Professional Documents
Culture Documents
DAS CRUDE
ANALYSIS
September 2015
Korangi Creek Rd., P.O. Box 4612, Karachi-74000. Phone: 5091771-79, 5091811-6 Fax: 92-21-5060145, 5091780
Website: www.prl.com.pk
SUMMARY
The Narrow Cut TBP Distillation on DAS CRUDE crude was performed twice. In two
Runs 6000 ml (approx.) samples were used. The Primary Products Yield at the PRL cut
points are based on the average of the two Runs while detailed testing of these cut fractions was
carried out on the fractions obtained from the first and second Run. Gas oil and Residue yields
at revised cut points of 235-400 C and 400 C plus (revamp cut points) were also established.
The Test Method ASTM D-2892 was followed. The column used was of 50 mm diameter,
Tilting Funnel Type having 15 theoretical plates packed with Helipak packing. Each fraction
was weighed and specific gravity was determined at 60/60 F. The volume yields have been
calculated from the weight of each fraction and its respective specific gravity.
The DAS CRUDE Assay includes the following determinations:
TBP distillation into wide cuts corresponding to the following PRL cut fractions:
-
Gas/LPG
Light Naphtha
Heavy Naphtha
Kerosene
Gas Oil
Residue
Gas Oil
Residue
0-40
40-110
110-145
145-235
235-371
371
235-400
400
C
C
C
C
C
C plus
C
C plus
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
M.T KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.8271
ASTM D-1298
API Gravity @ 60 F
39.57
ASTM D-97
Pour Point
minus 18
ASTM D-323
Psi
6.2
ASTM D-3230
Salt Contents
PTB
2.8
ASTM D-4294
Total Sulfur
%wt
1.1420
ASTM D-445
Kinematic Viscosity @ 40 C
cSt
2.9952
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
2.2810
ASTM D-1796
BS&W
%Vol
0.1
ASTM D-473
Sediments
%wt
0.05
ASTM D-95
Water
%vol.
Traces
UOP-375
Characterization factor
11.90
ASTM D-974
mg KOH/g
0.05
UOP-163
Hydrogen Sulfide
ppm
0.2
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
M.T KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-240
BTU/lb
19300
ASTM D-5863
Vanadium Contents
ppm
2.2
ASTM D-5863
Sodium Contents
ppm
< 1.0
UOP-163
Mercaptan Sulphur
ppm
104
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
The DAS CURDE Oil was fractionated into cuts approximating the PRL cut fractions under
the following conditions:
FRACTION
FRACTIONATION
COLUMN
PRESSURE
(mm Hg)
Light Naphtha
15 plate
Atmospheric
Column with Helipak Packing
Packed Height: 48 cm
Diameter: 50 mm
5/1
Heavy Naphtha
15 plate
Atmospheric
Column with Helipak Packing
Packed Height: 48 cm
Diameter: 50 mm
5/1
Kerosene
15 plate
Atmospheric/
5/1
Column with Helipak Packing
100 mm of Hg
Packed Height: 48 cm
Diameter: 50 mm
Gas Oil
15 plate
2.00 mm of Hg
Column with Helipak Packing
Packed Height: 48 cm
Diameter: 50 mm
2/1
Residue
15 plate
Column with Helipak Packing
Packed Height: 48 cm
Diameter: 50 mm
REFLUX
RATIO
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
Deg C
7.15
10
7.98
15
8.81
20
9.77
25
30
35
40
45
4.97
5.57
50
6.28
100
14.77 15.57 16.36 17.03 18.03 19.32 20.78 21.87 23.28 24.61
150
25.57 26.62 27.92 29.21 30.51 31.72 33.01 34.02 35.23 36.35
200
37.89 39.02 39.64 40.39 41.43 42.35 43.14 44.25 44.92 45.88
250
46.84 47.59 48.54 49.38 50.25 51.04 51.92 52.92 53.79 54.71
300
55.62 56.54 57.33 58.37 59.33 60.25 61.04 61.87 62.75 63.79
350
