Professional Documents
Culture Documents
I, pp. 65-72,
1986.
0
BREAKAGE
OF VISCOUS
AND NON-NEWTONIAN
IN STIRRED
DISPERSIONS
ocQ9-2509/86
s3.00 + 0.00
1986. Pergamon Press Ltd.
DROPS
J. S. LAGISETTY,
P. K. DAS and R. KUMAR
Department of Chemical Engineering, Indian Institute of Science, Bangalore 560012, India
and
K. S. GANDHI
Department of Chemical Engineering, Indian Institute of Technology.
INTRODUCTION
The analysis
of rate processes
in liquid-liquid
(1)
(2)
= constant (We)-o.6
(3)
41:1-E
65
J. S. LAGISEITY et al.
66
DEVELOPMENT
EXPERIMENTAL
Table
D.14.5
cm
OF THE MODEL
1. Experimental conditions
Impeller speed
Reynolds number of the
continuous phase
Dispersed phase volume
fraction
Temperature
3.33-iOrev/s
1.5 x l@-5
0.02
26C
x 104
67
Continuous phase
Description
c1
(Poise)
Description
Water
0.01
1.0
Kerosene
0.021
0.78
CT
13/(cn=2-)
(Mn3)
Polystyrene
in styrene
lO-30% by
wt
lOOm1 of
CMC in water
(2.5 %I +
60ml of 2%
PVA
CaCO, aqueous
suspension
(59.5 % Caco3 +
2.00 y0 polyvinyl
alcohol)
(dynes/cm)
(g/&3)
0X8-0.92
0.4337.50
20
14.5
2/3
50
45.2
1.47
0.137
Constitutive
equation for TV
For the fluids considered in this work, the constitutive equation for viscous stress can be written in a
generalized form as
7v =
Fig. 2. Voigt model for the deformation of a drop.
Constitutive
equation for T,
When the drop suffers a small but finite strain, the
interfacial tension force generates a restoring stress
proportional to the strain. However, as the drop
undergoes further deformation and approaches the
breaking point, its structure will be more like that of a
dumb bell: two yet to be born daughter droplets
connected by a thin filament of liquid. The filament will
break because of its inherent instability. Thus near the
break point,- surface tension has no restoring effect.
Hence a more realistic description of the role of surface
tension must be to assign to it a retractive force that
increases for small deformations of the drop but
decreases afterwards and eventually reaches zero at the
break point. Assuming that the total deformation
undergone by the drop up to the point of breakage is of
the order of magnitude of d, the following simple
functional relationship between 5, and 0, has been
assumed.
TS= $ es (1 -e,>
= 0
e, c 1
e, 3 I.
(5)
TV +
(de,/dtY.
(6)
r-=,--ae(l-e8)+K
d
e c
1.
(7)
68
J. S. Llsorszrrv et al.
Expressions
7 ~PcU2W
(17)
(18)
where
(9)
=&*
a = C We (d/D)s3
given
by
Coulaloglou
and
E = 0.407 IV= D2
(10)
(11)
and
Therefore + can be expressed as:
+ -_ C pc N2 D4/= d2j3
(12)
by
(13)
$213 _
(T,,
d/u) -
l/4.
(19)
tto
o<tgT.
- fi]_
Thus, Bean never reach a value of unity, and
breakage is not possible in the finite time interval ofT_
But tI can reach unity in a finite time period when a
> 0, and therefore to predict the maximum drop
diameter, only values of a greater than zero need to be
considered.
Our main concern is to know the maximum size of a
drop that can exist in the stirred vessel. All drops above
such a size will break. As stated earliei, the drop has
been assumed to deform under the influence of T for a
period of?? The maximum stable drop size therefore is
the maximum threshold drop size which reaches a
deformation of unity when exposed to a constant stress
F during the time interval F. Such a drop size can be
calculated as follows.
Equation (18) is integrated to find rl at 8 = 1. If rl at
8 = 1, the dimensionless time required to reach deformation corresponding to breakage, is more than the
nondimensional life time of the eddy, breakage would
not occur. Thus for breakage to occur, the following
condition must be satisfied:
q (0 = 1) < (u/dIQ1Z
The
Tg +1
-e)e+K
de
-&
(14)
(>
(dlJ/dt# = C We (d/D)/
- (q,d/o)
- (0 - 02)
(15)
t.
(16)
(20)
Maximum
q=O_
(8)
and
C PcN2
at
q (0 = 1) = (a/d_,
K)T.
(21)
(d/D)23-n
where
Re
D (NoI2 - nP,
2-(3+l/nrK
(23)
Forr,=Oandn=
1,1/3,1/2and2/3,eq.(18)canbe
integrated analytically; the solutions are listed in
Table 3. It should be noted that C = 8.0 has been used
in these results for both Newtonian and nonNewtonian fluids. This will be discussed further in the
Results and Discussion.
