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ELEMENTS
Introduction
Elements are the simplest pure substances. They cannot
be broken down into anything simpler by chemical
means. The periodic table of the elements lists about
116 known elements. Of these, hydrogen is by far the
most abundant element in the universe. On Earth, oxygen
is the most abundant element due to its presence in
many rock-making minerals as well as its important roles
in the hydrosphere, atmosphere and biosphere. The great
majority of elements occur naturally but some have been
synthesised using high-powered particle accelerators.
In this chapter
2.1 Classifying elements
2.2 The properties and uses of elements
Figure 2.1
Blue-black crystals of the non-metal iodine sublime to
produce a purple vapour composed of diatomic iodine
molecules.
page 40
page 46
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Remember
Before beginning this section,
you should be able to:
describe the behaviour of
matter in terms of particles
that are continuously moving
and interacting
relate properties of solids,
liquids and gases to the
particle model of matter
relate changes of state to the
motion of particles as energy
is removed or added
explain density in terms of a
simple particle model
classify elements as metals or
non-metals according to their
common characteristics
identify internationally
recognised symbols for
common elements.
Key content
By the end of this section, you
should be able to:
classify elements as metals,
non-metals and semi-metals
according to their physical
properties
plan and perform an
investigation to examine some
physical properties, including
malleability, hardness and
electrical conductivity, and to
present information about the
classification of elements as
metals, non-metals or
semi-metals
process information from
secondary sources and use
the periodic table to present
information about the
classification of elements as:
metals, non-metals and
semi-metals
solids, liquids and gases
at 25 C and normal
atmospheric pressure.
Figure 2.2
Titanium (above) is a metal with a
low density while platinum (right) has
a high density.
40
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The physical properties of elements
Every pure substance has its own unique set of physical properties. These
physical properties include:
melting point the lowest temperature at which a solid changes to a
liquid at normal atmospheric pressure (100 kPa).
boiling point the lowest temperature at which a liquid changes to a
vapour such that the vapour exerts a pressure of 100 kPa.
density the mass of the substance per unit volume, measured at 25 C
and 100 kPa.
electrical conductivity the quantity of electric current transmitted
through a unit cube of the material when there is a potential difference
of 1 volt across the cube.
thermal conductivity the rate at which heat energy is transferred through
a unit cube of the material when there is a 1 temperature difference
across the cube.
These properties can be used to check whether an element is 100% pure
or contaminated by impurities. Chemical data books provide lists of these
physical properties for each natural element. Table 2.1 gives examples of
these physical properties for some common elements, showing that these
three elements are quite different. A chemist can check whether a sample
of copper is pure by measuring its physical properties. If the melting point
of the copper sample is not 1085 C, the sample must be contaminated with
impurities. Impurities tend to lower the melting points of pure substances.
Similarly, if a copper sample is impure, its density will not be 8.96 g/cm3.
Table 2.1 Physical properties of some common elements.
copper
iodine
silicon
1085
114
1410
2572
184
3267
Density (g/cm3)
8.96
4.94
2.3
58.4
1 1013
1 103
401
0.45
148
Element
(*K Kelvin temperature units each Kelvin unit is the same size as a Celsius degree;
100 C = 373 K and 0 C 273 K)
SOLUTION
320
323
326
327
327
327
328
330
333
336
Time (min)
Temperature (C)
SOLUTION
338
336
334
332
330
328
326
324
322
320
318
0
2.1 PRACTICAL
ACTIVITIES
Investigating the
physical properties
of elements
4
6
8
Time (minutes)
10
Figure 2.3
CHAPTER 2 ELEMENTS
41
SYLLABUS FOCUS
5. USING SYMBOLS TO IDENTIFY ELEMENTS
The study of chemistry is simplified by the use of symbols. Each element is identified by a unique
symbol that consists of one or two letters. The first letter is written in uppercase. If there is a second
letter, it is written in lowercase. The symbols chosen for elements are not always related to their
English names. The symbols for some elements are based on its Latin, Greek or German name. For
example, the symbol for gold is Au (from the Latin word aurum). Elements are often named after
mythological gods, countries, scientists, properties or astronomical objects. For example, gallium is
named after Gallia, the ancient name for France. Table 2.3 gives the origins of some element names.
Use the periodic table on the inside cover of this book to find other examples.
Table 2.3 Origins of some element names
Element
Symbol
Source of
element name
Category
curium
Cm
scientist
germanium
Ge
Germany
country
helium
He
astronomy
iodine
property
Th
mythology
thorium
Figure 2.4
Some elements are named
for their properties, such as
their colour (far right), while
others are named after famous
scientists, such as Marie and
Pierre Curie (above),
or figures in mythology, such
as Thor (right).
