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I. Determine what is oxidized and what is reduced in each reaction. Identify the oxidizing
agent and the reducing agent, also.
1. 2Sr + O2
2. 2Li + S
2SrO
Li2S
3. 2Cs + Br2
2CsBr
4. 3Mg + N2
Mg3N2
5. 4Fe + 3O2
2Fe2O3
6. Cl2 + 2NaBr
7. Si + 2F2
8. 2Ca + O2
2NaCl + Br2
SiF4
2CaO
9. Mg + 2HCl
MgCl2 + H2
2NaOH + H2
b. Sn
c. S2-
d. Fe3+
e. Sn4+
f. nitrate
g. ammonium
b. Na2Cr2O7
c. CrSO4
d. chromate
e. dichromate
13. Use the changes in oxidation numbers to determine which elements are oxidized and which
are reduced in these reactions. (Note: it is not necessary to use balanced equations)
a. C + H2SO4
b. HNO3 + HI
NO + I2 + H2O
c. KMnO4 + HCl
d. Sb + HNO3
14. For each reaction in problem 13, identify the oxidizing agent and reducing agent.
15. Write half-reactions for the oxidation and reduction process for each of the following.
a. Fe2+ + MnO4b. Sn2+ + IO3c. S2- + NO3d. NH3 + NO2
Fe3+ + Mn2+
Sn4+ + IS + NO
N2 + H2O
16. Complet and balance each reaction using the half-reaction method.
a. Fe2+ + MnO4b. Sn2+ + IO3c. S2- + NO3d. NH3 + NO2
Fe3+ + Mn2+
Sn4+ + IS + NO
N2 + H2O
e. Mn2+ + BiO3-
Bi2+ + MnO4-
f. I2 + Na2S2O3
Na2S2O4 + NaI
Li2S
3. 2Cs + Br2
2CsBr
4. 3Mg + N2
Mg3N2
5. 4Fe + 3O2
2Fe2O3
6. Cl2 + 2NaBr
7. Si + 2F2
SiF4
9. Mg + 2HCl
MgCl2 + H2
14. For each reaction in problem 13, identify the oxidizing agent and reducing agent.
a. oxidizing agent: sulfur
reducing agent: carbon
b. oxidizing agent: nitrogen
reducing agent: iodine
c. oxidizing agent: manganese reducing agent: chlorine
d. oxidizing agent: nitrogen
reducing agent: antimony
15. Write half-reactions for the oxidation and reduction process for each of the following.
Fe3+ + Mn2+
a. Fe2+ + MnO4Fe3+; oxidation
Mn7+
Mn2+; reduction
Fe2+
Sn4+ + Ib. Sn2+ + IO3Sn4+; oxidation
I5+
I1-; reduction
Sn2+
S + NO
c. S2- + NO32S; oxidation
N5+
N2+; reduction
S
N2 + H2O
d. NH3 + NO2
30
N ; oxidation
N4+
N0; reduction
N
16. Complete and balance each reaction using the half-reaction method.
a. Fe2+ + MnO4Fe3+ + Mn2+
Fe3+ + 1e-] x 5
[Fe2+
2+
+
5Fe3+(aq) + Mn2+(aq) + 4H2O(l)
Mn2+ + 4H2O 5Fe (aq) + MnO4 (aq) + 8H (aq)
MnO4- + 8H+ + 5eSn4+ + Ib. Sn2+ + IO32+
+
Sn4+ 2+
Sn6H
3Sn4+(aq) + I (aq) + 3H2O(l)
(aq) + 3Sn (aq) + IO3 (aq)
IIO3S + NO
c. S2- + NO3+
223S(s) + 2NO(g) +4H2O(l)
S8H (aq) S+ 3S (aq) + 2NO3 (aq)
NO
NO3N2 + H2O
d. NH3 + NO2
8NH
7N2(g) + 12H2O(l)
NH33(g) + N6NO
2 2(g)
N2
NO2
2+
Bi2+ + MnO4e. Mn + BiO3- +
2+
3Mn
5Bi2+(aq) + 3MnO4-(aq) + 3H2O(l)
MnO
Mn2+
3 (aq)
(aq) + 5BiO
4 + 6H (aq)
BiO3Bi2+
Na2S2O4 + NaI
f. I2 + Na2S2O3
NaI+ H2O(l) + I2(s) + 2Na+(aq)
I2 2S2O3(aq)
Na
Na2S2O4(aq) + 2H+(aq) + 2NaI(aq)
Na2S2O4
Na2S203