Professional Documents
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Engineering Thermoplastics
Perspectives for the 21st Century
Dr.Gregory R. Gillette
Manager-Strategic Materials Program
GE Corporate Research and Development
Schenectady, NY
12309
Acknowledgments
Dan Brunelle-CRD
Ray Naar-GEP
Jon Rich-BF Goodrich
Carolyn Warden-CRD
Pam Northrop-CRD
GE CRD
GE CRD
Outline
Introduction
GE
GE Plastics
Definition of ETP
General Trends in ETP
Outlook for
Silicones
Polycarbonates
Crystalline Resins
Polyimides/High Temperature Resins
POSS in ETP
Discussion
GE CRD
GE CRD
GE Aircraft Engines
GE Appliances
GE Capital Services
GE Industrial Systems
GE Lighting
GE Medical Systems
GE Plastics
GE Power Systems
NBC
5-00
Great Britain
Appliances (GDA)
Lighting Systems
The Netherlands
Engineering Plastics (AKU)
GE CRD
France
Aircraft Engines (SNECMA)
Engineering Plastics
Medical Systems
Russia
Aircraft Engines Turbines (GE/VIAM, GE/IMSP)
Spain
Power Controls
Japan
Engineering Plastics
Medical Systems (YMS)
Silicone Products (Tosil)
China
Aircraft Engines
(GE/BIAM, CSUT)
Medical Systems
(GE/NIM, BRIRE, SICCAS)
Mexico
Appliances
Ukraine
Aircraft Engines
Turbines
United States
Aircraft Engines, Lynn, MA
Aircraft Engines, Evendale, OH
Medical Systems, Waukesha, WI
Appliances, Louisville, KY.
Communications, Raleigh, N.C.
Corporate R&D, Schenectady, N.Y.
Elec. Distribution Equipment,
Plainville,Ct.
Greg Gillette-GE CRD
Engineering Plastics, Pittsfield, MA
India
Engineering
Plastics
(GE/NCL)
Medical
Systems
99 RD&E: $1.9B
RD&E staff:
7300 U.S.
1800 non-U.S.
Many RD&E
approaches
3-00
GE Plastics Business
Resin
Business
GE CRD
$6.9
$6.9billion
billionin
insales
salesfor
for1999
1999
Greg Gillette-GE CRD
Engineering Thermoplastics-Definition
GE CRD
GE CRD
PPS
4%
PEI
1% Acetal
10%
PPO
7%
PES
1%
PC
13%
GE CRD
ETP-Business Trends
Forces Driving Reduced Time to ROI
High investor expectations (Stock Performance)
E-commerce (Rapid Information Exchange)
Global competition (Cost Pressure/Commoditization)
Time Scale for Technology Innovation Static
How does the Industry Accelerate Innovation
Reorganizations, restructuring, mergers
Growth Through Acquisition vs Organic Growth
Joint Venturing/Resource pooling
Tilt to life sciences and/or Core Business
(DuPont, Hoescht/ Ticona)
(Shell, BP Amoco)
Specialized vs. Diversified Portfolios ?
Globalization
Combi Chem
Time Scale of Technology Innovation vs Time to ROI
Greg Gillette-GE CRD
GE CRD
GE CRD
Polyimides, Polysulfones,
PEEK, LCPs, etc
High
Perf.
Engineering
Thermoplastics
Commodity
Thermoplastics
GE CRD
ETP-Market Trends
GE CRD
ETP-Major Markets
GE CRD
Polycarbonate Chemistry
GE CRD
Melt Process
O
catalyst
+
HO
PhO
OH
OPh
150-320oC
PhOH
Research Areas:
O
MeOH + CO
Advantages:
MeO
OPh
OMe
Interfacial Process
O
R 3N
+
HO
OH
+ ArOH
Cl
Cl
CH2Cl2 / NaOH
Ar
Research areas:
Advantages:
OAr
n
GE CRD
Development
Pilot
Commercial
P(Cyclocene Y)
PCHE
PCXA
Appear
Optorez
Topas
Arton
Zeonex
Material
Ethyl/phenyl
norbornene
copolymer
Hydrogend
Polystyrene
P(cyclohexane)
(Substituted)
norbornene
copolymer
Methyl/
norbornyl
methacrylate
Ethylene/
norbornene
copolymer
Norbornyl
adduct
(polar)
Norbornyl
adduct
Process
Metallocene
Fr. Radical + H 2
Anionic + H 2
Cationic
Fr. Radical
Metallocene
ROMP + H2
ROMP + H2
Producer
OPTATECH
DOW
ASAHI
BF GOODRICH
HITACHI
HOECHST
JSR
NIPPON
ZEON
intrinsic
birefringence
<PC
<PC
<PC
<PC
<<PC
<<PC
<<PC
% Water
absorption
<<PC
<<PC
<<PC
<<PC
0.2
<PC
<PC
<<PC
Tg( C)
113
145
to 235
to 330(390)
143
to 170
171
140
Impact
25 kJ/m2
Charpy, notch
good
<<PC
Elongation
break = 20%
<PC
<<PC
<<PC
<<PC
Others:
GE CRD
Crystalline--New Developments
GE CRD
Monomers:
GE CRD
250
2002 Data
200
MM lbs
Total Market
PPE
1997 Fit
2002 Fit
150
100
PPS
PSO
50
PEA PES
PEI
0
0
4
Price $/lb
Polyetherimides-Market Breakdown
Houseware
Packaging
14%
18%
E/E
7%
Houseware
Other
Medical
25%
CEIS
7%
12%
16%
14% Other
E/E 13%
43%
31%
Automotive
Automotive
Growth Platforms
Cookware
10%
Metallizing
40%
10%
40%
All Other
Dimensional
Stability
GE CRD
GE CRD
Weatherable
Parting Thoughts
The 21st century will bring many new things; expect surprises
GE CRD
Resin Types
GE CRD
O
n
n
Polysulfones
O
O
O
O
n
Resin Types
GE CRD
Nylons
N
H
O
R
O
N
H
R' n
R n
Nylon 6 and Nylon 6,6 largest volumes (~600,000 t/yr non-fiber), with
modest growth (5-8%/yr). Amorphous nylons only ~1000 t/yr,but with
higher growth. Fast-crystallizing polymer with HDT 194oC (6,6) and 129 oC
(6). from mp of 270oC and 228 oC, respectively. Poor impact strength. Good
hydrolytic stability but high water absorption (10%) and mold shrinkage.
Small parts, electrical, building construction applications, under-the hood
automotive.
Resin types
GE CRD
O
O (CH2)n O
Polyesters
n = 2,3,4
O
Polycarbonates
O
O
O
n