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Coal is largely composed of organic matter, but it is the inorganic matter in coal—
minerals and trace elements— that have been cited as possible causes of health,
environmental, and technological problems associated with the use of coal. Some trace
elements in coal are naturally radioactive. These radioactive elements include uranium
(U), thorium (Th), and their numerous decay products, including radium (Ra) and radon
(Rn). Although these elements are less chemically toxic than other coal constituents such
as arsenic, selenium, or mercury, questions have been raised concerning possible risk
from radiation.
Uranium association with coal has a long history. There is a continuing interest in
uranium in coal, because it is a source of radioactivity and because it may be an
economic source of uranium. It is just 200 years since the discovery of uranium by M.H.
Klaproth. The first detection in coal was by Berthoud (1875) who found up to 2%
uranium in coal from near Denver, USA. The samples were collected from a mineralized
section of the coal-bed. This mine was soon abandoned.
Subsequent field studies have proven several areas with high uranium coals, especially in
the United States, mainly in the Dakotas, Wyoming, Montana, Colorado and New
Mexico (Vine,1956). It seems that uranium is carried into the coal swamp in solution as
carbonate complexes (Breger, et. al. 1955), which then release uranyl ions to form
uranyl-organic complexes. In many coals, especially low-U coals, Uranium is
predominantly organically bound.
After World War II, a very intensive uranium search was initiated. The measurement of
coal radioactivity were performed in many countries; however only a few are
documented. For example, in year 1967 scientists have measured uranium concentration
in lignites from Spain (Huesca, Lerida, Ternel, Galicia, Murcia) and reported
concentration values 20 to 1200 parts per million (ppm).
Gott (1952) has determined uranium distribution in lignites, shales, and limestones from
throughout the US, and a possible mechanism for uranium accumulation in lignites was
suggested. Highest uranium concentrations were prevalent in lignites from the Dakotas,
Wyoming, and Montana (0.01%), and from high ash Nevada lignite which contained up
to 0.05 % uranium. It was postulated that uranium was possibly concentrated in lignite by
the action of percolating surface waters after having been leached from volcanic ash.
Uranium bearing coal in the Red Desert area in Wyoming has been studied by Masursky;
his findings are documented in several reports. In the first report in year 1952, core and
channel samples taken from the Red Desert area in Wyoming were used to investigate
the origin of uranium in the coal of the region. Specific uraniferous zones examined
included the Sourdough, Monument, Battle, and Luman zones. Areas which were
topographically higher and in which coal was overlain by conglomerate showed the
highest uranium concentration. Studies of core samples revealed that uranium
concentration in the coal beds correlates well with the degree of permeability of adjacent
rocks. Where coal beds are overlain or underlain by sandstone, the greatest
concentrations of uranium occur at the top and / or bottom of the bed.
J.R. Gill and others in the year 1959 have studied uranium bearing lignite in South
Dakota and Montana. They have reported some lignite deposits containing as much as
0.1% uranium.
Coal samples were analyzed for uranium concentration in the coals from the Western
United States and approximately 300 coals from the Illinois Basin. In the majority of
samples, concentrations of uranium fall in the range from slightly below 1 to 4 parts per
million (ppm). Coals with more than 20 ppm uranium are rare in the United States
(http://energy.er.usgs.gov/products/databases/ CoalQual/intro.htm).
Traces of uranium have been also found in the Permian coals of Jharkhand State of India.
Areas are KDH, Dakra, Rohini, and Rai Bachra in the North Karanpura coalfield.
Channeled samples were analyzed with the help of XRF instrument.
Uranium is associated with clays, zircon and phosphates and may also be organically
bound in coal. The accumulation of uranium in coal may vary markedly from place to
place, and the occurrence of uranium in each deposit should be interpreted in relation to
the geologic history of the region. Field evidence favors the epigenetic hypothesis of the
origin of uranium in U.S. western coals. Secondary concentration of uranium in coal may
occur when solution of small quantities of uranium by groundwater from overlying
volcanic rocks is followed by downward percolation of these waters through previous
strata until the uranium is taken up and retained by the highest of the underlying lignite
beds. Application of this theory led to the discovery of uranium-bearing coal in
Wyoming, Montana, Idaho and New Mexico.
Most coal also contains potassium-40, lead-210, and radium-226. The total levels are
generally about the same as in other rocks of the Earth's crust. Most emerge from a power
station in the light flyash, which is fused and chemically stable, or the bottom ash. Some
99% of flyash is typically retained in a modern power station (90% is some older ones),
and this is buried in an ash dam.
Reference:
Berthoud, E.L. 1875. on the occurrence of uranium, silver, iron etc., in the Tertiary
Formation of Colorado Territory. Proc. Nat. Acad. Sci., Philadelphia, 27, 363-365.
Denson, N.M., 1959. Uranium in coal in the Western United States, U.S. Geological
Survey Bull. 1055.
Gill, J.R. 1959. Reconnaissance for uranium in the Ekalaka Lignite field, Carter County,
Montana. US Geological Survey, Bull. 1055.
Gott, G.B. 1952. Uranium in black shales, lignites and limestones in the United States.
Selected papers on uranium deposits in the United States. U.S. Geological Survey,
Circ.220,Washington. 31-35.
Vine, J.D. 1956. Uranium-bearing coal in the United States. US Geol. Surv. Prof. Pap.,
No 300, 405-41.