42
Physical state
He
N2
O2
F2
Ne
Cl2
Ar
Kr
Xe
Rn
Heating and cooling can convert elements from one state to another.
For example, gallium, which has a melting point of 30 C, can be liquefied
by holding it in your hand. Other elements require much more heat to
melt them.
SOLUTION
lustrous: shiny
malleable: able to be shaped
without breaking by rolling,
hammering or pressing
ductile: able to be drawn into
wires without breaking
brittle: describes a substance
that shatters into fragments
when hammered
CHAPTER 2 ELEMENTS
43
Table 2.5 provides a summary of the physical properties of metals, semimetals and non-metals, and some representative examples. In the year
2005, 116 elements were known. Of these, 92 are classified as metals, 7 as
semi-metals and 17 as non-metals. (Note: At the time of writing, element
117 had not been synthesised. The discovery of the synthetic element
ununoctium (118) has been retracted.)
Table 2.5 Physical properties of metals, semi-metals and non-metals
metals
semi-metals
non-metals
lustrous
low sheen
dull
Electrical conductivity
high
low
(semi-conductors)
nil
(insulators)
Thermal conductivity
high
high
low
(insulators)
high
moderate
nil (brittle)
Density
generally
high
intermediate
low
Boiling point
generally
high
very high
low
Strength
high
variable
low
Examples
sodium,
magnesium,
iron,
chromium,
zinc,
platinum,
gold,
mercury,
lutetium
boron,
silicon,
germanium,
arsenic,
antimony,
tellurium,
astatine
hydrogen,
helium,
carbon,
nitrogen,
oxygen,
fluorine,
neon,
phosphorus
Group
Appearance
silicon
(semi-metal)
sulfur
(non-metal)
Lustre
high
moderately high
low
Electrical
conductivity
(MS/m)
63
1 r 103
1 r 1021
Density (g/cm3)
10.5
Element
2.2 DATA
ANALYSIS
Classifying elements
44
2.3
2.1
962
1410
113
2212
3267
445
2.1 QUESTIONS
Temperature (C)
36
34
32
31
30
30
30
29
28
26
CHAPTER 2 ELEMENTS
45
'#'
Remember
Before beginning this section,
you should be able to:
identify internationally
recognised symbols for
common elements.
Key content
By the end of this section, you
should be able to:
explain the relationship
between the reactivity of an
element and the likelihood of
it existing as an uncombined
element
account for the uses of metals
and non-metals in terms of
their physical properties
plan and perform an
investigation to examine some
uses of a range of common
elements
analyse information from
secondary sources to
distinguish the physical
properties of metals and
non-metals.
Figure 2.5
Sodium is very reactive and must
be stored in the absence
of water and air.
Of the non-metals, fluorine and oxygen are the most reactive and
helium and neon are the least reactive. Helium and neon are examples of
noble gases. All the noble gases exist as free elements in nature.
Although oxygen is reactive and forms many compounds, it also exists
as a free element in the atmosphere due to the very low reactivity of nitrogen and argon gases. Other reactive elements can exist as free elements in
46
nature if they are in environments that protect them from reaction. Thus,
sulfur can be found in the lithosphere in vast subterranean ore bodies
because of its insolubility in water and its low reactivity with oxygen at low
temperatures. Table 2.8 lists the elements that can exist free in nature.
Table 2.8 Elements can exist free in nature or as alloys.
Exist separately as metals or as alloys with one another
Au
Ag
Hg
Pt
Pd
Os
Ir
Rh
Ru
Fe
Xe
Rn
N2
O2
Ne
Ar
Kr
Na
Least active
Ca
Mg
Al
Zn
Fe
Pb
Cu
Hg
Ag
Au
Uses of elements
The uses of elements are directly related to their physical and chemical
properties. For example, aluminium is a malleable metal that can be
readily formed into saucepans, window frames and thin foils for cooking.
Its high thermal conductivity allows rapid heat transfer to the food in
saucepans or through foil. Its high tensile strength and reduced tendency
to corrode makes it an excellent building material.
Table 2.10 lists some common elements and the properties that make
them useful in our society.
Table 2.10 Uses and properties of some elements
Element
Figure 2.6
Aluminium is a malleable metal. It can
be pressed and rolled
into sheets.
2.3 DATA
ANALYSIS
Use
copper
electrical wiring
iron
zinc
galvanising of iron
gold
ornaments, jewellery
argon
inert
helium
meteorological balloons
low density
silicon
semi-conductor
CHAPTER 2 ELEMENTS
47
2.2 QUESTIONS
1. Identify the metal that is used as a filament in
incandescent light bulbs.
A Iron
B Magnesium
C Tungsten
D Gold
2. Identify the list that correctly places the metals
in increasing order of chemical reactivity.
