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I.
Abstract
The heat capacities of pure ionic liquids (ILs) are among the
thermophysical properties that are required for certain engineering
calculations and designs. In this paper, a simple correlation is
presented to determine the appropriate model equation of 1,3Diethyl-1H-imidazol-3-ium bromide (C7H13BrN2). This correlation
is a temperature-dependent relation that use temperatures and heat
capacities. It was observed that the heat capacity of the compound
increases slowly as the temperature increases. The values of R2 are
0.383, 0.417, 0.532, 0.613, 0.686, 0.748, 0.601, 0.282, and 0.905,
respectively. The lowest value of R2 is obtained from the plot of
logarithmic while the highest is from the power function.
II.
Introduction
III.
RESULTS
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
5.52
5.87
6.21
6.59
6.97
7.35
7.73
8.12
8.51
8.89
9.28
9.68
10.07
10.57
11.17
11.78
12.39
13
13.62
14.24
14.85
15.58
16.42
17.26
18.09
0.401
0.492
0.596
0.729
0.883
1.057
1.253
1.472
1.709
1.969
2.25
2.56
2.896
3.349
3.934
4.563
5.251
5.972
6.746
7.548
8.382
9.404
10.63
11.9
13.21
23.77
25.2
26.63
28.07
29.52
31.17
33.03
34.89
36.76
38.63
40.49
42.5
44.67
46.85
49.03
51.21
53.39
55.57
57.75
59.93
62.13
64.33
66.53
68.72
70.92
22.77
25.25
27.75
30.25
32.71
35.56
38.66
41.68
44.57
47.38
50.15
53
55.99
58.9
61.73
64.4
66.92
69.38
71.78
74.14
76.42
78.63
80.71
82.68
84.56
78.68
80.13
80.36
80.94
82.27
82.46
82.87
84.2
84.8
84.8
86.13
86.73
88.8
88.67
90.04
90.6
92.01
92.54
93.99
94.48
95.98
96.43
97.97
98.38
99.98
91.25
92.58
92.62
93.01
94.04
94.26
94.47
95.47
95.84
95.9
96.85
97.28
98.24
98.67
99.66
100
101.1
101.4
102.5
102.8
103.8
104.1
105.1
105.4
106.5
18.93
19.77
20.91
22.33
14.56
15.94
17.83
20.27
73.18
75.5
77.81
78.3
86.57
88.58
90.59
90.96
100.34
101.99
102.29
104.01
106.7
107.7
107.9
109
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
104.25
106.04
106.21
108.08
109.1
110.2
110.3
111.5
133.84
134.99
135.84
137.08
126
126.6
127
127.7
163.88
164.5
165.89
166.61
141.3
141.6
142.3
142.6
108.17
110.12
110.14
112.1
112.17
114.07
114.22
116.04
116.28
118.01
118.34
119.98
120.41
121.96
122.48
123.94
124.56
125.91
126.63
127.9
128.72
129.88
130.8
131.86
111.6
112.7
112.7
113.9
113.9
115
115.1
116.2
116.3
117.3
117.5
118.4
118.7
119.4
119.8
120.6
121
121.7
122.1
122.8
123.2
123.8
124.4
124.9
137.83
139.18
139.83
141.28
141.83
143.39
143.83
145.49
145.83
147.6
147.83
149.71
149.83
151.82
151.83
153.84
153.93
155.85
156.04
157.86
158.16
159.86
160.27
161.87
128
128.7
129.1
129.8
130.1
130.9
131.1
132
132.1
133
133.2
134.1
134.2
135.2
135.2
136.2
136.3
137.2
137.3
138.3
138.4
139.3
139.5
140.2
167.9
168.73
169.91
170.84
171.92
172.95
173.94
175.06
175.95
177.17
177.96
179.28
179.98
181.39
182
183.49
184.02
185.6
186.04
187.7
188.06
189.8
190.08
191.09
143.3
143.7
144.4
144.8
145.4
146.1
146.6
147.4
147.9
148.7
149.1
149.8
150.2
150.9
151.2
152
152.2
153
153.2
154.1
154.3
155.2
155.3
156.2
132.89
125.5
162.38
140.6
192.1
156.3
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
194
194.12
196.1
196.15
198.17
198.2
200.1
200.29
202.22
202.39
204.25
204.48
206.28
206.57
208.31
208.66
210.35
210.75
212.38
212.84
214.41
214.92
216.44
217
218.48
219.08
220.51
221.15
222.55
157.3
157.4
158.4
158.4
159.4
159.4
160.5
160.5
161.6
161.7
162.6
162.8
163.8
163.9
164.9
165.1
166
166.3
167.3
167.5
168.5
168.8
169.7
170.1
170.9
171.3
172.1
172.5
173.3
223.22
224.59
225.29
226.63
227.36
228.67
229.42
230.71
231.48
233.47
233.54
235.59
235.81
237.64
237.86
239.69
239.9
241.74
241.94
243.78
243.99
245.82
246.03
247.86
248.07
249.89
250.11
251.92
252.16
173.7
174.5
175
175.8
176.2
177
177.5
178.2
178.7
180
180
181.3
181.5
182.5
182.7
183.9
184.1
185.1
185.3
186.4
186.6
187.8
187.9
189.1
189.3
190.6
190.7
192
192.2
253.95
254.2
255.97
256.25
257.98
258.29
260
260.33
262
262.37
264.01
264.42
266.06
266.47
268.16
268.52
270.26
270.57
272.36
272.62
274.45
274.67
276.54
276.71
278.62
278.75
280.68
280.79
282.74
193.4
193.6
194.9
195.1
196.4
196.7
198
198.3
199.6
199.9
201.2
201.7
203.2
203.4
205.1
205.3
207.1
207.1
209.2
209.4
211.5
211.5
213.9
213.9
216.6
216.6
219.5
219.5
222.7
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
T,K
Cp, J/mol-K
282.84
284.78
284.88
286.82
288.82
290.81
222.7
226.4
226.6
230.9
236.3
242.8
292.77
294.69
296.57
298.39
300.12
301.74
251.5
262.7
278.5
300.9
334.9
387.4
303.2
304.47
305.51
306.32
306.93
470.7
613.7
844.2
1193
1697
800
600
400
200
0
0
50
350
B. Quadratic
800
600
400
200
0
0
100
150
200
Temperature, K
250
300
350
C. Cubic
800
600
400
200
0
0
50
100
150
200
Temperature, K
250
300
350
800
600
400
200
0
0
50
100
150
200
250
300
350
Temperature, K
800
f(x) = 0x^5 - 0x^4 + 0x^3 - 0.24x^2 + 11.05x - 99.26
600
R = 0.69
400
200
0
0
50
100
150
200
Temperature, K
250
300
350
50
100
150
200
Temperature, K
G. Exponential
250
300
350
800
600
400
200
0
0
50
100
150
200
250
300
Temperature, K
H. Logarithmic
I. Power function
300
350
350
800
600
400
200
0
0
100
150
200
250
300
350
Temperature, K
IV.
DISCUSSION
capacity
of
the
compound
V.
directly
debye
low
temperature
the
theory
temperatures.
of
Moreover,
CONCLUSION
proportional
especially
with
the
at
low
condition,
0.282,
and
0.905,
of1,2-Dimethyl-3-