; 0.35 per cent carbon (maximum)
11. Carbon-molybdenum steel
0.80-1.10 per cent manganese; 0.25 per cent molybdenum; 0.40-0.70 per cent carbon
12. Chromium-molybdenum steel
1.00-1.50 per cent chromium; 0.40-0.60 per cent molybdenum; 0.50-0.80 per cent silicon; 0.40-0.70 per cent
manganese; 0.42-0.50 per cent carbon
* This list
i s ndnlittedly f a r from conlplete: to hare included all the compositions and trade names mould have made it unduly long.
. ,
FUNDAMENTAL
CHARACTERISTICS
OF ALLOYSTEEL
readers who may not be familiar with metallographic
terminology; these terms have also been defined in the
body of the paper where they first occur.
Alcstenite-Gamma-iron
solid solution, stable only a t
temperatures above the transformation or critical
range; capable of dissolving carbon in amounts up to
about 1.7 per cent; crystal structure face-centered cubic.
F e r r i t e A l p h a - i r o n solid solution, stable only a t
temperatures below the transformation or critical
range; capable of dissolving carbon in amounts less
than about 0.04 per cent; crystal structure body-celltered
cubic.
compound, Fe3C, in plain-carbon
Carbide-Chemical
steels or special carbide compound in steels containing
strongly carbide-forming elements.
Pearlite-Aggregate
of ferrite and carbide formed
directly from austenite on cooling, alld consisting ,f
alternate lamellae of the two constituents. The spacing
between the lanlellae of ferrite and carbide is dependent
upon the temperature of transformation from austenite;
the lower the temperature (within limits) the finer the
spacing.
Martensite-Unstable
alpha-iron solid solution with
the carbon in some unstable unrejected form; results
from low-temperature transformation of austenite induced by rapid cooling.
225
BIBLIOGRAPHY
'1'. R . Brnce. " Special Metals in Oil-Field Practice,'' Metals
arid A l l o ~ s ,1S1, Sept. ( 1 0 3 4 ) .
2 " Xletnls Used i n t h e Oil I n d u s t r y , dletal Proyress, 47, Apr.
E. C. Bnjp, " Some ~ 1 ; n r a c t e r i s t i c s Common t o Carbon nnd
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