A Iron, calcium, lead, gold
B Silver, copper, iron, magnesium
C Copper, zinc, potassium, magnesium
D Potassium, zinc, iron, silver
3. Tungsten is a very useful metal. It can be
obtained from the mineral wolframite, so is
sometimes called wolfram, which provides
its symbol W. Wolframite is often found in
combination with tin ores and, in the early
days, this made the tungsten difficult to
isolate. Tungsten requires considerable heat
to melt; its melting point is 3410 C and
boiling point is 5930 C. The metal was first
used as the filament in electric light bulbs in
1913. Tungsten is classified as a heavy metal,
along with gold and platinum. Its density is
19.3 g/cm3; it has high tensile strength; its
carbide is exceptionally hard.
Identify the properties of tungsten that make it
suitable for use as (a) filaments in electric light
bulbs and (b) as a component of tool steel.
Property
1. high electrical
conductivity
2. low corrosion
C. carbon (graphite)
electrodes
3. high thermal
conductivity
D. gold jewellery
E. chromium stainless
steel sinks
SUMMARY
www.jaconline.com.au/chemnsw/chemistry1
48
PRACTICAL ACTIVITIES
2.1
Ammeter/milliammeter
( or lamp)
PRACTICAL
ACTIVITIES
Safety issues
Wear safety glasses throughout this experiment.
Do not touch iodine crystals or breathe the
vapours; examine them in a sealed tube.
Identify other safety issues relevant to this
experiment by reading the method.
Materials
samples (granules, wires, sheets) of zinc,
magnesium, iron, copper, lead, tin, aluminium,
sulfur (melted and allowed to cool into lumps),
red phosphorus, iodine, graphite (carbon) rods
1 cm cubes of various metals such as aluminium,
zinc, iron, copper, lead and tin
DC power supply
light bulb on stand
electrical leads/clips
ammeter
Petri dishes
electronic balance
10 mL measuring cylinder
ball hammer
Method
1. Appearance
For each element provided, describe its colour
and state whether it is lustrous or dull.
2. Electrical conductivity
(a) Set up a simple electrical circuit as shown
in figure 2.7 using a 12 V DC power supply
and electrical meters or lamps.
(b) Connect each element sample into the
circuit and measure the relative brightness
of the lamp (use a rating scale) or measure
the current on the ammeter/milliammeter).
Record your observations in your logbook.
+
+
Switch
DC power supply
02 V
Sample
Figure 2.7
Circuit for testing electrical conductivity
3. Density
(Note: Weigh samples in a dish or on filter
paper.)
(a) Some metal samples are available as 1 cm
cubes, so their volume is 1 cm3. Measure
their mass on an electronic balance and
calculate their density.
(b) For solid samples that are irregular in shape,
measure their mass on an electronic balance
and their volume by displacement of water
in a small measuring cylinder. Dry the
sample after use.
4. Malleability and hardness
(a) Use a ball hammer to determine whether
the solid samples deform or shatter when
struck. (Note: Iodine should be tested only
in a fume hood, using only one crystal.)
(b) Identify which samples are ductile by
finding out whether they are available
as wires.
(c) Identify which samples are malleable by
finding out whether they are available
as sheets.
Conclusion
Write a brief conclusion for this experiment.
CHAPTER 2 ELEMENTS
49
DATA ANALYSIS
2.2
DATA
ANALYSIS
CLASSIFYING ELEMENTS
Aim
To use second-hand data to classify elements as:
(a) solids, liquids or gases
(b) metals, non-metals or semi-metals
Materials
2 copies of the periodic table
coloured pencils or highlighters
Melting
point (C)
He
272
269
Li
180
1342
219
183
220
188
Ne
249
246
113
445
Cl
101
34
Ar
189
186
Se
217
685
Br
59
Kr
157
152
114
184
Xe
112
108
Rn
71
62
50
Boiling
point (C)
State (solid,
liquid or gas)
DATA ANALYSIS
Table 2.13
Element
symbol
Electrical
conductivity (MS/m)
1015
1021
Ga
3.9
Se
104
1013
Hg
Metal or
non-metal
1.0
2.3
DATA
ANALYSIS
ductility
malleability
low reactivity
low adherence to other materials such
as glass
high lustre and reflectivity
low melting point
high electrical conductivity
high density
uniform expansion rate on heating
Table 2.14
General questions
Element
silver
Use
mirrors
mercury
thermometers
tin
plating of steel
lead
soldering
(lead alloy)
lead
sinkers
(for fishing)
aluminium
nickel
chromium
Properties related
to use (a) (i)
high voltage
cables and wires
coinage
plating of steel
and copper
CHAPTER 2 ELEMENTS
51