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
Deg C
7.15
10
7.98
15
8.81
20
25
9.77
30
35
40
45
4.97
5.57
50
6.28
100
14.77 15.57 16.36 17.03 18.03 19.32 20.78 21.87 23.28 24.61
150
25.57 26.62 27.92 29.21 30.51 31.72 33.01 34.02 35.23 36.35
200
37.89 39.02 39.64 40.39 41.43 42.35 43.14 44.25 44.92 45.88
250
46.84 47.59 48.54 49.38 50.25 51.04 51.92 52.92 53.79 54.71
300
55.62 56.54 57.33 58.37 59.33 60.25 61.04 61.87 62.75 63.79
350
64.66 65.87 66.92 68.10 69.32 70.58 71.39 72.36 73.18 73.59
400
74.08
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
FRACTION
PERCENT WEIGHT
PERCENT VOLUME
Gas/LPG
(0 40 C)
3.45
4.97
Light Naphtha
(40 110 C)
9.65
11.39
Heavy Naphtha
(110 145 C)
7.50
8.25
Kerosene
(145 235 C)
18.75
19.64
Gas Oil
(235 371 C)
25.80
25.07
Residue
(371 C Plus)
34.85
30.68
Gas Oil
(235 400 C)
30.82
29.83
Residue
(400 C Plus)
29.83
25.92
PRL/DAS CRUDE
REF: TBP-01/2015
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
LIGHT HYDROCARBONS
PERCENT VOLUME
ON CRUDE
Ethane
0.02
Propane
0.31
Iso-Butane
0.33
n-Butane
1.42
iso-Pentane
0.44
n-Pentane
0.46
12
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.7036
ASTM D-1298
API Gravity @ 60 F
69.61
ASTM D-3242
Acid Number
mg KOH/g
0.010
ASTM D-611
Aniline Point
59.0
ASTM D-130
3b
ASTM D-1218
Refractive Index @ 20 C
1.3960
ASTM D-323
ASTM D-156
Color Saybolt
ASTM D-4294
Total Sulfur
ppm
290
UOP-163
Mercaptan Sulfur
ppm
225
UOP-313
Nitrogen Base
ppm
Nil
ASTM D-2699
RON F1 Clear
UOP-375
Characterization Factor
12.40
ASTM D-1319
Aromatics
% Vol
7.4
Psi
4.0
+ 30
58.5
13
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
ASTM D-86
Distillation
RESULT
IBP
10 % Vol
30 % Vol
50 % Vol
70 % Vol
90 % Vol
End Point
56
74
80
86
93
104
119
Residue
Loss
% Vol
% Vol
14
0.5
1.0
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.7525
ASTM D-1298
API Gravity @ 60 F
56.54
ASTM D-2386
Freezing Point
< - 80
ASTM D-381
Existent Gum
mg/100 ml
1.0
ASTM D-1218
Refractive Index @ 20 C
1.4220
ASTM D-156
Color Saybolt
+ 30
ASTM D-4294
Total Sulfur
ppm
415
UOP-163
Mercaptan Sulfur
ppm
150
UOP-313
Nitrogen Base
ppm
Nil
ASTM D-2699
UOP-273
PONA Analysis
42.0
% Vol
Paraffins
Olefins
Naphthenes
Aromatics
64.2
Nil
23.1
12.7
16
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
UOP-375
Characterization Factor
ASTM D-86
Distillation
IBP
10 % Vol
30 % Vol
50 % Vol
70 % Vol
90 % Vol
End Point
11.85
119
122
125
127
132
139
154
Residue
Loss
% Vol
% Vol
17
1.0
Nil
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
KEROSENE ANALYSIS
CUT RANGE 145 235 C
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.7900
ASTM D-1298
API Gravity @ 60 F
47.61
ASTM D-3242
Acid Number
mg KOH/g
0.058
ASTM D-611
Aniline Point
56.5
ASTM D-1218
Refractive Index @ 20 C
IP-170
Flash Point
43.0
ASTM D-2386
Freezing Point
- 49.0
ASTM D-381
Existent Gum
mg/100 ml
1.0
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
0.9734
ASTM D-130
2a
ASTM D-156
Color Saybolt
+30
ASTM D-1322
Smoke Point
mm
29
UOP-163
Mercaptan Sulfur
ppm
68.6
UOP-313
Nitrogen Base
ppm
0.1
19
1.4420
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
KEROSENE ANALYSIS
CUT RANGE 145 235 C
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1319
Aromatics
% Vol
17.9
ASTM D-3338
MJ/Kg
43.25
ASTM D-4294
Total Sulfur
ppm
672
UOP-375
Characterization Factor