It should be noted that the model developed in the
69
[32 We (d_/D)s3
= (RejWe) (d-/D)-
- I]* tanm
Ii3
>I=
(Re/We)3/2 (d-/D)-
u2
We (d_/D)
x tan-
13
1.6
(32 We (d_/D)513
c32 We(d_;D)
51.2
- 1) + [32 We (d_/D)53
1,~,2
cRe/~~
2.66(44We(d_/D)53
-1)
[(32We(d_/D)
-l)* Wez(d_/D)o]
x tan-
[32 We (d_;D)=
- l]*
- l]3/2
%axP-43
+ (32 We(d,,,f/$
=
56
- 1)5f*
- j3
AND
DISCUSSION
Newtonian fluids
= 0.125 (We)-*6.
Sprow (1967) has given the following empirical relationship when the dispersed phase viscosity is small:
(d-/D)
= a1 (We)-.6.
J. S. LAGISETN
70
et al.
d
2
= 0.083 (1 + a2#).
D
0.
0.
0.
0
I
Loo
300
Impcllsr
speed
N (r.p.m
pd c 3
CP
o-
z 20
dyneslcm
= 4.5
cm
0.5
B
i L-0
Non-Newtonian&ids
Figure 7 presents the experimental results of maximum stable drop diameter with change in impeller
speed for a power law fluid (2.5 0A CMC in water
+ PVA, n = 2/3). The grade of CMC used was the
same as that employed by Kumar and Saradhy (1972).
These authors used a test attributed to Philipoff to
ensure the absence of viscoelasticity in CMC solutions
up to a concentration of 4% by weight. The other
component of the solution used in the present work
was PVA, with a molecular weight of about 70,000. At
this molecular weight and low concentrations, PVA
will also not impart an elastic character to the solutions. Therefore the solution employed in this work
can be safely considered to be inelastic. The drop
diameter decreases with impeller speed in a nonlinear
fashion. As mentioned earlier, according to the model,
IJA
I
1.5
(26)
(We)-o.6.
I/ /
d/
/)/
A;./
_--,_A=
___--b-
Theoretical
Experimental
l3.P.M
xl0
400
0
0
a-
-.=
20
dyneslcm
600
j
D=
6.,5
cm
value of m
changes
Tavlarides, 1977)
m+=+
with
et al.)
4 as (Coulaloglou
= (1 +a2+)-2.0[uz(d)]+o.
with
and
(24)
= 0.125
(1 + r~~+)~ (We)-.6.
c-w
0
*
.
0
a2
0.15
0.Y)
0 05
0.025
z 4.0
Fig. 6. Comparison of Coulaloglou and Tavlarides experimental values (effect of 4) with those predicted by the present
model.
71
Impeller
speed
ti (r.p.m
Fig. 7. Comparison of experimental results with those predicted by the present model for a power law fluid.
Bin&am plastics
For Bingham plastic fluids the theoretical equations
can be easily developed by replacing 7 in the differential
equations for purely viscous fluids with (7 - 70)_ It is
easily shown that this corresponds to replacing
[32 We (d_jD)s3
- l]
by
[32 We (d_jD)5/3
- 4
(7,, d-/a)
- l]
Fig. 8. Effect of the Reynolds number on d,,, /D with the Weber number as a parameter.
72
J. S. LAGISETN
0.8
et al.
1
z
Re
0.5
t
T
u= (d)
We
1
0.31
300
400
lmprllrr
speed
N(r.,mm)
Greek letters
energy dissipation rate/mass, cm2/s3
&
dimensionless time
dispersed phase hold up
2
density of the continuous phase, g/cm
PC
viscosity of the dispersed phase, poise
c(d
a
constant
dimensionless strain; subscripts s and v refer
8
to spring and viscous parts
dynamic pressure difference across the dis
ameter of the drop, dynes/cm2
average value of t, dynes/cm
7
yield stress, dynes/cm
70
resistive stresses due to spring and viscous
=.,*,
dashpot, respectively, dynes/cm2
t7
interfacial tension, dynes/cm
CONCLUSIONS
REFERENCES
Arai, K.,Konno,
Konno, M., Arai, K. and Saito, S., 1982, The effect of stabilizer
NOTATION
01,
d
42
LX
D
K
02
constants
constant dependent only on the geometry of
vessel and agitator
drop diameter, cm
Sauter mean diameter, c nid:/C n,df,cm
maximum drop diameter, cm
impeller diameter, cm
power law constant, g/(cm s*-)
on coalescence of dispersed drops in suspension polymerization of styrene. J. &em. Engng Jap. 15, 131-135.
Kumar, R. and Saradhy, Y. P., 1972, Drop formation in nonNewtonian fluids. I.E.C. (Fund.) 11, 307-311.
Rallison, J. M., 1984, The deformation of small viscous drops
and bubbles in shear flow. Ann. Reu. Fiuid Mech. 16,4%X
Shinnar, R., 1961, On the behaviour of liquid-dispersions in
mixing vessels. J. Fluid Mech. 10, 259-275.
Sprow, F. B., 1967, Distribution of drop sizes produced in
turbulent liquid-liquid dispersion. Chem. Engng Sci. 22,
435-442.