2nd year

Subject: Chemistry
Total Marks: 40

Test No. C-II/C-8 (Test No.2)

Time: 1:15 Hours.

Students Name: _______________________________

Note: Overwriting cutting use of lead pencil is not allowed.

Q. No. 1

Encircle the correct Answer.

12x1=12

(i)

Marsh gas is:

(a) Ethane
(b) propylene (c) Acetylene (d) methane
(ii)
Acetylene Polymerize to make:
(a) Chloroprene
(b) Benzene
(c) Hexane (d) 1,3,5-cyclohexatriene
(iii)
Which types of reactions are given by alkanes?
(a) Polymerization (b) Elimination (c) Substitution
(d) Addition
(iv)
Which of the Following does not react with Baeyers reagent?
(a) Ethene
(b) Ethyne
(c) Ethane
(d) propylene
(v)
A gas decolorizes alkaline KMnO4 but has no action with ammonical AgNO3, this gas may be:
(a) C2 H2
(b) C2H4
(c) C2H6
(d) CH4
(vi)
Sodium Propionate on reaction with NaOH gives:
(a) Methane
(b) Ethylene
(c) Ethane
(d) Acetylene
(vii)
When calcium carbide is treated with water we get:
(a) Ethyne
(b) Ethane
(c) Ethene
(d) Ethanol
(viii)
Which one of the followings is the general formula of alkene?
(a) CnH2n
(b) CnH2n+2
(c) CnH2n-2
(d) CnH2n+1
(ix)
which one of the following solvents is unlikely to dissolve an organic compound?
(a) water
(b) benzene
(c) chloroform
(d) ether
(x)
Cyano group is present in.
(a) Alkane nitriles (b) Nitro compounds (c) Thiol compounds (d) none of them
(xi)
Ethyne on oxidation with strong alkaline KMnO4 gives.
(a) Glycol
(b) Glycerols (c) Glyoxal (d) None of them
(xii)
Ozonoloysis of Ethene causes the breaking of C-C bond, the products is?
(a) Formaldehyde (b) acetaldehyde (c) ethylene glycol (d) Ethylene chlorohydrin
Q No. 2
(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
(ix)
(x)
(xi)
(xii)

Attempt any 10 short questions of the following.

2X10=20

Prepare alkanes from two different carbonyl compounds.

Give the mechanism of the electrophilic addition reaction of alkenes:
How oxalic acid is prepared from acetylene:
How cis and trans alkenes are prepared from alkynes:
Convert ethylene into methanal:
Prepare acetone from alkyne:
Why ethyne behaves as acidic but ethene does not.
Write structural formulae of : (a) iso butylene (b) vinyl bromide
Define Markownikovs Rule. Give an example?
What is Baeyers test? Give its use.
Write the structural formulae of the isomers of C5H12.
Write IUPAC nomenclature of the following:
(a) CH2 = CH CH = CH2 (b) CH3 CH = CH CH2 CH3

Note: Attempt any one question.

Q. No. 3 (a) How would you convert ethylene into?
(i) Ethyl alcohol (ii) chlorohydrin
(iii) Ethylene glycol (iv) Mustard gas
(b) Explain chlorination of Methane in the presence of sun light along with
Mechanism.
Q. No. 4 (a) How would you prepare following compounds from C2 H2
(i) Acetaldehyde (ii) Methyl Nitrile
(iii) Chloroprene (iv) copper acetylide
(b) Explain with mechanism Kolbs electrolytic method for the Preparation of
ethane and ethene.

08
(4)
(4)
(4)
(4)