11.78
ASTM D-86
Distillation
IBP
10 % Vol
30 % Vol
50 % Vol
70 % Vol
90 % Vol
End Point
156
166
174
184
197
214
225
Residue
Loss
% Vol
% Vol
20
1.0
Nil
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.8514
ASTM D-1298
API Gravity @ 60 F
34.70
ASTM D-611
Aniline Point
ASTM D-130
ASTM D-93
Flash Point
126.5
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
3.2292
ASTM D-2500
Cloud Point
ASTM D-6371
CFPP
minus 02
ASTM D-97
Pour Point
minus 06
ASTM D-1500
Color
ASTM D-4294
Total Sulfur
ASTM D-976
Cetane Index
UOP-375
Characterization Factor
11.78
ASTM D-240
Btu/lb
19600
68.8
1a
< 1.0
% wt
1.0614
51.68
22
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
ASTM D-86
Distillation
RESULT
IBP
10 % Vol
30 % Vol
50 % Vol
70 % Vol
90 % Vol
End Point
262
276
282
293
308
330
344
Residue
Loss
% Vol
% Vol
23
1.0
Nil
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
RESIDUE ANALYSIS
CUT RANGE 371 C PLUS
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.9387
ASTM D-1298
API Gravity @ 60 F
19.24
ASTM D-93
Flash Point
204
ASTM D-97
Pour Point
24
UOP-375
Characterization factor
19.24
ASTM D-189
Carbon Residue
% wt
9.1
ASTM D-482
Ash Content
% wt
0.06
ASTM D-473
Sediments
%wt
0.02
ASTM D-1796
BS & W
%Vol
0.1
ASTM D-4294
Total Sulfur
% wt
2.4465
ASTM D-240
BTU/lb
18500
ASTM D-5863
Sodium Contents
ppm
3.0
ASTM D-5863
Vanadium Contents
ppm
12.0
ASTM D-95
Water
%vol.
traces
25
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
RESIDUE ANALYSIS
CUT RANGE 371 C PLUS
TEST METHOD
TEST DESCRIPTION
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
115.5
ASTM D-445
Kinematic Viscosity @ 60 C
cSt
66.56
ASTM D-445
Kinematic Viscosity @ 70 C
cSt
51.87
26
RESULT
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.8553
ASTM D-1298
API Gravity @ 60 F
33.94
ASTM D-611
Aniline Point
ASTM D-130
ASTM D-93
Flash Point
130
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
3.7500
ASTM D-2500
Cloud Point
ASTM D-6371
CFPP
ASTM D-97
Pour Point
minus 3
ASTM D-1500
Color
ASTM D-4294
Total Sulfur
ASTM D-976
Cetane Index
UOP-375
Characterization Factor
11.75
ASTM D-240
Btu/lb
19500
70.5
1a
< 1.5
% wt
1.1510
51.22
27
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
TEST METHOD
TEST DESCRIPTION
ASTM D-86
Distillation
RESULT
IBP
10 % Vol
30 % Vol
50 % Vol
70 % Vol
90 % Vol
End Point
260
265
280
298
317
348
365
Residue
Loss
% Vol
% Vol
28
1.0
Nil
PRL/DAS CRUDE
REF: TBP-01/2015
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
RESIDUE ANALYSIS
CUT RANGE 400 C PLUS
TEST METHOD
TEST DESCRIPTION
RESULT
ASTM D-1298
0.9401
ASTM D-1298
API Gravity @ 60 F
19.01
ASTM D-93
Flash Point
210
ASTM D-97
Pour Point
30
UOP-375
Characterization factor
11.75
ASTM D-189
Carbon Residue
% wt
10.5
ASTM D-482
Ash Content
% wt
0.03
ASTM D-473
Sediments
%wt
0.08
ASTM D-1796
BS & W
%Vol
0.1
ASTM D-4294
Total Sulfur
% wt
2.5665
ASTM D-240
BTU/lb
18400
IP-288
Sodium Contents
ppm
05
IP-288
Vanadium Contents
ppm
15
ASTM D-95
Water
%vol.
traces
30
TEST REPORT
Reference
Sample
Source
TBP-01/2015
DAS CRUDE
MT KARACHI
Testing Duration
Date of Sample
Sample Received
RESIDUE ANALYSIS
CUT RANGE 400 C PLUS
TEST METHOD
TEST DESCRIPTION
ASTM D-445
Kinematic Viscosity @ 50 C
cSt
270.0
ASTM D-445
Kinematic Viscosity @ 60 C
cSt
118.6
ASTM D-445
Kinematic Viscosity @ 70 C
cSt
73.25
31
RESULT